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Journal articles on the topic 'Super-Electron-Donor'

Author: Grafiati

Published: 4 June 2025

Last updated: 15 July 2025

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1

Nozawa-Kumada, Kanako, Shungo Ito, Koto Noguchi, Masanori Shigeno, and Yoshinori Kondo. "Super electron donor-mediated reductive desulfurization reactions." Chemical Communications 55, no. 86 (2019): 12968–71. http://dx.doi.org/10.1039/c9cc06775b.

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2

Panetti, Grace B., Patrick J. Carroll, Michael R. Gau, Brian C. Manor, Eric J. Schelter, and Patrick J. Walsh. "Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions." Chemical Science 12, no. 12 (2021): 4405–10. http://dx.doi.org/10.1039/d0sc04822d.

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The super electron donor (SED) capabilities of 2-azaallyl anions has recently been discovered and applied to diverse reactivity; their structures and electron transfer characteristics are reported herein.

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3

Nozawa-Kumada, Kanako, Erina Abe, Shungo Ito, Masanori Shigeno, and Yoshinori Kondo. "Super electron donor-mediated reductive transformation of nitrobenzenes: a novel strategy to synthesize azobenzenes and phenazines." Organic & Biomolecular Chemistry 16, no. 17 (2018): 3095–98. http://dx.doi.org/10.1039/c8ob00271a.

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4

Garnier, Jean, Douglas W. Thomson, Shengze Zhou, Phillip I. Jolly, Leonard E. A. Berlouis, and John A. Murphy. "Hybrid super electron donors – preparation and reactivity." Beilstein Journal of Organic Chemistry 8 (July 3, 2012): 994–1002. http://dx.doi.org/10.3762/bjoc.8.112.

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Neutral organic electron donors, featuring pyridinylidene–imidazolylidene, pyridinylidene–benzimidazolylidene and imidazolylidene–benzimidazolylidene linkages are reported. The pyridinylidene–benzimidazolylidene and imidazolylidene–benzimidazolylidene hybrid systems were designed to be the first super electron donors to convert iodoarenes to aryl radicals at room temperature, and indeed both show evidence for significant aryl radical formation at room temperature. The stronger pyridinylidene–imidazolylidene donor converts iodoarenes to aryl anions efficiently under appropriate conditions (3 eq

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5

Zi, Quanxing, Minyan Li, Jielun Cong, et al. "Super-Electron-Donor 2-Azaallyl Anions Enable Construction of Isoquinolines." Organic Letters 24, no. 9 (2022): 1786–90. http://dx.doi.org/10.1021/acs.orglett.2c00140.

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6

Vaid, Thomas P., and Melanie S. Sanford. "An organic super-electron-donor as a high energy density negative electrolyte for nonaqueous flow batteries." Chemical Communications 55, no. 74 (2019): 11037–40. http://dx.doi.org/10.1039/c9cc06080d.

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An organic “super-electron-donor” is well-suited as a negative electrolyte for nonaqueous redox flow batteries, with a highly negative 2<sup>+</sup>/0 reduction potential, a low mass per electron stored, and good solubility in CH<sub>3</sub>CN in both redox states.

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7

Humphries, Matthew E., Emily S. Wusterbarth, and Dennis L. Lichtenberger. "Weak acids with super-electron-donor dimetal complexes: Synergy in bifunctional activity." Polyhedron 158 (January 2019): 471–77. http://dx.doi.org/10.1016/j.poly.2018.11.001.

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8

Cumine, Florimond, Fabrizio Palumbo, and John A. Murphy. "Reduction of nitroarenes, azoarenes and hydrazine derivatives by an organic super electron donor." Tetrahedron 74, no. 38 (2018): 5539–45. http://dx.doi.org/10.1016/j.tet.2018.04.069.

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9

Jolly, Phillip I., Nadia Fleary-Roberts, Steven O'Sullivan, Eswararao Doni, Shengze Zhou, and John A. Murphy. "Reactions of triflate esters and triflamides with an organic neutral super-electron-donor." Organic & Biomolecular Chemistry 10, no. 30 (2012): 5807. http://dx.doi.org/10.1039/c2ob25116g.

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10

Schoenebeck, Franziska, John A. Murphy, Sheng-ze Zhou, Yoshitaka Uenoyama, Yves Miclo, and Tell Tuttle. "Reductive Cleavage of Sulfones and Sulfonamides by a Neutral Organic Super-Electron-Donor (S.E.D.) Reagent." Journal of the American Chemical Society 129, no. 44 (2007): 13368–69. http://dx.doi.org/10.1021/ja074417h.

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11

Murphy, John A, Sheng-ze Zhou, Douglas W Thomson, et al. "The Generation of Aryl Anions by Double Electron Transfer to Aryl Iodides from a Neutral Ground-State Organic Super-Electron Donor." Angewandte Chemie 119, no. 27 (2007): 5270–75. http://dx.doi.org/10.1002/ange.200700554.

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12

Murphy, John A, Sheng-ze Zhou, Douglas W Thomson, et al. "The Generation of Aryl Anions by Double Electron Transfer to Aryl Iodides from a Neutral Ground-State Organic Super-Electron Donor." Angewandte Chemie International Edition 46, no. 27 (2007): 5178–83. http://dx.doi.org/10.1002/anie.200700554.

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13

Murphy, John, Sylvain Cutulic, Hardeep Farwaha, Sheng-Ze Zhou, and Ewan Chrystal. "Metal-Free Reductive Cleavage of N-O Bonds in Weinreb Amides by an Organic Neutral Super-Electron Donor." Synlett 2008, no. 14 (2008): 2132–36. http://dx.doi.org/10.1055/s-2008-1078240.

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14

Cutulic, Sylvain P. Y., Neil J. Findlay, Sheng-Ze Zhou, Ewan J. T. Chrystal та John A. Murphy. "Metal-Free Reductive Cleavage of C−O σ-bonds in Acyloin Derivatives by an Organic Neutral Super-Electron-Donor†". Journal of Organic Chemistry 74, № 22 (2009): 8713–18. http://dx.doi.org/10.1021/jo901815t.

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15

Dilsizoglu Senol, Aysegul, Maura Samarani, Sylvie Syan та ін. "α-Synuclein fibrils subvert lysosome structure and function for the propagation of protein misfolding between cells through tunneling nanotubes". PLOS Biology 19, № 7 (2021): e3001287. http://dx.doi.org/10.1371/journal.pbio.3001287.

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The accumulation of α-synuclein (α-syn) aggregates in specific brain regions is a hallmark of synucleinopathies including Parkinson disease (PD). α-Syn aggregates propagate in a “prion-like” manner and can be transferred inside lysosomes to recipient cells through tunneling nanotubes (TNTs). However, how lysosomes participate in the spreading of α-syn aggregates is unclear. Here, by using super-resolution (SR) and electron microscopy (EM), we find that α-syn fibrils affect the morphology of lysosomes and impair their function in neuronal cells. In addition, we demonstrate that α-syn fibrils in

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16

Chen, Shiyue, Yujun Yang, Mingjun Zhang, et al. "Bioinspired Pd-Cu Alloy Nanoparticles as Accept Agent for Dye Degradation Performances." International Journal of Molecular Sciences 23, no. 22 (2022): 14072. http://dx.doi.org/10.3390/ijms232214072.

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Dye degradation is a key reaction in organic decomposition production through electron donor transferring. Palladium (Pd) is the best-known element for synthesis Pd-based catalyst, the surface status determines the scope of relative applications. Here we first prepare Pd-Cu alloy nanoparticles (NPs) by co-reduction of Cu(acac)2 (acac = acetylacetonate) and Pd(C5HF6O2)2 in the presence of sodium borohydride (NaBH4) and glutathione (GSH). The obtained Pd-Cu is about ~10 nm with super-hydrophilicity in aqueous mediums. The structural analysis clearly demonstrated the uniform distribution of Pd an

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17

Yong, Xue, Gang Wu, Wen Shi, et al. "Theoretical search for high-performance thermoelectric donor–acceptor copolymers: the role of super-exchange couplings." Journal of Materials Chemistry A 8, no. 41 (2020): 21852–61. http://dx.doi.org/10.1039/d0ta05765g.

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First-principles calculations of a series of representing D–A copolymers demonstrated the strong Super-Exchange couplings induce not only small hole effective mass but also weak electron-phonon couplings, and eventually high thermoelectric power factor.

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18

Deng, Yi-Hui, Qini Li, Manhong Li, Leifeng Wang, and Tian-Yu Sun. "Rational design of super reductive EDA photocatalyst for challenging reactions: a theoretical and experimental study." RSC Advances 14, no. 3 (2024): 1902–8. http://dx.doi.org/10.1039/d3ra07558c.

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We have developed a novel electron-donor-acceptor (EDA) photocatalyst through DFT-guided design. This photocatalyst is formed in situ from isoquinoline, a diboron reagent, and a weak base, and can be effectively utilized for challenging reactions.

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19

HALSTIAN, ANDRII, JURII VASHKURAK, and OLGA KOSENKO. "STUDY OF THE OZONE REACTION OF BENZYL ACETATE AND ITS DERIVATIVES IN THE LIQUID PHASE." Technologies and Engineering, no. 3 (October 6, 2022): 17–25. http://dx.doi.org/10.30857/2786-5371.2022.3.2.

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Purpose. Investigation of the kinetic regularities of the oxidation reaction of benzyl acetate and its derivatives by ozone in the liquid phase to determine the effect of alcohol on the ozonation of methylbenzenes by the methyl group. Methodоlogy. A 20 ml glass vessel equipped with a magnetic stirrer was loaded sequentially with a calculated amount of toluene or benzyl acetate of sulfuric acid and 10 ml of acetic anhydride. After dissolution, the reaction components were loaded into a thermostatic glass column. The column was connected to a reflux condenser, the resulting solution was co

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20

Xu, Yashi, Wenbo Ming, Libo Xiang, and Qing Ye. "A Bottleable Super-Electron-Donor for Catalytic Borylation of Aryl Halides." Chemical Communications, 2023. http://dx.doi.org/10.1039/d3cc01435e.

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[(Dpp-bian)B(DMAP)]2 (dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene, DMAP = 4-(dimethylamino)pyridine), a bottleable super electron donor (SED), was demonstrated to serve as a SED catalyst in the borylation of aryl iodides, bromides, and the...

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21

Lai, Runchen, Yangyi Liu, Xiao Luo, et al. "Shallow distance-dependent triplet energy migration mediated by endothermic charge-transfer." Nature Communications 12, no. 1 (2021). http://dx.doi.org/10.1038/s41467-021-21561-1.

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AbstractConventional wisdom posits that spin-triplet energy transfer (TET) is only operative over short distances because Dexter-type electronic coupling for TET rapidly decreases with increasing donor acceptor separation. While coherent mechanisms such as super-exchange can enhance the magnitude of electronic coupling, they are equally attenuated with distance. Here, we report endothermic charge-transfer-mediated TET as an alternative mechanism featuring shallow distance-dependence and experimentally demonstrated it using a linked nanocrystal-polyacene donor acceptor pair. Donor-acceptor elec

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22

Eymann, Léonard Y. M., Paul Varava, Andrei M. Shved, et al. "Synthesis of Organic Super-Electron-Donors by Reaction of Nitrous Oxide with N-Heterocyclic Olefins." October 17, 2019. https://doi.org/10.1021/jacs.9b10660.

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The reaction of nitrous oxide (N2O) with N-heterocyclic olefins (NHOs) results in cleavage of the N–O bond and formation of azo-bridged NHO dimers. The latter represent very electron-rich compounds with a low ionization energy. Cyclic voltammetry studies show that the dimers can be classified as new organic super-electron-donors, with a reducing power similar to what is found for tetraazafulvalene derivatives. Mild oxidants are able to convert the neutral dimers into radical cations, which can be isolated. Further oxidation gives stable dications.

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23

Dunlap, Megan K., Duncan P. Ryan, Peter Marvin Goodwin, et al. "Nanoscale imaging of quantum dot dimers using time-resolved super-resolution microscopy combined with scanning electron microscopy." Nanotechnology, April 3, 2023. http://dx.doi.org/10.1088/1361-6528/acc9c9.

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Abstract Time-resolved super-resolution microscopy was used in conjunction with scanning electron microscopy to image individual colloidal CdSe/CdS semiconductor quantum dots (QD) and QD dimers. The photoluminescence (PL) lifetimes, intensities, and structural parameters were acquired with nanometer scale spatial resolution and sub-nanosecond time resolution. The combination of these two techniques was more powerful than either alone, enabling us to resolve the PL properties of individual QDs within QD dimers as they blinked on and off, measure interparticle distances, and identify QDs that ma

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24

Wang, Miao, Hui‐Ying Ren, Shan Jiang, et al. "Rongalite‐Induced Cascade CC/CO Bond Formation from Indoles, Difluoromethyl Bromides, and H₂O via a Triple Cleavage Process." Advanced Synthesis & Catalysis, June 23, 2025. https://doi.org/10.1002/adsc.9604.

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Herein, an efficient rongalite‐induced cascade CC/CO bond formation reaction involving indoles, difluoromethyl bromides, and H2O for the synthesis of indole‐3‐glyoxylates and indole‐3‐yl‐glyoxylamides has been developed. Mechanistic studies suggest that rongalite may act as a precursor of a super electron donor to activate difluoromethyl bromides for CC bond formation, as well as a source of protons to facilitate the cleavage of the CF bond for CO bond formation. The cascade reaction exhibits remarkable efficiency, broad substrate compatibility, and scalability. Moreover, the products can

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25

Schoenebeck, Franziska, John A. Murphy, Sheng-ze Zhou, Yoshitaka Uenoyama, Yves Miclo, and Tell Tuttle. "ChemInform Abstract: Reductive Cleavage of Sulfones and Sulfonamides by a Neutral Organic Super-Electron-Donor (S.E.D.) Reagent." ChemInform 39, no. 8 (2008). http://dx.doi.org/10.1002/chin.200808044.

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26

Sato, K., H. Katayama-Yoshida, and T. Yamamoto. "Materials Design for the Low-Resistivity in p-Type ZnO and Transparent Ferromagnet With Transition Metal Atom Doped ZnO: Prediction vs. Experiment." MRS Proceedings 623 (2000). http://dx.doi.org/10.1557/proc-623-65.

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AbstractWe propose a new valence control method of codoping with doping Ga (or In, Al) donor and N acceptor at the same time for the fabrication of a low-resistivity p-type ZnO based upon the ab initio calculation. We compare our predicted materials design to fabricate a low resistivity p-type ZnO with the recent successful codoping. Based upon the success in the valence control of ZnO, we propose a materials design to fabricate the ferromagnetic Mn-doped p-type ZnO upon codoping. It is shown that the anti-ferromagnetic state is more stable than the ferromagnetic ones due to the anti-ferromagn

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27

Hoffmann, A., H. Born, A. Näser, et al. "Native Defect Characterization in ZnGeP2." MRS Proceedings 607 (1999). http://dx.doi.org/10.1557/proc-607-373.

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AbstractElectron paramagnetic resonance (EPR) as well as time-resolved and time-integrated photoluminescence (PL) are used to characterize the defect centers in ZnGeP2 bulk crystals. The samples, as-grown, electron-irradiated and annealed, reveal a strong intensity dependence of the VZn-correlated EPR-transitions. Photo-EPR experiments show that this intensity behavior is mainly caused by a recharging of the VZn centers owing to the preparation induced shift of the Fermi-level. The luminescence spectra show a broad infrared emission with peak position at 1.23 eV that exhibits features of class

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28

Sil, Swagata, Athul Santha Bhaskaran, Soumi Chakraborty, Bhagat Singh, Rositha Kuniyil, and Swadhin K. Mandal. "Reduced-Phenalenyl-Based Molecule as a Super Electron Donor for Radical-Mediated C–N Coupling Catalysis at Room Temperature." Journal of the American Chemical Society, November 30, 2022. http://dx.doi.org/10.1021/jacs.2c09225.

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29

Cutulic, Sylvain P. Y., John A. Murphy, Hardeep Farwaha, Sheng-Ze Zhou, and Ewan Chrystal. "ChemInform Abstract: Metal-Free Reductive Cleavage of N-O Bonds in Weinreb Amides by an Organic Neutral Super-Electron Donor." ChemInform 39, no. 52 (2008). http://dx.doi.org/10.1002/chin.200852032.

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30

Liu, Feng, Yuanyuan Jiang, Renjie Xu, et al. "Nonfullerene Acceptor Featuring Unique Self‐Regulation Effect for Organic Solar Cells with 19% Efficiency." Angewandte Chemie International Edition, December 5, 2023. http://dx.doi.org/10.1002/anie.202313791.

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The blend nanomorphology of electron‐donor (D) and ‐acceptor (A) materials is of vital importance to achieving highly efficient organic solar cells (OSCs). Exogenous additives especially aromatic additives are always needed to further optimize the nanomorphology of blend films, which is hardly compatible with industrial manufacture. Herein, we proposed a unique approach to meticulously modulate the aggregation behavior of NFAs in both crystal and thin film nanomorphology via self‐regulation effect. Nonfullerene acceptor Z9 was designed and synthesized by tethering phenyl groups on the inner si

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31

Liu, Feng, Yuanyuan Jiang, Renjie Xu, et al. "Nonfullerene Acceptor Featuring Unique Self‐Regulation Effect for Organic Solar Cells with 19% Efficiency." Angewandte Chemie, December 5, 2023. http://dx.doi.org/10.1002/ange.202313791.

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The blend nanomorphology of electron‐donor (D) and ‐acceptor (A) materials is of vital importance to achieving highly efficient organic solar cells (OSCs). Exogenous additives especially aromatic additives are always needed to further optimize the nanomorphology of blend films, which is hardly compatible with industrial manufacture. Herein, we proposed a unique approach to meticulously modulate the aggregation behavior of NFAs in both crystal and thin film nanomorphology via self‐regulation effect. Nonfullerene acceptor Z9 was designed and synthesized by tethering phenyl groups on the inner si

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32

Cutulic, Sylvain P. Y., Neil J. Findlay, Sheng-Ze Zhou, Ewan J. T. Chrystal та John A. Murphy. "ChemInform Abstract: Metal-Free Reductive Cleavage of C-O σ-Bonds in Acyloin Derivatives by an Organic Neutral Super-Electron-Donor." ChemInform 41, № 13 (2010). http://dx.doi.org/10.1002/chin.201013089.

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33

Jaiswal, Akash Deep, Jyoti Chourasia, Manas Mahato, et al. "Metal Ion‐Endows Orange‐Red Light Fluorogenicity of an Imine‐Linkage Probe Embracing Simple Electron Donor‐Acceptor Units." ChemistrySelect 9, no. 40 (2024). http://dx.doi.org/10.1002/slct.202403046.

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AbstractSelectively tracking and quantifying Al3+ ions is a significant concern to the scientific communities. In the present article, an imine‐linkage electron donor‐acceptor system, DSAN, (E)‐5‐(diethylamino)‐2‐(((2‐hydroxy‐4‐nitrophenyl)imino)methyl)phenol has been introduced which shows Al3+ ions endows red light fluorogenicity which could be utilized for sequential and detection of Al3+ ions and picric acid (PA) in both solid and liquid phases. Upon addition of Al3+ ions into the DSAN solution, an orange‐red fluorescence is noticed at 604 nm caused by the formation of Al3+ ions chelated D

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34

Ruidas, Pradip, Soumen Kumar Dubey, Sk Abdul Hafiz, et al. "Chiral Self‐Assembly of a Pyrene‐Appended Glutamylalanine Dipeptide and Its Charge Transfer Complex: Fabrication of Magneto‐Responsive Hydrogels and Human Cell Imaging." Macromolecular Rapid Communications, November 15, 2024. http://dx.doi.org/10.1002/marc.202400672.

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AbstractThe formation of a robust, self‐healing hydrogel of a novel pyrene‐appended dipeptide, Py‐E‐A (L‐Glutamic acid short as E; L‐Alanine short as A) is demonstrated. Detailed studies suggest that nanoscopic fibers with a length of several micrometers have formed by chiral self‐organization of Py‐E‐A gelators. Additionally, live human PBMCs imaging is shown using the Py‐E‐A fluorophore. Interestingly, electron‐rich Py‐E‐A couples with electron‐deficient NDI‐β‐A (β‐Alanine short as β‐A) by charge transfer (CT) complexation and forms stable deep violet‐colored CT super‐hydrogel. X‐ray diffrac

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35

Peng, Xiaogai, Wenjin Cao, Zhubin Hu, et al. "Observation of a super-tetrahedral cluster of acetonitrile-solvated dodecaborate dianion via dihydrogen bonding." Journal of Chemical Physics 160, no. 5 (2024). http://dx.doi.org/10.1063/5.0186614.

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We launched a combined negative ion photoelectron spectroscopy and multiscale theoretical investigation on the geometric and electronic structures of a series of acetonitrile-solvated dodecaborate clusters, i.e., B12H122−·nCH3CN (n = 1–4). The electron binding energies of B12H122−·nCH3CN are observed to increase with cluster size, suggesting their enhanced electronic stability. B3LYP-D3(BJ)/ma-def2-TZVP geometry optimizations indicate each acetonitrile molecule binds to B12H122− via a threefold dihydrogen bond (DHB) B3–H3 ⁝⁝⁝ H3C–CN unit, in which three adjacent nucleophilic H atoms in B12H122

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36

Yan, Chuanfang, Jinlong Zhou, Ao Xu, Hongping Long, Hang Luo, and Sheng Chen. "Sharply Improved Electrical Insulation of Polyimide Dielectrics at Elevated Temperatures by Charge Reassignment Engineering." Small, April 22, 2025. https://doi.org/10.1002/smll.202501050.

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AbstractThe electrical insulation of traditional polyimides (PI) dielectrics for capacitive energy storage will be significantly destroyed at elevated temperatures due to enhanced conductive loss caused by strong conjugated effect and charge transfer (CT) interactions. To address this issue, novel PI dielectrics are designed and synthesized based on charge reassignment engineering. Beneficial from non‐planar dianhydride and poor conjugated diamine, the main chain of synthesized PI (semi‐aromatic NA2‐alt‐OB1) significantly reduces the conjugated effect. Alicyclic dianhydride structural unit end

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