Academic literature on the topic 'Superconcentrated electrolyte'

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Journal articles on the topic "Superconcentrated electrolyte"

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Klorman, Jake A., and Kah Chun Lau. "The Relevance of Lithium Salt Solvate Crystals in Superconcentrated Electrolytes in Lithium Batteries." Energies 16, no. 9 (2023): 3700. http://dx.doi.org/10.3390/en16093700.

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Based on the unique ubiquity of similar solvate structures found in solvate crystals and superconcentrated electrolytes, we performed a systematic study of four reported solvate crystals which consist of different lithium salts (i.e., LiMPSA, LiTFSI, LiDFOB, and LiBOB) solvated by acetonitrile (MeCN) based on first principles calculations. Based on the calculations, these solvate crystals are predicted to be electronic insulators and are expected to be similar to their insulating liquid counterpart (e.g., 4 M superconcentrated LiTFSI-MeCN electrolyte), which has been confirmed to be a promisin
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Tian, Zengying, Wenjun Deng, Xusheng Wang, et al. "Superconcentrated aqueous electrolyte to enhance energy density for advanced supercapacitors." Functional Materials Letters 10, no. 06 (2017): 1750081. http://dx.doi.org/10.1142/s1793604717500813.

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We here report a superconcentrated potassium acetate (KAC) solution (75[Formula: see text]wt.%, K : H2O [Formula: see text] 1 : 1.8, called as “water-in-salt”) as an aqueous electrolyte to improve the working voltage and increasing capacitance in enhancing the energy density of the active carbon-based aqueous supercapacitor. The stability potential window of the superconcentrated electrolyte realizes an AC//AC symmetric supercapacitor with operating voltage of 2.0 V and excellent cyclic performance. Meanwhile, the energy density of such supercapacitor achieves about twice as high as that of th
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Dubouis, Nicolas, Pierre Lemaire, Boris Mirvaux, Elodie Salager, Michael Deschamps, and Alexis Grimaud. "The role of the hydrogen evolution reaction in the solid–electrolyte interphase formation mechanism for “Water-in-Salt” electrolytes." Energy & Environmental Science 11, no. 12 (2018): 3491–99. http://dx.doi.org/10.1039/c8ee02456a.

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Yang, Chongyin, Liumin Suo, Oleg Borodin, et al. "Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility." Proceedings of the National Academy of Sciences 114, no. 24 (2017): 6197–202. http://dx.doi.org/10.1073/pnas.1703937114.

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Leveraging the most recent success in expanding the electrochemical stability window of aqueous electrolytes, in this work we create a unique Li-ion/sulfur chemistry of both high energy density and safety. We show that in the superconcentrated aqueous electrolyte, lithiation of sulfur experiences phase change from a high-order polysulfide to low-order polysulfides through solid–liquid two-phase reaction pathway, where the liquid polysulfide phase in the sulfide electrode is thermodynamically phase-separated from the superconcentrated aqueous electrolyte. The sulfur with solid–liquid two-phase
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Pal, Urbi, Fangfang Chen, Derick Gyabang, et al. "Enhanced ion transport in an ether aided super concentrated ionic liquid electrolyte for long-life practical lithium metal battery applications." Journal of Materials Chemistry A 8, no. 36 (2020): 18826–39. http://dx.doi.org/10.1039/d0ta06344d.

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We explore a superconcentrated electrolyte comprising N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide, 1,2 dimethoxyethane and 3.2 mol kg<sup>−1</sup> LiFSI. It offers an alternative ion-transport mechanism, improved fluidity and ultra-stable Li metal battery performance.
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Rakov, Dmitrii. "(Best Student Presentation) Is Solid-Electrolyte Interphase Formation Affected by Electrode Conductivity?" ECS Meeting Abstracts MA2023-01, no. 5 (2023): 873. http://dx.doi.org/10.1149/ma2023-015873mtgabs.

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Accurate analysis of the mechanism of interphase formation and its composition is imperative for the development of stable and efficient lithium/sodium-ion batteries. One of the most practically scalable ways to optimize interphase chemistry and morphology for reversible charge transport is electrolyte engineering and the application of formation protocol with specific current/voltage conditions. In this sense, the analysis of structure and dynamics within the electrode/electrolyte interface, i.e., the so-called electric-double layer, is essential to predicting the possible chemistry and mecha
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Wang, Weijian, Wenjun Deng, Xusheng Wang, et al. "A hybrid superconcentrated electrolyte enables 2.5 V carbon-based supercapacitors." Chemical Communications 56, no. 57 (2020): 7965–68. http://dx.doi.org/10.1039/d0cc02040k.

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Yamada, Yuki, Makoto Yaegashi, Takeshi Abe, and Atsuo Yamada. "A superconcentrated ether electrolyte for fast-charging Li-ion batteries." Chemical Communications 49, no. 95 (2013): 11194. http://dx.doi.org/10.1039/c3cc46665e.

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Lundgren, Henrik, Johan Scheers, Mårten Behm, and Göran Lindbergh. "Characterization of the Mass-Transport Phenomena in a Superconcentrated LiTFSI:Acetonitrile Electrolyte." Journal of The Electrochemical Society 162, no. 7 (2015): A1334—A1340. http://dx.doi.org/10.1149/2.0961507jes.

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Sun, Ju, Luke A. O’Dell, Michel Armand, Patrick C. Howlett, and Maria Forsyth. "Anion-Derived Solid-Electrolyte Interphase Enables Long Life Na-Ion Batteries Using Superconcentrated Ionic Liquid Electrolytes." ACS Energy Letters 6, no. 7 (2021): 2481–90. http://dx.doi.org/10.1021/acsenergylett.1c00816.

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Dissertations / Theses on the topic "Superconcentrated electrolyte"

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Droguet, Léa. "Vers des électrolytes aqueux superconcentrés pour une application dans les batteries Li-ion." Electronic Thesis or Diss., Sorbonne université, 2021. http://www.theses.fr/2021SORUS330.

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Depuis 2015, le développement des électrolytes aqueux superconcentrés, dénommés « Water-in-salt electrolytes » (WiSE), a suscité un regain d’intérêt pour les batteries Li-ion (LIB) aqueuses. Les WiSE proposent une alternative aux électrolytes organiques commerciaux qui posent des problèmes de sécurité et de durabilité, tout en résolvant les faibles performances des électrolytes aqueux dilués limitées par l’étroitesse de la fenêtre électrochimique (1 .23 V). En effet, la superconcentration influe sur les propriétés physico-chimiques et la réactivité interfaciale. La formation d’une interphase s
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