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1

Kimura, Tomoaki, and Motohiko Murakami. "Fluid-like elastic response of superionic NH3 in Uranus and Neptune." Proceedings of the National Academy of Sciences 118, no. 14 (2021): e2021810118. http://dx.doi.org/10.1073/pnas.2021810118.

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Nondipolar magnetic fields exhibited at Uranus and Neptune may be derived from a unique geometry of their icy mantle with a thin convective layer on top of a stratified nonconvective layer. The presence of superionic H2O and NH3 has been thought as an explanation to stabilize such nonconvective regions. However, a lack of experimental data on the physical properties of those superionic phases has prevented the clarification of this matter. Here, our Brillouin measurements for NH3 show a two-stage reduction in longitudinal wave velocity (Vp) by ∼9% and ∼20% relative to the molecular solid in th
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2

Machado, K. D., J. C. de Lima, T. A. Grandi, et al. "Structural study of Cu2−x Se alloys produced by mechanical alloying." Acta Crystallographica Section B Structural Science 60, no. 3 (2004): 282–86. http://dx.doi.org/10.1107/s0108768104007475.

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The crystalline structures of the superionic high-temperature copper selenides Cu2−x Se (0 < x < 0.25) produced using mechanical alloying were investigated using X-ray diffraction (XRD). The measured XRD patterns showed the presence of peaks corresponding to the crystalline superionic high-temperature α-Cu2Se phase in the as-milled sample, and its structural data were determined by means of a Rietveld refinement procedure. After heat treatment in argon at 473 K for 90 h, this phase transforms to the superionic high-temperature α-Cu1.8Se phase, whose structural data were also determined b
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3

Raze, Rizwan, Xiao Di Wang, Ying Ma, Yi Zhong Huang, and Bin Zhu. "Enhancement of Conductivity in Ceria-Carbonate Nanocomposites for LTSOFCs." Journal of Nano Research 6 (June 2009): 197–203. http://dx.doi.org/10.4028/www.scientific.net/jnanor.6.197.

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This work first explores high resolution transmission electron microscopy (TEM) to determine the interfacial regions and provide experimental evidences for interfaces between the SDC and carbonate constituent phases of the SD-carbonate two-phase composites to further investigate the superionic conduction mechanism in the ceria-carbonate composite systems and enhancement of conductivity. Schober first reported interfacial superionic conduction in ceria-based composites but without direct experimental proofs. Such superionic conduction mechanism remains unknown. Especially, in the nano-scale, th
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4

Schwarz, Maximilian, Alf Mews, and August Dorn. "Superionic phase transition in individual silver selenide nanowires." Nanoscale 13, no. 17 (2021): 8017–23. http://dx.doi.org/10.1039/d1nr00491c.

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The superionic phase transition temperature in Ag<sub>2</sub>Se nanowires is diameter dependent and suppressed to below 100 °C. An increase in charge carrier density accompanied by a decrease in mobility was observed across the superionic phase transition.
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5

Schneider, Julius, and Wolfgang Schmahl. "Superionic phase transitions in anti-fluorite structures." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C72. http://dx.doi.org/10.1107/s2053273314099276.

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Fast ion conductors attract continuous and increasing interest in view of possible applications in battery technology. Early examples of superionic phase transitions in anti-fluorite type structures, where the small cations reside in a tetrahedral cage of large anions include Ag2Te [1]. At elevated temperatures anharmonic atom thermal displacements induce cation diffusion towards the large void formed by the central anion octahedron. Of the anti-fluorite structure type compounds Li2 X, where X=(O, S, Se, Te), the compounds Li2O and Li2S showed diffuse transitions to a superionic phase. Very re
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6

Fedoseev, A. I., S. G. Lushnikov, J. H. Ko, Seiji Kojima, and L. A. Shuvalov. "Specific Features of Brillouin Spectra at a High-Temperature Phase Transition in Cs5H3(SO4)4xnH2O Crystals." Solid State Phenomena 115 (August 2006): 279–84. http://dx.doi.org/10.4028/www.scientific.net/ssp.115.279.

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This paper presents detailed Brillouin light scattering studies of the acoustic response of a Cs5H3(SO4)4xnH2O (PCHS) crystal in the vicinity of a superionic (superprotonic) structural phase transition of the first order. Just above the phase transition, splitting of the Brillouin doublet is observed. The ‘two-mode’ behavior of the longitudinal acoustic phonon can be explained by coexistence of phases at a structural phase transition of the first order. Above the phase transition, in the superionic phase, an additional doublet forbidden by the selection rules appears in a narrow temperature in
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7

Ильинский, А. В., та Е. Б. Шадрин. "Фазовый переход полупроводник--суперионик в кристаллах AgI". Физика твердого тела 65, № 9 (2023): 1507. http://dx.doi.org/10.21883/ftt.2023.09.56245.54.

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The electronic configuration of chemical bonds between ions forming the structure of the AgI superionics existing in three different crystal modifications is discussed: α-, β- and γ-phases.On the basis of the formulated schemes of hybridization of ion orbitals, the structural phase transitions γ-&gt;β and β-&gt;α occurring with increasing temperature are considered.It is shown that in the high-temperature superionic α-phase of the AgI crystal in an external electric field, along with an increase in electronic conductivity, hopping conductivity occurs due to a weakening of the coordination bond
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8

Aliev, A. É., V. F. Krivorotov, and P. K. Khabibullaev. "Specific heat and thermal conductivity of superionic conductors in the superionic phase." Physics of the Solid State 39, no. 9 (1997): 1378–82. http://dx.doi.org/10.1134/1.1130083.

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9

den Hartog, H. W., and J. van der Veen. "Superionic phase transition of doped fluorites." Physical Review B 37, no. 4 (1988): 1807–13. http://dx.doi.org/10.1103/physrevb.37.1807.

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10

Qian, Yin, Jin Zhang, Yi-Ming Wang, Wan-Wan Yao, Dong-Sheng Shao, and Xiao-Ming Ren. "Magnetic bistable organic ionic plastic crystal with room temperature ion conductivity comparable to NASICON and superionic conduction in a broad temperature window." Materials Chemistry Frontiers 6, no. 6 (2022): 793–801. http://dx.doi.org/10.1039/d1qm01573g.

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A radical salt experiences crystal–crystal and crystal–plastic crystal phase transitions with magnetic bistability and negative thermal expansion, high room-temperature ion-conduction in crystal phase and superionic conduction in plastic crystal phase.
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11

Guin, Satya N., Dirtha Sanyal, and Kanishka Biswas. "The effect of order–disorder phase transitions and band gap evolution on the thermoelectric properties of AgCuS nanocrystals." Chemical Science 7, no. 1 (2016): 534–43. http://dx.doi.org/10.1039/c5sc02966j.

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The present study demonstrates an ambient solution phase capping free synthesis of superionic AgCuS nanocrystals. Nanoscale size reduction, order–disorder phase transition and band gap evolution tailor the thermoelectric properties in AgCuS.
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12

Hilczer, Bozena, Czeslaw Pawlaczyk, and Fathy E. Salman. "Superionic phase transition in CsHSeO4and CsDSeO4single crystal." Ferroelectrics 81, no. 1 (1988): 193–96. http://dx.doi.org/10.1080/00150198808008842.

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13

Berastegui, P., S. Hull, and S. G. Eriksson. "A high temperature superionic phase of CsSn2F5." Journal of Solid State Chemistry 183, no. 2 (2010): 373–78. http://dx.doi.org/10.1016/j.jssc.2009.11.020.

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14

Sakuma, Takashi, Fumihito Suzuki, Shoji Saitoh, Kazumasa Sugiyama, Eiichiro Matsubara, and Yoshio Waseda. "Diffuse Scattering of Superionic Phase of Cu2Se." Journal of the Physical Society of Japan 62, no. 10 (1993): 3513–18. http://dx.doi.org/10.1143/jpsj.62.3513.

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15

Basar, K., T. Shimoyama, D. Hosaka, XiangLian, T. Sakuma, and M. Arai. "Diffuse scattering of superionic phase of CuAgSe." Journal of Thermal Analysis and Calorimetry 81, no. 3 (2005): 507–10. http://dx.doi.org/10.1007/s10973-005-0813-4.

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16

KUMAR PATEL, RAJESH, SATYENDRA SINGH, and KANCHAN GAUR. "Phase Transition Study in Some Superionic Systems." Material Science Research India 4, no. 2 (2007): 435–40. http://dx.doi.org/10.13005/msri/040224.

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17

Plakida, N. M. "Superionic phase transitions in hydrogen bonded crystals." physica status solidi (b) 135, no. 1 (1986): 133–39. http://dx.doi.org/10.1002/pssb.2221350113.

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18

Bikkulova, N. N., Yu M. Stepanov, L. V. Bikkulova, A. R. Kurbangulov, A. Kh Kutov, and R. F. Karagulov. "Diffuse phase transition from the superionic to non-superionic state in Cu1.8Se single crystal." Crystallography Reports 58, no. 4 (2013): 622–27. http://dx.doi.org/10.1134/s1063774513040068.

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19

Hernández-Daguer, O. S., H. Correa, and R. A. Vargas. "Phase behaviour and superionic phase transition in K3H(SeO4)2." Ionics 21, no. 8 (2015): 2201–9. http://dx.doi.org/10.1007/s11581-015-1404-4.

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20

Udovic, Terrence J., Motoaki Matsuo, Atsushi Unemoto, et al. "Sodium superionic conduction in Na2B12H12." Chem. Commun. 50, no. 28 (2014): 3750–52. http://dx.doi.org/10.1039/c3cc49805k.

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Na<sub>2</sub>B<sub>12</sub>H<sub>12</sub>exhibits dramatic Na<sup>+</sup>conductivity (on the order of 0.1 S cm<sup>−1</sup>) above its order-disorder phase transition at ≈529 K, rivaling that of current, solid-state, ceramic-based, Na-battery electrolytes.
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21

Thompson, Travis, Jeff Wolfenstine, Jan L. Allen, et al. "Tetragonal vs. cubic phase stability in Al – free Ta doped Li7La3Zr2O12 (LLZO)." J. Mater. Chem. A 2, no. 33 (2014): 13431–36. http://dx.doi.org/10.1039/c4ta02099e.

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X-ray and neutron diffraction, Raman spectroscopy, complex impedance spectroscopy and electron microscopy were used to characterize the tetragonal vs. cubic phase stability in superionic conducting garnet-oxide electrolyte.
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22

Yarimitsu, Masakazu, and Masaru Aniya. "A Molecular Dynamics Study on Pressure Dependence of Ag Diffusion in Ag3SI." Advances in Science and Technology 72 (October 2010): 337–42. http://dx.doi.org/10.4028/www.scientific.net/ast.72.337.

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The pressure dependence of the diffusion coefficient in the superionic α- and β-phases of Ag3SI has been studied by using the method of molecular dynamics. It is shown that in the high temperature α-phase, the Ag diffusion coefficient decreases with pressure. On the hand, in the intermediate temperature β-phase, the Ag diffusion coefficient exhibits a maximum at around 2.8 GPa. The structural origin of this behavior is discussed through the pressure dependence of the pair distribution functions.
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23

A. Danilkin, Sergey, Mohana Yethiraj, and Gordon J. Kearley. "Phonon Dispersion in Superionic Copper Selenide: Observation of Soft Phonon Modes in Superionic Phase Transition." Journal of the Physical Society of Japan 79, Suppl.A (2010): 25–28. http://dx.doi.org/10.1143/jpsjs.79sa.25.

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24

Grasselli, Federico. "Investigating finite-size effects in molecular dynamics simulations of ion diffusion, heat transport, and thermal motion in superionic materials." Journal of Chemical Physics 156, no. 13 (2022): 134705. http://dx.doi.org/10.1063/5.0087382.

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The effects of the finite size of the simulation box in equilibrium molecular dynamics simulations are investigated for prototypical superionic conductors of different types, namely, the fluorite-structure materials PbF2, CaF2, and UO2 (type II), and the α phase of AgI (type I). Largely validated empirical force-fields are employed to run ns-long simulations and extract general trends for several properties, at increasing size and in a wide temperature range. This work shows that, for the considered type-II superionic conductors, the diffusivity dramatically depends on the system size and that
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25

Il’inskii, A. V., R. A. Castro, M. E. Pashkevich, I. O. Popova, and E. B. Shadrin. "Semiconductor–Superionic Phase Transition in Silver Sulfide Films." Physics of the Solid State 62, no. 12 (2020): 2403–11. http://dx.doi.org/10.1134/s1063783420120136.

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26

Balyakin, I. A., and S. I. Sadovnikov. "Deep learning potential for superionic phase of Ag2S." Computational Materials Science 202 (February 2022): 110963. http://dx.doi.org/10.1016/j.commatsci.2021.110963.

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27

Ukshe, A. J. "Constant Phase Angle Relaxation at Metal-Superionic Interface." Materials Science Forum 76 (January 1991): 233–36. http://dx.doi.org/10.4028/www.scientific.net/msf.76.233.

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28

Honda, Hiroyuki, Khairul Basar, Sainer Siagian, et al. "Low-Temperature Phase in Superionic Conductor Ag3SBrxI1-x." Journal of the Physical Society of Japan 76, no. 11 (2007): 114603. http://dx.doi.org/10.1143/jpsj.76.114603.

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29

Rafiuddin and Mohammed Hassan. "A superionic conducting phase in Cd-substituted CsAg2I3." Solid State Communications 144, no. 7-8 (2007): 293–95. http://dx.doi.org/10.1016/j.ssc.2007.09.005.

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30

Bolesta, I., V. Kovalisko, I. Savitski, and O. Futey. "Study of superionic phase transition in AG2CDI4thin films." Ferroelectrics 159, no. 1 (1994): 13–18. http://dx.doi.org/10.1080/00150199408007541.

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31

Połomska, M., B. Hilczer, J. Wolak, and A. Pietraszko. "Superionic Phase Transition in Rb4LiH3(SeO4)4Single Crystals." Acta Physica Polonica A 85, no. 5 (1994): 825–33. http://dx.doi.org/10.12693/aphyspola.85.825.

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32

Sakuma, T., T. Aoyama, H. Takahashi, Y. Shimojo, and Y. Morii. "Diffuse neutron scattering from superionic phase of Ag2Te." Solid State Ionics 86-88 (July 1996): 227–30. http://dx.doi.org/10.1016/0167-2738(96)00130-0.

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33

Vlieg, E., H. W. Den Hartog, and M. Winnink. "The superionic phase transition of fluorite-type crystals." Journal of Physics and Chemistry of Solids 47, no. 5 (1986): 521–28. http://dx.doi.org/10.1016/0022-3697(86)90052-1.

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34

Kubenova, Marzhan M., Kairat A. Kuterbekov, Malik K. Balapanov, Rais K. Ishembetov, Asset M. Kabyshev, and Kenzhebatyr Z. Bekmyrza. "Some Thermoelectric Phenomena in Copper Chalcogenides Replaced by Lithium and Sodium Alkaline Metals." Nanomaterials 11, no. 9 (2021): 2238. http://dx.doi.org/10.3390/nano11092238.

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This review presents thermoelectric phenomena in copper chalcogenides substituted with sodium and lithium alkali metals. The results for other modern thermoelectric materials are presented for comparison. The results of the study of the crystal structure and phase transitions in the ternary systems Na-Cu-S and Li-Cu-S are presented. The main synthesis methods of nanocrystalline copper chalcogenides and its alloys are presented, as well as electrical, thermodynamic, thermal, and thermoelectric properties and practical application. The features of mixed electron–ionic conductors are discussed. I
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35

Huang, He, Hong-Hui Wu, Cheng Chi, et al. "Phase-structure-dependent Na ion transport in yttrium-iodide sodium superionic conductor Na3YI6." Journal of Materials Chemistry A 9, no. 46 (2021): 26256–65. http://dx.doi.org/10.1039/d1ta08086e.

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The phase-structure dependent ion transport networks comprised of Oct–Tet and Oct–Oct pathways in Na3YI6 broaden the diffusion channels and provide rational guidance for the design of halide-based Na superionic conductors.
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36

Ding, Jingxuan, Jennifer L. Niedziela, Dipanshu Bansal, et al. "Anharmonic lattice dynamics and superionic transition in AgCrSe2." Proceedings of the National Academy of Sciences 117, no. 8 (2020): 3930–37. http://dx.doi.org/10.1073/pnas.1913916117.

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Intrinsically low lattice thermal conductivity (κlat) in superionic conductors is of great interest for energy conversion applications in thermoelectrics. Yet, the complex atomic dynamics leading to superionicity and ultralow thermal conductivity remain poorly understood. Here, we report a comprehensive study of the lattice dynamics and superionic diffusion in AgCrSe2 from energy- and momentum-resolved neutron and X-ray scattering techniques, combined with first-principles calculations. Our results settle unresolved questions about the lattice dynamics and thermal conduction mechanism in AgCrS
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37

Kato, Kenichi, Hidetaka Kasai, Akihiro Hori, et al. "Structural Basis for Emergence of Superionic Conductivity by an Ion Exchange." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C355. http://dx.doi.org/10.1107/s2053273314096442.

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Various superionic conductors have been examined in terms of the application to electrolytes for solid fuel cells [1]. Recently we demonstrated by impedance measurements that a simple two-step chemical reaction transformed an electronic conductor NaxCoO2into a superionic one. In the present study, we performed in situ synchrotron X-ray diffraction experiments to investigate a structural mechanism for the superionic conductivity driven by the chemical treatment of the layered oxide NaxCoO2. We developed a temperature- and humidity-controllable capillary cell under hydrogen and helium gas flow t
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38

Zhao, Xinye, Yu Chen, and Gerbrand Ceder. "Synthesis Mechanisms of over-Stoichiometric Rocksalt-Type Li Superionic Conductors." ECS Meeting Abstracts MA2024-02, no. 8 (2024): 1106. https://doi.org/10.1149/ma2024-0281106mtgabs.

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Oxides materials with a face-centered cubic (fcc) anion sublattice are generally unsuitable for use as solid-state electrolytes as such structural framework typically exhibits high migration energy barrier, preventing a facile Li transport [1,2]. A recent discovery involving a class of over-stoichiometric rocksalt (ORX) compounds has shown promise for achieving fast Li conduction in oxide materials by introducing Li-Li face-sharing configurations in a spinel-like arrangement (s-phase) [3]. In general, it is challenging to create rocksalts in which the cation to anion ratio is larger than 1. As
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39

Tsurui, Takao, and Junichi Kawamura. "Nano-phase Separation in CuI-Cu2MoO4 Superionic Conducting Glass." Materia Japan 48, no. 12 (2009): 601. http://dx.doi.org/10.2320/materia.48.601.

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40

Gargouri, M., T. Mhiri, and A. Daoud. "Vibrational study of the superionic - protonic phase transition of." Journal of Physics: Condensed Matter 9, no. 49 (1997): 10977–83. http://dx.doi.org/10.1088/0953-8984/9/49/015.

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41

Suzuki, Takahito, Kenji Yoshida, Kazuyoshi Uematsu, et al. "Stabilization of superionic conduction phase in Li3Sc2(PO4)3." Solid State Ionics 104, no. 1-2 (1997): 27–33. http://dx.doi.org/10.1016/s0167-2738(97)00404-9.

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42

Matsuo, Yasumitsu, Keisuke Takahashi, Junko Hatori, and Seiichiro Ikehata. "Proton dynamics in superionic phase of Tl3H(SO4)2." Journal of Solid State Chemistry 177, no. 11 (2004): 4282–85. http://dx.doi.org/10.1016/j.jssc.2004.08.028.

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43

Simonnin, Pauline, Michel Sassi, Benjamin Gilbert, Laurent Charlet, and Kevin M. Rosso. "Phase Transition and Liquid-like Superionic Conduction in Ag2S." Journal of Physical Chemistry C 124, no. 18 (2020): 10150–58. http://dx.doi.org/10.1021/acs.jpcc.0c00260.

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44

Pawłowski, Antoni, Maria Połomska, Bożena Hilczer, Ludwik Szcześniak, and Adam Pietraszko. "Superionic phase transition in Rb3D(SeO4)2 single crystals." Journal of Power Sources 173, no. 2 (2007): 781–87. http://dx.doi.org/10.1016/j.jpowsour.2007.05.068.

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45

Sharma, Vaishali, Diptikanta Swain, and Tayur N. Guru Row. "Superionic Behavior and Phase Transition in a Vanthoffite Mineral." Inorganic Chemistry 56, no. 11 (2017): 6048–51. http://dx.doi.org/10.1021/acs.inorgchem.7b00802.

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46

Collin, Anthony, Georges Dénès, Delphine Le Roux, M. Cecilia Madamba, Juanita M. Parris, and Alan Salaün. "Understanding the phase transitions and texture in superionic PbSnF4." International Journal of Inorganic Materials 1, no. 5-6 (1999): 289–301. http://dx.doi.org/10.1016/s1466-6049(99)00030-6.

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47

Pham-Thi, M., Ph Colomban, A. Novak, and R. Blinc. "Phase transitions in superionic protonic conductors CsHSO4 and CsHSeO4." Solid State Communications 55, no. 4 (1985): 265–70. http://dx.doi.org/10.1016/0038-1098(85)90605-2.

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48

Sakuma, T., T. Aoyama, H. Takahashi, Y. Shimojo, and Y. Morii. "Diffuse neutron scattering from the superionic phase of Cu2Se." Physica B: Condensed Matter 213-214 (August 1995): 399–401. http://dx.doi.org/10.1016/0921-4526(95)00169-a.

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49

MILAT, O., Z. VUCIC, and B. RUSCIC. "Superstructural ordering in low-temperature phase of superionic Cu2Se." Solid State Ionics 23, no. 1-2 (1987): 37–47. http://dx.doi.org/10.1016/0167-2738(87)90079-8.

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50

HORVATI, M., Z. VUI, J. GLADI, M. ILI, I. AVIANI, and Z. OGORELEC. "Electromotive force of the superionic phase of copper selenide." Solid State Ionics 27, no. 1-2 (1988): 31–36. http://dx.doi.org/10.1016/0167-2738(88)90486-9.

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