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1

Wang, Qian, Eiton Kaltgrad, Tianwei Lin, John E. Johnson, and M. G. Finn. "Natural Supramolecular Building Blocks." Chemistry & Biology 9, no. 7 (2002): 805–11. http://dx.doi.org/10.1016/s1074-5521(02)00165-5.

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2

Wang, Qian, Tianwei Lin, John E. Johnson, and M. G. Finn. "Natural Supramolecular Building Blocks." Chemistry & Biology 9, no. 7 (2002): 813–19. http://dx.doi.org/10.1016/s1074-5521(02)00166-7.

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3

van Nostrum, C. F., and R. J. M. Nolte. "Supramolecular architectures from phthalocyanine building blocks." Macromolecular Symposia 77, no. 1 (1994): 267–76. http://dx.doi.org/10.1002/masy.19940770128.

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4

Ariga, Katsuhiko, Qingmin Ji, Jonathan P. Hill, and Ajayan Vinu. "Supramolecular Materials from Inorganic Building Blocks." Journal of Inorganic and Organometallic Polymers and Materials 20, no. 1 (2010): 1–9. http://dx.doi.org/10.1007/s10904-009-9324-2.

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5

Davidson, Gregory J. E., Lok H. Tong, Paul R. Raithby, and Jeremy K. M. Sanders. "Aluminium(iii) porphyrins as supramolecular building blocks." Chemical Communications, no. 29 (2006): 3087. http://dx.doi.org/10.1039/b605435h.

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6

Jørgensen, Tine, Thomas Kruse Hansen, and Jan Becher. "Tetrathiafulvalenes as building-blocks in supramolecular chemistry." Chem. Soc. Rev. 23, no. 1 (1994): 41–51. http://dx.doi.org/10.1039/cs9942300041.

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7

Darling, Scott L., Eugen Stulz, Neil Feeder, Nick Bampos, and Jeremy K. M. Sanders. "Phosphine-substituted porphyrins as supramolecular building blocks." New Journal of Chemistry 24, no. 5 (2000): 261–64. http://dx.doi.org/10.1039/b000482k.

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8

Mukherjee, Anurag, and Suhrit Ghosh. "Core-Substituted Naphthalene-Diimides (cNDI) and Related Derivatives: Versatile Scaffold for Supramolecular Assembly and Functional Materials." Organic Materials 03, no. 03 (2021): 281–92. http://dx.doi.org/10.1055/a-1530-0476.

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Naphthalene-diimide (NDI)-derived building blocks have been explored extensively for supramolecular assembly as they exhibit attractive photophysical properties, suitable for applications in organic optoelectronics. Core-substituted derivatives of the NDI chromophore (cNDI) differ significantly from the parent NDI dye in terms of optical and redox properties. Adequate molecular engineering opportunities and substitution-dependent tunable optoelectronic properties make cNDI derivatives highly promising candidates for supramolecular assembly and functional materials. This short review discusses
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9

Nam, Seong, David C. Ware, and Penelope J. Brothers. "Campestarenes: new building blocks with 5-fold symmetry." Organic & Biomolecular Chemistry 16, no. 35 (2018): 6460–69. http://dx.doi.org/10.1039/c8ob00957k.

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10

Cheng, Fei, Wen-Ming Wan, Yan Zhou, Xiao-Li Sun, Edward M. Bonder, and Frieder Jäkle. "Borinic acid block copolymers: new building blocks for supramolecular assembly and sensory applications." Polymer Chemistry 6, no. 25 (2015): 4650–56. http://dx.doi.org/10.1039/c5py00607d.

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11

Tamminen, Jari, and Erkki Kolehmainen. "Bile Acids as Building Blocks of Supramolecular Hosts." Molecules 6, no. 12 (2001): 21–46. http://dx.doi.org/10.3390/60100021.

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12

Nieland, Esther, Oliver Weingart, and Bernd M. Schmidt. "Fluorinated azobenzenes as supramolecular halogen-bonding building blocks." Beilstein Journal of Organic Chemistry 15 (August 23, 2019): 2013–19. http://dx.doi.org/10.3762/bjoc.15.197.

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ortho-Fluoroazobenzenes are a remarkable example of bistable photoswitches, addressable by visible light. Symmetrical, highly fluorinated azobenzenes bearing an iodine substituent in para-position were shown to be suitable supramolecular building blocks both in solution and in the solid state in combination with neutral halogen bonding acceptors, such as lutidines. Therefore, we investigate the photochemistry of a series of azobenzene photoswitches. Upon introduction of iodoethynyl groups, the halogen bonding donor properties are significantly strengthened in solution. However, the bathochromi
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13

VAN NOSTRUM, C. F., and R. J. M. NOLTE. "ChemInform Abstract: Supramolecular Architectures from Phthalocyanine Building Blocks." ChemInform 25, no. 36 (2010): no. http://dx.doi.org/10.1002/chin.199436286.

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14

Kuhn, Hans. "π-Electron systems — building blocks of supramolecular machines". Colloids and Surfaces A: Physicochemical and Engineering Aspects 171, № 1-3 (2000): 3–12. http://dx.doi.org/10.1016/s0927-7757(99)00551-8.

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15

Park, Chiyoung, Jeonghun Lee, and Chulhee Kim. "Functional supramolecular assemblies derived from dendritic building blocks." Chemical Communications 47, no. 44 (2011): 12042. http://dx.doi.org/10.1039/c1cc11531f.

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16

She, Neng-Fang, Meng Gao, Xiang-Gao Meng, et al. "Supramolecular Rhombic Grids Formed from Bimolecular Building Blocks." Journal of the American Chemical Society 131, no. 33 (2009): 11695–97. http://dx.doi.org/10.1021/ja904920r.

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17

McLellan, Ross, Maria A. Palacios, Christine M. Beavers, et al. "Linked Supramolecular Building Blocks for Enhanced Cluster Formation." Chemistry - A European Journal 21, no. 7 (2015): 2804–12. http://dx.doi.org/10.1002/chem.201405746.

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18

Du, Xuewen, Jie Zhou, and Bing Xu. "Supramolecular Hydrogels Made of Basic Biological Building Blocks." Chemistry - An Asian Journal 9, no. 6 (2014): 1446–72. http://dx.doi.org/10.1002/asia.201301693.

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19

de la Moya Cerero, Santiago, Marc Böhme, Martin Nieger, and Fritz Vögtle. "Chiral Pyridinophanes as Hydrogen-Bonding Supramolecular Building Blocks." Liebigs Annalen 1997, no. 6 (1997): 1221–25. http://dx.doi.org/10.1002/jlac.199719970626.

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20

Schenning, Albertus P. H. J., Cristina Elissen-Román, Jan-Willem Weener, Maurice W. P. L. Baars, Sjerry J. van der Gaast, and E. W. Meijer. "Amphiphilic Dendrimers as Building Blocks in Supramolecular Assemblies." Journal of the American Chemical Society 120, no. 32 (1998): 8199–208. http://dx.doi.org/10.1021/ja9736774.

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21

Abrahams, Brendan F., Robert W. Elliott, Timothy A. Hudson, Richard Robson, and Ashley L. Sutton. "X4TCNQ2− dianions: versatile building blocks for supramolecular systems." CrystEngComm 20, no. 23 (2018): 3131–52. http://dx.doi.org/10.1039/c8ce00413g.

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22

Nielsen, Mogens Brøndsted, Christian Lomholt, and Jan Becher. "Tetrathiafulvalenes as building blocks in supramolecular chemistry II." Chemical Society Reviews 29, no. 3 (2000): 153–64. http://dx.doi.org/10.1039/a803992e.

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23

Atencio, Reinaldo, Lee Brammer, Shiyue Fang та F. Christopher Pigge. "π-Bonded organometallic building blocks for supramolecular chemistry". New Journal of Chemistry 23, № 5 (1999): 461–63. http://dx.doi.org/10.1039/a901925a.

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24

Maeda, Hiromitsu. "Acyclic oligopyrroles as building blocks of supramolecular assemblies." Journal of Inclusion Phenomena and Macrocyclic Chemistry 64, no. 3-4 (2009): 193–214. http://dx.doi.org/10.1007/s10847-009-9568-z.

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25

Becher, J., K. Nielsen, and J. O. Jeppesen. "Supramolecular systems derived from pyrrolo-tetrathiafulvalene building blocks." Journal de Physique IV (Proceedings) 114 (April 2004): 445–48. http://dx.doi.org/10.1051/jp4:2004114104.

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26

Miljkovic, Ana, Sonia La Cognata, Greta Bergamaschi, Mauro Freccero, Antonio Poggi, and Valeria Amendola. "Towards Building Blocks for Supramolecular Architectures Based on Azacryptates." Molecules 25, no. 7 (2020): 1733. http://dx.doi.org/10.3390/molecules25071733.

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In this work, we report the synthesis of a new bis(tris(2-aminoethyl)amine) azacryptand L with triphenyl spacers. The binding properties of its dicopper complex for aromatic dicarboxylate anions (as TBA salts) were investigated, with the aim to obtain potential building blocks for supramolecular structures like rotaxanes and pseudo-rotaxanes. As expected, UV-Vis and emission studies of [Cu2L]4+ in water/acetonitrile mixture (pH = 7) showed a high affinity for biphenyl-4,4′-dicarboxylate (dfc2−), with a binding constant of 5.46 log units, due to the best match of the anion bite with the Cu(II)-
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27

Gruschwitz, Franka V., Tobias Klein, Sylvain Catrouillet, and Johannes C. Brendel. "Supramolecular polymer bottlebrushes." Chemical Communications 56, no. 38 (2020): 5079–110. http://dx.doi.org/10.1039/d0cc01202e.

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The assembly of polymer building blocks into supramolecular bottlebrushes by non-covalent forces represents an exciting new field of research. This review provides an overview on suitable motifs and requirements for the formation of such structures.
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28

Zhong, Di-Chang, Ya-Qiong Wen, Ji-Hua Deng, Tao-Hua Jian, and Ke-Jun Wang. "Two cobalt(II) supramolecular isomers based onN,N′-bis(pyridin-3-yl)oxalamide induced by the molecular orientation of lattice DMF molecules." Acta Crystallographica Section C Structural Chemistry 72, no. 2 (2016): 170–73. http://dx.doi.org/10.1107/s205322961600156x.

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Supramolecular isomerism for coordination networks refers to the existence of different architectures having the same building blocks and identical stoichiometries. For a given building block, different arrangements can lead to the formation of a series of supramolecular isomers. Two one-dimensional CoIIcoordination polymers based onN,N′-bis(pyridin-3-yl)oxalamide (BPO), bothcatena-poly[[[dichloridocobalt(II)]-bis[μ-N,N′-bis(pyridin-3-yl)oxalamide-κ2N:N′]] dimethylformamide disolvate], {[CoCl2(C12H10N4O2)2]·2C3H7NO}n, have been assembled by the solvothermal method. Single-crystal X-ray diffrac
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29

Zhou, Chengcheng, Jianbin Huang та Yun Yan. "Chain length dependent alkane/β-cyclodextrin nonamphiphilic supramolecular building blocks". Soft Matter 12, № 5 (2016): 1579–85. http://dx.doi.org/10.1039/c5sm02698a.

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30

Li, Helin, Olga Mergel, Puja Jain, et al. "Electroactive and degradable supramolecular microgels." Soft Matter 15, no. 42 (2019): 8589–602. http://dx.doi.org/10.1039/c9sm01390c.

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31

Wise, Matthew D., and Kay Severin. "Functionalised Clathrochelate Complexes – New Building Blocks for Supramolecular Structures." CHIMIA International Journal for Chemistry 69, no. 4 (2015): 191–95. http://dx.doi.org/10.2533/chimia.2015.191.

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32

Lhoták, Pavel, and Seiji Shinkai. "Calix(n)alenes. Powerful Building-Blocks of Supramolecular Chemistry." Journal of Synthetic Organic Chemistry, Japan 53, no. 11 (1995): 963–74. http://dx.doi.org/10.5059/yukigoseikyokaishi.53.963.

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33

Schütrumpf, Alexandra, Erdoğan Kirpi, Aysun Bulut, et al. "Tetrahedral Tetraphosphonic Acids. New Building Blocks in Supramolecular Chemistry." Crystal Growth & Design 15, no. 10 (2015): 4925–31. http://dx.doi.org/10.1021/acs.cgd.5b00811.

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34

Albrecht, Markus. "Dicatechol ligands: novel building-blocks for metallo-supramolecular chemistry." Chemical Society Reviews 27, no. 4 (1998): 281. http://dx.doi.org/10.1039/a827281z.

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35

Datta, Sougata, Yasuki Kato, Seiya Higashiharaguchi, et al. "Self-assembled poly-catenanes from supramolecular toroidal building blocks." Nature 583, no. 7816 (2020): 400–405. http://dx.doi.org/10.1038/s41586-020-2445-z.

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36

Cotton, F. Albert, Chun Y. Liu, and Carlos A. Murillo. "Systematic Preparation of Mo24+Building Blocks for Supramolecular Assemblies." Inorganic Chemistry 43, no. 7 (2004): 2267–76. http://dx.doi.org/10.1021/ic035433s.

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37

Elacqua, Elizabeth, Anna Croom, Kylie B. Manning, et al. "Supramolecular Diblock Copolymers Featuring Well-defined Telechelic Building Blocks." Angewandte Chemie 128, no. 51 (2016): 16105–10. http://dx.doi.org/10.1002/ange.201609103.

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38

Würthner, Frank, Armin Sautter, and Christoph Thalacker. "Substituted Diazadibenzoperylenes: New Functional Building Blocks for Supramolecular Chemistry." Angewandte Chemie International Edition 39, no. 7 (2000): 1243–45. http://dx.doi.org/10.1002/(sici)1521-3773(20000403)39:7<1243::aid-anie1243>3.0.co;2-z.

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39

JOERGENSEN, T., T. K. HANSEN, and J. BECHER. "ChemInform Abstract: Tetrathiafulvalenes as Building Blocks in Supramolecular Chemistry." ChemInform 25, no. 28 (2010): no. http://dx.doi.org/10.1002/chin.199428321.

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40

McLellan, Ross, Maria A. Palacios, Christine M. Beavers, et al. "Frontispiece: Linked Supramolecular Building Blocks for Enhanced Cluster Formation." Chemistry - A European Journal 21, no. 7 (2015): n/a. http://dx.doi.org/10.1002/chem.201580762.

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41

Elacqua, Elizabeth, Anna Croom, Kylie B. Manning, et al. "Supramolecular Diblock Copolymers Featuring Well-defined Telechelic Building Blocks." Angewandte Chemie International Edition 55, no. 51 (2016): 15873–78. http://dx.doi.org/10.1002/anie.201609103.

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42

Tedesco, C., I. Immediata, R. Ferro, L. Gregoli, C. Gaeta, and P. Neri. "Calix[4]dihydroquinone as building blocks in supramolecular chemistry." Acta Crystallographica Section A Foundations of Crystallography 61, a1 (2005): c285. http://dx.doi.org/10.1107/s0108767305087866.

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43

Becher, Jan. "Tetrathiafulvalenes: Versatile Building Blocks in Macrocyclic and Supramolecular Chemistry." Phosphorus, Sulfur, and Silicon and the Related Elements 153, no. 1 (1999): 99–117. http://dx.doi.org/10.1080/10426509908546429.

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44

Hartlieb, Matthias, Edward D. H. Mansfield, and Sebastien Perrier. "A guide to supramolecular polymerizations." Polymer Chemistry 11, no. 6 (2020): 1083–110. http://dx.doi.org/10.1039/c9py01342c.

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45

Yang, Yu-Dong, Jonathan L. Sessler, and Han-Yuan Gong. "Flexible imidazolium macrocycles: building blocks for anion-induced self-assembly." Chemical Communications 53, no. 70 (2017): 9684–96. http://dx.doi.org/10.1039/c7cc04661h.

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46

Sosa-Vargas, Lydia, Eunkyoung Kim, and André-Jean Attias. "Beyond “decorative” 2D supramolecular self-assembly: strategies towards functional surfaces for nanotechnology." Materials Horizons 4, no. 4 (2017): 570–83. http://dx.doi.org/10.1039/c7mh00127d.

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47

Martin, Cibely S., Wesley B. S. Machini, and Marcos F. S. Teixeira. "Electropolymerization using binuclear nickel(ii) Schiff base complexes bearing N4O4donors as supramolecular building blocks." RSC Advances 5, no. 50 (2015): 39908–15. http://dx.doi.org/10.1039/c5ra03414k.

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48

Hofmeier, Harald, Philip R. Andres, Richard Hoogenboom, Eberhardt Herdtweck, and Ulrich S. Schubert. "Terpyridine - Ruthenium Complexes as Building Blocks for New Metallo-Supramolecular Architectures." Australian Journal of Chemistry 57, no. 5 (2004): 419. http://dx.doi.org/10.1071/ch03323.

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Supramolecular architectures are of great interest in modern materials research. The directed synthesis of asym-metric 2,2′:6′,2′′-terpyridine ruthenium(II) complexes is an important tool towards such systems. In this contribution, we report the synthesis of asymmetric terpyridine ruthenium(II) complexes as models for supramolecular architectures and polymers. Terpyridines, bearing different functional groups in the 4′-position, were complexed with unfunctionalized terpyridine ligands using Ru(III)/Ru(II) chemistry. The resulting compounds were characterized by UV-vis, one- and two-dimensional
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49

Ehni, Philipp, Kevin Guy, Max Ebert, et al. "Luminescent liquid crystalline hybrid materials by embedding octahedral molybdenum cluster anions with soft organic shells derived from tribenzo[18]crown-6." Dalton Transactions 47, no. 40 (2018): 14340–51. http://dx.doi.org/10.1039/c8dt03254h.

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50

Rosselli, Silvia, Anne-Désirée Ramminger, Thomas Wagner, et al. "Coil-Ring-Coil Block Copolymers as Building Blocks for Supramolecular Hollow Cylindrical Brushes." Angewandte Chemie International Edition 40, no. 17 (2001): 3137–41. http://dx.doi.org/10.1002/1521-3773(20010903)40:17<3137::aid-anie3137>3.0.co;2-#.

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