Academic literature on the topic 'Supramolecular catalysi'

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Journal articles on the topic "Supramolecular catalysi"

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Jansen, Dennis, Johannes Gramüller, Felix Niemeyer, et al. "What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts." Chemical Science 11, no. 17 (2020): 4381–90. http://dx.doi.org/10.1039/d0sc01026j.

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Dydio, Paweł, and Joost N. H. Reek. "Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization." Chem. Sci. 5, no. 6 (2014): 2135–45. http://dx.doi.org/10.1039/c3sc53505c.

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The Perspective highlights possibilities to use supramolecular interactions between a substrate molecule and a (bifunctional) catalyst as a powerful tool to control the selectivity in transition-metal catalysis.
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Llorente, Nuria, Héctor Fernández-Pérez, José L. Núñez-Rico, et al. "Efficient modular phosphorus-containing ligands for stereoselective catalysis." Pure and Applied Chemistry 91, no. 1 (2019): 3–15. http://dx.doi.org/10.1515/pac-2018-0805.

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Abstract Over several years, our research team has contributed to ligand design for metal-catalyzed stereoselective transformations. This has been achieved with the synthesis and application to organic transformations of interest of an array of structurally diverse P-containing ligands. These range from highly modular enantiopure phosphine–phosphite ligands to supramolecularly regulated enantioselective phosphorus-based catalysts. Our research in supramolecular interactions has also led to the discovery of an unprecedented halogen-bonded rhodium-catalyst.
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Qi, Miao, Benny Kia Jia Chew, Kwai Ga Yee, Zhong-Xing Zhang, David J. Young, and T. S. Andy Hor. "A catch–release catalysis system based on supramolecular host–guest interactions." RSC Advances 6, no. 28 (2016): 23686–92. http://dx.doi.org/10.1039/c6ra01846g.

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Chow, Cheuk-Fai, Pui-Yu Ho, Wing-Leung Wong, Yu-Jing Lu, Qian Tang, and Cheng-Bin Gong. "Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal." Chemical Science 8, no. 5 (2017): 3812–20. http://dx.doi.org/10.1039/c6sc05584b.

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Schifferer, Lukas, Martin Stinglhamer, Kirandeep Kaur, and Olga García Macheño. "Halides as versatile anions in asymmetric anion-binding organocatalysis." Beilstein Journal of Organic Chemistry 17 (September 1, 2021): 2270–86. http://dx.doi.org/10.3762/bjoc.17.145.

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This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several processes and contributed to the advance and consolidation of anion-binding catalysis as a field. Thus, the use of the halide in the catalyst–anion complex as both a mere counter-anion spectator or an active nucleophile has been depicted, along with the new trends toward additional noncovalent cont
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Schifferer, Lukas, Martin Stinglhamer, Kirandeep Kaur, and Mancheño Olga García. "Halides as versatile anions in asymmetric anion-binding organocatalysis." Beilstein J. Org. Chem. 17 (September 1, 2021): 2270–86. https://doi.org/10.3762/bjoc.17.145.

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This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several processes and contributed to the advance and consolidation of anion-binding catalysis as a field. Thus, the use of the halide in the catalyst-anion complex as both a mere counter-anion spectator or an active nucleophile has been depicted, along with the new trends toward additional non-covalent con
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Reek, Joost N. H. "ChemInform Abstract: New Supramolecular Approaches in Transition Metal Catalysis; Template-Ligand Assisted Catalyst Encapsulation, Self-Assembled Ligands and Supramolecular Catalyst Immobilization." ChemInform 41, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.201025226.

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Farzinpour, Farzaneh, Ayla Steinhauer, Morgan McKee, Arne Luetzen, and Nikolay Kornienko. "Molecular Cages Accelerate Electrocatalytic NO3 - Reduction to NH3." ECS Meeting Abstracts MA2025-01, no. 52 (2025): 2592. https://doi.org/10.1149/ma2025-01522592mtgabs.

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The use of a supramolecular cage to encapsulate a catalytic molecular in order to confer an enhancement to its activity, similar the functional catalytic pocket of enzymes, is an attractive strategy in chemical catalysis. Despite this appeal, functional examples are exceedingly rare. This is largely due to a lack of beneficial effects within the host cavity that can accelerate reactivity in an enzyme-mimetic fashion. Against this backdrop, we synthesize a new structure comprised of cobalt-bearing porphyrin encapsulated within a Fe8L6 cage and apply it in a model electrocatalytic context. We un
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Sokolova, Daria, and Konrad Tiefenbacher. "Optimized iminium-catalysed 1,4-reductions inside the resorcinarene capsule: achieving >90% ee with proline as catalyst." RSC Advances 11, no. 40 (2021): 24607–12. http://dx.doi.org/10.1039/d1ra04333a.

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Dissertations / Theses on the topic "Supramolecular catalysi"

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Zaramella, Davide. "Auto-assemblaggio di nano-sistemi catalitici a base di peptidi e nanoparticelle d'oro." Doctoral thesis, Università degli studi di Padova, 2013. http://hdl.handle.net/11577/3422618.

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The catalytic efficiency, mechanistic pathways, and structural complexity displayed by enzymes make them a tremendous source of inspiration for chemists involved in catalyst development[1, 2]. Nature has evolved enzymes as large multi-kilodalton complex structures in which even units that are remote from the actual active site may profoundly affect the activity of the enzyme[3]. The much lower complexity of artificial enzyme mimics may be an important reason for their typical modest performances with respect to enzymes. This awareness has led to an interest in catalysts based on multivalent sc
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Iniesta, Beteta Ester. "Supramolecular Catalytic Systems: Synthesis, Characterization and Application in Catalysis." Doctoral thesis, Universitat Rovira i Virgili, 2021. http://hdl.handle.net/10803/671551.

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Aquesta tesi doctoral abasta el disseny i el desenvolupament de catalitzadors supramoleculars derivats de metalls de transició per a la seva aplicació com a catalitzadors en transformacions d'interès. La primera part d'aquesta tesi doctoral està centrada en el desenvolupament de catalitzadors de coure(I) regulats supramolecularment i la seva aplicació en reaccions d'inserció d'espècies carbèniques metàl·liques a enllaços O–H, generant derivats α-alquil/aril-α-alcoxi/ariloxi. S’abordà el disseny, preparació, caracterització i aplicació dels catalitzadors de coure(I) derivats de lligands bisoxa
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Chen, Ran. "Highly efficient enantioselective catalysis through supramolecular chirality amplification." Electronic Thesis or Diss., Sorbonne université, 2025. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2025SORUS108.pdf.

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La réalisation d'une catalyse énantiosélective efficace et contrôlable est depuis longtemps un objectif central dans le domaine de la synthèse asymétrique. La catalyse asymétrique traditionnelle repose souvent sur la conception et le contrôle précis de catalyseurs chiraux, ces approches sont néanmoins peu généralisables et flexibles. En revanche, les catalyseurs polymères supramoléculaires chiraux suscitent un intérêt croissant en raison de leur modularité, de leur réversibilité dynamique et de leur sensibilité à divers stimuli externes. Bénéficiant de l'effet d'amplification de chiralité, ces
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La, Manna Pellegrino. "Supramolecular Scaffolds for Biomimetic Catalysis." Doctoral thesis, Universita degli studi di Salerno, 2018. http://hdl.handle.net/10556/3001.

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2016 - 2017<br>This PhD thesis is concerned with the design, synthesis and the characterization of supramolecular scaffolds for biomimetic catalysis. Development of new organocatalytic systems based upon well-designed calix[4]arene derivatives was made and their application for on water catalysis of the Vinylogous Mukaiyama Aldol Reaction (VMAR) was explored. The obtained results showed that combination of high hydrophobicity and synthetic versatility of calixarene macrocycles can be exploited for a kind of catalysis which permits the use of mild conditions and the choice of a reaction medium,
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La, Sorella Giorgio <1987&gt. "Supramolecular approaches to Homogeneous catalysis." Doctoral thesis, Università Ca' Foscari Venezia, 2015. http://hdl.handle.net/10579/8319.

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The development of homogeneous systems capable to mimic the enzymes activity is a fundamental topic for catalysis. For that purpose, in this thesis we reported the employment of supramolecular resorcin[4]arene capsule in organic solvents and micelles in water. The resorcin[4]arene capsule is a spherical hexamer. The high number of electron-rich aromatic rings on the surface of the capsule cause cation-π interactions that confer to the cavity the possibility to accommodate positively charged compounds. We demonstrated that the capsule is also capable to host formally neutral compounds with par
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Green, Riho Thomas Seljamae. "Supramolecular assemblies of bioinorganic complexes formed via reaction of (S)-proline with nickel clusters on Au(111)." Thesis, University of St Andrews, 2014. http://hdl.handle.net/10023/11956.

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Considerable research over several decades has been directed at the development of heterogeneous enantioselective hydrogenation catalysts via the chiral modification of Ni catalysts by chiral molecules such as α-hydroxy acids and α-amino acids. Some of these systems have proved to be very successful yielding catalysts achieving very high enantioselectivity. However, the modified surfaces display relatively poor stability under catalytic conditions, so there is a demand to produce more robust chiral architectures for application in this area of catalysis. The formation of metal organic coordina
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Cerqueira, Araújo Marco Filipe. "Supramolecular metallogels for application in catalysis." Doctoral thesis, Universitat Jaume I, 2016. http://hdl.handle.net/10803/387304.

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La tesis describe el diseño y la síntesis de geles moleculares funcionalizados con fragmentos catalíticos de feniltriazol (PhTzValn), benciltriazol (BzTzAValn) y azidocoumarinatriazol (RAzTzValn) y su aplicación como catalizadores heterogéneos de la reacción de cicloadición azida-alquino catalizada con cobre (CuAAC). Los gelantes sintetizados demostraron capacidad para complejar el cobre (I), resultando en un aumento de sus propiedades mecánicas. Aparte de la actividad catalítica verificada en la reacción `click' entre la bencilazida y el fenilacetileno, la familia de gelantes PhTzValn demuest
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Mortellaro, Mark Alan. "Supramolecular chemistry for catalysis and chemosensing /." The Ohio State University, 1994. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487857546388282.

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Elrabei, Abubakar Osman Zina <1994&gt. "Supramolecular Catalysis in Confined Nano-space." Master's Degree Thesis, Università Ca' Foscari Venezia, 2022. http://hdl.handle.net/10579/20687.

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Supramolecular structures have emerged as a promising enzyme mimetic. In this study we focused on the resorcinarene hexamer which is a self assembled capsule that have been studied intensively due to it’s ready availability. The hexameric capsule shows some catalytic features reminiscent of natural enzymes include; substrate selectivity , stabilization of transition state and intermediate through secondary interactions, an inherent Bronsted acidity and it’s ability to act as a hydrogen bond catalyst. Inside the cavity of the capsule reagents are confined in a restricted space in close proximit
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Hammoud, Ahmad. "Stereodivergent synthesis by means of chirally-amplified supramolecular catalysts." Electronic Thesis or Diss., Sorbonne université, 2021. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2021SORUS026.pdf.

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La catalyse supramoléculaire a émergé avec un tas de caractéristiques très intéressantes et attrayantes telles que la modularité, la réversibilité, la recyclabilité et les propriétés de réponse aux stimuli. Ces caractéristiques sont considérées comme des outils importants pour le développement de méthodes de synthèse efficaces et fiables, notamment dans le domaine de l'industrie pharmaceutique pour laquelle la configuration des médicaments dicte leur efficacité. Notamment, les voies de synthèse stéréo-divergentes sont vitales pour obtenir tous les stéréoisomères possibles d'un candidat médicam
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Books on the topic "Supramolecular catalysi"

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library, Wiley online, and Conference on Supramolecular Approaches to Catalysis (2008 : Barcelona, Spain), eds. Supramolecular catalysis. Wiley-VCH, 2008.

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Su, Cheng-Yong. Supramolecular catalysts: Design, fabrication and applications. World Scientific, 2020.

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Fenelonov, V. B. Vvedenie v fizicheskui︠u︡ khimii︠u︡ formirovanii︠a︡ supermolekuli︠a︡rnoĭ struktury adsorbentov i katalizatorov. 2nd ed. Izd-vo Sibirskogo otd. RAN, 2004.

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Canelas, D. A., J. M. DeSimone, A. Harada, et al., eds. Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture. Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/3-540-68442-5.

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A, Canelas D., ed. Metal complex catalysts, supercritical fluid polymerization, supramolecular architecture. Springer, 1997.

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Schubert, U. Terpyridine-based materials: For catalytic, optoelectronic and life science applications. Wiley-VCH, 2011.

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Leeuwen, Piet W. N. M. van. Supramolecular Catalysis. Wiley & Sons, Incorporated, John, 2008.

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van Leeuwen, Piet W. N. M., and Matthieu Raynal, eds. Supramolecular Catalysis. Wiley, 2022. http://dx.doi.org/10.1002/9783527832033.

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van Leeuwen, Piet W. N. M., ed. Supramolecular Catalysis. Wiley, 2008. http://dx.doi.org/10.1002/9783527621781.

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Wang, Leyong, and Cheng-Yong Su. Supramolecular Catalysts. WORLD SCIENTIFIC, 2020. http://dx.doi.org/10.1142/11759.

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Book chapters on the topic "Supramolecular catalysi"

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Takashima, Yoshinori, and Akira Harada. "Supramolecular Catalysis." In Encyclopedia of Polymeric Nanomaterials. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-36199-9_51-1.

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Takashima, Yoshinori, and Akira Harada. "Supramolecular Catalysis." In Encyclopedia of Polymeric Nanomaterials. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-29648-2_51.

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Hilvert, Donald. "Principles of Antibody Catalysis." In Supramolecular Stereochemistry. Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0353-4_10.

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Ribaudo, Fabrizio, Piet W. N. M. van Leeuwen, and Joost N. H. Reek. "Supramolecular Dendritic Catalysis: Noncovalent Catalyst Anchoring to Functionalized Dendrimers." In Dendrimer Catalysis. Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/3418_031.

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Breslow, Ronald. "Binding and Catalysis in Water." In Supramolecular Chemistry. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2492-8_28.

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Sanders, Jeremy K. M. "Supramolecular Catalysis in Transition." In Supramolecular Science: Where It Is and Where It Is Going. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4554-1_16.

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van Leeuwen, Piet W. N. M., and Matthieu Raynal. "Supramolecular Catalysis in Water." In Supramolecular Chemistry in Water. Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527814923.ch14.

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Baruah, Jubaraj Bikash. "Dendrimers in Supramolecular Catalysis." In Principles and Advances in Supramolecular Catalysis. CRC Press, 2019. http://dx.doi.org/10.1201/9780429059063-5.

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Baruah, Jubaraj Bikash. "Versatility in Supramolecular Catalysis." In Principles and Advances in Supramolecular Catalysis. CRC Press, 2019. http://dx.doi.org/10.1201/9780429059063-6.

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Hamilton, Andrew D. "New Synthetic Receptors for Complexation and Catalysis." In Supramolecular Chemistry. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2492-8_9.

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Conference papers on the topic "Supramolecular catalysi"

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DIAZ DE LOS BERNARDOS, MIRIAM. "Solar-driven CO2 reduction catalysed by hybrid supramolecular photocahodes and enhanced by ionic liquids." In 15th Mediterranean Congress of Chemical Engineering (MeCCE-15). Grupo Pacífico, 2023. http://dx.doi.org/10.48158/mecce-15.t3-o-29.

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Matienko, Ludmila, and Elena Mil. "THE ROLE SUPRAMOLECULAR STRUCTURES AND H-BONDS IN THE ENZYMATIC CATALYSIS (AFM METHOD). THE REGULATORY OUTER SPHERE INTERACTIONS." In XX INTERNATIONAL INTERDISCIPLINARY CONGRESS NEUROSCIENCE FOR MEDICINE AND PSYCHOLOGY. LCC MAKS Press, 2024. http://dx.doi.org/10.29003/m3963.sudak.ns2024-20/193.

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Matienko, Ludmila, Elena Mil, and Alexander Goloshchapov. "THE ROLE OF HYDROGEN BONDS AND SUPRAMOLECULAR STRUCTURES IN THE MECHANISM OF ENZYMATIC CATALYSIS. AFM STUDY OF MODEL SYSTEMS." In XVIII INTERNATIONAL INTERDISCIPLINARY CONGRESS NEUROSCIENCE FOR MEDICINE AND PSYCHOLOGY. LCC MAKS Press, 2022. http://dx.doi.org/10.29003/m2839.sudak.ns2022-18/223-224.

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Huijser, Annemarie, Jens Uhlig, David van Duinen, et al. "Shedding Light on the Nature of Excited States in a Hydrogen Generating Supramolecular RuPt Catalyst by Ultrafast X-Ray Spectroscopy." In nanoGe Fall Meeting 2018. Fundació Scito, 2018. http://dx.doi.org/10.29363/nanoge.fallmeeting.2018.093.

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Huijser, Annemarie, Jens Uhlig, David van Duinen, et al. "Shedding Light on the Nature of Excited States in a Hydrogen Generating Supramolecular RuPt Catalyst by Ultrafast X-Ray Spectroscopy." In nanoGe Fall Meeting 2018. Fundació Scito, 2018. http://dx.doi.org/10.29363/nanoge.nfm.2018.093.

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