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Journal articles on the topic 'Supramolecular catalysi'

Author: Grafiati

Published: 9 March 2023

Last updated: 31 July 2025

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1

Jansen, Dennis, Johannes Gramüller, Felix Niemeyer, et al. "What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts." Chemical Science 11, no. 17 (2020): 4381–90. http://dx.doi.org/10.1039/d0sc01026j.

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2

Dydio, Paweł, and Joost N. H. Reek. "Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization." Chem. Sci. 5, no. 6 (2014): 2135–45. http://dx.doi.org/10.1039/c3sc53505c.

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The Perspective highlights possibilities to use supramolecular interactions between a substrate molecule and a (bifunctional) catalyst as a powerful tool to control the selectivity in transition-metal catalysis.

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3

Llorente, Nuria, Héctor Fernández-Pérez, José L. Núñez-Rico, et al. "Efficient modular phosphorus-containing ligands for stereoselective catalysis." Pure and Applied Chemistry 91, no. 1 (2019): 3–15. http://dx.doi.org/10.1515/pac-2018-0805.

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Abstract Over several years, our research team has contributed to ligand design for metal-catalyzed stereoselective transformations. This has been achieved with the synthesis and application to organic transformations of interest of an array of structurally diverse P-containing ligands. These range from highly modular enantiopure phosphine–phosphite ligands to supramolecularly regulated enantioselective phosphorus-based catalysts. Our research in supramolecular interactions has also led to the discovery of an unprecedented halogen-bonded rhodium-catalyst.

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4

Qi, Miao, Benny Kia Jia Chew, Kwai Ga Yee, Zhong-Xing Zhang, David J. Young, and T. S. Andy Hor. "A catch–release catalysis system based on supramolecular host–guest interactions." RSC Advances 6, no. 28 (2016): 23686–92. http://dx.doi.org/10.1039/c6ra01846g.

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5

Chow, Cheuk-Fai, Pui-Yu Ho, Wing-Leung Wong, Yu-Jing Lu, Qian Tang, and Cheng-Bin Gong. "Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal." Chemical Science 8, no. 5 (2017): 3812–20. http://dx.doi.org/10.1039/c6sc05584b.

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6

Schifferer, Lukas, Martin Stinglhamer, Kirandeep Kaur, and Olga García Macheño. "Halides as versatile anions in asymmetric anion-binding organocatalysis." Beilstein Journal of Organic Chemistry 17 (September 1, 2021): 2270–86. http://dx.doi.org/10.3762/bjoc.17.145.

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This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several processes and contributed to the advance and consolidation of anion-binding catalysis as a field. Thus, the use of the halide in the catalyst–anion complex as both a mere counter-anion spectator or an active nucleophile has been depicted, along with the new trends toward additional noncovalent cont

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7

Schifferer, Lukas, Martin Stinglhamer, Kirandeep Kaur, and Mancheño Olga García. "Halides as versatile anions in asymmetric anion-binding organocatalysis." Beilstein J. Org. Chem. 17 (September 1, 2021): 2270–86. https://doi.org/10.3762/bjoc.17.145.

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This review intends to provide an overview on the role of halide anions in the development of the research area of asymmetric anion-binding organocatalysis. Key early elucidation studies with chloride as counter-anion confirmed this type of alternative activation, which was then exploited in several processes and contributed to the advance and consolidation of anion-binding catalysis as a field. Thus, the use of the halide in the catalyst-anion complex as both a mere counter-anion spectator or an active nucleophile has been depicted, along with the new trends toward additional non-covalent con

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8

Reek, Joost N. H. "ChemInform Abstract: New Supramolecular Approaches in Transition Metal Catalysis; Template-Ligand Assisted Catalyst Encapsulation, Self-Assembled Ligands and Supramolecular Catalyst Immobilization." ChemInform 41, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.201025226.

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9

Farzinpour, Farzaneh, Ayla Steinhauer, Morgan McKee, Arne Luetzen, and Nikolay Kornienko. "Molecular Cages Accelerate Electrocatalytic NO₃ ^- Reduction to NH₃." ECS Meeting Abstracts MA2025-01, no. 52 (2025): 2592. https://doi.org/10.1149/ma2025-01522592mtgabs.

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The use of a supramolecular cage to encapsulate a catalytic molecular in order to confer an enhancement to its activity, similar the functional catalytic pocket of enzymes, is an attractive strategy in chemical catalysis. Despite this appeal, functional examples are exceedingly rare. This is largely due to a lack of beneficial effects within the host cavity that can accelerate reactivity in an enzyme-mimetic fashion. Against this backdrop, we synthesize a new structure comprised of cobalt-bearing porphyrin encapsulated within a Fe8L6 cage and apply it in a model electrocatalytic context. We un

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10

Sokolova, Daria, and Konrad Tiefenbacher. "Optimized iminium-catalysed 1,4-reductions inside the resorcinarene capsule: achieving >90% ee with proline as catalyst." RSC Advances 11, no. 40 (2021): 24607–12. http://dx.doi.org/10.1039/d1ra04333a.

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11

Ludmila, Matienko, Zhigacheva Irina, Mil Elena, Albantova Anastasia, and Goloshchapov Alexander. "The Dual Function of PhOH Included in the Coordination Sphere of the Nickel Complexes in the Processes of Oxidation with Dioxygen." Molecules 27, no. 11 (2022): 3502. http://dx.doi.org/10.3390/molecules27113502.

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The role of ligands in the regulation of the catalytic activity of Ni-complexes (Ni(acac)2) in green process-selective ethylbenzene oxidation with O2 into α-phenyl ethyl hydroperoxide is considered in this article. The dual function of phenol (PhOH) included in the coordination sphere of the nickel complex as an antioxidant or catalyst depends on the ligand environment of the metal. The role of intermolecular H-bonds and supramolecular structures (AFM method) in the mechanisms of selective catalysis by nickel complexes in chemical and biological oxidation reactions is analyzed.

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12

Dalinger, Alexander I., Sabina F. Mamedova, Julia V. Burykina, Evgeniy O. Pentsak та Sergey Z. Vatsadze. "Reaction of β-Nitrostyrene with Diethyl Malonate in the Presence of Bispidines: The Unusual Role of the Organocatalyst". Chemistry 6, № 3 (2024): 387–406. http://dx.doi.org/10.3390/chemistry6030023.

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The aim of this work was the investigation of novel organocatalysts for the Michael addition of diethyl malonate to β-nitrostyrene. The methodology of the study included NMR titration, reaction monitoring by NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS), product characterization by MALDI, IR spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis (TGA), and elemental analysis. As a result, evidence of supramolecular interactions between two pairs of components of the reaction was found. In addition to the supramolecular complexes, an unusual rea

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13

Yan, Haotian. "Supramolecular catalysts: A critical review." Applied and Computational Engineering 84, no. 1 (2024): 124–33. http://dx.doi.org/10.54254/2755-2721/84/20240790.

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This critical review on Supramolecular Catalysts provides a comprehensive overview of the evolution and breakthroughs in this innovative field. The review highlights the contemporary breakthroughs in adaptive supramolecular catalysts as well as metal-organic counterparts, and their possible applications. The review also discusses the challenges that need to be addressed in the development of responsive supramolecular catalysts, such as optimizing the encapsulation process to achieve maximum stability and catalytic activity. The review combines concepts from responsive materials with phenomena

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14

Pappalardo, Puglisi, and Trusso Sfrazzetto. "Catalysis inside Supramolecular Capsules: Recent Developments." Catalysts 9, no. 7 (2019): 630. http://dx.doi.org/10.3390/catal9070630.

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In the last decades, supramolecular chemists have developed new molecular receptors able to include a wide range of guests. In addition, they have designed synthetic hosts able to form capsules having an internal volume of thousands of Å3. This inner space shows different features from the bulk solution. In particular, this environment has recently been employed to perform chemical reactions, obtaining reaction products different from the “normal” conditions. These supramolecular capsules act as nanoreactors, catalyzing many chemical transformations. This review collects the recent development

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15

Trausel, Fanny, Frank Versluis, Chandan Maity, et al. "Catalysis of Supramolecular Hydrogelation." Accounts of Chemical Research 49, no. 7 (2016): 1440–47. http://dx.doi.org/10.1021/acs.accounts.6b00137.

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16

Deraedt, Christophe, and Didier Astruc. "Supramolecular nanoreactors for catalysis." Coordination Chemistry Reviews 324 (October 2016): 106–22. http://dx.doi.org/10.1016/j.ccr.2016.07.007.

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17

Sanders, Jeremy K. M. "Supramolecular Catalysis in Transition." Chemistry - A European Journal 4, no. 8 (1998): 1378–83. http://dx.doi.org/10.1002/(sici)1521-3765(19980807)4:8<1378::aid-chem1378>3.0.co;2-3.

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18

Rix, Diane, and Jérôme Lacour. "Charged-Assisted Supramolecular Catalysis." Angewandte Chemie International Edition 49, no. 11 (2010): 1918–20. http://dx.doi.org/10.1002/anie.200906392.

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19

Lehn, J. M. "Supramolecular reactivity and catalysis." Applied Catalysis A: General 113, no. 2 (1994): 105–14. http://dx.doi.org/10.1016/0926-860x(94)80017-0.

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20

FEITERS, M. C. "ChemInform Abstract: Supramolecular Catalysis." ChemInform 28, no. 4 (2010): no. http://dx.doi.org/10.1002/chin.199704323.

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21

Howlader, Prodip, and Michael Schmittel. "Heteroleptic metallosupramolecular aggregates/complexation for supramolecular catalysis." Beilstein Journal of Organic Chemistry 18 (May 27, 2022): 597–630. http://dx.doi.org/10.3762/bjoc.18.62.

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Supramolecular catalysis is reviewed with an eye on heteroleptic aggregates/complexation. Since most of the current metallosupramolecular catalytic systems are homoleptic in nature, the idea of breaking/reducing symmetry has ignited a vivid search for heteroleptic aggregates that are made up by different components. Their higher degree of functional diversity and structural heterogeneity allows, as demonstrated by Nature by the multicomponent ATP synthase motor, a more detailed and refined configuration of purposeful machinery. Furthermore, (metallo)supramolecular catalysis is shown to extend

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22

Yang, Hui, and Ming Wah Wong. "Application of Halogen Bonding to Organocatalysis: A Theoretical Perspective." Molecules 25, no. 5 (2020): 1045. http://dx.doi.org/10.3390/molecules25051045.

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The strong, specific, and directional halogen bond (XB) is an ideal supramolecular synthon in crystal engineering, as well as rational catalyst and drug design. These attributes attracted strong growing interest in halogen bonding in the past decade and led to a wide range of applications in materials, biological, and catalysis applications. Recently, various research groups exploited the XB mode of activation in designing halogen-based Lewis acids in effecting organic transformation, and there is continual growth in this promising area. In addition to the rapid advancements in methodology dev

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23

Koshti, Vijay S., Anirban Sen, Dinesh Shinde, and Samir H. Chikkali. "Self-assembly of P-chiral supramolecular phosphines on rhodium and direct evidence for Rh-catalyst-substrate interactions." Dalton Trans. 46, no. 40 (2017): 13966–73. http://dx.doi.org/10.1039/c7dt02923c.

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The self-assembly of p-chiral supramolecular phosphines on a rhodium metal has been established and direct evidence to demonstrate the existence of hydrogen bonding between the supramolecular catalyst and the substrate has been presented.

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24

Leclercq, Loïc, Grégory Douyère, and Véronique Nardello-Rataj. "Supramolecular Chemistry and Self-Organization: A Veritable Playground for Catalysis." Catalysts 9, no. 2 (2019): 163. http://dx.doi.org/10.3390/catal9020163.

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The directed assembly of molecular building blocks into discrete supermolecules or extended supramolecular networks through noncovalent intermolecular interactions is an ongoing challenge in chemistry. This challenge may be overcome by establishing a hierarchy of intermolecular interactions that, in turn, may facilitate the edification of supramolecular assemblies. As noncovalent interactions can be used to accelerate the reaction rates and/or to increase their selectivity, the development of efficient and practical catalytic systems, using supramolecular chemistry, has been achieved during th

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25

Vaquero, Mónica, Laura Rovira, and Anton Vidal-Ferran. "Supramolecularly fine-regulated enantioselective catalysts." Chemical Communications 52, no. 74 (2016): 11038–51. http://dx.doi.org/10.1039/c6cc04474c.

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26

Noyori, Ryoji, Christian A. Sandoval, Kilian Muñiz, and Takeshi Ohkuma. "Metal–ligand bifunctional catalysis for asymmetric hydrogenation." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 363, no. 1829 (2005): 901–12. http://dx.doi.org/10.1098/rsta.2004.1536.

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Chiral diphosphine/1,2-diamine–Ru(II) complexes catalyse the rapid, productive and enantioselective hydrogenation of simple ketones. The carbonyl-selective hydrogenation takes place via a non-classical metal–ligand bifunctional mechanism. The reduction of the C=O function occurs in the outer coordination sphere of an 18e trans -RuH 2 (diphosphine)(diamine) complex without interaction between the unsaturated moiety and the metallic centre. The Ru atom donates a hydride and the NH 2 ligand delivers a proton through a pericyclic six-membered transition state, directly giving an alcoholic product

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27

Rosamilia, Anthony E., Christopher R. Strauss, and Janet L. Scott. "Distillable ionic liquids for a new multicomponent reaction." Pure and Applied Chemistry 79, no. 11 (2007): 1869–77. http://dx.doi.org/10.1351/pac200779111869.

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Adducts of dimethylamine and carbon dioxide form a "distillable ionic liquid" (DIMCARB) that may used as both a reaction medium and catalyst in the direct, atom-economical synthesis of useful synthetic building blocks, such as mono-condensed α,β-unsaturated ketones. The utilization of such building blocks in the synthesis of two new classes of versatile macrocycles, by a sequence of condensation reactions (H2O by-product), is described. Investigation into the mechanism of action of DIMCARB catalysis and observation of an aniline impurity arising from a competing reaction sequence led to develo

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28

Wu, Yuzhe, Yuntong Li, Jie Mao, et al. "Metallosupramolecular Polymer Precursor Design for Multi-Element Co-Doped Carbon Shells with Improved Oxygen Reduction Reaction Catalytic Activity." Catalysts 9, no. 1 (2019): 102. http://dx.doi.org/10.3390/catal9010102.

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Heteroatom-doped carbon materials have been extensively studied in the field of electrochemical catalysis to solve the challenges of energy shortage. In particular, there is vigorous research activity in the design of multi-element co-doped carbon materials for the improvement of electrochemical performance. Herein, we developed a supramolecular approach to construct metallosupramolecular polymer hollow spheres, which could be used as precursors for the generation of carbon shells co-doped with B, N, F and Fe elements. The metallosupramolecular polymer hollow spheres were fabricated through a

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29

Kadokawa, Jun-ichi, Takuya Shoji, and Kazuya Yamamoto. "Preparation of Amylose-Carboxymethyl Cellulose Conjugated Supramolecular Networks by Phosphorylase-Catalyzed Enzymatic Polymerization." Catalysts 9, no. 3 (2019): 211. http://dx.doi.org/10.3390/catal9030211.

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Enzymatic polymerization has been noted as a powerful method to precisely synthesize polymers with complicated structures, such as polysaccharides, which are not commonly prepared by conventional polymerization. Phosphorylase is one of the enzymes which have been used to practically synthesize well-defined polysaccharides. The phosphorylase-catalyzed enzymatic polymerization is conducted using α-d-glucose 1-phosphate as a monomer, and maltooligosaccharide as a primer, respectively, to obtain amylose. Amylose is known to form supramolecules owing to its helical conformation, that is, inclusion

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30

Haynes, Cally J. E., and Larissa K. S. von Krbek. "Hopping protons in supramolecular catalysis." Nature Chemistry 14, no. 9 (2022): 969–71. http://dx.doi.org/10.1038/s41557-022-01024-w.

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31

Klöck, Cornelius, Roy N. Dsouza, and Werner M. Nau. "Cucurbituril-Mediated Supramolecular Acid Catalysis." Organic Letters 11, no. 12 (2009): 2595–98. http://dx.doi.org/10.1021/ol900920p.

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32

Lehn, Jean-Marie. "Supramolecular Catalysis of Phosphoryl Transfer." Phosphorus, Sulfur, and Silicon and the Related Elements 75, no. 1-4 (1993): 1. http://dx.doi.org/10.1080/10426509308037349.

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33

Meeuwissen, Jurjen, and Joost N. H. Reek. "Supramolecular catalysis beyond enzyme mimics." Nature Chemistry 2, no. 8 (2010): 615–21. http://dx.doi.org/10.1038/nchem.744.

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34

Dawn, Arnab. "Supramolecular Gel as the Template for Catalysis, Inorganic Superstructure, and Pharmaceutical Crystallization." International Journal of Molecular Sciences 20, no. 3 (2019): 781. http://dx.doi.org/10.3390/ijms20030781.

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A supramolecular gel is a fascinating combination of flexibility and orderliness. While the supramolecular nature of crosslinking contributes towards the adaptivity and the reversibility of the system, orderliness at the molecular level amplifies the functional output and induces extraordinary selectivity into the system. Therefore, use of supramolecular gels as the soft template is an emerging area of research, which includes but not limited to catalysis of a chemical or a photochemical process, transcription of gel property to a substrate, or even controlling the nucleation of drug molecules

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35

Bernar, Ivan, Floris Rutjes, Johannes Elemans, and Roeland Nolte. "Aerobic Epoxidation of Low-Molecular-Weight and Polymeric Olefins by a Supramolecular Manganese Porphyrin Catalyst." Catalysts 9, no. 2 (2019): 195. http://dx.doi.org/10.3390/catal9020195.

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We report on the highly efficient epoxidation of low-molecular-weight and polymeric olefins catalyzed by a supramolecular manganese porphyrin complex using molecular oxygen as an oxidant and an aldehyde as a co-reductant. At ambient temperature and under optimized reaction conditions, the catalyst showed high activity and stereoselectivity. The efficiency of the supramolecular manganese porphyrin was higher than that of a reference porphyrin catalyst, possibly because it was more stable under the applied reaction conditions. Mechanistic studies suggest that a manganese oxo porphyrin complex ma

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36

Bilyachenko, Alexey N., Ivan S. Arteev, Victor N. Khrustalev, et al. "Cagelike Octacopper Methylsilsesquioxanes: Self-Assembly in The Focus of Alkaline Metal Ion Influence—Synthesis, Structure, and Catalytic Activity." Molecules 28, no. 3 (2023): 1211. http://dx.doi.org/10.3390/molecules28031211.

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A family of unusual octacopper cage methylsilsesquioxanes 1–4 were prepared and characterized. Features of their cagelike (prismatic) structure were established using X-ray diffraction studies. Effects of distortion of prismatic cages 1–4 due to variation of (i) additional alkaline metal ions (K, Rb, or Cs), (ii) combination of solvating ligands, and (iii) nature of encapsulating species were found. Opportunities for the design of supramolecular 1D extended structures were found. These opportunities are based on (i) formate linkers between copper centers (in the case of Cu8K2-based compound 2)

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37

Chai, Lan-Qin, Yu-Li Zhang, Jun-Feng Tong, and Gang Liu. "Synthesis, Crystal Structure and Fluorescence Behavior of 2,6- Di(thiophen-2-yl)-benzo[1,2-d:4,5-d´]bisoxazole." Zeitschrift für Naturforschung B 68, no. 3 (2013): 239–44. http://dx.doi.org/10.5560/znb.2013-2301.

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An effective and clean new aerobic approach for the synthesis of 2,6-disubstituted benzobisoxazole by using a one-pot reaction of an organic aminoxyl radical as the catalyst is reported. 2,6- Di(thiophen-2-yl)-benzo[1,2-d : 4,5-d´]bisoxazole was synthesized with catalysis by the free radical 4-methoxy-TEMPO and characterized by 1H and 13C NMR spectroscopy, HRMS, as well as by elemental analysis, UV/Vis and emission spectroscopy. The crystal structure of the title compound has been determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group C2/c with a=12.531(1

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38

Friščić, Tomislav, and Jean-Louis Do. "Chemistry 2.0: Developing a New, Solvent-Free System of Chemical Synthesis Based on Mechanochemistry." Synlett 28, no. 16 (2017): 2066–92. http://dx.doi.org/10.1055/s-0036-1590854.

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Mechanochemistry by grinding or milling has grown from a laboratory curiosity to a versatile approach for the synthesis and discovery of molecules, materials and reactivity. Focusing on organic synthesis and the chemistry of organic solids in general, we now provide a snapshot of this exciting, rapidly developing area, with the intention to illustrate its potential in establishing a more efficient and environmentally friendly system of chemical and materials synthesis, based on solid-state transformations rather than conventional, solution-dependent chemistry.1 What is Chemistry 2.0?2 Introduc

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Nurttila, Sandra S., Riccardo Zaffaroni, Simon Mathew, and Joost N. H. Reek. "Control of the overpotential of a [FeFe] hydrogenase mimic by a synthetic second coordination sphere." Chemical Communications 55, no. 21 (2019): 3081–84. http://dx.doi.org/10.1039/c9cc00901a.

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Hydrogen as a renewable fuel is viable when produced sustainably via proton reduction catalysis (PRC). Encapsulation of a hydrogenase mimic in a supramolecular cage results in a 150 mV decrease of the catalytic overpotential in proton reduction catalysis.

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40

Harraz, Deiaa M., and Jeffery T. Davis. "A self-assembled peroxidase from 5′-GMP and heme." Chemical Communications 54, no. 13 (2018): 1587–90. http://dx.doi.org/10.1039/c7cc09900b.

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41

Matienko, L. I., V. I. Binyukov, E. M. Mil, and G. E. Zaikov. "Supramolecular Macrostructures in the Mechanisms of Catalysis with Nickel or Iron Heteroligand Complexes." Current Organocatalysis 6, no. 1 (2019): 36–43. http://dx.doi.org/10.2174/2213337206666181231120410.

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Background: The AFM-techniques have been used for the research of the role of intermolecular H-bonds and stable supramolecular nanostructures, based on effective catalysts of oxidation processes, which are also models of Ni(Fe)ARD Dioxygenases, in mechanisms of catalysis. Methods and Results: The role of Histidine and Tyrosine ligands in the mechanisms of catalysis by FeARD on model systems is discussed based on AFM and UV-Spectroscopy data. Conclusion: We first offer the new approach – method of atomic force microscopy (AFM) – to study the possibility of the formation of supramolecular nanost

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42

Matienko, Ludmila, Mil Elena Mickhailovna, Binyukov Vladimir Ivanovich, and Goloshchapov Alexandr Nikolaevich. "AFM Research in Catalysis and Medicine." Current Organocatalysis 7, no. 3 (2020): 248–55. http://dx.doi.org/10.2174/2213337207999200717171645.

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Background: In this study, we show that the AFM method not only allows monitoring the morphological changes in biological structures fixed on the surface due to H-bonds, but also makes it possible to study the self-organization of metal complexes by simulating the active center of enzymes due to intermolecular H-bonds into stable nanostructures; the sizes of which are much smaller than the studied biological objects. The possible role of intermolecular hydrogen bonds in the formation of stable supramolecular metal complexes, which are effective catalysts for the oxidation of alkyl arenes to hy

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43

Feng, Zhaoqianqi, Tengfei Zhang, Huaimin Wang, and Bing Xu. "Supramolecular catalysis and dynamic assemblies for medicine." Chemical Society Reviews 46, no. 21 (2017): 6470–79. http://dx.doi.org/10.1039/c7cs00472a.

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44

Shome, Anshupriya. "Applications of Supramolecular Materials in Real World: A Mini Review." Asian Journal of Chemistry 35, no. 2 (2023): 305–15. http://dx.doi.org/10.14233/ajchem.2023.26952.

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The breakthrough in supramolecular chemistry came in the 1960s when Charles J. Pedersen utilized the concept of ‘chemistry beyond molecules’ in the synthesis of the crown ethers. Self-assembly could allow for the construction of fascinating supramolecular architectures that are otherwise challenging to prepare using covalent chemistry. Supramolecular chemistry has been extensively studied in recent decades and its applications have been explored to include everything from molecular machines and sensors to gas absorption and nanoreactors to chemical catalysis and drug delivery. In this review a

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45

Guo, Xiaojun, Xinyu Jia, Qin He, et al. "Supramolecular Double-Helical Polymers: Supramolecular Chiral Induction and Asymmetric Catalysis." Molecules 30, no. 7 (2025): 1517. https://doi.org/10.3390/molecules30071517.

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Seeking a supramolecular chiral system induced by trace chiral molecules instead of traditional complex and expensive chiral ligands to achieve high yield or ee value conversion of the products is of great significance in asymmetric synthesis but still remains a challenge. Herein, two types of double helical supramolecular chiral systems, (M)-Helix and (P)-Helix, with opposite chiral optics were constructed in situ using tyrosine-functionalized pillar[5]arene as inducers. These systems exhibit chiroptical stability and enable remarkable chirality amplification from 7 mol% chiral seeds. When ap

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46

Wennemers, Helma. "Peptides – Molecular Allrounders." CHIMIA International Journal for Chemistry 75, no. 6 (2021): 525–29. http://dx.doi.org/10.2533/chimia.2021.525.

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The enormous structural and functional diversity available through combining different amino acids into peptides offers numerous exciting opportunities. This article summarizes recent research highlights from my laboratory in the areas of asymmetric catalysis, supramolecular chemistry, and chemical biology. This scope includes the development of bioinspired peptide catalysts, synthetic collagen peptides, supramolecular porous assemblies, and cell-penetrating peptides.

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Matienko, Ludmila, Vladimir Binyukov, Larisa Mosolova, Elena Mil, and Gennady Zaikov. "Some Supramolecular Nanostructures Based on Catalytic Active Nickel and Iron Heteroligand Complexes. Functional Models of Ni(Fe) Dioxygenases." Chemistry & Chemical Technology 8, no. 3 (2014): 339–48. http://dx.doi.org/10.23939/chcht08.03.339.

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Ren, Yufeng, Wei Zhang, Jun Lu, Kai Gao, Xiali Liao, and Xiaozhen Chen. "One-pot synthesis of tetrahydro-4H-chromenes by supramolecular catalysis in water." RSC Advances 5, no. 97 (2015): 79405–12. http://dx.doi.org/10.1039/c5ra14385c.

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Bérubé, Christopher, Xavier Barbeau, Patrick Lagüe, and Normand Voyer. "Revisiting the Juliá–Colonna enantioselective epoxidation: supramolecular catalysis in water." Chemical Communications 53, no. 37 (2017): 5099–102. http://dx.doi.org/10.1039/c7cc01168g.

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Aleman Garcia, Miguel Angel, Yuwei Hu, and Itamar Willner. "Switchable supramolecular catalysis using DNA-templated scaffolds." Chemical Communications 52, no. 10 (2016): 2153–56. http://dx.doi.org/10.1039/c5cc08873a.

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