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1

Safarnejad Shad, Mastaneh, Pulikkal Veettil Santhini, and Wim Dehaen. "1,2,3-Triazolium macrocycles in supramolecular chemistry." Beilstein Journal of Organic Chemistry 15 (September 12, 2019): 2142–55. http://dx.doi.org/10.3762/bjoc.15.211.

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In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles that then can be quaternized. Applications of triazolium macrocycles thus prepared include receptors for molecular recognition of anionic species, pH sensors, mechanically interlocked molecules, molecular machines, and molecular reactors.
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2

Liu, Yu, and Shizhao Kang. "Molecular recognition on supramolecular systems (XXXV)." Science in China Series B: Chemistry 44, no. 3 (2001): 260–67. http://dx.doi.org/10.1007/bf02879616.

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3

Lehn, Jean-Marie. "Towards Complex Matter: Supramolecular Chemistry and Self-organization." European Review 17, no. 2 (2009): 263–80. http://dx.doi.org/10.1017/s1062798709000805.

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Chemistry has developed from molecular chemistry, mastering the combination and recombination of atoms into increasingly complex molecules, to supramolecular chemistry, harnessing intermolecular forces for the generation of informed supramolecular systems and processes through the implementation of molecular information carried by electromagnetic interactions. Supramolecular chemistry is actively exploring systems undergoing self-organization, i.e. systems capable of spontaneously generating well-defined functional supramolecular architectures by self-assembly from their components, on the bas
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4

Haino, Takeharu. "Supramolecular Polymerization Engineered with Molecular Recognition." Chemical Record 15, no. 5 (2015): 837–53. http://dx.doi.org/10.1002/tcr.201500012.

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5

Schalley, Christoph A. "Molecular recognition and supramolecular chemistry in the gas phase." Mass Spectrometry Reviews 20, no. 5 (2001): 253–309. http://dx.doi.org/10.1002/mas.10009.

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6

Zimmerman, Steven C. "A journey in bioinspired supramolecular chemistry: from molecular tweezers to small molecules that target myotonic dystrophy." Beilstein Journal of Organic Chemistry 12 (January 25, 2016): 125–38. http://dx.doi.org/10.3762/bjoc.12.14.

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This review summarizes part of the author’s research in the area of supramolecular chemistry, beginning with his early life influences and early career efforts in molecular recognition, especially molecular tweezers. Although designed to complex DNA, these hosts proved more applicable to the field of host–guest chemistry. This early experience and interest in intercalation ultimately led to the current efforts to develop small molecule therapeutic agents for myotonic dystrophy using a rational design approach that heavily relies on principles of supramolecular chemistry. How this work was infl
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7

Spaniol, Jacqueline M., and Kraig A. Wheeler. "Accessing Centnerszwer's quasiracemate – molecular shape controlled molecular recognition." RSC Advances 6, no. 69 (2016): 64921–29. http://dx.doi.org/10.1039/c6ra08131b.

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8

Yu, Liu, and You Changcheng. "Molecular recognition studies on supramolecular systems (XXIV)." Science in China Series B: Chemistry 43, no. 1 (2000): 27–33. http://dx.doi.org/10.1007/bf03028846.

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9

Zeng, Fanwen, and Steven C. Zimmerman. "Dendrimers in Supramolecular Chemistry: From Molecular Recognition to Self-Assembly." Chemical Reviews 97, no. 5 (1997): 1681–712. http://dx.doi.org/10.1021/cr9603892.

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10

Newkome, George R., Barry D. Woosley, Enfei He, et al. "Supramolecular chemistry of flexible, dendritic-based structures employing molecular recognition." Chem. Commun., no. 24 (1996): 2737–38. http://dx.doi.org/10.1039/cc9960002737.

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11

Bonifazi, Davide, Stefan Mohnani, and Anna Llanes-Pallas. "Supramolecular Chemistry at Interfaces: Molecular Recognition on Nanopatterned Porous Surfaces." Chemistry - A European Journal 15, no. 29 (2009): 7004–25. http://dx.doi.org/10.1002/chem.200900900.

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12

LEHN, J. M. "ChemInform Abstract: Supramolecular Chemistry - From Molecular Recognition Towards Self- Organization." ChemInform 27, no. 51 (2010): no. http://dx.doi.org/10.1002/chin.199651266.

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13

Lehn, J. M. "Perspectives in supramolecular chemistry: From molecular recognition towards self-organisation." Pure and Applied Chemistry 66, no. 10-11 (1994): 1961–66. http://dx.doi.org/10.1351/pac199466101961.

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14

Lehn, J. M. "Supramolecular Chemistry: From Molecular Recognition towards Molecular Information Processing and Self-Organization." Materials Science Forum 91-93 (January 1992): 100. http://dx.doi.org/10.4028/www.scientific.net/msf.91-93.100.

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15

Sharma, Hemant, Navneet Kaur, Amanpreet Singh, Anil Kuwar, and Narinder Singh. "Optical chemosensors for water sample analysis." Journal of Materials Chemistry C 4, no. 23 (2016): 5154–94. http://dx.doi.org/10.1039/c6tc00605a.

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16

Lehn, Jean-Marie. "Dynamers: Dynamic Molecular and Supramolecular Polymers." Australian Journal of Chemistry 63, no. 4 (2010): 611. http://dx.doi.org/10.1071/ch10035.

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Dynamers are defined as constitutional dynamic polymers, i.e. polymeric entities whose monomeric components are linked through reversible connections and have therefore the capacity to modify their constitution by exchange and reshuffling of their components. They may be either of supramolecular or molecular nature depending on whether the connections are non-covalent interactions or reversible covalent bonds. They are formed respectively either by polyassociation with interactional recognition or by polycondensation with functional recognition between the connecting subunits. Both types are i
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17

Liu, Yu, Bao-Hang Han, Ai-Di Qi, and Rong-Ti Chen. "Molecular Recognition Study of a Supramolecular System." Bioorganic Chemistry 25, no. 3 (1997): 155–62. http://dx.doi.org/10.1006/bioo.1997.1062.

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18

Mather, Brian D., Margaux B. Baker, Frederick L. Beyer, Michael A. G. Berg, Matthew D. Green, and Timothy E. Long. "Supramolecular Triblock Copolymers Containing Complementary Nucleobase Molecular Recognition." Macromolecules 40, no. 19 (2007): 6834–45. http://dx.doi.org/10.1021/ma070865y.

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19

Spruell, Jason M. "Molecular recognition and switching via radical dimerization." Pure and Applied Chemistry 82, no. 12 (2010): 2281–94. http://dx.doi.org/10.1351/pac-con-10-08-03.

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This article highlights the emerging use of the interactions of radical π-dimers to drive both molecular recognition and switching processes within supramolecular systems and mechanically interlocked molecular architectures. The enhanced stability experienced by dimers of radical cation species when encapsulated, as compared to when they are free in solution, is driving their useful incorporation into functional systems. The redox stimulation used in the production of radical cation species provides the ideal trigger for molecular switching events. Moreover, the nature and strength of the radi
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20

Toma, S. H., M. Nakamura, and H. E. Toma. "The Effect of -Cyclodextrin Inclusion on the Morphology of [Ru(bpy)2Cl(BPEB)](PF6) Films by Scanning Force Microscopy." Microscopy and Microanalysis 11, S03 (2005): 142–45. http://dx.doi.org/10.1017/s1431927605051093.

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Molecular level organization has been a subject of great relevance in supramolecular chemistry and nanotechnology. Supramolecular chemists count on the ability of molecules to form several kinds of organization, allowing the development of nanoscaled devices. In this way, the scanning probe microscopy provides a great tool for characterization, manipulation and interfacing such devices [1]. Regarding the ruthenium complexes [Ru(bpy)2Cl(BPEB)](PF6) and {[Ru(bpy)2Cl]2(BPEB)}(PF6)2, where bpy = 2,2'-bipyridine, the presence of the BPEB (1,4-bis[4-pyridyl)ethenyl]benzene) ligand has an important r
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21

Li, Dong-Hao, and Bradley D. Smith. "Molecular recognition using tetralactam macrocycles with parallel aromatic sidewalls." Beilstein Journal of Organic Chemistry 15 (May 9, 2019): 1086–95. http://dx.doi.org/10.3762/bjoc.15.105.

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This review summarizes the supramolecular properties of tetralactam macrocycles that have parallel aromatic sidewalls and four NH residues directed into the macrocyclic cavity. These macrocycles are versatile hosts for a large number of different guest structures in water and organic solvents, and they are well-suited for a range of supramolecular applications. The macrocyclic cavity contains a mixture of polar functional groups and non-polar surfaces which is reminiscent of the amphiphilic binding pockets within many proteins. In water, the aromatic surfaces in the tetralactam cavity drive hi
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22

Percec, V., J. Heck, G. Johansson, D. Tomazos, M. Kawasumi, and G. Ungar. "Molecular-Recognition-Directed Self-Assembly of Supramolecular Polymers." Journal of Macromolecular Science, Part A 31, no. 8 (1994): 1031–70. http://dx.doi.org/10.1080/10601329408545688.

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23

Percec, V., J. Heck, G. Johansson, et al. "Molecular Recognition Directed Self-Assembly of Supramolecular Architectures." Journal of Macromolecular Science, Part A 31, no. 11 (1994): 1719–58. http://dx.doi.org/10.1080/10601329408545879.

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24

Panja, Santanu, and Kumaresh Ghosh. "Progress in Benzimidazole/Benzimidazolium-Derived Supramolecular Gelators in Ion Recognition." Mini-Reviews in Organic Chemistry 17, no. 8 (2020): 1042–55. http://dx.doi.org/10.2174/1570193x17999200430090415.

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The benzimidazole moiety, being a versatile heterocyclic unit, finds potential utility in multiple applications ranging from material science to medicinal chemistry. Benzimidazole derivatives are widely chosen as a multifunctional unit for the synthesis of bioactive organic compounds because of their structural similarities to the natural nucleotides. They are also used as heteroaromatic scaffolds in molecular probes for sensing and bio-imaging. Amphoteric nature of the benzimidazole ring forms the basis of designing new fluorescent architectures for various metal ions, anions, nitroaromatics
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25

Barthélémy, Philippe, Stephen J. Lee, and Mark Grinstaff. "Supramolecular assemblies with DNA* (Special Topic Article)." Pure and Applied Chemistry 77, no. 12 (2005): 2133–48. http://dx.doi.org/10.1351/pac200577122133.

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Information storage in chemical and biological systems involves recognition processes occurring at the molecular and macromolecular level. The implementation of a "code" can consist of multiple noncovalent interactions, which include hydrogen bonds, π-stacking, hydrophobic interactions, and appropriate molecular and supramolecular architectures. With the double-helical DNA structure stabilized by Watson-Crick hydrogen bond base-pairing and aryl π-π stacking interactions, nature provides to scientists an example of one of the most sophisticated supramolecular systems. Molecular organization usi
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26

Chi, Xiaodong, Jinya Tian, Dan Luo, Han-Yuan Gong, Feihe Huang, and Jonathan L. Sessler. "“Texas-Sized” Molecular Boxes: From Chemistry to Applications." Molecules 26, no. 9 (2021): 2426. http://dx.doi.org/10.3390/molecules26092426.

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The design and synthesis of novel macrocyclic host molecules continues to attract attention because such species play important roles in supramolecular chemistry. However, the discovery of new classes of macrocycles presents a considerable challenge due to the need to embody by design effective molecular recognition features, as well as ideally the development of synthetic routes that permit further functionalization. In 2010, we reported a new class of macrocyclic hosts: a set of tetracationic imidazolium macrocycles, which we termed “Texas-sized” molecular boxes (TxSBs) in homage to Stoddart
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27

Kameta, Naohiro, and Kazuhisa Hiratani. "Synthesis of Supramolecular Boron Complexes and Their Molecular Recognition." Journal of Synthetic Organic Chemistry, Japan 65, no. 10 (2007): 959–68. http://dx.doi.org/10.5059/yukigoseikyokaishi.65.959.

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28

Yu, Guocan, Kecheng Jie, and Feihe Huang. "Supramolecular Amphiphiles Based on Host–Guest Molecular Recognition Motifs." Chemical Reviews 115, no. 15 (2015): 7240–303. http://dx.doi.org/10.1021/cr5005315.

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29

Pinalli, Roberta, Michele Suman, and Enrico Dalcanale. "Cavitands at Work: From Molecular Recognition to Supramolecular Sensors." European Journal of Organic Chemistry 2004, no. 3 (2004): 451–62. http://dx.doi.org/10.1002/ejoc.200300430.

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30

Lehn, Jean-Marie. "Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self-Organization." Angewandte Chemie International Edition in English 29, no. 11 (1990): 1304–19. http://dx.doi.org/10.1002/anie.199013041.

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31

Sanders, Jeremy K. M. "Adventures in molecular recognition. The ins and outs of templating." Pure and Applied Chemistry 72, no. 12 (2000): 2265–74. http://dx.doi.org/10.1351/pac200072122265.

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Two different approaches are described for the creation of supramolecular systems potentially capable of recognition and catalysis. Using the design approach, we have been able to accelerate and influence two different Diels­Alder reactions within the cavities of porphyrin dimers and trimers; this is templating from the outside inwards. The selection approach is a synthetic chemical attempt to capture some of the key evolutionary features of biological systems: dynamic combinatorial chemistry is used to create equilibrating mixtures of potential receptors, and then a template is used to select
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32

LEHN, J. M. "ChemInform Abstract: Perspectives in Supramolecular Chemistry: From Molecular Recognition Towards Self-Organisation." ChemInform 26, no. 7 (2010): no. http://dx.doi.org/10.1002/chin.199507280.

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33

ZENG, F., and S. C. ZIMMERMAN. "ChemInform Abstract: Dendrimers in Supramolecular Chemistry: From Molecular Recognition to Self-Assembly." ChemInform 28, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199744319.

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34

LEHN, J. M. "ChemInform Abstract: Perspectives in Supramolecular Chemistry: From Molecular Recognition Towards Self-Organization." ChemInform 26, no. 2 (2010): no. http://dx.doi.org/10.1002/chin.199502275.

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35

Diederich, Francois. "Molecular recognition in aqueous solution: Supramolecular complexation and catalysis." Journal of Chemical Education 67, no. 10 (1990): 813. http://dx.doi.org/10.1021/ed067p813.

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36

Kim, Dong Sub, and Jonathan L. Sessler. "Calix[4]pyrroles: versatile molecular containers with ion transport, recognition, and molecular switching functions." Chemical Society Reviews 44, no. 2 (2015): 532–46. http://dx.doi.org/10.1039/c4cs00157e.

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Calix[4]pyrroles function as “molecular containers” as illustrated by their ability to act as carriers for the through-membrane transport of ions and as “monomers” in the construction of aggregated supramolecular constructs.
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37

Bag, Braja Gopal, and Shaishab Kumar Dinda. "Arjunolic acid: A renewable template in supramolecular chemistry and nanoscience." Pure and Applied Chemistry 79, no. 11 (2007): 2031–38. http://dx.doi.org/10.1351/pac200779112031.

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Arjunolic acid, a triterpenoid, renewably resourced from Terminalia arjuna sawdust, has the potential of being used as a structural molecular framework in supramolecular chemistry and nanoscience. The nanosized chiral triterpenoid on derivatization could immobilize varieties of organic solvents at low concentrations. The low-molecular-mass organic compounds self-assembled in organic media to form fibrous network structures having fibers of nano- to micrometer diameters. A dual-component supramolecular gelation has been demonstrated, exhibiting interesting thermochromic property. An arjunolic a
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38

Konishi, Toshifumi, Masaki Horie, Tatsuo Wada, Shin Ogasawara, Jun-ichi Kikuchi, and Atsushi Ikeda. "Supramolecular photocurrent-generating systems using porphyrin composite materials." Journal of Porphyrins and Phthalocyanines 11, no. 05 (2007): 342–47. http://dx.doi.org/10.1142/s1088424607000382.

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Supramolecular design principles for a porphyrin-sensitized, wet-type solar cell are described. To construct efficient organic photocurrent-generating systems, the following two important targets exist: (i) kinetic control of photoinduced electron-transfer processes by spatial, three-dimensional alignment of photo-functional molecules (sensitizers, electron donors, acceptors, and mediators) and (ii) highly dense deposition of composites of the photo-functional molecules on an electrode. These objectives can be achieved by tailoring a photoactive multilayer using supramolecular interactions, su
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39

Wang, Yiliang, Guchuan Ping, and Chunju Li. "Efficient complexation between pillar[5]arenes and neutral guests: from host–guest chemistry to functional materials." Chemical Communications 52, no. 64 (2016): 9858–72. http://dx.doi.org/10.1039/c6cc03999e.

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40

Czapik, Agnieszka, Maciej Jelecki, and Marcin Kwit. "Chiral Cocrystal Solid Solutions, Molecular Complexes, and Salts of N-Triphenylacetyl-l-Tyrosine and Diamines." International Journal of Molecular Sciences 20, no. 20 (2019): 5004. http://dx.doi.org/10.3390/ijms20205004.

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The molecular recognition process and the ability to form multicomponent supramolecular systems have been investigated for the amide of triphenylacetic acid and l-tyrosine (N-triphenylacetyl-l-tyrosine, TrCOTyr). The presence of several supramolecular synthons within the same amide molecule allows the formation of various multicomponent crystals, where TrCOTyr serves as a chiral host. Isostructural crystals of solvates with methanol and ethanol and a series of binary crystalline molecular complexes with selected organic diamines (1,5-naphthyridine, quinoxaline, 4,4′-bipyridyl, and DABCO) were
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41

Wu, Dan, Yang Li, Jie Shen, et al. "Supramolecular chemotherapeutic drug constructed from pillararene-based supramolecular amphiphile." Chemical Communications 54, no. 59 (2018): 8198–201. http://dx.doi.org/10.1039/c8cc04334e.

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A therapeutic supramolecular amphiphile, P5⊃CPT-ss-Py, with GSH-responsiveness was constructed using pillar[5]arene-based host–guest molecular recognition. Cellular internalization and anticancer efficacy were greatly increased through this supramolecular strategy.
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42

Ling, Xing Yi, David N. Reinhoudt, and Jurriaan Huskens. "From supramolecular chemistry to nanotechnology: Assembly of 3D nanostructures." Pure and Applied Chemistry 81, no. 12 (2009): 2225–33. http://dx.doi.org/10.1351/pac-con-09-07-04.

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Fabricating well-defined and stable nanoparticle crystals in a controlled fashion receives growing attention in nanotechnology. The order and packing symmetry within a nanoparticle crystal is of utmost importance for the development of materials with unique optical and electronic properties. To generate stable and ordered 3D nanoparticle structures, nanotechnology is combined with supramolecular chemistry to control the self-assembly of 2D and 3D receptor-functionalized nanoparticles. This review focuses on the use of molecular recognition chemistry to establish stable, ordered, and functional
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43

Yu, Raymond B., and Joselito P. Quirino. "Chiral Selectors in Capillary Electrophoresis: Trends During 2017–2018." Molecules 24, no. 6 (2019): 1135. http://dx.doi.org/10.3390/molecules24061135.

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Chiral separation is an important process in the chemical and pharmaceutical industries. From the analytical chemistry perspective, chiral separation is required for assessing the fit-for-purpose and the safety of chemical products. Capillary electrophoresis, in the electrokinetic chromatography mode is an established analytical technique for chiral separations. A water-soluble chiral selector is typically used. This review therefore examines the use of various chiral selectors in electrokinetic chromatography during 2017–2018. The chiral selectors were both low and high (macromolecules) molec
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44

Resnati, Giuseppe, Elena Boldyreva, Petra Bombicz, and Masaki Kawano. "Supramolecular interactions in the solid state." IUCrJ 2, no. 6 (2015): 675–90. http://dx.doi.org/10.1107/s2052252515014608.

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In the last few decades, supramolecular chemistry has been at the forefront of chemical research, with the aim of understanding chemistry beyond the covalent bond. Since the long-range periodicity in crystals is a product of the directionally specific short-range intermolecular interactions that are responsible for molecular assembly, analysis of crystalline solids provides a primary means to investigate intermolecular interactions and recognition phenomena. This article discusses some areas of contemporary research involving supramolecular interactions in the solid state. The topics covered a
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45

LEHN, J. M. "ChemInform Abstract: Perspectives in Supramolecular Chemistry. From Molecular Recognition Towards Molecular Information Processing and Selforganization." ChemInform 23, no. 48 (2010): no. http://dx.doi.org/10.1002/chin.199248329.

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46

Wan, Decheng, Hongting Pu, and Ming Jin. "Highly Specific Molecular Recognition by a Roughly Defined Supramolecular Nanocapsule: A Fuzzy Recognition Mechanism." Macromolecules 43, no. 8 (2010): 3809–16. http://dx.doi.org/10.1021/ma100181f.

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47

Aldaye, Faisal A., and Hanadi F. Sleiman. "Supramolecular DNA nanotechnology." Pure and Applied Chemistry 81, no. 12 (2009): 2157–81. http://dx.doi.org/10.1351/pac-con-09-08-13.

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Nature uses deoxyribonucleic acid (DNA) as the main material for the storage and transmission of life’s blueprint. Today, DNA is being used as a “smart” material to help solve a number of long-standing issues facing researchers in materials science and nanotechnology. In DNA nanotechnology, DNA’s powerful base-pair molecular recognition criteria are utilized to control the final structure and function of the material being generated. A sub-area of research that our group has recently termed “supramolecular DNA nanotechnology” is emerging and is extending the limits of this molecule in nanotech
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48

Lu, Dairen, Yun Wang, Kang Tao, and Ruke Bai. "Synthesis of Amphiphilic Supramolecular Miktoarm Star Copolymers by Molecular Recognition." Macromolecular Rapid Communications 30, no. 2 (2009): 104–8. http://dx.doi.org/10.1002/marc.200800567.

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49

Mallon, Madeleine, Som Dutt, Thomas Schrader, and Peter B. Crowley. "Protein Camouflage: Supramolecular Anion Recognition by Ubiquitin." ChemBioChem 17, no. 8 (2016): 774–83. http://dx.doi.org/10.1002/cbic.201500477.

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50

Goshe, Andrew J., Ian M. Steele, and B. Bosnich. "Supramolecular recognition: association of palladium molecular clefts with planar platinum complexes." Inorganica Chimica Acta 357, no. 15 (2004): 4544–51. http://dx.doi.org/10.1016/j.ica.2004.06.037.

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