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Dissertations / Theses on the topic 'Supramolecular Compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 6 September 2023

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1

Gensler, Manuel. "Binding forces in metallo-supramolecular coordination compounds." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät, 2017. http://dx.doi.org/10.18452/17728.

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Multivalente Wechselwirkungen sind in diversen biomolekularen und supramolekularen Systemen anzutreffen. Gewöhnlich werden sie durch ihre thermische Stabilität charakterisiert. Doch auch das mechanische Reißverhalten ist relevant: Ein System mit großer Reißlänge (Verformbarkeit) weist zwar eine geringere Reißkraft auf, kann aber besser auf äußere Einflüsse ohne Bindungsbruch reagieren. Daher besteht ein zunehmendes Interesse an Modellen zur Vorhersage der mechanischen Stabilität multivalenter Wechselwirkungen. Einzelmolekül-Kraftspektroskopie (SMFS) ist eine nützliche Methode, um den Reißproze

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2

Lock, Julia. "Cyclodextrins : molecular wheels for supramolecular chemistry /." Title page, table of contents and abstract only, 2004. http://web4.library.adelaide.edu.au/theses/09PH/09phl8131.pdf.

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Thesis (Ph.D.)--University of Adelaide, School of Chemistry and Physics, Discipline of Chemistry, 2005?<br>"July 2004" Includes copies of publications by the author as appendix. Includes bibliographical references.

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3

BERTON, GIACOMO. "SYNTHESIS OF TRIPHENYLENES FOR SUPRAMOLECULAR APPLICATIONS." Doctoral thesis, Università degli Studi di Trieste, 2020. http://hdl.handle.net/11368/2969361.

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In this Doctoral Thesis, through several examples of new chemical modifications characterized by high yields and selectivities and new supramolecular structures, held together by a wide range of intermolecular forces forming several new host systems, we reached our target to revamp triphenylene and derivatives as a new molecular scaffold in supramolecular chemistry. More specifically, the introduction in our triphenylenic scaffold of alkyl thiol chains allowed the formation of sulphide and disulphide covalent cages, while by insertion of pyridine moieties through Mannich reaction it was possib

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4

Darawsheh, Mohanad D. "Spin crossover supramolecular coordination compounds: design, synthesis and properties." Doctoral thesis, Universitat de Barcelona, 2016. http://hdl.handle.net/10803/400859.

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The results obtained in this thesis demonstrate the importance of supramolecular chemistry for the design of potential new SCO clusters. Starting from synthesizing the suitable ligands with suitable functional groups, novel host-guest systems could be obtained where the guest play a major role in tuning the physical properties of the guest. Two bis-pyrazolylpyridine lignads, H2L4 and H2L6 were designed and prepared to achieve the assembly of transition metal ions in a triple-stranded helicate fashion where the central cavity can encapsulate different counterions depending on the size of thi

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5

Cho, Don Mark. "Partially fluorinated polycyclic aromatic compounds synthesis and supramolecular behavior /." Lexington, Ky. : [University of Kentucky Libraries], 2006. http://lib.uky.edu/ETD/ukychem2007t00544/Cho_thesis.pdf.

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Thesis (M.S.)--University of Kentucky, 2006.<br>Title from document title page (viewed on February 27, 2007). Document formatted into pages; contains: xiv, 69 p. : ill. (some col.). Includes abstract and vita. Includes bibliographical references (p. 64-68).

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6

Cho, Don Mark. "PARTIALLY FLUORINATED POLYCYCLIC AROMATIC COMPOUNDS: SYNTHESIS AND SUPRAMOLECULAR BEHAVIOR." UKnowledge, 2007. http://uknowledge.uky.edu/gradschool_theses/443.

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The field of organic electronics has received much attention over the last few years, and engineering of organic crystals to grow with pi-electron systems arranged in a face-to-face motif has been shown to be beneficial in electronic devices. The effects of combining aromatic and perfluorinated aromatic derivatives have shown that the intramolecular stacking pattern can be changed from an edge-to-face arrangement to that of a face-to-face motif. Before the work described herein, there were no reported studies of the supramolecular behavior of fused polycyclic aromatic compounds with partial pe

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7

Samsodien, Halima. "Supramolecular derivatives of selected bioactive compounds : a physicochemical study." Doctoral thesis, University of Cape Town, 2010. http://hdl.handle.net/11427/6360.

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Includes abstract.<br>Includes bibliographical references (p. 270-271).<br>The author’s objective was to prepare new solid phases of three bioactive compounds: the steroidal anticancer agent 2-methoxyestradiol [polymorphs and cyclodextrin (CD) inclusion complexes], its derivative 2-methoxyestradiol-bis-sulfamate (polymorphs), and the antiretroviral agent, nevirapine (co-crystals). The solubility and dissolution profiles of the three compounds and those of selected ‘supramolecularly-derived’ species were also assessed. Three distinct phases of 2-methoxyestradiol (2ME) were successfully isolated

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8

Lorenzo, Susan Chemistry Faculty of Science UNSW. "The supramolecular chemistry of cucurbituril molecules." Awarded by:University of New South Wales. School of Chemistry, 2006. http://handle.unsw.edu.au/1959.4/26990.

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The set of molecules cucurbit[n]uril (Qn) are macrocycles composed of n glycoluril monomers linked by methylene groups. These molecules have two oxygen-ringed portals of a diameter slightly smaller than their internal cavity diameter. This thesis describes syntheses, crystallisations, crystal structure determinations, crystal packing analyses and force field calculations exploring the supramolecular chemistry of Qn molecules and their derivatives. Qn acts as a host for guest molecules and at the outset of this project no metal containing molecule had been encapsulated in a Qn molecule. One aim

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9

Morales, Leslie Ann. "Crystal Engineering of Binary Compounds Containing Pharmaceutical Molecules." [Tampa, Fla.] : University of South Florida, 2003. http://purl.fcla.edu/fcla/etd/SFE0000166.

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10

Bis, Joanna A. "Crystal engineering of organic compounds including pharmaceuticals." [Tampa, Fla] : University of South Florida, 2006. http://purl.fcla.edu/usf/dc/et/SFE0001424.

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11

Larkin, Scott A. "Synthesis and Supermolecular Chemistry of Biphenylthioatogold(I)Phosphine Complexes." Fogler Library, University of Maine, 2007. http://www.library.umaine.edu/theses/pdf/LarkinSA2007.pdf.

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12

He, Xiaoming. "Design, synthesis and characterization of alkynyl- and thiolato- gold (I) complexes with various receptor groups for host-guest chemistry." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43571979.

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13

Archer, Rosanna Juliet. "The Effects of Supramolecular Interactions on Iron(II) Spin Crossover Compounds." Thesis, University of Canterbury. Chemistry, 2013. http://hdl.handle.net/10092/9053.

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Molecules with functional properties, especially ones that display spin crossover behaviour, are becoming increasingly well researched due to their potential applications as the active components in molecular memory, optical displays or sensors.1,2 To this end, a series of Fe(II) coordination compounds utilising imidazolylimine and pyridylimine based ligands have been synthesised and their spin crossover behaviour analysed through a variety of techniques including variable temperature X-ray crystallography, magnetic susceptibility, surface reflectivity and UV-Visible spectroscopy. Light-Induce

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14

Freeman, James D. "Amino acid ligand mimics : synthons for supramolecular self-assembled coordination compounds." Thesis, University of East Anglia, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.398796.

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15

Watson, Walter Philip. "Hybrid Macrocycles for Supramolecular Assemblies." Diss., Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/6958.

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Hybrid macrocycles, which chimerically integrate multiple chemical compositions and architectures, provide an effective way to impart new properties to polymers that are not found in their linear or homocyclic analogues. This dissertation addresses the incorporation of hydrophilic blocks into hydrophobic polymer, as either a poly(dimethyl siloxane)-block-poly(oxyethylene) (PDMS-POE) tadpole with a hydrophobic head and a hydrophilic tail or as a diblock poly(styrene)-block-diethylene glycol (PS-DEG) hydrophobic-hydrophilic macrocycle. The supramolecular association properties of both kinds of

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16

Zhang, Jingjing, and 张晶晶. "The anti-cancer properties of cyclometalated gold(III) complexes and organogold(III) supramolecular polymers." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/208171.

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Prompted by the successful clinical application of cisplatin in cancer therapy, worldwide efforts have been devoted to develop new metal-based drugs for anticancer treatment. Gold(III) complexes at first received attention as anti-cancer drug candidates because of their square-planar geometry which resembles that of platinum(II) complexes. Subsequent studies revealed that various gold(III) complexes displayed promising anti-cancer activities with different biological mechanisms. Although some achievements have been obtained in the development of anti-cancer gold(III) complexes, challenges incl

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17

Pitt, Melanie A. "Main group supramolecular coordination chemistry : design strategies and dynamic assemblies /." Connect to title online (Scholars' Bank) Connect to title online (ProQuest), 2009. http://hdl.handle.net/1794/10287.

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18

Lo, Hiu-suet. "Design and syntheses of luminescent alkynyl complexes containing multinuclear platinum (II) and coinage metal centres from photophysics to host-guest chemistry and supramolecular architectures /." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B41633714.

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19

Lafuente, Fabra Maria. "Study and applications of dynamic chemical networks of pseudopeptidic compounds." Doctoral thesis, Universitat de Barcelona, 2018. http://hdl.handle.net/10803/663060.

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The present research project can be included in the broad supramolecular chemistry field that was defined by Nobel laureate Jean Marie Lehn as the "chemistry beyond the molecule".1 It is based on processes of molecular assembly through intermolecular forces and it has allowed synthesizing fascinating architectures with very important applications in Biology, Material Science and Catalysis. Our project is specifically defined within the dynamic combinatorial chemistry that has emerged as an important methodology for the generation of new molecules formed by reversible reactions of simple "Build

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20

Huang, Qiao Xian. "Supramolecular encapsulation of polycation by cucurbit[7]uril and their biomedical applications." Thesis, University of Macau, 2018. http://umaclib3.umac.mo/record=b3952135.

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21

Forbes, Safiyyah. "Hydrogen-bond driven supramolecular chemistry for modulating physical properties of pharmaceutical compounds." Diss., Manhattan, Kan. : Kansas State University, 2010. http://hdl.handle.net/2097/3756.

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22

Yip, Sung-kong. "Design, synthesis, characterization and luminescence properties of alkynylgold(I) complexes strategies towards supramolecular architectures and host guest chemistry /." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B31941734.

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23

Vine, Tracy Anne. "Novel approaches towards metallocene-based molecular boxes." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295611.

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24

Hui, Chi-kuen, and 許志權. "Design and synthesis of novel classes of alkynyl-containing platinum (II) complexes as building blocks for supramolecular assemblies andhost-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B31244257.

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25

He, Xiaoming, and 何晓明. "Design, synthesis and characterization of alkynyl- and thiolato-gold (I) complexes with various receptor groups for host-guestchemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B43571979.

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26

Lam, Siu-tung, and 林肇東. "Design and syntheses of alkynylrhenium (I) tricarbonyl diimine complexes: from luminescence to metallogelformation, chemosensing, molecular architecture and light-harvesting." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45826766.

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27

Lai, Siu-wai. "Luminescent organoplatinum chemistry : photophysical and supramolecular properties of metallacyclic and polypyridine platinum(II) complexes /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B20792943.

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28

Tangouna, Liambo Bissa Marie-Louise. "Host-guest compounds : structure and thermal behaviour." Thesis, Cape Peninsula University of Technology, 2016. http://hdl.handle.net/20.500.11838/2442.

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Thesis (MTech (Chemistry))--Cape Peninsula University of Technology, 2016.<br>Inclusion compounds of two hydroxyl hosts with a variety of guests have been investigated. These host compounds are bulky molecules and have the ability to interact with smaller organic guests to form new compounds. The host 9-(1-naphthyl)-9H-xanthen-9-ol (H1), forms inclusion compounds with pyridine (PYR), N,N-dimethylacetamide (DMA), morpholine (MORP) and N-methyl-2-pyrrolidinone (NMP). The crystal structures of H1•NMP, H1•DMA and H1•MORP1 were successfully solved in the triclinic space group PĪ, whereas the inclus

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29

Morita, Tomoyuki. "Photoinduced Electron Transfer in Supramolecular Thin Films Composed of N-Ethylcarbazole-Containing Compounds." Kyoto University, 1999. http://hdl.handle.net/2433/77930.

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30

Piana, Francesca. "Urea-based supramolecular gelators : molecular structure-gelation relationship and sensing of organophosphorus compounds." Thesis, University of Southampton, 2015. https://eprints.soton.ac.uk/387350/.

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The aim of this thesis was to study the phenomenon of supramolecular gelation of urea-based gelators and their application as sensors for neutral organophosphorus species such as nerve agents. The work was therefore naturally divided into two major parts. The first part consisted in an investigation of the structure-gelation relationship of a series of urea gelators, in an effort to overcome the serendipitous approach that is widely applied to their discovery. Among the components of the common gelator scaffold that were optimised to deliver the best gelation performance, particular attention

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31

Yuen, Mai-yan, and 袁美恩. "Semiconducting and electroluminescent cyclometalated platinum (II) complexes: from molecular functionalmaterials to supramolecular architecture and self-assemblednanomaterials." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B44758121.

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32

Au, Ka-man, and 區嘉雯. "Luminescent cyclometalated gold (III) complexes with ancillary N-heterocyclic carbene and alkynyl ligands : from design, synthesis, photophysics to supramolecular assembly and functions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hdl.handle.net/10722/207995.

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A library of luminescent cyclometalated gold(III) complexes containing various bis-cyclometalating R-C^N^C ligands derived from 2,6-diphenylpyridine and ancillary alkynyl ligands, [Au(R-C^N^C)(C≡CR’)], has been synthesized. Some of the complexes have been structurally determined by X-ray crystallography. These complexes were found to exhibit intense emission in dichloromethane solution at 298 K, originating from metal-perturbed triplet intraligand (IL) excited states of the R-C^N^C ligand, with substantial charge transfer character from the aryl moiety to the pyridyl ring. In the presen

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33

Lai, Siu-wai, and 黎小慧. "Luminescent organoplatinum chemistry: photophysical and supramolecular properties of metallacyclic andpolypyridine platinum(II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31238737.

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34

Tang, Hau-san. "Design and synthesis of metal phosphine complexes of palladium(II) and gold(I) with various receptor ligands for ion-controlled or photoresponsive host-guest chemistry." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B37877422.

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35

Lo, Hiu-suet, and 盧曉雪. "Design and syntheses of luminescent alkynyl complexes containing multinuclear platinum (II) and coinage metal centres: from photophysics to host-guest chemistry andsupramolecular architectures." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B41633714.

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36

Lee, Kwok-ming, and 李國明. "Synthesis, characterization and photophysical properties of chalcogenido, phosphinidene and alkynyl complexes of gold (I) and itscongener and their supramolecular assembly arising from metal--metalinteractions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B45983422.

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37

Coombes, Matthew. "A Comparative study of two copper(II) based metal-organic frameworks : Cu2¼(OH)½B4C•8H2O and Cu2Na(OH)B4C•7H2O." Thesis, Rhodes University, 2013. http://hdl.handle.net/10962/d1016245.

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This study focussed on two copper(II)-containing metal-organic frameworks (MOFs): Cu2Na(OH)B4C•7H2O and Cu2¼(OH)½B4C•8H2O (B4C = 1,2,4,5- benzenetetracarboxylate). They are both covalent, three-dimensional metalorganic framework polymers containing voids filled with water molecules. Both were characterised by elemental analysis, infrared spectroscopy, X-ray powder diffractometry (both in situ and regular), thermogravimetric analysis, differential scanning calorimetry and X-ray photoelectron spectroscopy. These two MOFs are essentially identical, with the only difference being the substitution

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38

Groeneman, Ryan H. "Investigating the inclusion chemistry of multi-dimensional coordiation polymers /." free to MU campus, to others for purchase, 2000. http://wwwlib.umi.com/cr/mo/fullcit?p9999289.

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39

Tam, Yiu-yan. "Design, synthesis and functionalization of luminescent alkynylplatinum(II) complexes of tridentate N-donor ligands as building blocks for metallogelation and supramolecular assembly." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B43223849.

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40

Tam, Yiu-yan, and 譚耀欣. "Design, synthesis and functionalization of luminescentalkynylplatinum(II) complexes of tridentate N-donor ligands asbuilding blocks for metallogelation and supramolecular assembly." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B43223849.

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41

Guo, Jianping. "Synthesis, structure and characterization of long distance electrostatic force and hydrogen bond supramolecular polymers synthesis, structure and characterization of bis[2,4-di(pyridyl)-1,3,5-triazapenta-dienato] metal complexes." HKBU Institutional Repository, 2004. http://repository.hkbu.edu.hk/etd_ra/506.

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42

Chen, Junpeng. "Enzymatic formation of supramolecular hydrogels based on self-assembly of DNA derivatives." Waltham, Mass. : Brandeis University, 2009. http://dcoll.brandeis.edu/handle/10192/23323.

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43

Ivy, Joshua F. "Optoelectronically Active Metal-Inorganic Frameworks and Supramolecular Extended Solids." Thesis, University of North Texas, 2018. https://digital.library.unt.edu/ark:/67531/metadc1248495/.

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Metal-organic frameworks (MOFs) have been intensely researched over the past 20 years. In this dissertation, metal-inorganic frameworks (MIFs), a new class of porous and nonporous materials using inorganic complexes as linkers, in lieu of traditional organic linkers in MOFs is reported. Besides novel MIF regimes, the previously described fluorous MOF "FMOF-1", is re-categorized herein as "F-MIF1". F-MIF-1 is comprised of [Ag4Tz6]2- (Tz = 3,5-bis-trifluoromethyl-1,2,4-triazolate) inorganic clusters connected by 3-coordinate Ag+ metal centers. Chapter 2 describes isosteric heat of adsorption stu

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44

Wood, Evan Alexander. "Designing hypercyclic replicating networks /." St Andrews, 2007. http://hdl.handle.net/10023/360.

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45

Lee, Eun-ju. "The study of molecular assemblies formed via non-covalent interactions between calixarenes /." free to MU campus, to others for purchase, 2003. http://wwwlib.umi.com/cr/mo/fullcit?p1418042.

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46

Kang, Xu. "Supramolecular modification of commonly used photoactive drugs regarding their photochemistry, stability, and safety." University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1626456443488287.

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47

Zhao, Tiejun. "NMR pulse sequence development and studies of threaded macromolecules." Diss., Available online, Georgia Institute of Technology, 2004:, 2004. http://etd.gatech.edu/theses/available/etd-06072004-131430/unrestricted/zhao%5Ftiejun%5F200405%5Fphd.pdf.

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48

Tang, Hau-san, and 鄧巧珊. "Design and synthesis of metal phosphine complexes of palladium(II) andgold(I) with various receptor ligands for ion-controlled orphotoresponsive host-guest chemistry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B37877422.

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49

Pi, i. Boleda Bernat. "Supramolecular studies on the behaviour of different chiral cycloalkane-based compounds as receptors, gelators and surfactants." Doctoral thesis, Universitat Autònoma de Barcelona, 2016. http://hdl.handle.net/10803/400575.

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En aquesta tesi, s’han estudiat quatre diferent sistemes supramoleculars com a receptors, gelificadors o tensioactius. S’ha analitzat la influència de diferents factors estructurals de la molècula senzilla en la seva propietat supramolecular final. S’han utilitzat diferents estratègies per a preparar els compostos estudiats. La combinació de diferents tècniques ens ha permès entendre millor aquests sistemes obtenint un resultat sinèrgic. Els resultats d’aquesta tesi estan dividits en quatre capítols: 1) Diferents receptors d’anions tripodals s’han sintetitzat i la seva complexació amb difer

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50

Rota, Martir Diego. "Chiral iridium(III) and ruthenium(II) complexes as phosphorescent scaffolds for heterometallic supramolecular self-assembly." Thesis, University of St Andrews, 2018. http://hdl.handle.net/10023/14555.

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This thesis explores the design, synthesis and optoelectronic properties of supramolecular photoactive materials based on chiral iridium(III) and ruthenium(II) metalloligands. Our design strategies aim to create a high concentration of chromophoric units that, when self-assembled in well-defined geometrical arrangements, exhibit emergent photophysical properties.

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