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Journal articles on the topic 'Surface structure, reactivity and catalysis'

Author: Grafiati

Published: 17 September 2021

Last updated: 30 July 2025

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1

KIM, D. "Surface structure and reactivity of CrO3/SiO2 catalysts." Journal of Catalysis 136, no. 1 (1992): 209–21. http://dx.doi.org/10.1016/0021-9517(92)90120-7.

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2

Kim, Do Gun, Seong Won Im, Kyung Hwan Ryu, Seoung Ho Jo, Min Gyeong Choe, and Seok Oh Ko. "Dependency of Catalytic Reactivity on the Characteristics of Expanded Graphites as Representatives of Carbonaceous Materials." Molecules 30, no. 11 (2025): 2275. https://doi.org/10.3390/molecules30112275.

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Carbonaceous materials (CMs) have gained great attention as heterogeneous catalysts in water treatment because of their high efficiency and potential contribution to achieving carbon neutrality. Expanded graphite (EG) is ideal for studying CMs because the reactivity in CMs largely depends on graphitic structures, and most surface of EG is exposed, minimizing mass transfer resistance. However, EG is poor in adsorption and catalysis. In this study, EG was modified by simple thermal treatment to investigate the effects of characteristics of graphitic structures on reactivity. Tetracycline (TC) re

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3

Wu, Zhiyi, Jiahui Shen, Chaoran Li, et al. "Niche Applications of MXene Materials in Photothermal Catalysis." Chemistry 5, no. 1 (2023): 492–510. http://dx.doi.org/10.3390/chemistry5010036.

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MXene materials have found emerging applications as catalysts for chemical reactions due to their intriguing physical and chemical applications. In particular, their broad light response and strong photothermal conversion capabilities are likely to render MXenes promising candidates for photothermal catalysis, which is drawing increasing attention in both academic research and industrial applications. MXenes are likely to satisfy all three criteria of a desirable photothermal catalyst: strong light absorption, effective heat management, and versatile surface reactivity. However, their specific

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4

Herrero, Enrique, Pepe Jordá-Faus, Rubén Rizo, and Rosa Aran-Ais. "(Invited) Understanding the Oxygen Reduction Reaction on PtPd Single-Crystal Electrodes: The Role of Surface Structure and Composition." ECS Meeting Abstracts MA2025-01, no. 55 (2025): 2666. https://doi.org/10.1149/ma2025-01552666mtgabs.

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The oxygen reduction reaction (ORR) is critical for energy conversion technologies, and its efficiency depends strongly on the electrocatalyst's surface structure and composition. In this study, well-defined PtPd single-crystal electrodes were employed to investigate the influence of surface orientation and Pd incorporation on ORR catalysis in both HClO4 (acidic) and NaOH (alkaline) solutions. Voltammetric analysis in the supporting electrolyte revealed that the addition of Pd alters the adsorption strength of hydroxyl (OH) species, with this effect varying depending on the surface orientation

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5

Derouane, EricG. "Studies in surface science and catalysis, volume 48 structure and reactivity of surfaces." Journal of Molecular Catalysis 60, no. 1 (1990): 136–37. http://dx.doi.org/10.1016/0304-5102(90)85076-t.

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6

Trudeau, M. L., and J. Y. Ying. "Nanocrystalline materials in catalysis and electrocatalysis: Structure tailoring and surface reactivity." Nanostructured Materials 7, no. 1-2 (1996): 245–58. http://dx.doi.org/10.1016/0965-9773(95)00308-8.

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7

Morankar, Ankita, Siddharth Deshpande, Gaurav Deshmukh, Pushkar Ghanekar, Zhenhua Zeng, and Jeffrey Greeley. "(Invited) First Principles Treatments of Heterogeneous Electrocatalysis – Reactivity Trends and Electrocatalyst Structure." ECS Meeting Abstracts MA2024-01, no. 45 (2024): 2553. http://dx.doi.org/10.1149/ma2024-01452553mtgabs.

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Advances in the theoretical understanding of electrochemical systems have, over the past decade, led to growing use of periodic Density Functional Theory studies to treat a surprisingly large ensemble of electrocatalytic reactions, ranging from carbon dioxide electroreduction to oxygen evolution. Many such studies have employed simplified models of the electrochemical environment to determine reactivity trends across a broad space of catalytic materials, while other efforts have focused on developing detailed descriptions of electrochemical phenomena, such as the structure of electrochemical d

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8

Légaré, Pierre, Gabriela F. Cabeza, and Norberto J. Castellani. "Atomic and electronic structure dependence of surface chemical reactivity." Catalysis Today 89, no. 3 (2004): 363–68. http://dx.doi.org/10.1016/j.cattod.2003.12.009.

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9

Šutka, Anna, Andris Šutka, Mārtiņš Vanags, et al. "Identifying Iron-Bearing Nanoparticle Precursor for Thermal Transformation into the Highly Active Hematite Photo-Fenton Catalyst." Catalysts 10, no. 7 (2020): 778. http://dx.doi.org/10.3390/catal10070778.

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The hematite photo-Fenton catalysis has attracted increasing attention because it offers strong oxidation of organic pollutants under visible light at neutral pH. In the present work, aqueous synthesis of hematite photo-Fenton catalysts with high activity is demonstrated. We compare photo-Fenton activity for hematite obtained by hydrolyzation at 60 °C or by a thermally induced transformation from iron-bearing nanoparticles, such as amorphous iron oxyhydroxide or goethite. A link between their structure and visible light photo-Fenton reactivity is established. The highest activity was observed

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10

Sun, Qian, Chun Zeng, Meng-Meng Xing, et al. "Efficiently Engineering Cu-Based Oxide by Surface Embedding of Ce for Selective Catalytic Reduction of NO with NH3." Nano 14, no. 06 (2019): 1950079. http://dx.doi.org/10.1142/s1793292019500796.

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Deliberately engineering oxide composites on constructing and manipulating interactive structures particularly in surface layers was highly desirable for heterogeneous catalysis. Herein, upon the redox replacement reaction between Ce(IV) precursor (Ce(NO[Formula: see text] and Cu2O nano-substrate, an attempt to directly engineer the surface structure of Cu-based substrate was performed by the Ce(IV)–Cu2O etching-embedding process, then the obtained powders were thermo-treated to get a series of Ce–O–Cu catalysts with different Ce:Cu molar ratios for NH3 selective catalytic reduction (NH3-SCR)

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11

Nematollahi, Parisa, Mehdi D. Esrafili, and Amin Bagheri. "Functionalization of single-walled (n,0) carbon and boron nitride nanotubes by carbonyl derivatives (n = 5, 6): a DFT study." Canadian Journal of Chemistry 94, no. 1 (2016): 105–11. http://dx.doi.org/10.1139/cjc-2015-0334.

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By using density functional theory calculations, the chemical functionalization of finite-sized (5,0) and (6,0) carbon nanotubes (CNTs) and boron nitride nanotubes (BNNTs) by different carbonyl derivatives –COX (X = H, CH3, OCH3, OH, and NH2) is studied in terms of geometrical and electronic structure properties. Also, the benefits of local reactivity descriptors is studied to characterize the reactive sites of the external surface of the tubes. These local reactivity descriptors include the electrostatic potential VS(r) and average local ionization energy ĪS(r) on the surfaces of these nanotu

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12

Woo, Ho K., R. Srinivasan, L. Rice, P. J. Reucroft, and R. J. De Angelis. "Reactivity and structure of nickel-cobalt bimetallic catalysts." Proceedings, annual meeting, Electron Microscopy Society of America 46 (1988): 698–99. http://dx.doi.org/10.1017/s0424820100105552.

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Ni and Co catalyst systems have been extensively dealt with in the catalyst research literature but investigations on Ni/Co alloy systems have been relatively sparse. An early study attempted to correlate catalysed hydrogenation activity with metal/alloy lattice parameter. Matsuyama et al. investigated catalytic hydrogenation of ethylene by nickel alloys as a function of surface and bulk composition. The activity increased as the proportion of Ni increased but decreased from 90 to 100%Ni. A study has been initiated to relate catalytic activity to the structure of Ni/Co bimetallic catalyst part

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13

Zhang, Yu, Dongdong Feng, Yijun Zhao, et al. "Evolution of Char Structure During In-Situ Biomass Tar Reforming: Importance of the Coupling Effect Among the Physical-Chemical Structure of Char-Based Catalysts." Catalysts 9, no. 9 (2019): 711. http://dx.doi.org/10.3390/catal9090711.

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In order to illustrate the importance of a coupling effect in the physical-chemical structure of char-based catalysts on in-situ biomass tar reforming, three typical char-based catalysts (graphite, Zhundong coal char, and sawdust biochar) were studied in the fixed-bed/fluidized-bed reactor. The physical-chemical properties of carbon-based catalysts associated with their catalytic abilities were characterized by inductively coupled plasma-atomic emission spectroscopy (ICP-AES), Raman, X-ray photoelectron spectroscopy (XPS), scanning electron microscope–energy dispersive spectrometer (SEM-EDS) a

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14

Grinter, David C., and Geoff Thornton. "Structure and reactivity of model CeO₂ surfaces." Journal of Physics: Condensed Matter 34, no. 25 (2022): 253001. http://dx.doi.org/10.1088/1361-648x/ac5d89.

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Abstract As a key component in many industrial heterogeneous catalysts, the surface structure and reactivity of ceria, CeO2, has attracted a lot of attention. In this topical review we discuss some of the approaches taken to form a deeper understanding of the surface physics and chemistry of this important and interesting material. In particular, we focus on the preparation of ultrathin ceria films, nanostructures and supported metal nanoparticles. Cutting-edge microscopic and spectroscopic experimental techniques are highlighted which can probe the behaviour of oxygen species and atomic defec

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15

TRUDEAU, M. L., and J. Y. YING. "ChemInform Abstract: Nanocrystalline Materials in Catalysis and Electrocatalysis: Structure Tailoring and Surface Reactivity." ChemInform 27, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.199625269.

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16

Sun, Kewei, Aixi Chen, Meizhuang Liu, et al. "Surface-Assisted Alkane Polymerization: Investigation on Structure–Reactivity Relationship." Journal of the American Chemical Society 140, no. 14 (2018): 4820–25. http://dx.doi.org/10.1021/jacs.7b09097.

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17

Stettner, Jochim, Tim Wiegmann, Canrong Qiu, et al. "Operando Surface X-Ray Diffraction Studies of Co Oxide Catalyst Films for Electrochemical Water Splitting." ECS Meeting Abstracts MA2023-02, no. 55 (2023): 2697. http://dx.doi.org/10.1149/ma2023-02552697mtgabs.

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The need for environmental friendly and sustainable energy conversion has triggered renewed interest into the electrochemical and photoelectrochemical splitting of water. A key challenge in this field is the development of economically viable electrocatalyst materials for the oxygen evolution reaction (OER). Transition-metal oxide catalysts, in particular the cobalt (hydr)oxide materials, have been found as promising candidates, since they are earth-abundant, efficient and scalable over a wide range of electrochemical conditions [1]. They present good catalytic properties and stability in alka

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18

Shipilin, M., E. Lundgren, J. Gustafson, et al. "Fe Oxides on Ag Surfaces: Structure and Reactivity." Topics in Catalysis 60, no. 6-7 (2016): 492–502. http://dx.doi.org/10.1007/s11244-016-0714-8.

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Abstract One layer thick iron oxide films are attractive from both applied and fundamental science perspectives. The structural and chemical properties of these systems can be tuned by changing the substrate, making them promising materials for heterogeneous catalysis. In the present work, we investigate the structure of FeO(111) monolayer films grown on Ag(100) and Ag(111) substrates by means of microscopy and diffraction techniques and compare it with the structure of FeO(111) grown on other substrates reported in literature. We also study the NO adsorption properties of FeO(111)/Ag(100) and

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19

Arshad, Malik Waqar, Dong Hun Kim, Young-Woo You, Soo Min Kim, Iljeong Heo, and Seok Ki Kim. "A first-principles understanding of the CO-assisted NO reduction on the IrRu/Al2O3 catalyst under O2-rich conditions." Catalysis Science & Technology 11, no. 13 (2021): 4353–66. http://dx.doi.org/10.1039/d1cy00744k.

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The IrRu alloy offered optimal energetics for NO reduction by CO. The ensemble effect plays a key role in promoting the reactivity of the IrRu alloy. Making the IrRu surface alloy is better for CO-SCR than forming an alloy over the bulk structure.

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20

Asl, Shahab Khameneh. "Photocatalytic Activity of the Modified Coupled Semiconductors and Its Relationship with Surface Properties." Nanoscience & Nanotechnology-Asia 9, no. 3 (2019): 337–43. http://dx.doi.org/10.2174/2210681208666180913132329.

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Background: In photocatalysis and surface chemistry, charge trapping extends the lifetime of photogenerated electrons and holes and decreases their recombination rate. The stable surface of crystals with lowest energy is (110) for rutile and (101), (010) or (100) for anatase. When these surfaces are exposed to simple molecules such as water, oxygen or methane, different reactions can occur. In this paper, the activity and mechanism of dye adsorption were studied and demonstrated significant increase in the resulting photo-catalysis with optimizing surface properties for the first time. Methods

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21

Esrafili, Mehdi D. "A DFT study on electronic structure and local reactivity descriptors of pristine and carbon-substituted AlN nanotubes." Canadian Journal of Chemistry 91, no. 8 (2013): 711–17. http://dx.doi.org/10.1139/cjc-2013-0103.

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A density functional theory study was carried out to investigate the structural and electronic structure properties of pristine and carbon-substituted (6,0) aluminum nitride nanotubes (AlNNTs). We examine the usefulness of local reactivity descriptors to predict the reactivity of AlN atomic sites on the external surface of the tubes. The properties determined include the Fukui function f(k) and local softness s(k) on the surfaces of the investigated tubes. According to the values of f(k) and s(k) for the pristine AlNNT, the aluminum atoms are highly preferred sites for nucleophile addition. Mo

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22

Giocondi, Jennifer L., and Gregory S. Rohrer. "The Influence of Surface Termination and Domain Structure on the Photochemical Reactivity of SrTiO3 and BaTiO3." Microscopy and Microanalysis 7, S2 (2001): 1062–63. http://dx.doi.org/10.1017/s143192760003138x.

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The crystallographic orientation and atomic termination layer of oxide catalysts are known to influence their reactivity. The objective of this work was to measure how the relative photochemical reactivities of two ternary titanates vary with surface orientation and composition. The surface structure property relationships derived from these observations can be used to define optimized photocatalyst microstructures.To measure the relative reactivity of surfaces with different orientations, crystallites (∽ 20 μm in diameter) in a polycrystalline ceramic were examined individually. First, polycr

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23

Schmal, Martin, and Hans-Joachim Freund. "Towards an atomic level understanding of niobia based catalysts and catalysis by combining the science of catalysis with surface science." Anais da Academia Brasileira de Ciências 81, no. 2 (2009): 297–318. http://dx.doi.org/10.1590/s0001-37652009000200016.

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The science of catalysis and surface science have developed, independently, key information for understanding catalytic processes. One might argue: is there anything fundamental to be discovered through the interplay between catalysis and surface science? Real catalysts of monometallic and bimetallic Co/Nb2O5 and Pd-Co/Nb2O5 catalysts showed interesting selectivity results on the Fischer-Tropsch synthesis (Noronha et al. 1996, Rosenir et al. 1993). The presence of a noble metal increased the C+5 selectivity and decreased the methane formation depending of the reduction temperature. Model catal

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24

Taudul, Beata, Frederik Tielens, and Monica Calatayud. "On the Origin of Raman Activity in Anatase TiO2 (Nano)Materials: An Ab Initio Investigation of Surface and Size Effects." Nanomaterials 13, no. 12 (2023): 1856. http://dx.doi.org/10.3390/nano13121856.

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Titania-based materials are abundant in technological applications, as well as everyday products; however, many of its structure–property relationships are still unclear. In particular, its surface reactivity on the nanoscale has important consequences for fields such as nanotoxicity or (photo)catalysis. Raman spectroscopy has been used to characterize titania-based (nano)material surfaces, mainly based on empirical peak assignments. In the present work, we address the structural features responsible for the Raman spectra of pure, stoichiometric TiO2 materials from a theoretical characterizati

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25

A.D. "Studies in Surface Science and Catalysis, Vol. 18, Structure and Reactivity of Modified Zeolites." Journal of Molecular Structure 127, no. 3-4 (1985): 385–86. http://dx.doi.org/10.1016/0022-2860(85)80024-7.

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26

Ishikawa, Shinji, Shoei Tsuji, and Yasuhiko Sawaki. "Structure and reactivity of nitroso oxides." Journal of the American Chemical Society 113, no. 11 (1991): 4282–88. http://dx.doi.org/10.1021/ja00011a035.

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27

McKillop, Kristen L., Gregory R. Gillette, Douglas R. Powell, and Robert West. "1,2-Disiladioxetanes: structure, rearrangement and reactivity." Journal of the American Chemical Society 114, no. 13 (1992): 5203–8. http://dx.doi.org/10.1021/ja00039a035.

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28

Nie, Junfang, and Haichao Liu. "Aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran on supported vanadium oxide catalysts: Structural effect and reaction mechanism." Pure and Applied Chemistry 84, no. 3 (2011): 765–77. http://dx.doi.org/10.1351/pac-con-11-07-02.

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The structure–activity relationship and reaction mechanism for selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) in toluene were studied on vanadium oxide domains on TiO2, Al2O3, Nb2O5, ZrO2, and MgO and with a wide range of VOx surface densities. The structures of these catalysts were characterized by X-ray diffraction (XRD), diffuse reflectance UV–vis spectroscopy (UV–vis DRS), and Raman spectroscopy, and their reducibility was probed by H2-temperature programmed reduction. The structures of the VOx domains evolved from monovanadate to polyvanadate structures wi

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29

Park, Jongmin, Hyo Seok Kim, Won Bo Lee, and Myung-June Park. "Trends and Outlook of Computational Chemistry and Microkinetic Modeling for Catalytic Synthesis of Methanol and DME." Catalysts 10, no. 6 (2020): 655. http://dx.doi.org/10.3390/catal10060655.

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The first-principle modeling of heterogeneous catalysts is a revolutionarily approach, as the electronic structure of a catalyst is closely related to its reactivity on the surface with reactant molecules. In the past, detailed reaction mechanisms could not be understood, however, computational chemistry has made it possible to analyze a specific elementary reaction of a reaction system. Microkinetic modeling is a powerful tool for investigating elementary reactions and reaction mechanisms for kinetics. Using a microkinetic model, the dominant pathways and rate-determining steps can be elucida

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30

DELMON, BERNARD. "MODIFICATION OF SURFACE STRUCTURE BY SPILLOVER SPECIES: CONSEQUENCES IN THE REACTION OF SOLIDS AND CATALYSIS." Surface Review and Letters 02, no. 01 (1995): 25–41. http://dx.doi.org/10.1142/s0218625x95000042.

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Transition metals can dissociate hydrogen to a surface mobile species called spillover hydrogen ( H so ). Similarly, oxides like α- Sb 2 O 4, BiPO 4, Bi 2 O 3 (donors) can dissociate molecular oxygen to a mobile surface species ( O so ). These metals or oxides are conveniently called donors. This article reviews effects which are due to spillover species when reacting with the surface of a solid distinct from the donors: (i) acceleration of the nucleation steps in the reduction of oxides, (ii) control of the nature of active sites on sulfides (e.g., MoS 2), and (iii) control of the adequate ox

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31

Yan, Juanzhu, Jun Zhang, Xumao Chen, et al. "Thiol-stabilized atomically precise, superatomic silver nanoparticles for catalysing cycloisomerization of alkynyl amines." National Science Review 5, no. 5 (2018): 694–702. http://dx.doi.org/10.1093/nsr/nwy034.

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Abstract Both the electronic and surface structures of metal nanomaterials play critical roles in determining their chemical properties. However, the non-molecular nature of conventional nanoparticles makes it extremely challenging to understand the molecular mechanism behind many of their unique electronic and surface properties. In this work, we report the synthesis, molecular and electronic structures of an atomically precise nanoparticle, [Ag206L72]q (L = thiolate, halide; q = charge). With a four-shell Ag7@Ag32@Ag77@Ag90 Ino-decahedral structure having a nearly perfect D5h symmetry, the m

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32

BERTOLINI, J. C. "LOCAL ORDER AT THE SURFACE OF BINARY ALLOYS IN RELATION TO THEIR CHEMICAL REACTIVITY." Surface Review and Letters 03, no. 05n06 (1996): 1857–68. http://dx.doi.org/10.1142/s0218625x96002783.

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The behavior of binary alloys with respect to catalysis can be understood in terms of the geometric “ensemble effect” and/or the electronic “ligand effect.” For understanding, one has consequently to know precisely the local concentration and arrangement of both components at the very surface (in contact with the reactants), and also in the sublayers which influence electronically the outer atoms. Two kinds of well-defined surface are considered: binary alloys and well-controlled deposits of a given metal on a foreign metallic substrate. After a brief description of the driving forces for surf

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33

Lichtenberg, Crispin. "Molecular bismuth(iii) monocations: structure, bonding, reactivity, and catalysis." Chemical Communications 57, no. 37 (2021): 4483–95. http://dx.doi.org/10.1039/d1cc01284c.

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34

Lv, Ze-Jie, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang, and Zhenfeng Xi. "Well-Defined Scandacyclopropenes: Synthesis, Structure, and Reactivity." Journal of the American Chemical Society 141, no. 51 (2019): 20547–55. http://dx.doi.org/10.1021/jacs.9b11631.

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35

Wu, Pengcheng, Glenn P. A. Yap, and Klaus H. Theopold. "Structure and Reactivity of Chromium(VI) Alkylidenes." Journal of the American Chemical Society 140, no. 23 (2018): 7088–91. http://dx.doi.org/10.1021/jacs.8b04882.

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36

Ishii, Takuya, Katsunori Suzuki, Taichi Nakamura, and Makoto Yamashita. "An Isolable Bismabenzene: Synthesis, Structure, and Reactivity." Journal of the American Chemical Society 138, no. 39 (2016): 12787–90. http://dx.doi.org/10.1021/jacs.6b08714.

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37

Houk, Janette, and George M. Whitesides. "Structure-reactivity relations for thiol-disulfide interchange." Journal of the American Chemical Society 109, no. 22 (1987): 6825–36. http://dx.doi.org/10.1021/ja00256a040.

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38

Segawa, Yasutomo, Yuta Suzuki, Makoto Yamashita, and Kyoko Nozaki. "Chemistry of Boryllithium: Synthesis, Structure, and Reactivity." Journal of the American Chemical Society 130, no. 47 (2008): 16069–79. http://dx.doi.org/10.1021/ja8057919.

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Yun, Sang Young, Mansuk Kim, Daesung Lee, and Donald J. Wink. "Structure and Reactivity of Alkynyl Ruthenium Alkylidenes." Journal of the American Chemical Society 131, no. 1 (2009): 24–25. http://dx.doi.org/10.1021/ja806218x.

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Segawa, Yasutomo, Yuta Suzuki, Makoto Yamashita, and Kyoko Nozaki. "Chemistry of Boryllithium: Synthesis, Structure, and Reactivity." Journal of the American Chemical Society 131, no. 27 (2009): 9600. http://dx.doi.org/10.1021/ja903763a.

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41

Jimenez, Juan D., Cun Wen, and Jochen Lauterbach. "Design of highly active cobalt catalysts for CO2 hydrogenation via the tailoring of surface orientation of nanostructures." Catalysis Science & Technology 9, no. 8 (2019): 1970–78. http://dx.doi.org/10.1039/c9cy00402e.

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42

Rabinovich, Daniel, and Gerard Parkin. "Hexakis(trimethylphosphine)tungsten(0): synthesis, structure, and reactivity." Journal of the American Chemical Society 112, no. 13 (1990): 5381–83. http://dx.doi.org/10.1021/ja00169a073.

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43

Barnes, Craig E., Jeffery A. Orvis, Donna L. Staley, Arnold L. Rheingold, and David C. Johnson. "Synthesis, structure, and reactivity of Cp3Co3(CO)2." Journal of the American Chemical Society 111, no. 13 (1989): 4992–94. http://dx.doi.org/10.1021/ja00195a070.

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44

Dube, Jonathan W., Yiying Zheng, Walter Thiel та Manuel Alcarazo. "α-Cationic Arsines: Synthesis, Structure, Reactivity, and Applications". Journal of the American Chemical Society 138, № 21 (2016): 6869–77. http://dx.doi.org/10.1021/jacs.6b03500.

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45

Staten, G. Joseph, Matthew K. Musho, and John J. Kozak. "Influence of structure on reaction efficiency in surface catalysis. 2. Reactivity at terraces, ledges, and kinks." Langmuir 1, no. 4 (1985): 443–52. http://dx.doi.org/10.1021/la00064a008.

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46

del Arco, Margarita, Cristina Martín, Vicente Rives, et al. "Surface structure and reactivity of molybdena–titania catalysts prepared by different methods." J. Chem. Soc., Faraday Trans. 89, no. 7 (1993): 1071–78. http://dx.doi.org/10.1039/ft9938901071.

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47

Yacob, Abdul Rahim, and Nur Fatin Sulaiman. "Hydration Dehydration Effect on Morphology and Basic Strength of Nano-Calcium Oxide." Advanced Materials Research 488-489 (March 2012): 967–71. http://dx.doi.org/10.4028/www.scientific.net/amr.488-489.967.

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Recently, attention has been given to base heterogeneous catalysis reactions and have attracted broad field of scientific researches. Alkaline earth metal oxide calcium oxide (CaO) having rock salt crystal structure, with surface defect and cavities are important for their basic catalytic reactivity. In this study CaO with high surface area and at nano level was prepared by hydration-dehydration method, calcined at various temperatures and of high vacuum of 10-3 mbar. The effect of thermal decomposition of the samples towards the morphology and chemical reactivity was characterized using Therm

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48

Shipilin, M., E. Lundgren, J. Gustafson, et al. "Erratum to: Fe Oxides on Ag Surfaces: Structure and Reactivity." Topics in Catalysis 63, no. 11-14 (2017): 1374. http://dx.doi.org/10.1007/s11244-017-0811-3.

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49

Mazur, Ursula, and K. W. Hipps. "Cooperativity at the Solution/Solid Interface: Formation and Reactivity of Self-Assembled Monolayers." ECS Meeting Abstracts MA2023-01, no. 15 (2023): 1438. http://dx.doi.org/10.1149/ma2023-01151438mtgabs.

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Abstract:

Cooperativity is a molecular phenomenon, in which multiple interactions participate synchronously to significantly affect the activity and/or selectivity of the interacting components by accelerating (or impeding) their chemical or physical processes. Cooperative effects are prevalent in biology and can be observed in chemistry and materials science. Synthesis of functional materials frequently requires surfaces and interfaces where cooperative interactions can propagate with substrate assistance. In this context, of great interest is the characterization and control of ligands binding to meta

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Zecchina, Adriano, and Carlos Otero Aréan. "Structure and Reactivity of Surface Species Obtained by Interaction of Organometallic Compounds with Oxidic Surfaces: IR Studies." Catalysis Reviews 35, no. 2 (1993): 261–317. http://dx.doi.org/10.1080/01614949308014607.

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