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Journal articles on the topic 'Suzuki polymerization'

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1

Tokita, Yu, Masaru Katoh, Kentaro Kosaka, Yoshihiro Ohta, and Tsutomu Yokozawa. "Precision synthesis of a fluorene-thiophene alternating copolymer by means of the Suzuki–Miyaura catalyst-transfer condensation polymerization: the importance of the position of an alkyl substituent on thiophene of the biaryl monomer to suppress disproportionation." Polymer Chemistry 12, no. 48 (2021): 7065–72. http://dx.doi.org/10.1039/d1py01184g.

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The Suzuki–Miyaura coupling polymerization of PinB-F8T(3)-Br was accompanied by disproportionation, whereas that of PinB-F8T(4)-Br proceeded in a chain-growth polymerization manner to afford a well-defined fluorene-thiophene alternating copolymer.
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2

Namgung, Ho, Jeong Jun Lee, Young Jin Gwon, and Taek Seung Lee. "Synthesis of tetraphenylethylene-based conjugated microporous polymers for detection of nitroaromatic explosive compounds." RSC Advances 8, no. 60 (2018): 34291–96. http://dx.doi.org/10.1039/c8ra06463f.

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3

Guo, Ting, Wenkai Zhong, Jianhua Zou, Lei Ying, Wei Yang, and Junbiao Peng. "Efficient binary white light-emitting polymers grafted with iridium complexes as side groups." RSC Advances 5, no. 109 (2015): 89888–94. http://dx.doi.org/10.1039/c5ra16717e.

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4

Dai, Chunhui, Dongliang Yang, Xiao Fu, et al. "A study on tunable AIE (AIEE) of boron ketoiminate-based conjugated polymers for live cell imaging." Polymer Chemistry 6, no. 28 (2015): 5070–76. http://dx.doi.org/10.1039/c5py00733j.

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5

Wang, Ziyu, Cheng Wang, Yayun Fang, Hong Yuan, Yiwu Quan, and Yixiang Cheng. "Color-tunable AIE-active conjugated polymer nanoparticles as drug carriers for self-indicating cancer therapy via intramolecular FRET mechanism." Polymer Chemistry 9, no. 23 (2018): 3205–14. http://dx.doi.org/10.1039/c8py00329g.

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6

Bautista, Michael V., Anthony J. Varni, Josué Ayuso-Carrillo, Matthew C. Carson, and Kevin J. T. Noonan. "Pairing Suzuki–Miyaura cross-coupling and catalyst transfer polymerization." Polymer Chemistry 12, no. 10 (2021): 1404–14. http://dx.doi.org/10.1039/d0py01507e.

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7

Yokozawa, Tsutomu, Yutaka Nanashima, Haruhiko Kohno, Ryosuke Suzuki, Masataka Nojima та Yoshihiro Ohta. "Catalyst-transfer condensation polymerization for precision synthesis of π-conjugated polymers". Pure and Applied Chemistry 85, № 3 (2012): 573–87. http://dx.doi.org/10.1351/pac-con-12-03-13.

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Catalyst-transfer condensation polymerization, in which the catalyst activates the polymer end-group, followed by reaction with the monomer and transfer of the catalyst to the elongated polymer end-group, has made it feasible to control the molecular weight, polydispersity, and end-groups of π-conjugated polymers. In this paper, our recent progress of Kumada–Tamao Ni catalyst-transfer coupling polymerization and Suzuki–Miyaura Pd catalyst-transfer coupling polymerization is described. In the former polymerization method, the polymerization of Grignard pyridine monomers was investigated for the
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8

Wang, Yunshu, Shuangshuang Zhang, Laibing Wang, et al. "The Suzuki coupling reaction as a post-polymerization modification: a promising protocol for construction of cyclic-brush and more complex polymers." Polymer Chemistry 6, no. 25 (2015): 4669–77. http://dx.doi.org/10.1039/c5py00551e.

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9

Wang, Haiqing, Dehui Sun, Qichen Lu, et al. "Bio-inspired synthesis of mesoporous HfO2 nanoframes as reactors for piezotronic polymerization and Suzuki coupling reactions." Nanoscale 11, no. 12 (2019): 5240–46. http://dx.doi.org/10.1039/c9nr00707e.

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Mesoporous HfO<sub>2</sub> nanoframes were elaborately fabricated, inspired by the flexible assembly principles in the biomolecules, and were demonstrated as nanoreactors for piezotronic polymerization and Suzuki coupling reactions.
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10

Sugita, Hajime, Masataka Nojima, Yoshihiro Ohta, and Tsutomu Yokozawa. "Unusual cyclic polymerization through Suzuki–Miyaura coupling of polyphenylene bearing diboronate at both ends with excess dibromophenylene." Chemical Communications 53, no. 2 (2017): 396–99. http://dx.doi.org/10.1039/c6cc08333a.

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11

Yang, Po-Chih, Hua-Wen Wen, Chih-Wei Huang, and Yi-Ning Zhu. "Synthesis and chemosensory properties of two-arm truxene-functionalized conjugated polyfluorene containing terpyridine moiety." RSC Advances 6, no. 90 (2016): 87680–89. http://dx.doi.org/10.1039/c6ra15965f.

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We report the responsive fluorescence chemosensory phenomena of a truxene-functionalized conjugated polymer (P1) with pendant terminal terpyridine (tpy) groups as receptors for metal ions synthesized via a Suzuki polymerization reaction.
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12

Huang, Cheng-Wei, Wen-Yu Ji, and Shiao-Wei Kuo. "Stimuli-responsive supramolecular conjugated polymer with phototunable surface relief grating." Polymer Chemistry 9, no. 20 (2018): 2813–20. http://dx.doi.org/10.1039/c8py00439k.

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A facile method to synthesize azobenzene- and thymine (T)-functionalized conjugated copolymers through Suzuki coupling polymerization and click reactions and used in surface relief gratings displaying long-range-ordered interference patterns.
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13

Zhu, Xiaoyan, Feng Liu, Xinwu Ba, and Yonggang Wu. "Tandem Suzuki Polymerization/Heck Cyclization Reaction to Form Ladder-Type 9,9′-Bifluorenylidene-Based Conjugated Polymer." Polymers 15, no. 16 (2023): 3360. http://dx.doi.org/10.3390/polym15163360.

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The synthesis of ladder-type 9,9′-bifluorenylidene-based conjugated polymer is reported. Unlike the typical synthetic strategy, the new designed ladder-type conjugated polymer is achieved via tandem Suzuki polymerization/Heck cyclization reaction in one-pot. In the preparation process, Suzuki polymerization reaction occurred first and then the intramolecular Heck cyclization followed smoothly under the same catalyst Pd(PPh3)4. The model reaction proved that the introduction of iodine (I) for this tandem reaction can effectively control the sequential bond-forming process and inhibit the additi
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14

Page, Zachariah A., Feng Liu, Thomas P. Russell, and Todd Emrick. "Rapid, facile synthesis of conjugated polymer zwitterions in ionic liquids." Chem. Sci. 5, no. 6 (2014): 2368–73. http://dx.doi.org/10.1039/c4sc00475b.

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Ionic liquids (ILs) were utilized for the rapid air-stable Suzuki polymerization of polar zwitterionic thiophene monomers, precluding the need for volatile organic solvents, phosphine ligands and phase transfer catalysts typically used in conjugated polymer synthesis.
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15

Sugita, Hajime, Masataka Nojima, Yoshihiro Ohta, and Tsutomu Yokozawa. "Unstoichiometric Suzuki–Miyaura cyclic polymerization of extensively conjugated monomers." Polymer Chemistry 10, no. 10 (2019): 1182–85. http://dx.doi.org/10.1039/c8py01741g.

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Suzuki–Miyaura polycondensation of an excess of extensively conjugated aromatic dibromide with 1.0 equivalent of phenylenediboronate in the presence of <sup>t</sup>Bu<sub>3</sub>PPd(0) precatalyst afforded cyclic polymers.
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16

Zhang, Hong-Hai, Yu-Xing Zhu, Weiyu Wang, Jiahua Zhu, Peter V. Bonnesen, and Kunlun Hong. "Controlled synthesis of ortho, para-alternating linked polyarenes via catalyst-transfer Suzuki coupling polymerization." Polymer Chemistry 9, no. 24 (2018): 3342–46. http://dx.doi.org/10.1039/c8py00070k.

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A novel class of ortho, para-alternating linked polyarenes is synthesized via catalyst-transfer Suzuki coupling polymerization with Pd<sub>2</sub>(dba)<sub>3</sub>/t-Bu<sub>3</sub>P/p-BrC<sub>6</sub>H<sub>4</sub>COPh as initiator.
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17

Nau, Jennifer, and Thomas J. J. Müller. "Dithienothiazine Copolymers – Synthesis and Electronic Properties of Novel Redox-Active Fluorescent Polymers." Organic Materials 03, no. 02 (2021): 293–301. http://dx.doi.org/10.1055/a-1528-6301.

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Dithienothiazine copolymers are efficiently obtained by Suzuki polymerization or in situ lithiation–Negishi polymerization in good to excellent yields. Gel permeation chromatography was applied to characterize the dispersities and degrees of polymerization of these novel materials. Thermogravimetric analysis shows that the copolymers are stable towards side-chain cleavage up to 200 °C. The materials are deep red to black amorphous solids or resins and their absorption and emission spectra in solution reveal broad absorption bands in the visible and orange to deep red luminescence upon UV excit
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18

Wang, Mingyu, Jie Liu, Jinpeng Li, and Tiesheng Li. "A New Chiral Cyclopalladated Ferrocenylimine Self-assembly Polymeric Film supported on Silicon for Heck and Suzuki-coupling Reactions." Catalysis Research 2, no. 2 (2022): 1. http://dx.doi.org/10.21926/cr.2202010.

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A new chiral cyclopalladated ferrocenyl imine catalyst (called 4a2) was designed and synthesized, and its self-assembly catalytic polymeric brush supported on silicon (denoted as Si@PB4a2) was also fabricated by surface-initiated atom transfer radical polymerization (ATRP) and characterized. The catalytic properties of monomer 4a2 in homogeneous and Si@PB4a2 in heterogeneous in Heck and Suzuki cross-coupling were investigated, respectively. They exhibited higher catalytic activity in Heck, and Suzuki coupling reactions in homogeneous and heterogeneous using water as the solvent, and the cataly
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19

Elmalem, Einat, Anton Kiriy, and Wilhelm T. S. Huck. "Chain-Growth Suzuki Polymerization of n-Type Fluorene Copolymers." Macromolecules 44, no. 22 (2011): 9057–61. http://dx.doi.org/10.1021/ma201934q.

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20

Seto, Hirokazu, Takumi Tono, Akiko Nagaoka, Mai Yamamoto, Yumiko Hirohashi, and Hiroyuki Shinto. "Preparation and characterization of glycopolymers with biphenyl spacers via Suzuki coupling reaction." Organic & Biomolecular Chemistry 19, no. 20 (2021): 4474–77. http://dx.doi.org/10.1039/d1ob00617g.

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21

Kobayashi, Saburo, Mayoh Ashiya, Takuya Yamamoto, et al. "Suzuki–Miyaura Catalyst-Transfer Polycondensation of Triolborate-Type Carbazole Monomers." Polymers 13, no. 23 (2021): 4168. http://dx.doi.org/10.3390/polym13234168.

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Herein, we report the Suzuki–Miyaura catalyst-transfer polycondensation (SCTP) of triolborate-type carbazole monomers, i.e., potassium 3-(6-bromo-9-(2-octyldodecyl)-9H-carbazole-2-yl)triolborate (M1) and potassium 2-(7-bromo-9-(2-octyldodecyl)-9H-carbazole-2-yl) triolborate (M2), as an efficient and versatile approach for precisely synthesizing poly[9-(2-octyldodecyl)-3,6-carbazole] (3,6-PCz) and poly[9-(2-octyldodecyl)-2,7-carbazole] (2,7-PCz), respectively. The SCTP of triolborate-type carbazole monomers was performed in a mixture of THF/H2O using an initiating system consisted of 4-iodobenz
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22

Huang, Louguangshu, Hui Liu, Xiaoxia Xue, Wuduo Zhao, and Tiesheng Li. "Controllable Cyclopalladated Polythiophene Imine Monolayer by Self-Assembly, Hybrid Doping and Electrochemical Polymerization: A Simple Way to Enhance Activity and Stability." Catalysis Research 2, no. 1 (2021): 1. http://dx.doi.org/10.21926/cr.2201003.

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In this article, an approach to generate self-assembly cyclopalladated polythiophene imine monolayers (denoted as ITO@Pd-CPTIMs) is described. The monolayers were fabricated by combining self-assembly (SA), hybrid doping (HD), and electrochemical polymerization (ECP) called SA-HD-ECP. The catalytic activity and stability of the polymerized monolayers in the Suzuki coupling reaction were improved by modulating the structure and morphology in hybrid doping using different thiophene derivatives, concentrations, and scanning numbers during electrochemical polymerization. Morphological changes in t
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23

Ramaotsoa, G. Valerie, Ian Strydom, Jenny-Lee Panayides, and Darren Riley. "Immobilized tetrakis(triphenylphosphine)palladium(0) for Suzuki–Miyaura coupling reactions under flow conditions." Reaction Chemistry & Engineering 4, no. 2 (2019): 372–82. http://dx.doi.org/10.1039/c8re00235e.

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An immobilized triphenylphosphine scaffold was prepared by precipitation polymerization and functionalized to afford a cost-effective source of solid-supported tetrakis(triphenylphosphine)palladium(0).
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24

Akbayrak, Merve, and Ahmet M. Önal. "Synthesis and electrochemical polymerization of diketopyrrolopyrrole based donor–acceptor–donor monomers containing 3,6- and 2,7-linked carbazoles." Polymer Chemistry 7, no. 39 (2016): 6110–19. http://dx.doi.org/10.1039/c6py01489e.

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Three new donor–acceptor–donor type monomers bearing 2,7- or 3,6-linked carbazoles as the donor unit and diketopyrrolopyrrole as the acceptor unit were synthesized via a Suzuki cross coupling reaction.
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25

Lee, Junghoon, A.-Reum Han, Sang Myeon Lee, Dohyuk Yoo, Joon Hak Oh, and Changduk Yang. "Siloxane-Based Hybrid Semiconducting Polymers Prepared by Fluoride-Mediated Suzuki Polymerization." Angewandte Chemie International Edition 54, no. 15 (2015): 4657–60. http://dx.doi.org/10.1002/anie.201411557.

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26

Lee, Junghoon, A.-Reum Han, Sang Myeon Lee, Dohyuk Yoo, Joon Hak Oh, and Changduk Yang. "Siloxane-Based Hybrid Semiconducting Polymers Prepared by Fluoride-Mediated Suzuki Polymerization." Angewandte Chemie 127, no. 15 (2015): 4740–43. http://dx.doi.org/10.1002/ange.201411557.

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27

Gobalasingham, Nemal S., Seyma Ekiz, Robert M. Pankow, Francesco Livi, Eva Bundgaard, and Barry C. Thompson. "Carbazole-based copolymers via direct arylation polymerization (DArP) for Suzuki-convergent polymer solar cell performance." Polymer Chemistry 8, no. 30 (2017): 4393–402. http://dx.doi.org/10.1039/c7py00859g.

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28

Liu, Fangfei, and Xiong Liu. "Amphiphilic Dendronized Copolymer-Encapsulated Au, Ag and Pd Nanoparticles for Catalysis in the 4-Nitrophenol Reduction and Suzuki–Miyaura Reactions." Polymers 16, no. 8 (2024): 1080. http://dx.doi.org/10.3390/polym16081080.

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The branched structures of dendronized polymers can provide good steric stabilization for metal nanoparticle catalysts. In this work, an amphiphilic dendronized copolymer containing hydrophilic branched triethylene glycol moieties and hydrophobic branched ferrocenyl moieties is designed and prepared by one-pot ring-opening metathesis polymerization, and is used as the stabilizer for metal (Au, Ag and Pd) nanoparticles. These metal nanoparticles (Au nanoparticles: 3.5 ± 3.0 nm; Ag nanoparticles: 7.2 ± 4.0 nm; Pd nanoparticles: 2.5 ± 1.0 nm) are found to be highly active in both the 4-nitropheno
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29

Fischer, Christoph S., Christian Jenewein, and Stefan Mecking. "Conjugated Star Polymers from Multidirectional Suzuki–Miyaura Polymerization for Live Cell Imaging." Macromolecules 48, no. 3 (2015): 483–91. http://dx.doi.org/10.1021/ma502294n.

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30

ten Hove, Jan Bart, Jeroen Appel, Johanna M. van den Broek, Alexander J. C. Kuehne, and Joris Sprakel. "Conjugated Polymer Shells on Colloidal Templates by Seeded Suzuki-Miyaura Dispersion Polymerization." Small 10, no. 5 (2013): 957–63. http://dx.doi.org/10.1002/smll.201302039.

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31

Yang, Yun Xian, Ji Ping Yang, Bing Zhou, and Jing Yu Zhang. "Synthesis and Characterization of Novel Polymer of Vinyl Carbazole Bearing Thiophene Groups." Advanced Materials Research 562-564 (August 2012): 512–15. http://dx.doi.org/10.4028/www.scientific.net/amr.562-564.512.

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Combination of vinyl carbazole and thiophene groups’ excellent thermal properties and optical properties, a novel polymer named poly(2,7-bi-2-thienyl-9-vinyl-9-H-carbazole) was synthesized via radical polymerization and Suzuki reaction. The polymer was characterized using Fourier transform infrared spectrometer(FT-IR), gel permeation chromatography(GPC), differential scanning calorimetry(DSC), and X-Ray fluorescence spectrometer(XRF). It was found that this π-conjugated polymer containing vinyl carbazole and thiophene groups gave a high glass transition temperature (Tg=251°C). This feature mad
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32

Soo Choi, Moon, Hyung Jun Kim, Taek Seung Lee, and Won Seok Lyoo. "Newly Synthesized Branch-type Aromatic Oxadiazole Polymer and Binary Fluorescence Patterning on its Film." High Performance Polymers 19, no. 5-6 (2007): 531–40. http://dx.doi.org/10.1177/0954008306081195.

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Aromatic side-chain oxadiazole polymer linked with 9,9'-dioctylfluorene was successfully synthesized via Suzuki coupling reaction. Hydroxyphenyl group was attached in the 2-position of the oxadiazole unit in the polymer side chain to control the optical properties of the polymer. We confirmed the presence of the t-butoxycarbonyl group on the hydroxyl group using thermogravimetric analysis, which was incorporated to avoid side reaction during polymerization. We also performed the simple and easy fabrication method for the dual fluorescence image using photochemical cleavage of the t-butoxycarbo
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33

Carrillo, Josué Ayuso, Michael J. Ingleson, and Michael L. Turner. "Thienyl MIDA Boronate Esters as Highly Effective Monomers for Suzuki–Miyaura Polymerization Reactions." Macromolecules 48, no. 4 (2015): 979–86. http://dx.doi.org/10.1021/ma502542g.

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34

Brookins, Robert N., Kirk S. Schanze, and John R. Reynolds. "Base-Free Suzuki Polymerization for the Synthesis of Polyfluorenes Functionalized with Carboxylic Acids." Macromolecules 40, no. 10 (2007): 3524–26. http://dx.doi.org/10.1021/ma070070r.

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35

Yokozawa, Tsutomu, Haruhiko Kohno, Yoshihiro Ohta, and Akihiro Yokoyama. "Catalyst-Transfer Suzuki−Miyaura Coupling Polymerization for Precision Synthesis of Poly(p-phenylene)." Macromolecules 43, no. 17 (2010): 7095–100. http://dx.doi.org/10.1021/ma101073x.

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36

Vogt, Christian G., Sven Grätz, Stipe Lukin, et al. "Direct Mechanocatalysis: Palladium as Milling Media and Catalyst in the Mechanochemical Suzuki Polymerization." Angewandte Chemie International Edition 58, no. 52 (2019): 18942–47. http://dx.doi.org/10.1002/anie.201911356.

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37

Yokozawa, Tsutomu, Ryosuke Suzuki, Masataka Nojima, Yoshihiro Ohta, and Akihiro Yokoyama. "Precision Synthesis of Poly(3-hexylthiophene) from Catalyst-Transfer Suzuki−Miyaura Coupling Polymerization." Macromolecular Rapid Communications 32, no. 11 (2011): 801–6. http://dx.doi.org/10.1002/marc.201100037.

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38

Kosaka, Kentaro, Tatsuya Uchida, Koichiro Mikami, Yoshihiro Ohta, and Tsutomu Yokozawa. "AmPhos Pd-Catalyzed Suzuki–Miyaura Catalyst-Transfer Condensation Polymerization: Narrower Dispersity by Mixing the Catalyst and Base Prior to Polymerization." Macromolecules 51, no. 2 (2018): 364–69. http://dx.doi.org/10.1021/acs.macromol.7b01990.

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39

Matsumura, Yoshimasa, and Sota Hokimoto. "Synthesis of Polybromothiophene By Electrooxidative Polymerization and Its Polymer Reactions." ECS Meeting Abstracts MA2024-02, no. 53 (2024): 3627. https://doi.org/10.1149/ma2024-02533627mtgabs.

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π-Conjugated polymers exhibit unique properties such as electronic conductivity, photoluminescence, and visible light absorption due to the delocalization of π-electrons on the main chain. Although these polymers are typically synthesized by polycondensation techniques using transition metal catalysts, this method can not be used for polymerization of monomers containing reactive building blocks for transition metal catalysis. To prepare reactive precursors for catalytic transformation, we focused on electrochemical synthesis of bromo-substituted polythiophene for introduction of various funct
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40

Bautista, Michael V., Anthony J. Varni, Josué Ayuso-Carrillo, Chia-Hua Tsai, and Kevin J. T. Noonan. "Chain-Growth Polymerization of Benzotriazole Using Suzuki–Miyaura Cross-Coupling and Dialkylbiarylphosphine Palladium Catalysts." ACS Macro Letters 9, no. 9 (2020): 1357–62. http://dx.doi.org/10.1021/acsmacrolett.0c00580.

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41

Kosaka, Kentaro, Yoshihiro Ohta, and Tsutomu Yokozawa. "Influence of the Boron Moiety and Water on Suzuki-Miyaura Catalyst-Transfer Condensation Polymerization." Macromolecular Rapid Communications 36, no. 4 (2014): 373–77. http://dx.doi.org/10.1002/marc.201400530.

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42

Parrenin, Laurie, Cyril Brochon, Georges Hadziioannou, and Eric Cloutet. "Low Bandgap Semiconducting Copolymer Nanoparticles by Suzuki Cross-Coupling Polymerization in Alcoholic Dispersed Media." Macromolecular Rapid Communications 36, no. 20 (2015): 1816–21. http://dx.doi.org/10.1002/marc.201500324.

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43

Sun, Huiliang, Shuren Zhang, Yike Yang, Xiao Li, Hongmei Zhan, and Yanxiang Cheng. "Excellent Control of Perylene Diimide End Group in Polyfluorene via Suzuki Catalyst Transfer Polymerization." Macromolecular Chemistry and Physics 217, no. 24 (2016): 2726–35. http://dx.doi.org/10.1002/macp.201600412.

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44

Reddy, Lavanya, Suja T. Dharmabalan, Kanakaraju Manupati, et al. "Concise Synthesis of 1,1-Diarylvinyl Sulfones and Investigations on their Antiproliferative Activity via Tubulin Inhibition." Anti-Cancer Agents in Medicinal Chemistry 20, no. 12 (2020): 1469–74. http://dx.doi.org/10.2174/1871520620666200423075630.

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Background: Discovery of small molecules that inhibit tubulin polymerization is an attractive strategy for the development of new and improved anti-proliferative agents. Objective: A series of novel 2-sulfonyl-1,1-diarylethenes were designed towards this end keeping in view the favorable chemical and pharmacological virtues of unsaturated sulfones. Methods: Rapid, convenient and efficient two-step assembly of the designed molecules was achieved by the vicinal iodo-sulfonylation-Suzuki coupling sequence. Results: As hypothesized, these compounds showed good anti-proliferative activity against d
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45

Otaki, Masashi, Reiji Kumai, Hajime Sagayama, and Hiromasa Goto. "Synthesis of Polyazobenzenes Exhibiting Photoisomerization and Liquid Crystallinity." Polymers 11, no. 2 (2019): 348. http://dx.doi.org/10.3390/polym11020348.

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While only a few studies have investigated the synthesis of main chain-type polyazobenzenes, they continue to draw an increasing amount of attention owing to their industrial applications in holography, dyes, and functional adhesives. In this study, dibromoazobenzene was prepared as a monomer for constructing azo-based π-conjugated polymers. Miyaura–Suzuki cross-coupling polymerization was conducted to develop copolymers containing an azobenzene unit as a photoisomerization block and a pyrimidine-based liquid crystal generator block. The prepared polymers exhibited thermotropic liquid crystall
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46

Lim, Eunhee. "Synthesis and Characterization of Carbazole-Benzothiadiazole-Based Conjugated Polymers for Organic Photovoltaic Cells with Triazole in the Main Chain." International Journal of Photoenergy 2013 (2013): 1–7. http://dx.doi.org/10.1155/2013/607826.

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We have synthesized a series of carbazole-benzothiadiazole-triazole based copolymers, poly[(N-9′-heptadecanyl-2,7-carbazole)-co-(5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole))-co-((4-(4-butylphenyl)-3,5-diphenyl-4H-1,2,4]triazole))] (PCz3TBTz) by Suzuki coupling polymerization. The optical and electrochemical properties of the copolymers could be tuned by changing the comonomer unit of triazole from 0% to 80%. Organic photovoltaic (OPV) cells were fabricated by blending the synthesized polymers as a donor and PCBM as an acceptor. The material solubility and film morphology were improved b
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47

Wang, Qing Xiu, Li Jie Duan, Bo Yang Qu, Juan Wang, and Fu De Liu. "Synthesis and Optical/Electrochemical Properties of Conjugated Polymers with Diphenyl and Thiophene in Main Chain." Advanced Materials Research 1035 (October 2014): 497–501. http://dx.doi.org/10.4028/www.scientific.net/amr.1035.497.

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Two thiophene derivatives 4,4'-di (thiophen-2-yl) biphenyl and 4,4'-di (thiophen-2-yl) -2-nitrobiphenyl ,which were used as monomers for preparing poly (4,4'-di (thiophen-2-yl) biphenyl) (DPBT) and poly (4,4'-di (thiophen-2-yl)-2-nitrobiphenyl) (DPNT) by ferric chloride oxidation polymerization, were synthesized via Suzuki reaction with 4,4'-dibromobiphenyl as the raw material. UV-vis absorption spectra, fluorescence spectra, photoluminescence spectra and electrochemical properties of the polymers were recorded and used for calculating the band-gap (Eg), HOMO orbital energy (EHOMO) and LUMO or
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48

Shaya, Janah, Gabriel Correia, Benoît Heinrich, et al. "Functionalization of Biphenylcarbazole (CBP) with Siloxane-Hybrid Chains for Solvent-Free Liquid Materials." Molecules 27, no. 1 (2021): 89. http://dx.doi.org/10.3390/molecules27010089.

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Abstract:
We report herein the synthesis of siloxane-functionalized CBP molecules (4,4′-bis(carbazole)-1,1′-biphenyl) for liquid optoelectronic applications. The room-temperature liquid state is obtained through a convenient functionalization of the molecules with heptamethyltrisiloxane chains via hydrosilylation of alkenyl spacers. The synthesis comprises screening of metal-catalyzed methodologies to introduce alkenyl linkers into carbazoles (Stille and Suzuki Miyaura cross-couplings), incorporate the alkenylcarbazoles to dihalobiphenyls (Ullmann coupling), and finally introduce the siloxane chains. Th
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49

Liu, Qian, Dhanashree Moghe, Gopa Sardar, et al. "Structural Geometry Variation of 1,4-Naphthalene-Based Co-Polymers to Tune the Device Performance of PVK-Host-Based OLEDs." Polymers 13, no. 17 (2021): 2914. http://dx.doi.org/10.3390/polym13172914.

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Abstract:
Blue-color-emitting organic semiconductors are of significance for organic light-emitting diodes (OLEDs). In this study, through Suzuki coupling polymerization, three 1,4-naphthalene-based copolymers—namely, PNP(1,4)-PT, PNP(1,4)-TF, and PNP(1,4)-ANT—were designed and synthesized. The variation of comonomers, phenothiazine (PT), triphenylamine substituted fluorene (TF), and anthanthrene (ANT), effectively tuned the emitting color and device performance of poly(9-vinyl carbazole) (PVK)-based OLEDs. Especially, the polymer PNP(1,4)-TF, bearing perpendicular aryl side groups, showed a most twiste
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50

Li, Haibo, Xiaofu Wu, Bowei Xu, Hui Tong, and Lixiang Wang. "Solution-processible hyperbranched conjugated polymer nanoparticles with tunable particle sizes by Suzuki polymerization in miniemulsion." RSC Advances 3, no. 23 (2013): 8645. http://dx.doi.org/10.1039/c3ra40901e.

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