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Dissertations / Theses on the topic 'Synthesis of cyclopropanes'

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Published: 4 June 2021

Last updated: 14 February 2022

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1

Ambler, P. W. "Asymmetric synthesis of cyclopropanes." Thesis, University of Oxford, 1988. https://ora.ox.ac.uk/objects/uuid:958e77c2-d15e-4d8f-af84-36dca36e4215.

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This thesis is concerned with the asymmetric synthesis of cyclopropyl derivatives via the use of chiral iron acyl complexes of the type (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO)(PPh<sub>3</sub>)(COCH=CR'R), Chapter 1 reviews previous routes to optically active cyclopropyl derivatives and reviews the use of the chiral auxiliary (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO)(PPh<sub>3</sub>) for asymmetric synthesis. Chapter 2 describes the synthesis of the complexes (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO)(PPh<sub>3</sub>)(COCH=CRR') and presents a conformational an

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2

Watson, Hayley. "Synthesis and reactivity of cyclopropanes and cyclopropenes." Thesis, Loughborough University, 2011. https://dspace.lboro.ac.uk/2134/9032.

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Activated cyclopropanes have been extensively used in synthetic chemistry as precursors for cycloaddition reactions. The rationale behind this is their ability to undergo ring-opening when activated by a Lewis acid, this can be enhanced further by the presence of a carbocation stabilising group like electron-rich aromatics. The stabilised dipole formed after ring opening can be trapped with suitable electrophiles such as imines and aldehydes via a [3+2] cycloaddition reaction. This results in the synthesis of pyrrolidines and tetrahydrofurans in excellent yields but moderate diastereoselectivi

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3

Minicone, Fabrizio. "Stereoselective synthesis of cyclopropanes with quaternary carbon centres." Thesis, Queen Mary, University of London, 2014. http://qmro.qmul.ac.uk/xmlui/handle/123456789/8766.

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Multi-substituted optically pure cyclopropanes are important motifs present in many agrochemicals, pharmaceuticals and materials employed in manifold applications. Their synthesis is challenging due to both the strained conformation and the need to control both the relative and absolute stereochemistry. This thesis describes an investigation of the scope of the Wadsworth-Emmons cyclopropanation, highlighting it as a potential efficient methodology for diastereoselective and enantiospecific synthesis of these valuable ring systems. Chapter 1 is an introduction to the cyclopropanation protocols

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4

Sweesi, Miloud E. M. "Studies of the synthesis of cyclopropanes and cyclobutenes." Thesis, Bangor University, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438828.

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5

Clarke, C. "Comparative chemistry of protected phosphines within the synthesis of cyclopropanes." Thesis, University of Cambridge, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.597723.

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On treatment with base, diphenylphosphinoyl esters 3 (X=O) give cyclopropanes 4 <i>via</i> a series of steps including intramolecular acyl and phosphinoyl transfer processes. β-Substituted esters have been shown to give cyclopropanes with high diastereoselectivity. This thesis describes the synthesis of optically active β-substituted esters using Evans’ alkylation methodology and their use in the stereocontrolled synthesis of substituted cyclopropanes. It was found that that phosphine oxide 1 (X=O) is unstable in the conditions of the alkylation reaction and the corresponding phosphine borane

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6

Ner, S. K. "The synthesis and testing of cyclopropane inhibitors of Carboxypeptidase A." Thesis, University of Strathclyde, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381719.

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7

Huang, Weisheng. "Catalytic asymmetric cyclopropanation and oxidation of tri-, di- and monofluoromethyl styrenes Rhodium catalysed enantioselective synthesis of mono-(halo)-methyl-cyclopropanes Catalytic enantioselective synthesis of highly functionalized difluoromethylated cyclopropanes General catalytic enantioselective access to monohalomethyl and trifluoromethyl cyclopropanes Catalytic asymmetric synthesis of α,α-difluoromethylated and α-fluoromethylated tertiary alcohols". Thesis, Normandie, 2019. http://www.theses.fr/2019NORMIR25.

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Ce manuscrit décrit la synthèse énantiosélective de cyclopropanes trifluorométhylés, difluorométhylés et mono-halométhylés hautement fonctionnalisés. Cette synthèse repose sur la cyclopropanation d’alcènes. De plus, la synthèse d’alcools tertiaires difluorométhylés à partir des oléfines fluorées correspondantes suivant un processus de dihydroxylation asymétrique est décrite. Ce manuscrit se découpe en 3 chapitres. Le premier chapitre décrit la première synthèse catalytique asymétrique de cyclopropanes difluorométhylés en utilisant le Rh₂((S)-BTPCP)₄ comme catalyseur pour la réaction de cyclopr

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8

Dorsey, Gordon Owen. "Design and synthesis of substituted cyclopropanes as conformationally restrained dipeptide mimics." Thesis, Austin, Texas : University of Texas at Austin, 1992. http://handle.dtic.mil/100.2/ADA252441.

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Thesis (M.A. in Chemistry)--University of Texas at Austin, May 1992.<br>"May 1992." Description based on title screen as viewed on April 8, 2009. Includes bibliographical references (p. 94-101). Also available in print.

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9

Ivashkin, Pavel. "Synthesis of original fluorinated cyclopropylcarboxylates." Phd thesis, INSA de Rouen, 2013. http://tel.archives-ouvertes.fr/tel-00924650.

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Organofluorine compounds constitute a large part of all the drugs, crop protection agents and advanced materials produced nowadays. Therefore, there is a great interest in developing the new methods of synthesis of organofluorine compounds. In this thesis we report a novel method of synthesis of monofluorinated cyclopropanes based on the Michael-initiating ring closure (MIRC) reaction. Our method allows obtaining polysubstituted monofluorinated cyclopropanes from ethyl dibromofluoroacetate and various Michael acceptors. We have also implemented the asymetric version of cyclopropanation using a

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10

Highton, Adrian. "Organic synthesis using iron (III) mediated fragmentation reactions of silyoxycyclopropanes." Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311749.

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11

Pale, Patrick. "Synthese et reactivite d'epoxyalcools acetyleniques chiraux : application a la synthese de cyclopropanes et d'heterocycles fonctionnalises." Reims, 1988. http://www.theses.fr/1988REIMS012.

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12

Hackett, Siobhán. "Exploring the reactions of small rings." Thesis, Queen Mary, University of London, 2014. http://qmro.qmul.ac.uk/xmlui/handle/123456789/8965.

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Small rings are frequently found in natural products as well as incorporated into drugs and agrochemicals in which they impart valuable properties on the biological activity of these compounds. Cyclopropanes are also extremely useful as reagents in organic synthesis, in particular as “umpolung” reagents, allowing access to products which would otherwise be more difficult to synthesise. This thesis will describe forays into the synthesis and further substitution of small rings as well as the iminium-catalysed ring-opening of cyclopropanes. The introduction will outline the uses and properties o

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13

Huber, Florian Anton Martin. "Stereocontrolled cyclopropane synthesis." Thesis, Bangor University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297672.

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14

Pedersen, Daniel Sejer. "Asymmetric cyclopropane synthesis." Thesis, University of Cambridge, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.613762.

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15

Patil, Dadasaheb V. "Intramolecular cyclization strategies for synthesizing medium-ring polycycles and the total synthesis of natural products." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/50118.

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Carbo- and heterocyclic compounds are of great interest to chemists. Intramolecular cyclization strategies of donor-acceptor (D-A) cyclopropanes and alkylidene malonate monoamides have excellent potential for synthesis as they offer easy access to structurally-diverse compounds. The work described in this thesis accesses the scope of the In(OTf)3-catalyzed cyclization reaction of cyclopropanes and alkylidene malonate monoamides. In(OTf)3-catalyzed reactions of alkenyl and heteroaryl cyclopropyl ketones were examined in the synthesis of functionalized cyclohexenone-based derivatives (Chapter 2)

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16

Thomas, Stephen Patrick. "Phosphorus mediated asymmetric cyclopropane synthesis." Thesis, University of Cambridge, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.613118.

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17

Mohanathas, Rajaratnam. "Synthetic studies of cyclopropanes and cyclobutanes." Thesis, Bangor University, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.431491.

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18

Jacoby, Denis. "Synthese et reactivite des cyclopropanes actives." Paris 6, 1987. http://www.theses.fr/1987PA066439.

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Ce travail decrit des mises au point originales de preparations de pyrrolines et de dihydrofurannes a partir de cyclopropylcetoesters. Ces derniers sont prepares a partir de sels de triphenylphosphonium, precurseurs de derives cyclopropaniques. La reactivite de ces composes cyclopropaniques vis a vis de nucleophiles varies est etudiee. L'action des amines primaires permet d'obtenir des pyrrolines. Une etude biologique montre l'activite biocide des composes prepares

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19

Coxon, Geoffrey David. "The synthesis and chirality of cyclopropane fatty acids." Thesis, University of Newcastle Upon Tyne, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285742.

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20

Licence, Peter. "Synthetic studies in cyclopropane chemistry." Thesis, Bangor University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.364988.

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21

DIEP-VOHUULE, NGOC-ANH. "Synthese asymetrique d'epoxydes et de cyclopropanes chiraux." Université Louis Pasteur (Strasbourg) (1971-2008), 1996. http://www.theses.fr/1996STR13269.

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Le travail decrit dans ce memoire porte sur la synthese asymetrique d'epoxydes et de cyclopropanes enantiomeriquement enrichis au depart des ylures de soufre chiraux derives de (+)-(r,r,r) ou de (-)-(s,s,s)-oxathiane d'eliel 1. Nous avons mis au point une methode de synthese asymetrique courte d'epoxydes mono et disubstitues ayant une purete enantiomerique elevee de 84 a 99. 9%. Cette methode est aisement realisee en deux etapes a partir de l'oxathiane d'eliel 1: une s-alkylation stereoselective de l'oxathiane 1 par un triflate ou un halogenure d'alkyle ou d'aryle conduit au sel de sulfonium q

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22

Glen, Anthony D. "Synthetic studies on cyclopropane fatty acids." Thesis, University of Newcastle Upon Tyne, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386040.

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23

Campbell, Matthew James Johnson Jeffrey Scott. "I. Mechanistic studies of a copper-catalyzed electrophilic amination of diorganozinc reagents reagents by O-benzoyl N,N-dialkylhydroxylamines II. Development of a 3-Exo-Dig cyclization for the preparation of vinylidene cyclopropanes III. Total synthesis of +-polyanthellin A." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2009. http://dc.lib.unc.edu/u?/etd,2881.

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Thesis (Ph. D.)--University of North Carolina at Chapel Hill, 2010.<br>Title from electronic title page (viewed Jun. 23, 2010). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.

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24

Walther, Stefan. "Cyclopropane als Edukte zur Synthese von Calicenen /." [S.l : s.n.], 1985. http://www.ub.unibe.ch/content/bibliotheken_sammlungen/sondersammlungen/dissen_bestellformular/index_ger.html.

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25

Pietruszka, Jörg. "Enantiomerenreine Cyclopropane : neue Bausteine für die Natur- und Wirkstoffsynthese /." Herdecke : GCA-Verl, 2001. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=009621579&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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26

Hanlon, David James. "u-vinylidene and n-1-cyclopropenyliron complexes : chemistry and synthesis via 1, 1-dichlorocyclopropanes /." Full-text version available from OU Domain via ProQuest Digital Dissertations, 1985.

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27

Jevric, Martyn. "Synthesis of 1,2-Dihydronaphtho[2,1-b]furans. Reactions of 1,2-Dioxines and stabilised phosphorus ylides /." Title page, Index and abstract only, 2004. http://web4.library.adelaide.edu.au/theses/09PH/09phj589.pdf.

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28

GRANDJEAN, DIDIER. "Synthese enantioselective d'epoxyde et de cyclopropanes. Application a la synthese de produits naturels." Reims, 1991. http://www.theses.fr/1991REIM5008.

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Dans ce travail, deux molecules chirales extremement importantes sur le plan synthetique ont ete preparees, l'une epoxydique: le (2s,3r)-4-butyryloxy-2,3-epoxybutan-1-ol, l'autre cyclopropanique: le (1r,2s)-1-butyryloxymethyl-2-hydroxymethylcyclopropane. Ces deux synthons, optiquement purs, ont ete obtenus par hydrolyse enzymatique des diols diesterifies meso correspondants. L'epoxyalcool(2s,3r)-4-butyryloxy-2,3-epoxybutan-1-ol a ete transforme en epoxyalcools acetyleniques cis diversement substitues. L'etude de ces ethynyloxiranes nous a permis de mettre en evidence trois nouveaux aspects de

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29

Jerome, L. "The generation and reactivity of functionalised organozinc carbenoids for cyclopropane synthesis." Thesis, University College London (University of London), 2009. http://discovery.ucl.ac.uk/17481/.

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This thesis describes the generation and reactivity of functionalised organozinc carbenoids for cyclopropane synthesis with alkenes. In the introductory chapter, a brief overview of the different methods for preparation of heteroatom-functionalised cyclopropanes is presented, including [2+1] cycloaddition reactions using a carbene or carbenoid as a cyclopropanating agent with an alkene, ionic stepwise methods, and chemical modifications from existing cyclopropanes. The remainder of this chapter then focuses on previous work within our own group in this area. The second chapter presents the res

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30

Troxler, Thomas. "B₁₂-katalysierte, enantioselektive Isomerisierung von Cyclopropanen : Synthese von Carbovir /." Bern, 1993. http://www.ub.unibe.ch/content/bibliotheken_sammlungen/sondersammlungen/dissen_bestellformular/index_ger.html.

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31

NEVELLEC, LAURENCE. "Synthese d'analogues de nucleosides cyclobutaniques et cyclopropaniques." Le Mans, 1995. http://www.theses.fr/1995LEMA1018.

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Ce travail est axe sur la synthese d'analogues de nucleosides cyclobutaniques et cyclopropaniques a visee antivirale, par differentes voies d'introduction directe de la base purique ou pyrimidique sur des carbocycles fonctionnalises. Des composes cyclobuteniques ont ete synthetises a partir de l'anhydride cis-4-cyclobut-3-ene-1,2-dicarboxylique, obtenu par la reaction photochimique entre l'acetylene et l'anhydride maleique. L'ouverture nucleophile d'epoxydes cyclobutaniques en derivant a ainsi conduit a la synthese d'analogues de nucleosides cyclobutaniques trihydroxyles. La contraction de cyc

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32

BERUBEN, DOV. "Carbometallation diastereoselective de vinylmetaux. Application a la synthese de cyclopropanes metalles." Paris 6, 1994. http://www.theses.fr/1994PA066050.

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Au cours de ce travail, nous avons realise la carbometallation d'ethers allyliques metalles en position 3, pour obtenir la formation d'un organogembismetallique-1,1. Dans des conditions experimentales precises, celui-ci peut subir une reaction d'elimination -1,3 pour conduire au cyclopropylmetal correspondant, via un etat de transition en w, avec double inversion de configuration au niveau des centres reactifs. Ce meme protocole a pu etre realise a partir d'ethers homoallyliques secondaires metalles en position 3. Un organogembismetallique-n,n dialkyle est alors mis en evidence pour la premier

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33

盧偉祥 and Wai-cheung Lo. "Metal complexes of porphyrins and porphycenes in catalytic cyclopropanation and aziridination of alkenes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237484.

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34

Chawner, Stephen John. "Divergent synthesis of cyclopropane-containing fragments and lead-like compounds for drug discovery." Thesis, Imperial College London, 2017. http://hdl.handle.net/10044/1/56635.

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The cyclopropane ring is key to a large number of medicinally‑relevant compounds that possess a broad spectrum of biological activities. This thesis details the preparation of novel bifunctional cyclopropanes through a divergent functionalisation approach utilising two readily accessible cyclopropyl‑scaffolds. The cyclopropanes generated sampled new areas of chemical space whilst being suitable 3‑dimensional fragments and lead-like compounds for drug discovery. A novel CoII-catalysed cyclopropanation generates two diastereoisomeric bifunctional cyclopropyl-scaffolds from commercially available

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35

Badiani, Kamal. "Synthesis and evaluation of enzyme inhibitors based on amino- and cyclopropane carboxylic acids." Thesis, University of St Andrews, 1997. http://hdl.handle.net/10023/14052.

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The coenzyme B12-dependent enzyme, glutamate mutase (E. C. 5.4.99.1), catalyses the reversible carbon-skeleton rearrangement of (2S)-glutamic acid to (25.35)-3-methylaspartic acid. Glutamate mutase is the first enzyme on the mesaconate pathway. A variety of glutamate and 3-methylaspartate analogues (which also include isotopically labelled molecules), were synthesised as molecular probes of the enzyme. Synthesis of stereospecifically labelled 3-ethylaspartic acid: (2S,3S)-[3'-C2H3], and (2S,3S)-[C2H2C2H3]-ethylaspartic acids were constructed using appropriately labelled iodoethane. (2S,3S)-2-B

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36

Johnson, William T. G. "Synthesis of precursors of a highly pyramidalized alkene and ab initio calculations on methylenecyclopropane, cyclopropene, and 1,3-diradicals /." Thesis, Connect to this title online; UW restricted, 1999. http://hdl.handle.net/1773/11586.

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37

Natchus, Michael George. "Low-temperature vinylcyclopropane rearrangement in the total synthesis of (-) - specionin." Diss., Virginia Tech, 1992. http://hdl.handle.net/10919/40075.

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38

Hillier, Michael Campion. "The intramolecular cyclopropanation reaction and its application towards the synthesis of pseudopeptides and natural products /." Digital version accessible at:, 1999. http://wwwlib.umi.com/cr/utexas/main.

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39

Grech, Jason Mark. "The synthetic applications of organomercurials arising by the cleavage of cyclopropane derivatives." Thesis, University of Leicester, 1996. http://hdl.handle.net/2381/33701.

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Organomercurial esters 2a-c obtained from cyclopropyl alcohols la-c in three or five (depending on whether the system is cis or trans) steps, react with organocuprates via an intramolecular addition across the carbonyl bond to generate the corresponding lactolate. Quenching of the latter intermediate with water leads to the lactol 3a, c in the cycloheptane and cyclopentane series, whereas the open hydroxyketone 4b is formed in the cyclohexane series. Quenching of the lactolate with BF3 Et2O gives different products, as demonstrated for the cyclohexane series. The Pd(II)-catalysed carbonylation

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40

Fleming, Alison A. "Synthesis and rearrangements of vinylcyclopropanes in a [2+3] cyclopentene and oxycyclopentene annulation methodology approach to (-)- specionin." Diss., Virginia Polytechnic Institute and State University, 1989. http://hdl.handle.net/10919/54358.

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The addition of lithium dienolate 130, formed from ethyl 2-bromocrotonate, to enones and aldehydes yielding vinylcyclopropanes and vinyloxiranes was optimized. Various methods, pyrolytic and nonpyrolytic, were examined for the rearrangement of the resulting vinylcyclopropanes to cyclopentenes in an overall [2+3] annulation sequence. During the course of these studies, a new rearrangement pathway of these vinylcyclopropanes to bridged [3.2.n] bicyclic systems was discovered thus establishing a new [3+4] annulation technology. The extension of the [2+3] annulation technology to oxygenated cyclo

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41

Le, Gall Lefas Marie. "Synthese et proprietes biologiques de derives beta-substitutes ou cyclopropaniques de ligands melatoninergiques." Paris 11, 1998. http://www.theses.fr/1998PA114850.

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42

ISARNO, THOMAS. "Synthese asymetrique d'epoxydes et de cyclopropanes via des ylures de soufre chiraux. Utilisation de bases phosphazenes." Université Louis Pasteur (Strasbourg) (1971-2008), 2000. http://www.theses.fr/2000STR13023.

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Le travail decrit dans ce memoire porte sur la synthese asymetrique d'epoxydes et de cyclopropanes enantiomeriquement enrichis au depart d'ylures de soufre chiraux derives du (+)-(r,r,r)-oxathiane d'eliel. Les sels de sulfonium correspondants, aisement obtenus notamment grace a l'emploi de triflate d'argent, sont deprotones a l'aide de bases phosphazenes, deja utilisees avec succes lors d'additions de michael asymetriques en quantites catalytiques de base. Dans un premier temps les ylures ainsi obtenus ont ete mis en reaction avec des aldehydes aromatiques afin de generer des epoxydes diaromat

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43

Yet, Larry. "Chapter I: Synthesis and Chemistry of 1-(Benzenesulfonyl)-2- (Trimethylsilyl)Cyclopropane : Chapter II: 1,1-(Dilithio)-1- (Benzenesulfonyl)-2-(Trimethylsilyl)Ethane as an Effective Synthetic Equivalent for Symmetrical.. /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487864986611748.

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44

RECHSTEINER, BENNO. "Reactions organiques sans solvant activees par les microondes : application a la synthese d'enaminocetones, imidazolines, oxazolines et cyclopropanes." Rennes 1, 1994. http://www.theses.fr/1994REN10030.

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La premiere partie de ce travail est relative a la condensation de derives dicarbonyles avec les amines primaires et secondaires sans solvant et sous activation par les microondes. Cette reaction effectuee dans des recipients ouverts a une puissance d'irradiation determinee, conduit en quelques minutes a des enaminocetones avec d'excellents rendements. L'utilisation de recipients fermes entraine la formation d'acylamines. Dans la deuxieme partie, nous avons etendu notre etude a la condensation de diamines avec les composes dicarbonyles. Nous avons egalement mis en evidence l'influence des cond

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45

朱煒章 and Wai-cheung Chu. "Syntheses and reactions of copper and manganese complexes of tetradentate polyanionic chelating ligands and their applications incarbon-heteroatom bond formation reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B31236789.

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46

Chu, Wai-cheung. "Syntheses and reactions of copper and manganese complexes of tetradentate polyanionic chelating ligands and their applications in carbon-heteroatom bond formation reactions /." Hong Kong : University of Hong Kong, 1997. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19324893.

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47

Glass, Adam Cameron 1983. "The Synthesis of Novel and Sterically Demanding Tetra-ortho-substituted Aryl Naphthalenes." Thesis, University of Oregon, 2011. http://hdl.handle.net/1794/11978.

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xiv, 326 p. : ill. (some col.)<br>Tetra-ortho -substituted aryl naphthalenes (TOANs) are a motif of great importance, being present in biologically active natural products, chiral ligands, and building blocks relevant to materials science. The synthesis of sterically demanding and enantioenriched TOANs continues to be a challenge for current synthetic methods. Herein, we describe the highly effective synthesis of a variety of sterically demanding and enantioenriched TOANs through a rearrangement-based method. Our method utilizes a cyclopropyl carbinol moiety as the key rearrangement precurs

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48

Hewitt, Russell James. "Investigations of ring-opening reactions of cyclopropanated carbohydrates : towards the synthesis of the natural product (--)-TAN-2483B : a thesis submitted to the Victoria University of Wellington in fulfilment of the requirements for the degree of Doctor of Philosophy in Chemistry /." ResearchArchive@Victoria e-Thesis, 2010. http://hdl.handle.net/10063/1249.

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49

Kan, Tze-wai Jovi, and 簡紫慧. "Development of new polymer-supported reagents for organic synthesis, solvent effects in samarium promoted allylic alcohol cyclopropanationreactions and time resolved resonance studies of the photodeprotectionof p-hydroxyphenacyl caged phototrigger compounds." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B37925660.

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Denis, Alexis. "Fonctionnalisations selectives a l'aide des complexes du palladium : synthese de composes d'interet biologiques, cyclopropanes vinyliques, aryl-3 oxazolidinones-2 (inhibiteurs potentiels de la monoamine oxydase)." Paris 6, 1987. http://www.theses.fr/1987PA066335.

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Abstract:

Ce travail porte sur l'utilisation du palladium (o) pour la synthese de molecules d'interet biologique. En premier lieu, on decrit la synthese stereoselective de cyclopropanes vinyliques et de pyrethrinoides. Dans un second temps, on etudie l'echange acetate phenol et l'amination de derives allyliques fibonctionnels. Enfin, on presente la synthese d'aryl-3 dihydroxy-5,5 oxazolidones-2 erythro et threo et etudie leur utilisation en tant qu'inhibiteur d'enzyme monoamine oxidase

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