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Journal articles on the topic 'Synthesis of metal dithiocarbamates'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Maurya, Chandan, and Sangeeta Bajpai. "Biological Applications of Metal Complexes of Dithiocarbamates." Journal of Applied Science and Education (JASE) 2, no. 1 (2022): 1–16. http://dx.doi.org/10.54060/jase/002.01.002.

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Dithiocarbamates are organosulphur ligands and form chelate compounds with metals. Their uses are reported in the field of accelerating vulcanization, pesticide, material science, organic synthesis, etc. Recent research demonstrated the potential of metal complexes of these ligands as good antifungal, antibacterial, and antitumor agents. Dithiocarbamate complexes have also been reported to use as a plasmonic sensor, as an inhibitor of proteasome, and for antioxidant and antileishmanial activity. This brief review presents the biological activities of metal complexes of dithiocarbamate.

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2

Gallio, Andrea E., Leonardo Brustolin, Nicolò Pettenuzzo, and Dolores Fregona. "Binuclear Heteroleptic Ru(III) Dithiocarbamate Complexes: A Step towards Tunable Antiproliferative Agents." Inorganics 10, no. 3 (2022): 37. http://dx.doi.org/10.3390/inorganics10030037.

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Binuclear dithiocarbamate complexes of Ru(III) are promising candidates in the search for outstanding metal-based anticancer agents. While different dithiocarbamates have shown ligand-dependent cytotoxicity in homoleptic binuclear Ru(III) complexes, the properties of heteroleptic analogues with different dithiocarbamate (DTC) ligands have yet to be explored. We herein propose the introduction of heteroleptic ligands as tunable features for the development of improved ruthenium-based antiproliferative agents and report a synthetic strategy for their synthesis as well as the evaluation of the cy

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3

Khajavali, S., A. Jayaraju, and J. Sreeramulu. "Synthesis, Characterization and Biological activities of 2-Amino-3-Methyl pyridine New Dithiocarbamate metal complexes." Journal of Drug Delivery and Therapeutics 9, no. 3-s (2019): 36–39. http://dx.doi.org/10.22270/jddt.v9i3-s.2742.

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Dithiocarbamates are a class of sulfur-based metal-chelating compounds with various applications in medicine. A new series of new transition metal [Cu(II), and Ni(II)] complexes of dithiocarbamates were synthesized from 2-Amino-3-Methyl pyridine and Carbon disulfide and further characterized. The investigation of these complexes confirmed that the stability of metal–ligands coordination through, S&S,N atoms as bidendate chelates.. It is necessary to understand the binding properties in developing new potential Protein targeting against neurological disorders. Keywords:2-Amino-3-Methylpyrid

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4

Mangelsen, Sebastian, Patrick Zimmer, Christian Näther, and Wolfgang Bensch. "Nb2S4(CS2NH2)4—A New Precursor for NbS2 and Its Transition Metal Inserted Derivatives." Inorganics 11, no. 12 (2023): 478. http://dx.doi.org/10.3390/inorganics11120478.

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Transition metal inserted NbS2 (TxNbS2) compounds receive great attention due to their intriguing and diverse magnetic and electric transport properties. Typically, these compounds are prepared by high-temperature synthesis from the elements, which is time and energy-consuming and yields highly crystalline products. So far, no route for preparing these compounds from precursors by thermal decomposition has been reported. Herein, we report the synthesis of a dithiocarbamate of niobium Nb2S4(CS2NH2)4 as a precursor for the synthesis of NbS2 by this preparative strategy. Furthermore, we demonstra

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5

Saiyed, Tanzimjahan A., Jerry O. Adeyemi, and Damian C. Onwudiwe. "The structural chemistry of zinc(ii) and nickel(ii) dithiocarbamate complexes." Open Chemistry 19, no. 1 (2021): 974–86. http://dx.doi.org/10.1515/chem-2021-0080.

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Abstract Dithiocarbamate complexes are of immense interest due to their diverse structural properties and extensive application in various areas. They possess two sulfur atoms that often act as the binding sites for metal coordination in a monodentate, bidentate, or anisodentate fashion. These different coordination modes enhance the possibility for complex formation and make them useful in different areas especially in biomedical fields. A synergy exists in the metal ions and dithiocarbamate moieties, which tends to exert better properties than the respective individual components of the comp

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6

Siddiqi, Khwaja S., Shahab A. A. Nami, Lutfullah, and Yonas Chebude. "Template synthesis of symmetrical transition metal dithiocarbamates." Journal of the Brazilian Chemical Society 17, no. 1 (2006): 107–12. http://dx.doi.org/10.1590/s0103-50532006000100016.

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7

R. Mohammed, Eman, Intesar A. Sulleman, Shakir M. Saied, and Assim A. Sabah. "Synthesis of novel complexes derived from methyl or benzyl 4-amino antipyrinyl dithiocarbamtes with divalent Mn(II), Co(II), Ni(II), Zn(II) and Cu(II)." Bulletin of the Chemical Society of Ethiopia 39, no. 3 (2024): 447–57. https://doi.org/10.4314/bcse.v39i3.5.

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Two new ligands, methyl 4-amino antipyrinyl dithiocarbamates (MAC) and benzyl 4-amino antipyrinyl dithiocarbamates (BAC), were synthesized from 4-amino antipyrine and corresponding methyl or benzyl halides with potassium hydroxide in dimethylformamide. Then they were coordinated with five divalent transition metals: M = Mn, Co, Ni, Zn, and Cu(II) to produce ten novel complexes, [M(MAC)2]Cl2 I(a-e) and [M(BAC)2]Cl2 II(a-e), which were characterized by some physical properties and spectral methods, elemental analyses, molar conductance, and magnetic susceptibility, in addition to 1H NMR, FT-IR a

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8

Yeo, Chien Ing, Edward R. T. Tiekink, and Jactty Chew. "Insights into the Antimicrobial Potential of Dithiocarbamate Anions and Metal-Based Species." Inorganics 9, no. 6 (2021): 48. http://dx.doi.org/10.3390/inorganics9060048.

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Bacterial infection remains a worldwide problem that requires urgent addressing. Overuse and poor disposal of antibacterial agents abet the emergence of bacterial resistance mechanisms. There is a clear need for new approaches for the development of antibacterial therapeutics. Herein, the antibacterial potential of molecules based on dithiocarbamate anions, of general formula R(R’)NCS2(−), and metal salts of transition metals and main group elements, is summarized. Preclinical studies show a broad range of antibacterial potential, and these investigations are supported by appraisals of possibl

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9

Kareem, Abdul, Shahab A. A. Nami, Mohd Shoeb Khan, et al. "Self-assembled transition metal dithiocarbamates of pyridine-3-carboxamide: synthesis, spectral characterization, thermal and biological studies." New Journal of Chemistry 43, no. 11 (2019): 4413–24. http://dx.doi.org/10.1039/c8nj03660h.

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Synthesis of self assembled transition metal dithiocarbamates of pyridine-3-carboxamide by conventional as well as in situ methodology was reported. Characterization was done with a variety of spectroscopic techniques. Anticancer and antioxidant activity of ligand and its complexes is also tested.

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10

Ranu, Brindaban C., Kalicharan Chattopadhyay, Laksmikanta Adak, et al. "Metal nanoparticles as efficient catalysts for organic reactions." Pure and Applied Chemistry 81, no. 12 (2009): 2337–54. http://dx.doi.org/10.1351/pac-con-08-11-19.

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Pd(0) nanoparticles have been demonstrated to be very efficient catalysts for C–C bond-forming reactions. These include coupling of vicinal-diiodoalkenes and acrylic esters and nitriles leading to the stereoselective synthesis of 2-alkene-4-yn-esters and nitriles, allylation of active methylene compounds by allyl acetate, and Hiyama cross-coupling of aryliodides with arylsilanes. Cu(0) nanoparticles catalyze aryl-sulfur bond formation, accomplishing the synthesis of functionalized aryl sulfides and aryl- and vinyl dithiocarbamates. Cu nanoparticles have also been used for the chemoselective re

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11

Halimehjani, Azim, Yazdanbakhsh Nosood, Shaghayegh Didaran, and Fezzeh Aryanasab. "Metal-Free Oxidative Dimerization of Dithiocarbamates: Direct Access to 3,5-Bis-mercapto-1,2,4-thiadiazoles." SynOpen 01, no. 01 (2017): 0138–42. http://dx.doi.org/10.1055/s-0036-1590964.

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A facile and efficient protocol for the synthesis of 3,5-bis-mercapto-1,2,4-thiadiazoles by the oxidative dimerization of S-alkyl dithiocarbamates using periodic acid as an inexpensive and commercially available oxidant is reported. High to excellent yields and short reaction times are the main advantages of this procedure.

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12

Engelhardt, LM, PC Healy, BW Skelton, and AH White. "Lewis-Base Adducts of Group 11 Metal(I) Compounds. L. Heterobimetallic Tris(dithiocarbamato)metal(III)/Copper(I) Iodide Adducts [Metal(III) = Cr, Rh]." Australian Journal of Chemistry 42, no. 6 (1989): 885. http://dx.doi.org/10.1071/ch9890885.

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A variety of heterobimetallic adducts formed between tris(dithiocarbarnato)cobalt(lII) complexes and copper(1) halides have been recorded. In the present paper, reports of the synthesis and structure determinations of [Rh {S2CN(CH2)4}3]3Cul (1), [Cr(S2CNEt2)3]. [Cr(S2CNEt2)3] and [Cr{S2CN(CH2)4}3].3Cul.MeCN (3), similar to cobalt(llI) counterparts, suggest that, in principle, the previously described chemistry of the cobalt(III) systems may be extended to analogous systems for dithiocarbamates of any non-labile trivalent metal. The novel Cu3I3 ring of (3) is disordered between possible boat fo

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13

Martini, Petra, Alessandra Boschi, Lorenza Marvelli, et al. "Synthesis and Characterization of Manganese Dithiocarbamate Complexes: New Evidence of Dioxygen Activation." Molecules 26, no. 19 (2021): 5954. http://dx.doi.org/10.3390/molecules26195954.

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(1) Background: Metal dithiocarbamate compounds have long been the subject of research due to their ease of formation, excellent properties and potential applications. However, manganese complexes with dithiocarbamates, to our knowledge, have never been used for medical imaging applications. With the aim of developing a new class of mononuclear manganese(II)-based agents for molecular imaging applications, we performed a specific investigation into the synthesis of mononuclear bis-substituted Mn(II) complexes with dithiocarbamate ligands. (2) Methods: Synthesis in either open or inert atmosphe

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14

Cesarec, Sara, Fraser Edgar, Titan Lai, Christophe Plisson, Andrew J. P. White, and Philip W. Miller. "Synthesis of carbon-11 radiolabelled transition metal complexes using ¹¹C-dithiocarbamates." Dalton Transactions 51, no. 13 (2022): 5004–8. http://dx.doi.org/10.1039/d2dt00266c.

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15

McClain, Aliecia, and You-Lo Hsieh. "Synthesis of polystyrene-supported dithiocarbamates and their complexation with metal ions." Journal of Applied Polymer Science 92, no. 1 (2004): 218–25. http://dx.doi.org/10.1002/app.13623.

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16

Maurya, Chandan. "Glimpses of Synthesis and Biological Applications of Metal - Dithiocarbamate Derivatives." International Journal of Science and Research (IJSR) 11, no. 7 (2022): 876–86. http://dx.doi.org/10.21275/sr22708193015.

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17

Zungu, Mlungisi Malusi, and Viswanadha Srirama Rajasekhar Pullabhotla. "Exploring Diverse Precursors for Metal Sulfide Nanoparticle Synthesis: A Comprehensive Review." Research Journal of Chemistry and Environment 29, no. 2 (2024): 101–10. https://doi.org/10.25303/292rjce1010110.

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Metal complex chalcogenides and metal sulfides have been of interest in the scientific research world for their tunable chemical, optical and physical properties. A favourable synthesis method, using a single-source precursor for control purposes and the electrosynthesis method included for comparison reasons is articulated in this review. The effects of dithiocarbamates and their role in forming metal-sulfides' morphology are discussed. Based on the data collected by various microscopic and spectroscopic techniques, the chemical and physical properties of the metal-sulfides are also discussed

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18

Onwudiwe, Damian C., and Peter A. Ajibade. "Synthesis and characterization of metal complexes of N-alkyl-N-phenyl dithiocarbamates." Polyhedron 29, no. 5 (2010): 1431–36. http://dx.doi.org/10.1016/j.poly.2010.01.011.

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19

Onwudiwe, Damian C., and Anthony C. Ekennia. "Synthesis, characterization, thermal, antimicrobial and antioxidant studies of some transition metal dithiocarbamates." Research on Chemical Intermediates 43, no. 3 (2016): 1465–85. http://dx.doi.org/10.1007/s11164-016-2709-2.

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20

Aryanasab, Fezzeh, and Mohammad Reza Saidi. "Transition metal-free addition of dithiocarbamates to alkynes: one-pot regioselective synthesis of S-vinyl dithiocarbamates under solvent-free conditions." Monatshefte für Chemie - Chemical Monthly 145, no. 3 (2013): 521–26. http://dx.doi.org/10.1007/s00706-013-1112-6.

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21

Elliott, RL, PJ Nichols, and BO West. "Synthesis of Heterobinuclear Oxo-Bridged Compounds of Chromium, Iron, Manganese and Molybdenum." Australian Journal of Chemistry 39, no. 7 (1986): 975. http://dx.doi.org/10.1071/ch9860975.

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The synthesis of a series of heterobinuclear oxo -bridged compounds has been accomplished by redox reactions between FeII or MnII complexes of pentadentate and tetradentate salicylideneimines and thiosalicylideneimines and bidentate dithiocarbamates and either CrIVO ( tpp )( tpp ≡ dianion of 5,10,15,20-tetraphenylporphyrin) or MoVI (O)2( dtc )2 ( dtc ≡ diethyldithiocarbamato anion). The compounds are stable in solution in the absence of air but yield various homonuclear derivatives of the metals in its presence, these results indicating a degree of disproportionation of the oxo complexes. The

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22

Siddiqi, K. S., Shahab A. A. Nami, Lutfullah, and Yonas Chebude. "Synthesis, Characterization and Thermal Studies of Bipyridine Metal Complexes Containing Different Substituted Dithiocarbamates." Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 35, no. 6 (2005): 445–51. http://dx.doi.org/10.1081/sim-200066980.

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23

Aryanasab, Fezzeh, and Mohammad Reza Saidi. "ChemInform Abstract: Transition Metal-Free Addition of Dithiocarbamates to Alkynes: One-Pot Regioselective Synthesis of S-Vinyl Dithiocarbamates under Solvent-Free Conditions." ChemInform 45, no. 28 (2014): no. http://dx.doi.org/10.1002/chin.201428048.

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24

Kumar, Abhinav, Ratna Chauhan, Kieran C Molloy, Gabriele Kociok-Köhn, Lal Bahadur, and Nanhai Singh. "Synthesis, Structure and Light-Harvesting Properties of Some New Transition-Metal Dithiocarbamates Involving Ferrocene." Chemistry - A European Journal 16, no. 14 (2010): 4307–14. http://dx.doi.org/10.1002/chem.200903367.

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25

PRADIP, K. GOGOI, and P. PHUKAN DEBA. "Synthesis and Spectral Studies of 2-Methyl-piperazinedithiocarbamato Complexes with some First Row Transition Metals." Journal of Indian Chemical Society Vol. 68, Jul 1991 (1991): 377–79. https://doi.org/10.5281/zenodo.5990740.

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Department of Chemistry, Dibrugarh University, Dibrugarh-786 004 <em>Manuscript received 28 June 1989, revised 11 May 1990, accepted 18 July 7991</em> New complexes or Cr<sup>III</sup>, Fe<sup>III</sup>, Co<sup>II</sup> Ni<sup>II</sup> and Cu<sup>ll</sup> with 1-methylplperazlne- dithiocarbamate (2-Mepipzdtc) have been synthesised and characterised by elemental analyses magnetic. ir, electronic and esr spectral data The ligand exhibits bidentate nature and the complexes are soluble only in strongly coordinating and highly polar solvents like DMF and DMSO. From the esr spectral data of copper(I

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26

Ziyaei Halimehjani, A., and B. Breit. "Catalyst-free hydrothiolation of alkynes with dithiocarbamic acids." Chemical Communications 55, no. 9 (2019): 1253–55. http://dx.doi.org/10.1039/c8cc09726g.

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A highly regio- and stereocontrolled procedure for the synthesis of vinyl dithiocarbamates via catalyst-free hydrothiolation of unactivated alkynes with in situ prepared dithiocarbamic acids with total atom economy is reported.

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27

Victoriano, Luis I. "Erratum to “The reactivity of metal species towards thiuram sulfides: an alternative route to the synthesis of metal dithiocarbamates”." Coordination Chemistry Reviews 213, no. 1 (2001): 333. http://dx.doi.org/10.1016/s0010-8545(01)00306-x.

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28

Kane, Sonila, Pranvera Lazo, Fatos Ylli, Trajce Stafilov, Flora Qarri, and Elda Marku. "Separation of heavy metal from water samples—The study of the synthesis of complex compounds of heavy metal with dithiocarbamates." Journal of Environmental Science and Health, Part A 51, no. 4 (2016): 335–40. http://dx.doi.org/10.1080/10934529.2015.1109408.

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29

Siddiqi, K. S., and N. Nishat. "Synthesis and Characterization of Succinimide and Phthalevhde Dithiocarbamates and their Complexes with Some Transition Metal Ions." Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 30, no. 8 (2000): 1505–18. http://dx.doi.org/10.1080/00945710009351849.

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30

Bobinihi, Felicia F., Damian C. Onwudiwe, Anthony C. Ekennia, Obinna C. Okpareke, Charmaine Arderne, and Joseph R. Lane. "Group 10 metal complexes of dithiocarbamates derived from primary anilines: Synthesis, characterization, computational and antimicrobial studies." Polyhedron 158 (January 2019): 296–310. http://dx.doi.org/10.1016/j.poly.2018.10.073.

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31

Akhilesh, Kumar Srivastava. "Synthesis, spectroscopic and antibacterial studies on bis(cyclopentadienyl)- hafnium(IV) derivatives with dithiocarbamates derived from α-amino acids". Journal of Indian Chemical Society Vol. 86, Mar 2009 (2009): 281–86. https://doi.org/10.5281/zenodo.5808853.

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Chemistry Department, Bareilly College, Bareilly-243 001, Uttar Pradesh, India <em>E-mail</em> : aksbareilly@yahoo.co.in <em>Manuscript received 3 October 2007, revised 15 July 2008, accepted 21 October 2008</em> The reactions of bis(cyclopentadienyl)hafnium(IV) dichloride with novel dithiocarbamate ligands [Na<sub>2</sub>(S<sub>2</sub>CNH-(R)-COO)], derived from a-amino acids (glycine, leucine, β-alanine and dl-alanine), have been studied in THF/DMF mixture and binuclear complexes of type [{(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>HfCI}<sub>2</sub>(S<sub>2</sub>C-NH-(R)-COO)) ha

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32

Sardarian, Ali Reza, Iman Dindarloo Inaloo, and Ali Reza Modarresi-Alam. "Highly efficient synthesis of alkyl and aryl primary thiocarbamates and dithiocarbamates under metal- and solvent-free conditions." Molecular Diversity 22, no. 4 (2018): 863–78. http://dx.doi.org/10.1007/s11030-018-9831-6.

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33

Cheng, Yu, Han-Ying Peng, and Zhi-Bing Dong. "Synthesis of alkyl dithiocarbamates by using thiuram disulfide reagents: A metal-free C(sp3)-S bond formation." Tetrahedron Letters 60, no. 8 (2019): 617–20. http://dx.doi.org/10.1016/j.tetlet.2019.01.044.

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34

Victoriano, Luis I. "The reactivity of metal species towards thiuram sulfides: an alternative route to the syntheses of metal dithiocarbamates." Coordination Chemistry Reviews 196, no. 1 (2000): 383–98. http://dx.doi.org/10.1016/s0010-8545(99)00221-0.

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35

Hussain, Shabbir, Saqib Ali, and Saira Shahzadi. "Thermogravimetric and Biological Studies of Organotin(IV) Complexes with 4-(Hydroxymethyl)piperidine-1-Carbodithioic Acid." Proceedings of the Pakistan Academy of Sciences: B. Life and Environmental Sciences 58, no. 2 (2021): 91–98. http://dx.doi.org/10.53560/ppasb(58-2)633.

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Present studies were conducted to perform thermogravimetric characterization and biological activity investigations of organotin dithiocarbamates of general formulae R3SnL (R = n-Bu, 1; Ph, 2; Cy, 3), R2Sn(Cl)L (R = Me, 4; Ph, 5) and R2SnL2 (R = Me, 6) where L = 4-(hydroxymethyl)piperidine-1-carbodithioate. A novel procedure was also developed for the synthesis of product 2 by direct reflux of 4-(hydroxymethyl)piperidine-1-carbodithioic acid (HL) with triphenyltin(IV) hydroxide. HL was decomposed at low temperatures as compared to the metal complexes. The coordinated products were degraded lea

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36

Nami, Shahab A. A., Irfan Ullah, Mahboob Alam, Dong-Ung Lee, and Nursabah Sarikavakli. "Synthesis, characterization, molecular docking and biological studies of self assembled transition metal dithiocarbamates of substituted pyrrole-2-carboxaldehyde." Journal of Photochemistry and Photobiology B: Biology 160 (July 2016): 392–99. http://dx.doi.org/10.1016/j.jphotobiol.2016.05.010.

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S. Al-fahdawi, Aeed, Shaaban K. Mohamed, Herman Potgeiter, and Abdullatif Alfutimie. "Heavy metal ions in polluted water removable by synthesising a new compounds for dithiocarbamate derivatives." Bulletin of the Chemical Society of Ethiopia 38, no. 6 (2024): 1583–93. http://dx.doi.org/10.4314/bcse.v38i6.7.

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Metal ion poisoning in water and industrial effluents threatens ecosystems and human health. The development of efficient metal ion removal technologies has garnered attention in recent years. This work synthesizes and characterizes dithiocarbamate complexes as metal ion scavengers. Used to make dithiocarbamate ligands. Different metal salts were added to carbon disulfide and the proper amines to initiate substitution reactions. The complexes were characterized using FTIR, UV-Vis, mass spectroscopy, 13C-, 1H-NMR, magnetic susceptibility, melting point, and electrical conductivity molar EC. Dat

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38

Laxmi, Gond, and Bajpai Anjali. "Synthesis, characterization and application of gelatine and dithiocarbamylated chitin." Abstracts of International Conferences & Meetings (AICM) 1, no. 3 (2021): 14. https://doi.org/10.5281/zenodo.5047579.

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<strong>Introduction: </strong>Gelatin or gelatine is a translucent, colorless, flavorless, and biodegradable material obtained from collagen present in animal body parts, such as skin, bones, and connective tissues of animals, e.g., domestic cattle, chicken, pigs, and fish. It is a mixture of peptides and proteins obtained by acid and alkaline processing of collagen and is commonly used as a gelling agent in food, pharmaceuticals, photographic films and papers, and cosmetics. Dithiocarbamates (DTC) are well known adsorbents (1-2). We reported preparation and characterization of dithiocarbamyl

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39

Leka, Zorica, Slobodan Grujic, Zivoslav Tesic, Svetlana Lukic, Sonja Skuban, and Srecko Trifunovic. "The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate." Journal of the Serbian Chemical Society 69, no. 2 (2004): 137–44. http://dx.doi.org/10.2298/jsc0402137l.

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Complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2.nH2O (M= Zn(II), Cd(II), n = 2, or M= Pt(II) Pd(II), n = 0), have been prepared and characterized by elemental analysis IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl este

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40

Sivasekar, Subburayan, Kuppukkannu Ramalingam, and Corrado Rizzoli. "Metal dithiocarbamate precursors for the preparation of a binary sulfide and a pyrochlore: Synthesis, structure, continuous shape measure and bond valence sum analysis of antimony(III) dithiocarbamates." Polyhedron 85 (January 2015): 598–606. http://dx.doi.org/10.1016/j.poly.2014.09.028.

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41

Victoriano, Luis I. "ChemInform Abstract: The Reactivity of Metal Species Towards Thiuram Sulfides: An Alternative Route to the Syntheses of Metal Dithiocarbamates." ChemInform 31, no. 13 (2010): no. http://dx.doi.org/10.1002/chin.200013240.

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42

Lu, Chengrong, Lijuan Hu, Bei Zhao, and Yingming Yao. "Addition of Thiols to Isocyanates Catalyzed by Simple Rare-Earth-Metal Amides: Synthesis of S-Alkyl Thiocarbamates and Dithiocarbamates." Organometallics 38, no. 9 (2019): 2167–73. http://dx.doi.org/10.1021/acs.organomet.9b00147.

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Abbas Ali, Wissam, Hayder Mihsen, and Sajid H. Guzar. "Synthesis, Characterization and Antibacterial Activity of Sn(II) and Sn(IV) Ions Complexes Containing N-Alkyl-N-Phenyl Dithiocarbamate Ligands." Chemistry & Chemical Technology 17, no. 4 (2023): 729–39. http://dx.doi.org/10.23939/chcht17.04.729.

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In the current study, ligands S2 donor atoms, sodium N-methyl-N-phenyldithiocarbamate [L1], and sodium N-ethyl-N-phenyldithiocarbamate [L2] are prepared from carbon disulfide with N-methyl aniline and N-ethyl aniline, respectively. Sn(II) and Sn(IV) ions complexes containing N-alkyl-N-Phenyl dithiocarbamateare prepared and characterized by CHNS elemental analysis, infrared spectroscopy (FT-IR), 1HNMR-spectroscopy, mass spectroscopy, UV-visible spectroscopy, magnetic susceptibility and conductivity measurements. The analytical and spectral data show that the stoichiometry for all complexes is 1

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Burdonov, A. E., N. V. Vchislo, E. A. Verochkina, and I. B. Rozentsveig. "Synthesis of new dithiocarbamate and xanthate complexes and their application in enrichment processes." Proceedings of Universities. Applied Chemistry and Biotechnology 13, no. 2 (2023): 160–71. http://dx.doi.org/10.21285/2227-2925-2023-13-2-160-171.

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Ore flotation is the main and defining technological process in ore benefication and non-ferrous metals production. The flotation process requires the use of a variety of chemical reagents, including collectors, frothers, surface modifiers, and pH regulators. The development and selection of suitable reagents for the processed material play a vital role in efficient flotation. The flotation activity of collectors depends fundamentally on the composition and structure of the hydrophobic and hydrophilic fragments forming the flotation agent molecule, as well as on the nature of the ore that unde

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Nasir, H. M., T. A. Saki, and M. Y. Al-Luaibi. "Synthesis, identification and thermal study of some new inorganic polymers based on bis-dithiocarbamate ligands with silicone, tellurium and some transition metals." Innovaciencia Facultad de Ciencias Exactas Físicas y Naturales 7, no. 1 (2019): 1–13. http://dx.doi.org/10.15649/2346075x.507.

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Introduction: In recent years, there has been considerable interest in dithiocarbamate complexes because of its diverse biological roles, very few reports have been made on polymeric bis- dithiocarbamate compounds with carbon chain of n-propyl or hexamethelene with transition metals in addition of the absence of any report of organosilicone or tellurium halides with such compounds Our interest in this report based on the preparation of new series of polymers with an expected activity as a fungi side compounds followed by the using of prepared amino compound as a hardners for epoxy paints Mater

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Chatterjee, Tanmay, Sukalyan Bhadra, and Brindaban C. Ranu. "Transition metal-free procedure for the synthesis of S-aryl dithiocarbamates using aryl diazonium fluoroborate in water at room temperature." Green Chemistry 13, no. 7 (2011): 1837. http://dx.doi.org/10.1039/c1gc00001b.

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Peng, Han-Ying, and Zhi-Bing Dong. "Transition-Metal-Free C(sp3 )-S Coupling in Water: Synthesis of Benzyl Dithiocarbamates Using Thiuram Disulfides as an Organosulfur Source." European Journal of Organic Chemistry 2019, no. 5 (2018): 949–56. http://dx.doi.org/10.1002/ejoc.201801520.

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Hao, Shuai, Xiefeng Ye, Mingqin Zhao, et al. "Synthesis of 2‐Aryl‐2‐hydroxyethyl Dithiocarbamates via Regioselective Addition of Tetraalkylthiuram Disulfides to Styrenes under Transition‐Metal‐Free Conditions." Advanced Synthesis & Catalysis 362, no. 22 (2020): 5014–19. http://dx.doi.org/10.1002/adsc.202000729.

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Roffey, Anna, Nathan Hollingsworth, and Graeme Hogarth. "Synthesis of ternary sulfide nanomaterials using dithiocarbamate complexes as single source precursors." Nanoscale Advances 1, no. 8 (2019): 3056–66. http://dx.doi.org/10.1039/c9na00275h.

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Heating mixtures of dithiocarbamate complexes in oleylamine leads to the formation of nanoparticulate ternary metal sulfides, the physical nature and phase of which can be tailored depending upon the reaction conditions adopted.

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Zheng, Huai-li, Xiu-ping Sun, Qiang He, Kun Liang, and Peng Zhang. "Synthesis and trapping properties of dithiocarbamate macromolecule heavy-metal flocculants." Journal of Applied Polymer Science 110, no. 4 (2008): 2461–66. http://dx.doi.org/10.1002/app.28526.

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