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Journal articles on the topic 'Synthetic host-guest chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 6 February 2022

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1

Kilburn, Jeremy D., and Hitesh K. Patel. "Synthetic developments in host–guest chemistry." Contemp. Org. Synth. 1, no. 4 (1994): 259–86. http://dx.doi.org/10.1039/co9940100259.

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2

Dowden, James, Jeremy D. Kilburn, and Paul Wright. "Synthetic developments in host–guest chemistry." Contemp. Org. Synth. 2, no. 5 (1995): 289–314. http://dx.doi.org/10.1039/co9950200289.

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3

Perry, Justin J. B., and Jeremy D. Kilburn. "Synthetic developments in host–guest chemistry." Contemp. Org. Synth. 4, no. 1 (1997): 61–86. http://dx.doi.org/10.1039/co9970400061.

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4

Organo, Voltaire G., and Dmitry M. Rudkevich. "Emerging host–guest chemistry of synthetic nanotubes." Chemical Communications, no. 38 (2007): 3891. http://dx.doi.org/10.1039/b704231k.

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5

DOWDEN, J., J. D. KILBURN, and P. WRIGHT. "ChemInform Abstract: Synthetic Developments in Host-Guest Chemistry." ChemInform 27, no. 20 (2010): no. http://dx.doi.org/10.1002/chin.199620252.

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6

KILBURN, J. D., and H. K. PATEL. "ChemInform Abstract: Synthetic Developments in Host-Guest Chemistry." ChemInform 26, no. 20 (2010): no. http://dx.doi.org/10.1002/chin.199520269.

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7

PERRY, J. J. B., and J. D. KILBURN. "ChemInform Abstract: Synthetic Developments in Host-Guest Chemistry." ChemInform 28, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.199725269.

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8

Hof, Fraser. "Host–guest chemistry that directly targets lysine methylation: synthetic host molecules as alternatives to bio-reagents." Chemical Communications 52, no. 66 (2016): 10093–108. http://dx.doi.org/10.1039/c6cc04771h.

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Post-translational methylation regulates the function of hundreds of proteins in profound ways, and is the target of many efforts to use host–guest chemistry to solve biochemical and biological problems.

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9

Zyryanov, Grigory V., and Dmitry M. Rudkevich. "Toward Synthetic Tubes for NO2/N2O4: Design, Synthesis, and Host−Guest Chemistry." Journal of the American Chemical Society 126, no. 13 (2004): 4264–70. http://dx.doi.org/10.1021/ja0392869.

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10

Wang, Guo, Hui Qiang, Yun-Zhe Guo, Jie Yang, Ke Wen, and Wei-Bo Hu. "Systematic rim cyano-functionalization of pillar[5]arene and corresponding host–guest property varieties." Organic & Biomolecular Chemistry 17, no. 18 (2019): 4600–4604. http://dx.doi.org/10.1039/c9ob00396g.

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Synthetic investigation of the systematic replacement of alkoxy groups in pillar[5]arene by cyano ones was carried out. Host–guest property studies of nCN-pillar[5]arenes and 1,4-dicyanobutane showed the functionization number related host–guest interaction varieties.

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11

Beatty, Meagan A., and Fraser Hof. "Host–guest binding in water, salty water, and biofluids: general lessons for synthetic, bio-targeted molecular recognition." Chemical Society Reviews 50, no. 8 (2021): 4812–32. http://dx.doi.org/10.1039/d0cs00495b.

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12

Shurpik, Dmitriy N., Alan A. Akhmedov, Peter J. Cragg, Vitaliy V. Plemenkov, and Ivan I. Stoikov. "Progress in the Chemistry of Macrocyclic Meroterpenoids." Plants 9, no. 11 (2020): 1582. http://dx.doi.org/10.3390/plants9111582.

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In the last decade, the chemistry of meroterpenoids—conjugated molecules formed from isoprenyl fragments through biosynthetic pathways—has developed rapidly. The class includes some natural metabolites and fully synthetic fragments formed through nonbiological synthesis. In the field of synthetic receptors, a range of structures can be achieved by combining fragments of different classes of organic compounds into one hybrid macrocyclic platform which retains the properties of these fragments. This review discusses the successes in the synthesis and practical application of both natural and syn

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13

Sawada, Tomohisa, Hayato Hisada, and Makoto Fujita. "Mutual Induced Fit in a Synthetic Host–Guest System." Journal of the American Chemical Society 136, no. 12 (2014): 4449–51. http://dx.doi.org/10.1021/ja500376x.

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14

Mendoza, Johan, Luis Cruz, Victor de Freitas, Fernando Pina, and Nuno Basílio. "Anthocyanin Color Stabilization by Host-Guest Complexation with p-Sulfonatocalix[n]arenes." Molecules 26, no. 17 (2021): 5389. http://dx.doi.org/10.3390/molecules26175389.

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Flavylium-based compounds in their acidic and cationic form bring color to aqueous solutions, while under slightly acidic or neutral conditions they commonly bring discoloration. Selective host-guest complexation between water-soluble p-sulfonatocalix[n]arenes (SCn) macrocycles and the flavylium cationic species can increase the stability of the colored form, expanding its domain over the pH scale. The association constants between SCn and the cationic (acid) and neutral basic forms of flavylium-based compounds were determined through UV-Vis host-guest titrations at different pH values. The af

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15

Murphy, Rhys B., Duc-Truc Pham, Jonathan M. White, Stephen F. Lincoln, and Martin R. Johnston. "Molecular tweezers with a rotationally restricted linker and freely rotating porphyrin moieties." Organic & Biomolecular Chemistry 16, no. 34 (2018): 6206–23. http://dx.doi.org/10.1039/c8ob00944a.

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The different host–guest behaviour of non-interconvertible bis-porphyrin tweezer isomers was examined, contributing to ongoing discussions regarding rigidity/flexibility and preorganisation in synthetic receptors.

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16

Mandal, Pradeep K., Brice Kauffmann, Harry Destecroix, Yann Ferrand, Anthony P. Davis та Ivan Huc. "Crystal structure of a complex between β-glucopyranose and a macrocyclic receptor with dendritic multicharged water solubilizing chains". Chemical Communications 52, № 60 (2016): 9355–58. http://dx.doi.org/10.1039/c6cc04466b.

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17

Gubeli, R. J., S. Sonzini, A. Podmore, P. Ravn, O. A. Scherman, and C. F. van der Walle. "Selective, non-covalent conjugation of synthetic peptides with recombinant proteins mediated by host–guest chemistry." Chemical Communications 52, no. 22 (2016): 4235–38. http://dx.doi.org/10.1039/c6cc00405a.

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18

Suwinska, Kinga. "Intermolecular interactions in inclusion complexes." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C673. http://dx.doi.org/10.1107/s2053273314093267.

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The whole range of interactions can be found between host and guest in supramolecular assemblies from ion-ion interactions, ion-dipole interactions, dipol-dipol interactions through hydrogen bonding, cation-π interactions, π-π stacking to van der Waals forces. Additionally, the same interactions exist between the supramolecular complex and its surrounding, i.e. solvent molecules, neighboring complexes, gases, etc. Recently the interest of scientists in the field of supramolecular chemistry is focused on design and synthesis of water-soluble synthetic macrocyclic ligands which are good receptor

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19

Kuang, Shengjian, Zhixiong Hu, Hao Zhang, et al. "Enhancement of metal–metal interactions inside a large-cavity synthetic host in water." Chemical Communications 54, no. 17 (2018): 2169–72. http://dx.doi.org/10.1039/c8cc00593a.

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20

Silva, Vera L. M., and Artur M. S. Silva. "Palladium-Catalysed Synthesis and Transformation of Quinolones." Molecules 24, no. 2 (2019): 228. http://dx.doi.org/10.3390/molecules24020228.

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Palladium-catalysed reactions have had a large impact on synthetic organic chemistry and have found many applications in target-oriented synthesis. Their widespread use in organic synthesis is due to the mild conditions associated with the reactions together with their tolerance of a wide range of functional groups. Moreover, these types of reactions allow the rapid construction of complex molecules through multiple bond-forming reactions in a single step, the so-called tandem processes. Pd-catalysed reactions have been applied to the synthesis of a large number of natural products and bioacti

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21

Kost, Bartłomiej, Marek Brzeziński, Marta Socka, Małgorzata Baśko, and Tadeusz Biela. "Biocompatible Polymers Combined with Cyclodextrins: Fascinating Materials for Drug Delivery Applications." Molecules 25, no. 15 (2020): 3404. http://dx.doi.org/10.3390/molecules25153404.

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Cyclodextrins (CD) are a group of cyclic oligosaccharides with a cavity/specific structure that enables to form inclusion complexes (IC) with a variety of molecules through non-covalent host-guest interactions. By an elegant combination of CD with biocompatible, synthetic and natural polymers, different types of universal drug delivery systems with dynamic/reversible properties have been generated. This review presents the design of nano- and micro-carriers, hydrogels, and fibres based on the polymer/CD supramolecular systems highlighting their possible biomedical applications. Application of

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22

Yang, Liu-Pan, Song-Bo Lu, Arto Valkonen, Fangfang Pan, Kari Rissanen, and Wei Jiang. "A conformationally adaptive macrocycle: conformational complexity and host–guest chemistry of zorb[4]arene." Beilstein Journal of Organic Chemistry 14 (June 27, 2018): 1570–77. http://dx.doi.org/10.3762/bjoc.14.134.

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Large amplitude conformational change is one of the features of biomolecular recognition and is also the basis for allosteric effects and signal transduction in functional biological systems. However, synthetic receptors with controllable conformational changes are rare. In this article, we present a thorough study on the host–guest chemistry of a conformationally adaptive macrocycle, namely per-O-ethoxyzorb[4]arene (ZB4). Similar to per-O-ethoxyoxatub[4]arene, ZB4 is capable of accommodating a wide range of organic cations. However, ZB4 does not show large amplitude conformational responses t

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23

Gomez-Casado, Alberto, Henk H. Dam, M. Deniz Yilmaz, Daniel Florea, Pascal Jonkheijm, and Jurriaan Huskens. "Probing Multivalent Interactions in a Synthetic Host–Guest Complex by Dynamic Force Spectroscopy." Journal of the American Chemical Society 133, no. 28 (2011): 10849–57. http://dx.doi.org/10.1021/ja2016125.

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24

Sung, Gihyun, Song-Yi Lee, Myeong-Gyun Kang, et al. "Supra-blot: an accurate and reliable assay for detecting target proteins with a synthetic host molecule–enzyme hybrid." Chemical Communications 56, no. 10 (2020): 1549–52. http://dx.doi.org/10.1039/c9cc09699j.

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25

Cohen, Yoram, Sarit Slovak, and Liat Avram. "Solution NMR of synthetic cavity containing supramolecular systems: what have we learned on and from?" Chemical Communications 57, no. 71 (2021): 8856–84. http://dx.doi.org/10.1039/d1cc02906a.

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NMR has played a pivotal role in the study of host–guest complexes and supramolecular systems. Here selected examples are used to demonstrate the impact and the added values of using multi-parametric NMR when studying such systems in solution.

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26

Sheng, Tian-Pu, Xin-Xia Fan, Guo-Zong Zheng, Feng-Rong Dai, and Zhong-Ning Chen. "Cooperative Binding and Stepwise Encapsulation of Drug Molecules by Sulfonylcalixarene-Based Metal-Organic Supercontainers." Molecules 25, no. 11 (2020): 2656. http://dx.doi.org/10.3390/molecules25112656.

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The cooperative binding behavior of a face-directed octahedral metal-organic supercontainer featuring one endo cavity and six exo cavities was thoroughly examined in chloroform solution through ultraviolet-visible (UV-Vis) titration technique using two representative drug molecules as the guests. The titration curves and their nonlinear fit to Hill equation strongly suggest the efficient encapsulation of the guest molecules by the synthetic host, which exhibit interesting cooperative and stepwise binding behavior. Based on the control experiments using tetranuclear complex as a reference, it i

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27

Schneider, Hans-J�rg, and Thomas Blatter. "Modification of Hydrophobic and Polar Interactions by Charged Groups in Synthetic Host-Guest Complexes." Angewandte Chemie International Edition in English 27, no. 9 (1988): 1163–64. http://dx.doi.org/10.1002/anie.198811631.

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28

Sapchenko, Sergey A., Danil N. Dybtsev, and Vladimir P. Fedin. "Cage amines in the metal–organic frameworks chemistry." Pure and Applied Chemistry 89, no. 8 (2017): 1049–64. http://dx.doi.org/10.1515/pac-2016-1206.

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AbstractNitrogen-rich porous materials have outstanding gas sorption and separation capacity. Using cage amines in the synthesis of metal–organic frameworks is a simple approach for generating the free nitrogen donor centers within the channels of porous materials without the post-synthetic modification. 1,4-Diazabicyclo[2.2.2]octane has a linear arrangement of nitrogen centers and can be used as a linear linker for the design of porous MOF materials. Urotropine has four nitrogen atoms and can act as a tetrahedral four-connected, pyramidal three-connected or bent two-connected linker. Such a d

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29

Mbarek, Amira, Ghina Moussa, and Jeanne Leblond Chain. "Pharmaceutical Applications of Molecular Tweezers, Clefts and Clips." Molecules 24, no. 9 (2019): 1803. http://dx.doi.org/10.3390/molecules24091803.

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Synthetic acyclic receptors, composed of two arms connected with a spacer enabling molecular recognition, have been intensively explored in host-guest chemistry in the past decades. They fall into the categories of molecular tweezers, clefts and clips, depending on the geometry allowing the recognition of various guests. The advances in synthesis and mechanistic studies have pushed them forward to pharmaceutical applications, such as neurodegenerative disorders, infectious diseases, cancer, cardiovascular disease, diabetes, etc. In this review, we provide a summary of the synthetic molecular t

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30

Klärner, Frank-Gerrit, Johannes Benkhoff, Roland Boese, Ulrich Burkert, Markus Kamieth, and Ulf Naatz. "Molecular Tweezers as Synthetic Receptors in Host—Guest Chemistry: Inclusion of Cyclohexane and Self-Assembly of Aliphatic Side Chains." Angewandte Chemie International Edition in English 35, no. 10 (1996): 1130–33. http://dx.doi.org/10.1002/anie.199611301.

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31

Sasmal, Ranjan, Nilanjana Das Saha, Meenakshi Pahwa, et al. "Synthetic Host–Guest Assembly in Cells and Tissues: Fast, Stable, and Selective Bioorthogonal Imaging via Molecular Recognition." Analytical Chemistry 90, no. 19 (2018): 11305–14. http://dx.doi.org/10.1021/acs.analchem.8b01851.

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32

Nuñez, Ana J., Maxwell S. Chang, Ilich A. Ibarra, and Simon M. Humphrey. "Tuning the Host–Guest Interactions in a Phosphine Coordination Polymer through Different Types of post-Synthetic Modification." Inorganic Chemistry 53, no. 1 (2013): 282–88. http://dx.doi.org/10.1021/ic4022239.

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33

Wang, Yi, Jason R. King, Pan Wu, Daniel L. Pelzman, David N. Beratan, and Eric J. Toone. "Enthalpic Signature of Methonium Desolvation Revealed in a Synthetic Host–Guest System Based on Cucurbit[7]uril." Journal of the American Chemical Society 135, no. 16 (2013): 6084–91. http://dx.doi.org/10.1021/ja311327v.

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34

Kowalewska, Anna, and Maria Nowacka. "Supramolecular Interactions in Hybrid Polylactide Blends—The Structures, Mechanisms and Properties." Molecules 25, no. 15 (2020): 3351. http://dx.doi.org/10.3390/molecules25153351.

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The conformation of polylactide (PLA) chains can be adjusted by supramolecular interactions (the formation of hydrogen bonds or host-guest complexes) with appropriate organic molecules. The structures formed due to those intermolecular interactions may act as crystal nuclei in the PLA matrix (“soft templating”). In this review, the properties of several supramolecular nucleating systems based on synthetic organic nucleators (arylamides, hydrazides, and 1,3:2,4-dibenzylidene-d-sorbitol) are compared to those achieved with biobased nucleating agents (orotic acid, humic acids, fulvic acids, nanoc

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35

SCHNEIDER, H. J., and D. RUF. "ChemInform Abstract: Host-Guest Chemistry. Part 24. A Synthetic Allosteric System with High Cooperativity Between Polar and Hydrophobic Binding Sites." ChemInform 22, no. 1 (2010): no. http://dx.doi.org/10.1002/chin.199101076.

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36

Ruloff, Robert, Uta P. Seelbach, André E. Merbach, and Frank-Gerrit Klärner. "Molecular tweezers as synthetic receptors: the effect of pressure and temperature on the formation of host-guest complexes." Journal of Physical Organic Chemistry 15, no. 4 (2002): 189–96. http://dx.doi.org/10.1002/poc.477.

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37

Colasson, Benoit, and Olivia Reinaud. "Selective Hetero-Trisfunctionalization of the Large Rim of a Biomimetic Calix[6]arene Using Host−Guest Chemistry as a Synthetic Tool." Journal of the American Chemical Society 130, no. 46 (2008): 15226–27. http://dx.doi.org/10.1021/ja803878g.

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38

Xue, Bin, Dehua Tang, Xin Wu, et al. "Engineering hydrogels with homogeneous mechanical properties for controlling stem cell lineage specification." Proceedings of the National Academy of Sciences 118, no. 37 (2021): e2110961118. http://dx.doi.org/10.1073/pnas.2110961118.

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The extracellular matrix (ECM) is mechanically inhomogeneous due to the presence of a wide spectrum of biomacromolecules and hierarchically assembled structures at the nanoscale. Mechanical inhomogeneity can be even more pronounced under pathological conditions due to injury, fibrogenesis, or tumorigenesis. Although considerable progress has been devoted to engineering synthetic hydrogels to mimic the ECM, the effect of the mechanical inhomogeneity of hydrogels has been widely overlooked. Here, we develop a method based on host–guest chemistry to control the homogeneity of maleimide–thiol cros

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39

Wang, Yi, Jason R. King, Pan Wu, Daniel L. Pelzman, David N. Beratan, and Eric J. Toone. "Correction to “Enthalpic Signature of Methonium Desolvation Revealed in a Synthetic Host–Guest System Based on Cucurbit[7]uril”." Journal of the American Chemical Society 135, no. 46 (2013): 17650. http://dx.doi.org/10.1021/ja408346j.

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40

Yang, Zhengqiang, Guanqun Cai, Craig L. Bull, et al. "Hydrogen-bond-mediated structural variation of metal guanidinium formate hybrid perovskites under pressure." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 377, no. 2149 (2019): 20180227. http://dx.doi.org/10.1098/rsta.2018.0227.

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The hybrid perovskites are coordination frameworks with the same topology as the inorganic perovskites, but with properties driven by different chemistry, including host-framework hydrogen bonding. Like the inorganic perovskites, these materials exhibit many different phases, including structures with potentially exploitable functionality. However, their phase transformations under pressure are more complex and less well understood. We have studied the structures of manganese and cobalt guanidinium formate under pressure using single-crystal X-ray and powder neutron diffraction. Under pressure

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41

Čeklovský, Alexander, and Shinsuke Takagi. "Oxygen sensing materials based on clay/metalloporphyrin hybrid systems." Open Chemistry 11, no. 7 (2013): 1132–36. http://dx.doi.org/10.2478/s11532-013-0238-z.

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AbstractThis study was focused on the investigation of novel hybrid organo/inorganic systems for oxygen sensing applications. As a host material, a synthetic clay mineral Sumecton SA was chosen, while, as guest materials, metalloporphyrins containing Pt(II) and Pd(II) were chosen. These are known to be very efficient agents for sensing applications because of a “heavy atom effect”. This effect promotes a spin-orbit coupling, resulting in the fact that almost all of the radiation from a singlet excited state undergoes intersystem crossing, followed by a de-excitation via a triplet state. The co

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42

Arrais, Aldo, Marta Manzoni, Alessia Cattaneo, et al. "Host–Guest Inclusion Complexes of Essential Oils with Strong Antibacterial and Antifungal Features in Beta-Cyclodextrin for Solid-State Pharmaceutical Applications." Applied Sciences 11, no. 14 (2021): 6597. http://dx.doi.org/10.3390/app11146597.

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Essential oils are widely recognized as natural alternatives to pharmaceutical antibacterial and antifungal agents. With respect to standard pharmaceutics, the advantages of essential oils are their (i) low production costs, (ii) lack of chemical and biochemical drawbacks that are intrinsic to the synthetic production process and (iii) good tolerance by humans. On the other hand, the liquid nature of essential oils poses concerns about their actual application in different therapeutic issues regarding their persistence and the ability to control or prolong drug release. In this study, two esse

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43

Li, Meng, Ara Lee, Kyung Lock Kim, et al. "Autophagy Caught in the Act: A Supramolecular FRET Pair Based on an Ultrastable Synthetic Host-Guest Complex Visualizes Autophagosome-Lysosome Fusion." Angewandte Chemie International Edition 57, no. 8 (2018): 2120–25. http://dx.doi.org/10.1002/anie.201711629.

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44

Sartorius, Joachim, and Hans-Jörg Schneider. "A General Scheme Based on Empirical Increments for the Prediction of Hydrogen-Bond Associations of Nucleobases and of Synthetic Host–Guest complexes." Chemistry - A European Journal 2, no. 11 (1996): 1446–52. http://dx.doi.org/10.1002/chem.19960021118.

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45

Mio, Matthew J., and Jeffrey S. Moore. "Supramolecular Aufbau: Folded Polymers as Building Blocks for Adaptive Organic Materials." MRS Bulletin 25, no. 4 (2000): 36–41. http://dx.doi.org/10.1557/mrs2000.27.

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The design of inorganic and organic solids with novel structures and properties has long been the object of materials research. The classical examples of porous materials (i.e., involving reversible guest passage) are zeolites. First discovered in the mid-1700s, zeolites are hydrated, crystalline aluminosilicates that organize into stable, discrete frameworks. Basic structures employ tetrahedral atoms (silicon or aluminum) bridged by oxygen atoms, where each oxygen is shared between two metalloid tetrahedra. Resulting covalent lattices can be neutral or negatively charged (as a result of bridg

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46

Choy, Jin-Ho, Soon-Jae Kwon, Seong-Ju Hwang, and Eue-Soon Jang. "Soft Chemical Routes to Heterostructured High-Tc Superconducting Materials." MRS Bulletin 25, no. 9 (2000): 32–39. http://dx.doi.org/10.1557/mrs2000.177.

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Recently, inorganic/inorganic and organic/inorganic heterostructured materials have attracted considerable research interest, due to their unusual physicochemical properties, which cannot be achieved by conventional solid-state reactions. In order to develop new hybrid materials, various synthetic approaches, such as vacuum deposition, Langmuir–Blodgett films, selfassembly, and intercalation techniques, have been explored. Among them, the intercalation reaction technique—that is, the reversible insertion of guest species into the two-dimensional host lattice—is expected to be one of the most e

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47

Sydnes, Leiv K. "Preface." Pure and Applied Chemistry 79, no. 1 (2007): iv. http://dx.doi.org/10.1351/pac20077901iv.

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For IUPAC, the global, scientific organization that cares about chemistry and the chemical sciences in all senses of the word, it is a duty, but also a pleasure to follow the development in chemical research closely with the aim of spotting pioneering work and new trends as early as possible. In doing so, it became abundantly clear that the young chemists were about to become more important for the future of our science than they were just a decade or so ago. For chemistry, it is therefore important to encourage our young colleagues in their work, and IUPAC does so through the IUPAC Prize for

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48

Sudhölter, Ernst J. R., Peter D. van der Wal, Maria Skowronska-Ptasinska, Albert van den Berg, David N. Reinhoudt, and Piet Bergveld. "Transduction of host-guest complexation into electronic signals: Favoured complexation of potassium ions by synthetic macrocyclic polyethers using membrane-modified, ion-sensitive field-effect transistors (ISFETs)." Recueil des Travaux Chimiques des Pays-Bas 109, no. 3 (1990): 222–25. http://dx.doi.org/10.1002/recl.19901090316.

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49

Nortcliffe, Chris, Lukasz G. Migas, Xuejian Liu, Huy Tien Ngo, Katrina A. Jolliffe, and Perdita E. Barran. "The potential of ion mobility mass spectrometry for tuning synthetic host guest systems: A case study using novel zinc(II)dipicolylamine anion sensors." International Journal of Mass Spectrometry 391 (November 2015): 62–70. http://dx.doi.org/10.1016/j.ijms.2015.07.030.

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50

Khan, Sadaf Bashir, and Shern-Long Lee. "Supramolecular Chemistry: Host–Guest Molecular Complexes." Molecules 26, no. 13 (2021): 3995. http://dx.doi.org/10.3390/molecules26133995.

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In recent times, researchers have emphasized practical approaches for capturing coordinated and selective guest entrap. The physisorbed nanoporous supramolecular complexes have been widely used to restrain various guest species on compact supporting surfaces. The host–guest (HG) interactions in two-dimensional (2D) permeable porous linkages are growing expeditiously due to their future applications in biocatalysis, separation technology, or nanoscale patterning. The different crystal-like nanoporous network has been acquired to enclose and trap guest molecules of various dimensions and contour

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