Relevant bibliographies by topics / Synthetic ketone

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Synthetic ketone'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Synthetic ketone"

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Matsuo, Yutaka, and Hao-Sheng Lin. "(Invited) Evaporable Fullerene-Fused Ketone Via One-Step Direct Oxidation of Alkoxy to Ketone: Fullerene As a Redox Active Pendant." ECS Meeting Abstracts MA2022-01, no. 11 (2022): 812. http://dx.doi.org/10.1149/ma2022-0111812mtgabs.

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We developed a direct oxidation reaction from a methoxy group to a keto group using a mild oxidizing agent with the aid of an oxidizable fullerene pendant. By using this key reaction, we developed a fullerene derivative that is stable even at high temperatures of 400 deg-C or higher and can be used for vacuum deposition to make thin films in organic electronic devices. A highly efficient CuBr2 promoted one-step direct oxidation of alkoxy indano[60]fullerenes to [60]fullerene-fused ketones is showcased. It is shown that the fullerene can behave as an electron-pool controlling the electron trans
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Murarka, Sandip, and Andrey Antonchick. "Metal-Catalyzed Oxidative Coupling of Ketones and Ketone Enolates." Synthesis 50, no. 11 (2018): 2150–62. http://dx.doi.org/10.1055/s-0037-1609715.

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Recent years have witnessed a significant advancement in the field of radical oxidative coupling of ketones towards the synthesis of highly useful synthetic building blocks, such as 1,4-dicarbonyl compounds, and biologically important heterocyclic and carbocyclic compounds. Besides oxidative homo- and cross-coupling of enolates, other powerful methods involving direct C(sp3)–H functionalizations of ketones­ have emerged towards the synthesis of 1,4-dicarbonyl compounds. Moreover, direct α-C–H functionalization of ketones has also allowed an efficient access to carbocycles and heterocycles. Thi
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Mamedova, N., and N. Nabiyeva. "SYNTHESIS AND STUDY OF PROPERTIES OF DERIVATIVES OF NATURAL AND SYNTHETIC PETROLEUM ACIDS." Znanstvena misel journal, no. 89 (April 23, 2024): 22–26. https://doi.org/10.5281/zenodo.11049281.

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Among the derivatives of natural and synthetic petroleum acids, esters are one of those that have the greatest practical importance. In this article, ketoesters of natural and synthetic petroleum acids were obtained and their properties were studied. The structure of the obtained ketoesters was confirmed with the help of IR – spectral analysis. Due to the low freezing point of ketoesters obtained on the basis of vinyl ketones of natural and synthetic petroleum acids, they were used as a depressant additive in diesel fuels. It was found that when adding 0.2% esters of methoxyethyl ketone
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ROMAN, Gheorghe. "Novel aminobenzenesulfonamides as potential inhibitors of carbonic anhydrases." Revue Roumaine de Chimie 69, no. 3-4 (2024): 111–17. http://dx.doi.org/10.33224/rrch.2024.69.3-4.01.

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A synthetic approach to N-[3-(hetero)aryl-3-oxoprop-1-yl]sulfonamides by N-alkylation of sulfanilamide with structurally diverse ketone Mannich base hydrochlorides is being reported. This scarcely explored synthetic strategy that involves aminomethylated ketones as starting materials has afforded novel compounds, potentially useful as inhibitors of carbonic anhydrases, with moderate to good yields.
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Benz, Scott, та Andrew S. Murkin. "α-Ketol and α-iminol rearrangements in synthetic organic and biosynthetic reactions". Beilstein Journal of Organic Chemistry 17 (15 жовтня 2021): 2570–84. http://dx.doi.org/10.3762/bjoc.17.172.

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In the presence of a suitable acid or base, α-hydroxyaldehydes, ketones, and imines can undergo isomerization that features the 1,2-shift of an alkyl or aryl group. In the process, the hydroxy group is converted to a carbonyl and the aldehyde/ketone or imine is converted to an alcohol or amine. Such α-ketol/α-iminol rearrangements are used in a wide variety of synthetic applications including asymmetric synthesis, tandem reactions, and the total synthesis and biosynthesis of natural products. This review explores the use of α-ketol rearrangements in these contexts over the past two decades.
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Zhao, Peng, Jie Min Liu, and Shi Chuan Tang. "The Interaction of Mixing Odorants with Similar Chemical Properties: A Case Study on Ketone Compounds." Advanced Materials Research 850-851 (December 2013): 32–37. http://dx.doi.org/10.4028/www.scientific.net/amr.850-851.32.

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To investigate more about the interaction of mixing odorants, a series of sensory tests were conducted using five ketones [butanone (Bu), 2-Pentanone (Pe), 2-Hexanone (Hex), 2-Heptanone (Hep), 2-Octanone (Oc)] at varying concentration levels. The determination of odor threshold (OT) was initially conducted by the triangle odor bag method (GB/T 14675, China). The odor activity values (OAVs) of individual odorants at a wide range of concentrations were derived from concentration-to-odor threshold ratios. The resulting data were then evaluated to define the empirical relationship for each ketone
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Fu, Jiayue, Bingbing Li, Zefang Zhou, Maosheng Cheng, Lu Yang, and Yongxiang Liu. "Formal total synthesis of macarpine via a Au(I)-catalyzed 6-endo-dig cycloisomerization strategy." Beilstein Journal of Organic Chemistry 18 (November 23, 2022): 1589–95. http://dx.doi.org/10.3762/bjoc.18.169.

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The formal total synthesis of macarpine was accomplished by the construction of a naphthol intermediate in Ishikawa’s synthetic route with two different synthetic routes. The convergent synthetic strategies feature the utilization of Au(I)-catalyzed cycloisomerizations of a 1,5-enyne and alkynyl ketone substrates, which were prepared by Sonogashira coupling reactions.
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Song, J. H., S. M. Bae, E. J. Lee, J. H. Cho, and D. I. Jung. "Formation of Benzodiazepines and Pyrazinylquinoxalines from Aromatic and Heteroaromatic Ketones via Deoximation." Asian Journal of Chemistry 32, no. 7 (2020): 1676–80. http://dx.doi.org/10.14233/ajchem.2020.22639.

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The report stated that the treatment of o-phenylenediamine with acetone dicarboxylic acid, acetone and acetophenone afforded 2,4,4-trimethyl-3H-5-hydro-1,5-benzodiazepine. However, direct reactions of o-phenylenediamine with oximes (acetone oxime, acetophenone oxime, and benzophenone oxime) as ketone equivalents did not occur. In the course of present investigations, it is found that dichloroamine-T can be an efficient reagent for the conversion of oximes into the corresponding carbonyl compounds. As a part of a research program related to the synthetic study of pharmacologically interesting b
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Chun, Stephanie W., та Alison R. H. Narayan. "Biocatalytic Synthesis of α-Amino Ketones". Synlett 30, № 11 (2019): 1269–74. http://dx.doi.org/10.1055/s-0037-1611755.

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Stereospecific generation of α-amino ketones from common α-amino acids is difficult to achieve, often employing superstoichiometric alkylating reagents and requiring multiple protecting group manipulations. In contrast, the α-oxoamine synthase protein family performs this transformation stereospecifically in a single step without the need for protecting groups. Herein, we detail the characterization of the 8-amino-7-oxononanoate synthase (AONS) domain of the four-domain polyketide-like synthase SxtA, which natively mediates the formation of the ethyl ketone derivative of arginine. The function
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Brown, RFC, and AJ Robinson. "A Synthetic Approach to (±)-Tridentoquinone." Australian Journal of Chemistry 48, no. 3 (1995): 515. http://dx.doi.org/10.1071/ch9950515.

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Synthesis of the ansa-bridged benzofuranquinone (�)- tridentoquinone (�)-(1) is approached by construction of a C4 methyl ketone chain at the 3-position of 6-bromo-4,5,7-trimethoxy-2,2-dimethyl-2,3-dihydrobenzofuran (10) and alkylation at its 6-position leading after modification to a dimethyl C10 aldehydic chain. Closure of the ansa bridge by McMurry coupling of the aldehyde and ketone groups of the intermediate (33) with C8K/TiCl3 appears to occur, but in poor yield and with uncertain stereochemistry, and the synthesis has not been completed.
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Dissertations / Theses on the topic "Synthetic ketone"

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Jiao, Guansheng. "Ketone catalyzed diastereoselective and enantioselective epoxidation of olefins : catalyst design and synthetic application /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21981772.

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Waymouth, Robert M. Grubbs Robert H. "Synthesis and reactivity of alkylaluminum adducts of zirconium ketene and ketone complexes /." Diss., Pasadena, Calif. : California Institute of Technology, 1987. http://resolver.caltech.edu/CaltechETD:etd-10142008-080353.

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Cerone, Matthew. "Synthesis of Alkyl Substituted Phenylated Poly(Ether Ether Ketone Ketone)s." Wright State University / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=wright1496856789109456.

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Dziadulewicz, E. K. "Ketene dithioacetals in synthesis." Thesis, University of Bath, 1987. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375640.

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Lynam, Jason Martin. "Vinyl ketone and vinyl aldehyde complexes of ruthenium." Thesis, University of York, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265558.

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Walker, Louise F. "Synthetic applications of alkylidene carbenes." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343952.

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Howard-Jones, Andrew Glyn. "A synthetic approach to C←2 symmetric guanidine bases and the synthesis of model compounds of ptilomycalin A." Thesis, Bangor University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.340956.

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Silvanus, Andrew. "Exploring the synthetic utility of divinyl ketones." Thesis, University of Bath, 2010. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.535271.

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Divided into three distinct research areas, this thesis investigates the synthetic utility of divinyl ketones as versatile substrates in the construction of novel cyclic structures. The first volume of work (Chapter 2) examines the one-pot Brønsted acid-catalysed tandem double alkylation of indole with non-symmetrical divinyl ketones. The [6,5,7] tricyclic indole products are often furnished in excellent yield, with complete regioselectivity and high levels of syn-diastereoselectivity. Optimisation, a thorough substrate investigation and initial results are all discussed within. An in-depth me
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Ko, Jinren. "Synthetic Applications of Ketene Cycloadditions: Natural and Novel Pyrethroid Insecticides." Thesis, North Texas State University, 1985. https://digital.library.unt.edu/ark:/67531/metadc331031/.

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A new synthetic route to natural and novel pyrethroid acids was developed utilizing ketene cycloaddition which is a significant improvement over existing syntheses. The newly synthesized pyrethroid acids were converted to pyrethroid esters and used to study structure-activity relationships. The cycloaddition of dichloroketene with 2,5-dimethyl-2,4-hexadiene yields (2+2) cycloaddition products, 2,2-dichlorocyclobutanones. The reductive removal of one chlorine atom from these cycloaddition products gave monochlorocyclobutanones which underwent a Favorskii-type ring contraction to yield cis- and
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Salter, D. P. "The synthesis and chemistry of ketene-o,o-acetal and ketene-o,s,acetals." Thesis, Lancaster University, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381786.

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Books on the topic "Synthetic ketone"

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Nenajdenko, Valentine G. Chemistry of [alpha], [beta]-unsaturated trifluoromethly [i.e. trifluoromethyl] ketones. Nova Science Publishers, Inc., 2007.

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Schäfer, Andrea. Ansa-Metallocene: Enantiomerentrennung und katalytische Aktivität bei der Reduktion von Ketonen. Hartung-Gorre, 1986.

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Norret, M. Synthetic approaches towards enantiopure axially-symmetric cyclic ketones and related compounds. UMIST, 1996.

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Metwally, M. A. Cyclic beta-keto esters: Synthesis and reactions. Nova Science Publishers, 2009.

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Ruane, Patrick H. The synthesis and detection of monoalkyl-aryl ketenes and ketenimines. University College Dublin, 1997.

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Drayton, C. J. Cumulative index. Thieme, 2008.

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Zerizer, Hafiza. Synthesis and photochemistry of B-amino-ketones and A-substituted succinimides. University of Salford, 1985.

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Brunet, Gaetan. Aluminum vapour synthesis: Reaction of A1 atoms with ketones at 77K. Laurentian University, 1993.

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Doran, Robert. Asymmetric Synthesis of Bioactive Lactones and the Development of a Catalytic Asymmetric Synthesis of α-Aryl Ketones. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-20544-1.

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Winders, John Alexander. Synthesis of natural products via intramolecular trapping of photogenerated ketenes. University of Salford, 1988.

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Book chapters on the topic "Synthetic ketone"

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Shi, Yian. "Organocatalytic Oxidation. Ketone-Catalyzed Asymmetric Epoxidation of Alkenes and Synthetic Applications." In Modern Oxidation Methods. Wiley-VCH Verlag GmbH & Co. KGaA, 2010. http://dx.doi.org/10.1002/9783527632039.ch3.

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Meguro, Yasuhiro, Masaru Enomoto, and Shigefumi Kuwahara. "Total Synthesis of Amycolamicin." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_2.

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AbstractAmycolamicin (also called kibdelomycin) produced by two species of soil actinomycetes is a potent antibiotic against a broad range of drug-resistant bacteria with a novel binding mode to bacterial type II DNA topoisomerases and with no cross-resistance to existing antibacterial agents. The unique hybrid molecular architecture of amycolamicin attracted interest of many synthetic organic chemists and three total syntheses have been reported so far. In this chapter, we describe our total synthesis of amycolamicin in detail, which features a nucleophilic addition of a vinyllithiun reagent
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Yokoshima, Satoshi. "Construction of Quinoline N-Oxides and Synthesis of Aurachins A and B: Discovery, Application, and Mechanistic Insight." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_17.

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AbstractA method to synthesize 3-hydroxyquinoline N-oxides from ketones having a 2-nitrophenyl group at the α-position relative to the carbonyl group was developed. The substrates were easily prepared via a SNAr reaction or a Sonogashira coupling, and treatment with sodium tert-butoxide in dimethyl sulfoxide produced the corresponding quinoline N-oxides. The method was successfully applied to the total synthesis of aurachins A and B. On the basis of the quinoline N-oxide synthesis, related reactions of α-(2-nitrophenyl)ketones, including nitrone formation and photoinduced rearrangement, were a
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Taber, Douglass F. "Best Synthetic Methods: Oxidation and Reduction." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0010.

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Johannes G. de Vries of DSM Pharmaceuticals prepared (Chem. Commun. 2009, 3747) Fe nanoparticles that selectively mediated the hydrogenation of Z alkenes and not trisubstituted alkenes. This should allow the conversion of 1 to 2. In the course of a synthesis (Tetrahedron Lett. 2009, 50, 4368) of centrolobine, Teck-Peng Loh of Nanyang Technological University employed an elegant protocol for the reduction of the secondary bromide 3. István Markó of the Université catholique de Louvain observed (Tetrahedron 2009, 65, 10930) that toluates such as 5 can be reduced smoothly with SmI2 to the corresp
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Chiu, C. K. F., S. V. Govindan, and P. L. Fuchs. "Synthetic Efforts Towards Bruceantin." In Exercises in Synthetic Organic Chemistry. Oxford University PressOxford, 1997. http://dx.doi.org/10.1093/oso/9780198559443.003.0063.

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Abstract Discussion Points What is the controlling factor in the stereochemical outcome of the conjugate addition of cyanide to enone 1? Based on the above fact, what would you predict the product of step c to be? Give a rationalisation for the difference in reactivity displayed by epimers 7 and 8 under basic conditions. In the transformation of ketone 11 into nitrile 12 the phenylselenyl group undergoes epimerisation. What is the driving force behind this process? Suggest a mechanism for the oxidation step u carried out in the absence of triethylamine.
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Thomas, Susan E. "Silyl enol ethers and related silyl ethers." In Organic Synthesis. Oxford University Press, 1991. http://dx.doi.org/10.1093/hesc/9780198557913.003.0009.

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This chapter focuses on related silyl ethers and silyl enol ethers. It defines silyl enol ethers as stable molecules which may be isolated, purified, and characterized using standard organic procedures. The chapter contends that they are sources of regiochemically-pure enolate ions and their equivalents, and as such, they play an important role in modern synthetic organic chemistry. The chapter then moves to explicate the formation of silyl enol ethers. It illustrates the deprotonation of an unsymmetrically substituted ketone such as 2-methylcyclohexanone, then explores the process of conjugat
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Thomas, Susan E. "Silyl enol ethers and related silyl ethers." In Organic Synthesis. Oxford University Press, 1991. http://dx.doi.org/10.1093/hesc/9780198556626.003.0009.

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Abstract This chapter focuses on related silyl ethers and silyl enol ethers. It defines silyl enol ethers as stable molecules which may be isolated, purified, and characterized using standard organic procedures. The chapter contends that they are sources of regiochemically-pure enolate ions and their equivalents, and as such, they play an important role in modern synthetic organic chemistry. The chapter then moves to explicate the formation of silyl enol ethers. It illustrates the deprotonation of an unsymmetrically substituted ketone such as 2-methylcyclohexanone, then explores the process of
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Mukaiyama, Teruaki. "Ring-opening polymerization." In Challenges in Synthetic Organic Chemistry. Oxford University PressOxford, 1990. http://dx.doi.org/10.1093/oso/9780198556442.003.0005.

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Abstract In Chapter 3, I have described the chemistry in which compounds with cumulated double bonds (X=Y=Z) or an unsaturated carbon-carbon bond (e.g. isocyanate, carbodiimide, alkoxyacetylene, vinyl ether, and ketene acetal) undergo reaction with aldoximes, primary nitroalkanes, hydroxamic acids, etc. to give intramolecular dehydration products (e.g. nitriles, nitrile oxides, isocyanates, etc.) in high yields. In order to broaden the scope of such dehydration reactions, we examined the dehydration of aldoximes with diethyl N-phenyliminocarbonate, which can be regarded as the acetal of isocya
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Roush, W. R., and R. J. Sciotti,. "Total Synthesis of (–)-Chlorothricolide." In Exercises in Synthetic Organic Chemistry. Oxford University PressOxford, 1997. http://dx.doi.org/10.1093/oso/9780198559443.003.0070.

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Abstract Discussion Points Propose suitable methods for the synthesis of optically active alcohol 1 from its corresponding ketone. Suggest a mechanism for the iodination of compound 2. What is the purpose of the DIBAL-H in the sequence? Give the mechanism of step f. Explain the stereoselectivity of steps g and i. What is the structure of 7 introduced in step j? Rationalise both the mechanism and stereocontrol that led to the cyclic system 8, the major product of step j. What is the purpose of the 2-methyl-2-butene used in step r?
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Taber, Douglass F. "The Paterson Synthesis of (−)-Leiodermatolide." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0096.

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(−)-Leiodermatolide 4, isolated from the lithistid sponge Leiodermatium sp., showed 5.0-nM activity against PANC-1 pancreatic carcinoma cells, and reduced toxicity toward normal cells. Ian Paterson of the University of Cambridge established (Angew. Chem. Int. Ed. 2014, 53, 2692) a synthetic route to 4 based on sp2–sp2 coupling, as exemplified by the combination of 1 with 2 to give 3. Addition of the boron enolate of the enantiomerically-pure benzoate 5 to the iodoaldehyde 6 gave 7, that was silylated, reduced, and deprotected to give 1. Addition of the boron enolate of ent-5 to propanal gave 8
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Conference papers on the topic "Synthetic ketone"

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Ducrot, Paul, and Josiane Beauhaire. "New Strategy in Agarofuran synthesis : Baeyer-Villiger reaction of Wieland-Misher ketone analogs." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01897.

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Kezuka, H., N. Hosokawa, K. Hirata, K. Ishibash, C. Kannai, and T. Naito. "Synthesis of fine particle-YBCO superconductor by wet-type jet mill with methyl-ethyl-ketone." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835824.

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Ramasami, Ponnadurai, Naziah Jaufeerally, and Hassan Abdallah. "Theoretical Insights into Novel Telluro-ketones." In The 16th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2012. http://dx.doi.org/10.3390/ecsoc-16-01088.

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Solovyev, Pavel, Anastasia Fesenko, Ekaterina Dem'yachenko, and Anatoly Shutalev. "A novel selective synthesis of β-isothiocyanato ketones." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a017.

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Ramasami, Ponnadurai, and Naziah Jaufeerally. "Structures, Energetics and Stabilities of Novel Telluro-Ketones." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-e023.

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Al-Mufti, Salah M. S., Mawlood Maajal Ali, and S. J. A. Rizvi. "Synthesis and structural properties of sulfonated poly ether ether ketone (SPEEK) and Poly ether ether ketone (PEEK)." In 3RD INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2019). AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0001760.

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Polo, Ellen Christine, and Luiz Carlos Dias. "Boron-mediated aldol reactions of a methyl ketone containing a cyclic silicon protecting group." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0087-1.

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Bulavka, Vladimir. "Modified Clemmensen reduction of some diaryl ketones with non-amalgamated zinc." In The 10th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01399.

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Solaja, Bogdan, and Iris Dordevic. "One-Pot Synthesis of syn-Epoxyalcohols from a,b-Unsaturated Ketones." In The 2nd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1998. http://dx.doi.org/10.3390/ecsoc-2-01685.

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Lo Fiego, Marcos, Alicia Chopa, and Maria Lockhart. "Catalyst-free synthesis of symmetrical diaryl ketones from arylstannanes and oxalyl chloride." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00613.

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Reports on the topic "Synthetic ketone"

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BrownJason Fuentes, Raymond. Study of Poly(ether ketone ketone) (PEKK): Outgassing Characteristics and Likely Residual Synthesis Impurities. Office of Scientific and Technical Information (OSTI), 2020. http://dx.doi.org/10.2172/1643746.

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Yang, C. Y., and G. E. Wnek. Synthesis and Reactivity of Silyl-Ketene Acetal-Modified Polysiloxanes Preparation of Polysiloxanes with High Dielectric Constraints. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada240754.

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