Academic literature on the topic 'Tartrate complexes'

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Journal articles on the topic "Tartrate complexes"

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Prananto, Yuniar Ponco, Rafi Dwiasis Wibisono, Sasti Gona Fadhilah, Rachmat Tjahjanto, Darjito, and Firsta Luthfiani Salsabila. "Crystallization of Mn(II) and Cd(II) Complexes in A Water-Methanol System: Tartrate vs Nicotinamide Ligand Selectivity." Acta Chimica Asiana 5, no. 1 (2022): 166–72. http://dx.doi.org/10.29303/aca.v5i1.114.

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Ligand selectivity of tartrate vs nicotinamide in a water-methanol system has been observed in the crystallization of Mn(II) and Cd(II) complexes. These complexes were crystallized at room temperature by a layered solution technique using a water-methanol mixture solvent in a M(II):tartrate:nicotinamide (M = Mn, Cd) molar ratio of 1:1:2. Complexes of M(II)-nicotinamide and M(II)-tartrate were also prepared for data comparison. Analysis of the crystals by infrared spectroscopy, powder-X-ray diffraction and qualitative anion test showed that in a presence of both tartrate and nicotinamide, the M
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Bott, Raymond C., Graham Smith, Dalius S. Sagatys, Daniel E. Lynch та Colin H. L. Kennard. "Group 15 Complexes with α-Hydroxy Carboxylic Acids: 7. The Preparation and Structure Determination of Sodium (+)-Tartrato Arsenate(III), [Na8As10(C4H2O6)8(C4H3O6)2(H2O)19]n; Silver(I) (+)-Tartrato Arsenate(III), [Ag9As10(C4H2O6)9(C4H3O6)(H4As2O5) (H2O)10]n and Rubidium Citrato Antimonate(III), [Rb2Sb4(C6H5O7)2(C6H6O7)2(C6H7O7)4(H2O)2]". Australian Journal of Chemistry 53, № 12 (2000): 917. http://dx.doi.org/10.1071/ch00138.

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The structures of sodium (+)-tartrato arsenate(III),[Na8As10(C4H2O6)8(C4H3O6)2(H2O)19]n(1), silver (+)-tartrato arsenate(III),[Ag9As10(C4H2O6)9(C4H3O6)(H4As2O5)(H2O)10](2) and rubidium citrato antimonate(III)[Rb2Sb4(C6H6O7)6(C6H7O7)2(H2O)2](3) have been determined by X-ray methods and refined to residuals of 0.085(1), 0.072 (2) and 0.065 (3) for 5018, 4487 and 8207 observed reflections,respectively. The (+)-tartrato complexes (1) and (2) are similar instructure to the two known isomorphous silver(I) (+)-tartratoarsenate(III) complexes in that independent anionic[As2(tartrate)2] dimericcages ar
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Potvin, Pierre G., and Benjamin G. Fieldhouse. "An NMR study of mixed, tartrate-containing TiIV complexes." Canadian Journal of Chemistry 73, no. 3 (1995): 401–13. http://dx.doi.org/10.1139/v95-053.

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The reactions of amines and amino alcohols with diisopropyl or diethyl R,R- or S,S-tartrate and Ti(OiPr)4 were examined by 1H and 13C NMR to obtain and characterize nonfluxional complexes with the tartrate units in novel binding modes. The mildly acidic 8-hydroxyquinoline and N-phenyl-N-benzoylhydroxylamine selectively formed the products of a double OiPr substitution, Ti2(tartrate)2(ligand)2(OiPr)2, and the products of double tartrate substitution, Ti(ligand)2(OiPr)2, while 2,4-pentanedione formed only the latter Basic amino alkanols formed diastereomerically pure Ti2(tartrate)2(aminoalkoxide
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Selvaraj, M., S. Thamotharan, Siddhartha Roy, and M. Vijayan. "X-ray studies of crystalline complexes involving amino acids and peptides. XLIV. Invariant features of supramolecular association and chiral effects in the complexes of arginine and lysine with tartaric acid." Acta Crystallographica Section B Structural Science 63, no. 3 (2007): 459–68. http://dx.doi.org/10.1107/s010876810701107x.

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The tartaric acid complexes with arginine and lysine exhibit two stoichiometries depending upon the ionization state of the anion. The structures reported here are DL-argininium DL-hydrogen tartrate, bis(L-argininium) L-tartrate, bis(DL-lysinium) DL-tartrate monohydrate, L-lysinium D-hydrogen tartrate and L-lysinium L-hydrogen tartrate. During crystallization, L-lysine preferentially interacts with D-tartaric acid to form a complex when DL-tartaric acid is used in the experiment. The anions and the cations aggregate into separate alternating layers in four of the five complexes. In bis(L-argin
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Abi, Faustina De Yesu Prisila, Rachmat Triandi Tjahjanto, and Yuniar Ponco Prananto. "Extraction of Manganese Ore from East Nusa Tenggara-Indonesia for Production of Mn(II)-Terephthalate and Mn(II)-Tartrate Coordination Polymers." Journal of Geoscience, Engineering, Environment, and Technology 10, no. 02 (2025): 252–60. https://doi.org/10.25299/jgeet.2025.10.02.21556.

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Pyrolusite, a manganese ore from East Nusa Tenggara (Indonesia), was explored and utilized in the production of crystalline Mn(II) based coordination polymers materials, namely Mn(II)-terephthalate and Mn(II)-tartrate. The pyrolusite was extracted into Mn(II) sulfate by acid method in the presence of hydrogen peroxide. The Mn(II) sulfate, characterized by X-ray fluorescence (XRF), infrared spectroscopy (IR), and X-ray powder diffraction (PXRD), was then used as a precursor in the production of crystalline Mn(II) based coordination polymers materials using a solution method at room temperature.
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Jia, Yihong, Asma A. Alothman, Rui Liang, et al. "Oligomeric (Salen)Mn(III) Complexes Featuring Tartrate Linkers Immobilized over Layered Double Hydroxide for Catalytically Asymmetric Epoxidation of Unfunctionalized Olefins." Materials 13, no. 21 (2020): 4860. http://dx.doi.org/10.3390/ma13214860.

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A series of oligomeric (salen)Mn(III) complexes featuring tartrate linkers were prepared and immobilized over layered double hydroxide, and then used as catalysts for asymmetric epoxidation of unfunctionalized olefins. Comprehensive characterizations including 1H NMR, FT-IR, UV-Vis, elemental analysis, GPC, and ICP-AES were used to illustrate structures of oligomeric (salen)Mn(III) complexes, while powdered XRD, nitrogen physisorption, together with XPS studies provided further details to detect structures of heterogeneous catalysts. Interestingly, scanning electron microscopy found an interes
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Bezryadin, S. G., V. V. Chevela, O. P. Ajsuvakova, V. Yu Ivanova, and D. V. Kuzyakin. "Titanium(iv) tartrate complexes in aqueous solutions." Russian Chemical Bulletin 64, no. 11 (2015): 2655–62. http://dx.doi.org/10.1007/s11172-015-1204-z.

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Skorik, Nina, Evgeniya Tomilova, Ekaterina Pastushchak, and Irina Kurzina. "Interaction of Copper(II) Ions with Certain Oxyacids and Azoles." Inorganics 11, no. 6 (2023): 232. http://dx.doi.org/10.3390/inorganics11060232.

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Compounds composed of [[Cu(HIm, metIm)2–3L] ∙ nH2O (n = 0, 2) were obtained during the interaction of slightly soluble tartrate and copper(II) salicylate composed of CuL ∙ nH2O (n = 1–2, L2−—Tar2−, Sal2−) with imidazole (HIm) and 2-methylimidazole (metIm). Mono- and bi-ligand salts were analyzed; the process of their thermal decomposition was studied. The solubility constants KS of the CuC4H4O6 ∙ 2H2O tartrate and CuC7H4O3 ∙ H2O salicylate of copper(II) with at ionic strength of 0.3 were determined. The IR spectroscopy method showed the participation in complexation of the nitrogen atom N(3) o
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Potvin, Pierre G., Robert Gau, Patrick C. C. Kwong, and Stephen Bianchet. "The solution structures of chiral Ti4+ alkoxides." Canadian Journal of Chemistry 67, no. 10 (1989): 1523–37. http://dx.doi.org/10.1139/v89-233.

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1,4-Di-O-methyl-L-threitol and 1,2,5,6-tetra-O-methyl-L-mannitol were prepared by new, more convenient, and higher yielding routes. These and 1,2;5,6-di-O-isopropylidene-D-mannitol formed 2:2 complexes with Ti(OiPr)4, but did not readily form 1:2 complexes in the presence of excess Ti4+. 1H and 13C nuclear magnetic resonance spectra showed that the structures in solution of the 2:2 complexes were analogous to solid-state structures of tartaric acid derivatives, i.e., possessing bridging diolate oxygens. In contrast, R,R- and meso-diisopropyl tartrates, Ν,Ν′-dibenzyl tartramide, and Ν,Ν′-di(2-p
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Lakshmichhaya Ramkrishna Patil, Arun Madhukar Patil, and Sharda Jayantrao Shitole. "Electro-optical and thermal characterization of cadmium doped copper tartrate crystals grown in silica gel." Global Journal of Engineering and Technology Advances 21, no. 3 (2024): 009–18. https://doi.org/10.30574/gjeta.2024.21.3.0221.

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Cadmium doped copper tartrate crystals were grown by Gel Growth technique by single diffusion. Silica gel of optimum specific gravity was set with tartaric acid at optimum pH and aging period for crystal growth. Band gap of cadmium doped copper tartrate crystal is determined using Ultraviolet-Visible Spectroscopy is 5.780 eV. Blue Color of cadmium Copper tartrate crystal and transparency is confirmed using Photoluminescence spectroscopy. Emission originates from Cu2+ vacancy-related defects or their complexes. Dimensions of crystals are found from Powder X-Ray Diffraction data. The edge length
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Dissertations / Theses on the topic "Tartrate complexes"

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Pileckienė, Jolanta. "Katodiniai procesai Cu(II) tartratinių kompleksų tirpaluose." Master's thesis, Lithuanian Academic Libraries Network (LABT), 2005. http://vddb.library.lt/obj/LT-eLABa-0001:E.02~2005~D_20050613_185602-23753.

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Cathodic processes occurring in the solutions containing Cu(II) tartaric complexes have been investigated. The equations accounting for the material balance have been constructed and used for the estimation of distribution of complexes and ligands in the bulk of solution. It was established that dominating particles in acidic media (pH < 3) are: Cu2+ and tartaric complex CuL, tartaric acid LH2 and its anion LH-. Potentials of non-polarized copper electrodes were found to be reversible and to follow Nernst equation. According to the analysis performed, surface oxide Cu2O is not able to form in
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Сьомкіна, Олена Володимирівна. "Удосконалення електрохімічного осадження функціональних покрить міддю на сплави заліза та алюмінію". Thesis, Національний технічний університет "Харківський політехнічний інститут", 2018. http://repository.kpi.kharkov.ua/handle/KhPI-Press/39104.

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Дисертація на здобуття наукового ступеня кандидата технічних наук за спеціальністю 05.17.03 – технічна електрохімія. – Національний технічний університет "Харківський політехнічний інститут", Харків, 2018 р. Дисертацію присвячено удосконаленню технологічного процесу нанесення функціональних мідних покриттів на вироби зі сплавів заліза й алюмінію, які використовуються для підвищення електро- та теплопровідності, забезпечення надійності контактних з'єднань, надання поверхні каталітичних властивостей. Досліджено кінетику і механізм відновлення гідроксотартратного комплексу міді. Встановлено, що
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Сьомкіна, Олена Володимирівна. "Удосконалення електрохімічного осадження функціональних покрить міддю на сплави заліза та алюмінію". Thesis, Національний технічний університет "Харківський політехнічний інститут", 2018. http://repository.kpi.kharkov.ua/handle/KhPI-Press/39049.

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Дисертація на здобуття наукового ступеня кандидата технічних наук за спеціальністю 05.17.03 – технічна електрохімія. – Національний технічний університет "Харківський політехнічний інститут", Харків, 2018 р. Дисертацію присвячено удосконаленню технологічного процесу нанесення функціональних мідних покриттів на вироби зі сплавів заліза й алюмінію, які використовуються для підвищення електро- та теплопровідності, забезпечення надійності контактних з'єднань, надання поверхні каталітичних властивостей. Досліджено кінетику і механізм відновлення гідроксотартратного комплексу міді. Встановлено, що
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Wang, Lei. "Photodegradation of organic pollutants induced by Fe(III)-caoxylate complexes in aqueous solution." Clermont-Ferrand 2, 2008. https://tel.archives-ouvertes.fr/tel-00728829.

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La photodégradation de l'herbicide 2,4-D (acide 2,4-dichlorophénoxyacétique) et de son principal photoproduit (2,4-DCP) en présence de trois complexes Fe(III)-carboxylate (citrate, pyruvate, tartrate) a été étudiée. Les rendements quantiques de disparition du 2,4-D augmentent dans cet ordre : Fe(III)-TAr < Fe(III)-Cit < Fe(OH)2+ < Fe(III)-Pyr. Le même mécanisme de dégradation du 2,4-D est observé pour les trois complexes de fer et correspond à celui déjà décrit avec des processus généraux de radicaux hydroxyle. Le 2,4-D est dégradé sélectivement en 2,4-DCP, qui après formation de différents ph
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Wang, Lei. "Photodégradation de pollutants organiques induite par des complexes Fe(III)-carboxylate en solutions aqueuses." Phd thesis, Université Blaise Pascal - Clermont-Ferrand II, 2008. http://tel.archives-ouvertes.fr/tel-00728829.

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La photodégradation de l'herbicide 2,4-D (acide 2,4-dichlorophénoxyacétique) et de son principal photoproduit (2,4-DCP) en présence de trois complexes Fe(III)-carboxylate (citrate, pyruvate, tartrate) a été étudiée. Les rendements quantiques de disparition du 2,4-D augmentent dans cet ordre : Fe(III)-TAr < Fe(III)-Cit < Fe(OH)2+ < Fe(III)-Pyr. Le même mécanisme de dégradation du 2,4-D est observé pour les trois complexes de fer et correspond à celui déjà décrit avec des processus généraux de radicaux hydroxyle. Le 2,4-D est dégradé sélectivement en 2,4-DCP, qui après formation de différents ph
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Book chapters on the topic "Tartrate complexes"

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Orešková, Gabriela, Lukáš Krivosudský, Ján Šimunek, and Jozef Noga. "Structural and spectral properties of tartrato complexes of vanadium(V) from quantum chemical calculations." In Péter R. Surján. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-49825-5_15.

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Ley, S. V., J. Norman, and C. Pinel,. "Studies Towards the Total Synthesis of Rapamycin." In Exercises in Synthetic Organic Chemistry. Oxford University PressOxford, 1997. http://dx.doi.org/10.1093/oso/9780198559443.003.0033.

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Abstract Discussion Points Which enantiomer of diethyl tartrate is necessary in the Sharpless epoxidation step g to obtain the required stereoisomer? Further Reading For the synthesis of lactones via tricarbonyliron-lactone complexes, see: S. V. Ley, L. R. Cox and G. Meek, Chem. Rev.,1996, 96,423; G.D. Gary, S. V. Ley, C.R. Self and R. Sivaramakrishnan, J. Chem. Soc., Perkin Trans. 1,1981, 1,270; R. Aumann, H. Ring, C. Krueger and R. Goddard, Chem. Ber.,1979, 112,3644. For reviews on the use of iron carbonyl complexes, see: G.D. Annis, E. M. Hebblethwaite, S. T. Hodgson, A. M. Horton, D. M. Ho
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E. Coleman, Robert, Alexei A. Stuchebrukhov, and Roger B. Boulton. "The Kinetics of Autoxidation in Wine." In Recent Advances in Chemical Kinetics [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.103828.

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The kinetics of autoxidation in wine begins with Fenton (1876) who observed that tartaric acid could be oxidized in the presence of iron without peroxide if left in air. Rodopulo (1951) demonstrated that iron tartrate complexes added to wine promoted more extensive oxygen consumption than the molar equivalent of inorganic ferrous or ferric salts. The role of iron complexes in the activation of oxygen, the formation of reactive oxygen species and the initiation of autoxidation are crucial for understanding wine oxidation kinetics. Mechanisms based on hydroxyl radicals versus the ferryl species
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Tripathi, Keshawanand, Yashdeep Srivastava, Santosh Kumar Mishra, and Narendra Kumar. "Biuret assay for protein estimation: Principles, methodology, and analytical applications." In Biotechnology Lab Techniques: Culture Media, Microscopy, and Microbial Analysis. Deep Science Publishing, 2025. https://doi.org/10.70593/978-93-49307-52-0_32.

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The Biuret reagent, made of sodium potassium tartrate and alkaline CuSO4 solution, is used to detect compounds with adjacent peptide bonds, forming a distinctive violet complex (Voet, et al., 2018). The intensity of this color directly indicates protein concentration, measured at 540 nm using a green filter. The Biuret method is highly sensitive, detecting protein concentrations as low as 1-2 mg/mL (González et al., 2008; Berg et al.,2015).
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Taber, Douglass F. "The Nicolaou Synthesis of (+)-Hirsutellone B." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0089.

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(+)-Hirsutellone B 3, isolated from the insect pathogenic fungus Hirsutella nivea BCC 2594, shows good activity (MIC = 0.78 μg/mL) against Mycobacterium tuberculosis. Approaching the synthesis of 3, K. C. Nicolaou of Scripps/La Jolla envisioned and reduced to practice (Angew. Chem. Int. Ed. 2009, 49, 6870) a spectacular tandem intramolecular epoxide opening: internal Diels-Alder cyclization (1 2) that established all three of the carbocyclic rings of 3 with the proper relative and absolute configuration. The construction of 1 began with commercial ( R) -(+)-citronellal 4. Wittig homologation e
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Taber, Douglass F. "The Qin Synthesis of (+)-Gelsemine." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0093.

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(+)-Gelsemine 3 has no particular biological activity, but its intricate architecture continues to inspire the ingenuity of organic synthesis chemists. Yong Qin of Sichuan University devised (Angew. Chem. Int. Ed. 2012, 51, 4909) an enantiospecific synthesis of 3, a key step of which was the cyclization of 1 to 2. The starting material for the synthesis was the inexpensive diethyl tartrate 4, which was converted over six steps into the N-sulfonyl aziridine 5. The addition of 6 was highly regioselective, leading, after N-methylation, to the alkyne 7. After alcohol protection, the sulfonyl group
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Taber, Douglass. "The Roush Synthesis of ( + )-Superstolide A." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0093.

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( + )-Superstolide A 3, isolated from the New Caledonian sponge Neosiphonia superstes, shows interesting cytotoxicity against malignant cell lines at ~ 4 ng/mL concentration. The key transformation in the synthesis of 3 described (J. Am. Chem. Soc. 2008, 130, 2722) by William R. Roush of Scripps Florida was the transannular Diels-Alder cyclization of 2, which established, in one step with high diastereocontrol, both the cis decalin and the macrolactone of 3. The octaene 1 was assembled from four stereodefined fragments. The first, the linchpin 6, was prepared from the stannyl aldehyde 4. Homol
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Taber, Douglass. "Alkaloid Synthesis: (-)-Aurantioclavine (Stoltz), (-)-Esermethole (Nakao/Hiyama/ Ogoshi), (-)-Kainic Acid (Tomooka), Dasycarpidone (Bennasar), (-)-Cephalotaxine (Ishibashi) and Lysergic Acid (Fujii/Ohno)." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0060.

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Intriguing strategies have been developed for the stereocontrolled assembly of complex alkaloid structures. Brian M. Stoltz of Caltech prepared (J. Am. Chem. Soc. 2008, 130, 13745) the enantiomerically-pure alcohol precursor to the secondary amine 1 by enantioselective oxidation of the racemic alcohol. Intramolecular Mitsunobu coupling of 1 then led to (-)-Aurantioclavine 3. Yoshiaki Nakao and Tamejiro Hiyama of Kyoto University and Sensuke Ogoshi of Osaka University developed (J. Am. Chem. Soc. 2008, 130, 12874) an enantioselective Ni catalyst for the cyclization of 4 to 5. Oxidation and cycl
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Taber, Douglass. "The Kozmin Synthesis of Spirofungin A." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0089.

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Often, 6,6-spiroketals such as Spirofungin A 3 have a strong anomeric bias. Spirofungin A does not, as the epimer favored by double anomeric stabilization suffers from destabilizing steric interactions. In his synthesis of 3, Sergey A. Kozmin of the University of Chicago took advantage (Angew. Chem. Int. Ed. 2007, 46, 8854) of the normally-destablizing spatial proximity of the two alkyl branches of 3, joining them with a siloxy linker to assure the anomeric preference of the spiroketal. The assembly of 1 showcased the power of asymmetric crotylation, and of Professor Kozmin’s linchpin cyclopro
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Conference papers on the topic "Tartrate complexes"

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"Sunlight mediated enhanced removal of metoprolol using graphitic carbon nitride (g-C3N4)." In Sustainable Processes and Clean Energy Transition. Materials Research Forum LLC, 2023. http://dx.doi.org/10.21741/9781644902516-4.

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Abstract. Graphitic carbon nitride (g-C3N4) is a photocatalyst that has recently been given a lot of attention due to its effectiveness in wastewater and environmental treatment, solar energy utilization, biomedical applications, etc. In this study, g-C3N4 was synthesized and characterized to carry out the degradation of metoprolol tartrate salt (MET), which is classified as an emerging contaminant. MET is one of the most commonly used pharmaceuticals to treat patients with cardiovascular diseases and disorders, a common disease in Malaysia. Recent discoveries of MET in surface waters and drin
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Prananto, Yuniar P., Ade H. Rafika, Sasti G. Fadhilah, Muhammad M. Khunur, and Rachmat T. Tjahjanto. "Effect of type of Fe(III) salts and reaction temperature in the synthesis of Fe(III)-Mn(II)-Tartrate heteronuclear complex." In CHEMISTRY BEYOND BORDERS: INTERNATIONAL CONFERENCE ON PHYSICAL CHEMISTRY: The 1st Annual Meeting of the Physical Chemistry Division of the Indonesian Chemical Society. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0174980.

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Yunita, Yana, Rachmat Triandi Tjahjanto, Danar Purwonugroho, and Yuniar Ponco Prananto. "Ongoing attempt on the incorporation of pyrazine as pillar in the construction of Zn(II)-tartrate polymeric complex for renewable porous materials." In INTERNATIONAL CONFERENCE ON ENVIRONMENTAL, MINING, AND SUSTAINABLE DEVELOPMENT 2022. AIP, 2024. http://dx.doi.org/10.1063/5.0184577.

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