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Journal articles on the topic 'Terbium carbonate'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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1

Balakrishna, Kurra, S. Dadhich Anima та Babu Mukkamala Saratchandra. "Biomimetic mineralization of CaCO3 , TbCO3 and Ca-TbCO3 mediated by HEDTA and β -CD". Journal of Indian Chemical Society Vol. 91, Jun 2014 (2014): 1029–34. https://doi.org/10.5281/zenodo.5722907.

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Department of Chemistry, GITAM University, Visakhapatnam-530 045, Andhra Pradesh, India <em>E-mail</em> : mscbabu@yahoo.com Fax : 91-891-2790032 <em>Manuscript received online 04 November 2013, revised 13 December 2013, accepted 13 December 2013</em> Growth morphology of calcium carbonate, terbium carbonate and their mixed metal carbonates have been investigated in presence of organic additives namely <em>N</em>-(2-hydroxyethyl)ethylenediamine-<em>N,N&acute;,N</em>&acute;-triaceticacid (HEDTA) and &beta; -cyclodextrin (&beta; -CD). Rhombohedral calcite phase of calcium carbonate transformed to
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2

Litvinova, Tatiana, Stepan Gerasev, Vasiliy Sergeev, and Egor Lidanovskiy. "Rare Earth Metal Ion-Associates in Ln3+—CO32−—H2O System." Metals 15, no. 3 (2025): 239. https://doi.org/10.3390/met15030239.

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This study focused on the nature of rare earth metal complex compounds that can form during the carbonate–alkaline processing of industrial waste materials, such as phosphogypsum and red mud, at 70–100 °C and 1–10 atm. Experimental findings revealed that the dissolution of synthetic carbonates of rare earth elements (REEs) in a concentrated carbonate-ion medium (3 mol/L) leads to the formation of ion-associates of varying strengths. Light (lanthanum, praseodymium, and neodymium) and medium (samarium) REE groups exhibited a tendency to form loose ion-associates, whereas heavy REEs (terbium, dys
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3

Fialkovsky, Igor, Denis Lutskiy, Andrey Alekseev, and Alexey Blinov. "Modelling the Effect of Temperature on the Stability of Bromide and Carbonate Complexes of Europium, Gadolinium, Terbium and Determination of their Thermodynamic Functions." Materials Science Forum 1031 (May 2021): 103–8. http://dx.doi.org/10.4028/www.scientific.net/msf.1031.103.

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A method has been developed for calculating the stability constants of inorganic complexes of rare-earth metals at various temperatures, based on analysis of the literature data by obtaining a linear regression equation on the form: . Using this method, the stability constants of bromide LnBr2+ and carbonate LnCO3+ complexes of europium, terbium, and gadolinium in aqueous solutions at temperatures of 50, 75, and 100 ° C were obtained. The obtained values of the coefficients А(T1) and В(T1) of the linear regression equation can be used to calculate the stability constants of complexes of europi
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4

Varlashkin, P. G., G. M. Begun, and J. R. Peterson. "On the nature of tetravalent terbium in carbonate-hydroxide solutions." Journal of the Less Common Metals 109, no. 1 (1985): 123–34. http://dx.doi.org/10.1016/0022-5088(85)90112-2.

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5

Ünal, Fatma. "Straightforward route for terbium oxide powders: synthesis, morphology, and microstructural parameters." International Journal of Materials Research 113, no. 4 (2022): 287–94. http://dx.doi.org/10.1515/ijmr-2021-8484.

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Abstract The goals of this study lie in the endeavour to synthesise terbium oxide powders, calculation of the average crystallite size, lattice parameter, lattice strain and dislocation density by using X-ray diffraction peak broadenings and, particularly, examination of the effects of precursor molarity on morphology, microstructural parameters and crystal imperfections. The X-ray diffraction patterns demonstrated that the powders had pure cubic bixbyite body-centred phase with high crystallinity. The crystallite size values varied between 21.05 and 31.45 nm depending on both precursor molari
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Song, Miaomiao, Dongliang Tao, Guohua Luo, et al. "Preparation and properties of polyethylene-coated terbium complex/calcium carbonate composite fluorescent material." Journal of Luminescence 203 (November 2018): 292–98. http://dx.doi.org/10.1016/j.jlumin.2018.06.013.

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7

Liu, Kang, Xin Shi, Tingjian Wang, Penghui Ai, Wei Gu, and Ling Ye. "Terbium-doped manganese carbonate nanoparticles with intrinsic photoluminescence and magnetic resonance imaging capacity." Journal of Colloid and Interface Science 485 (January 2017): 25–31. http://dx.doi.org/10.1016/j.jcis.2016.09.010.

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8

Rahimi-Nasrabadi, Mehdi, Seied Mahdi Pourmortazavi, Mohmmad Reza Ganjali, and Parviz Norouzi. "Nanosized terbium carbonate and oxide particles: optimized synthesis, and application as photodegradation catalyst." Journal of Materials Science: Materials in Electronics 29, no. 4 (2017): 2988–98. http://dx.doi.org/10.1007/s10854-017-8229-z.

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9

Saputra, Heru Agung, Anni Anggraeni, Abdul Mutalib, and Husein Hernandi Bahti. "Development of a Fast Simultaneous Analysis Method for Determination of Middle Rare-Earth Elements in Monazite Samples." Jurnal Kimia Sains dan Aplikasi 24, no. 5 (2021): 177–84. http://dx.doi.org/10.14710/jksa.24.5.177-184.

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Rare earth elements are a set of seventeen metallic elements, which is an essential part of many high-tech devices. Hence, analysis and/or separation of the rare earth elements from their mineral become crucial. A novel analysis method combining ultraviolet-visible spectroscopic and multivariate analysis was developed to determine middle rare earth elements quickly and simultaneously. The data collected from ultraviolet-visible spectroscopic were analyzed by multivariate analysis. The results showed that the developed method has good accuracy and precision with a detection limit of 1.375 (± 0.
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10

JIN Feng, 金. 凤., 张文军 ZHANG Wen-jun, 陶栋梁 TAO Dong-liang, et al. "Preparation of Novel Terbium Complexes Using Anhydrous Sodium Carbonate as Base and Nanometer Core." Chinese Journal of Luminescence 36, no. 7 (2015): 782–87. http://dx.doi.org/10.3788/fgxb20153607.0782.

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11

Gómez-Morales, Jaime, Raquel Fernández-Penas, Ismael Romero-Castillo, et al. "Crystallization, Luminescence and Cytocompatibility of Hexagonal Calcium Doped Terbium Phosphate Hydrate Nanoparticles." Nanomaterials 11, no. 2 (2021): 322. http://dx.doi.org/10.3390/nano11020322.

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Luminescent lanthanide-containing biocompatible nanosystems represent promising candidates as nanoplatforms for bioimaging applications. Herein, citrate-functionalized calcium-doped terbium phosphate hydrate nanophosphors of the rhabdophane type were prepared at different synthesis times and different Ca2+/Tb3+ ratios by a bioinspired crystallization method consisting of thermal decomplexing of Ca2+/Tb3+/citrate/phosphate/carbonate solutions. Nanoparticles were characterized by XRD, TEM, SEM, HR-TEM, FTIR, Raman, Thermogravimetry, inductively coupled plasma spectroscopy, thermoanalysis, dynami
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12

Daryono, Lutfian Rusdi, Kazunori Nakashima, Satoru Kawasaki, Anastasia Dewi Titisari, and Didit Hadi Barianto. "Sediment Characteristics of Beachrock: A Baseline Investigation Based on Microbial Induced Carbonate Precipitation at Krakal-Sadranan Beach, Yogyakarta, Indonesia." Applied Sciences 10, no. 2 (2020): 520. http://dx.doi.org/10.3390/app10020520.

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Isolation of ureolytic bacteria and geochemical analysis of beachrock from Krakal-Sadranan Beach (Yogyakarta, Indonesia) were conducted to determine natural sedimentary characteristics of the beachrock. The beachrock was also examined to determine the depositional conditions and distribution of rare earth elements. An increased concentration of total rare earth elements, both heavy rare earth elements (terbium, dysprosium, yttrium, holmium, erbium, thulium, ytterbium, and lutetium) and light rare earth elements (lanthanum, cesium, praseodymium, neodymium, samarium, europium, and gadolinium) si
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13

Greco, T., A. Lehmann, M. H. Nejad, and B. Volkert. "Modified Polysaccharides as New Commodity Materials and for Light-Converting Systems: Syntheses, Characterization and Processing." Materials Science Forum 636-637 (January 2010): 779–86. http://dx.doi.org/10.4028/www.scientific.net/msf.636-637.779.

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Potato starch (PS), also one amylose-rich starch (high amylose maize starch, HAMS) and one amlyopectin-rich starch (waxymaize starch, WMS) were used for the syntheses as raw materials. Starch acetates were synthesized by reaction with acetic acid anhydride and potassium carbonate as activator. Tests of thermoplastic processability of the starch acetates were performed by extrusion followed by injection molding to specimens. Glycerine triacetate (triacetin, TAc) was attached as plasticizer to starch acetate. For this system a processing procedure was acquired under variation of different parame
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14

Bi, Jun, Ji Guang Li, Wei Ming Guan, Jia Lin Chen, and Xun Dong Sun. "Co-Precipitation Synthesis and Photoluminescence Properties of Ce3+ Activated Terbium Aluminum Garnet (Tb1-xCex)3Al5O12 (0≤x≤0.05) Yellow Phosphors." Key Engineering Materials 602-603 (March 2014): 1028–33. http://dx.doi.org/10.4028/www.scientific.net/kem.602-603.1028.

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Ce3+activated terbium aluminum garnet ((Tb1-xCex)3Al5O12, 0≤x≤0.05) phosphors have been converted from their precursors synthesized via co-precipitation from mixed solutions of aluminum and rare earth nitrates with ammonium hydrogen carbonate (AHC) as the precipitant. Detailed characterizations of the precursors and the phosphor oxides were performed by the combined techniques of X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR), field-emission scanning electron microscopy (FE-SEM), differential scanning calorimetry/thermogravimetry (DSC/TG), and photoluminescence spe
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15

Belyi, V. I., A. A. Rastorguev, A. A. Remova, G. V. Romanenko, and N. P. Sokolova. "X-Ray Diffraction Analysis and Luminescent Study of the Structure of the Tb2(CF3COO)6(H2O)6Dimer Obtained from Terbium(III) Carbonate." Journal of Structural Chemistry 45, no. 1 (2004): 130–38. http://dx.doi.org/10.1023/b:jory.0000041511.92521.1e.

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16

Poorghazi-Mahmoodabadi, Mehdy, Hassan Ali Zamani, and Samaneh Pasyar. "Design of Highly Selective and Sensitive PVC-Membrane Sensor for Terbium Ions Based on Di(N-succinimidyl)carbonate as a Neutral Ion Carrier." International Journal of Electrochemical Science 8, no. 3 (2013): 4010–22. http://dx.doi.org/10.1016/s1452-3981(23)14449-x.

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17

KRALJ, Polona. "Rare earth elements and yttrium in cold mineral and thermal (􀂽30-60 °C) waters from Tertiary aquifers in the Mura Basin, north-eastern Slovenia: A review." Geologija 65, no. 1 (2022): 73–92. http://dx.doi.org/10.5474/geologija.2022.005.

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bazenAbstractCold mineral and thermal waters from Tertiary aquifers in the Mura Basin mainly belong to the Ca-(Mg)-(Na)-HCO3 and Na-HCO3 hydrogeochemical facies, respectively, and the concentrations of yttrium (Y) and lanthanides or rare earth elements (REEs) are far below (10-2 – 10-4) the abundances in the aquifer sediments. Mineral waters are high pCO2, and the plots of concentrations of YREEs normalised to Post Archean Australian Shale (PAAS) show fractionation of Y and heavy REEs (HREEs) over light REEs (LREEs), and a significant positive europium (Eu) anomaly. Thermal water from regional
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18

Somrani, Chaima, Fouad Souissi, Radhia Souissi, et al. "The Geochemical Characteristics of Ore-Forming Fluids in the Jebel Stah Fluorite Deposit in Northeast Tunisia: Insights from LA-ICP-MS and Sr Isotope Analyses." Minerals 15, no. 4 (2025): 331. https://doi.org/10.3390/min15040331.

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The Zaghouan Fluorite Province (ZFP) encloses F-Ba(Pb-Zn) ores hosted within Jurassic carbonate series, in northeastern Tunisia. Critical breakthroughs on the Jebel Stah fluorite deposits, an MVT-style F-mineralization, have been made within the Lower Jurassic limestones along the Zaghouan Fault, which is a major target for mineralization. This study presents the first REE-Y analyses conducted by LA-ICP-MS on fluorites in Tunisia, and specifically on the fluorites of Jebel Stah deposit. This analytical technique provides highly accurate insights into the geochemical regime of mineralizing flui
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19

Bruce, James I., Rachel S. Dickins, Linda J. Govenlock, et al. "The Selectivity of Reversible Oxy-Anion Binding in Aqueous Solution at a Chiral Europium and Terbium Center: Signaling of Carbonate Chelation by Changes in the Form and Circular Polarization of Luminescence Emission." Journal of the American Chemical Society 122, no. 40 (2000): 9674–84. http://dx.doi.org/10.1021/ja001797x.

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20

Gómez-Morales, Jaime, Raquel Fernández-Penas, Francisco Javier Acebedo-Martínez, et al. "Luminescent Citrate-Functionalized Terbium-Substituted Carbonated Apatite Nanomaterials: Structural Aspects, Sensitized Luminescence, Cytocompatibility, and Cell Uptake Imaging." Nanomaterials 12, no. 8 (2022): 1257. http://dx.doi.org/10.3390/nano12081257.

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This work explores the preparation of luminescent and biomimetic Tb3+-doped citrate-functionalized carbonated apatite nanoparticles. These nanoparticles were synthesized employing a citrate-based thermal decomplexing precipitation method, testing a nominal Tb3+ doping concentration between 0.001 M to 0.020 M, and a maturation time from 4 h to 7 days. This approach allowed to prepare apatite nanoparticles as a single hydroxyapatite phase when the used Tb3+ concentrations were (i) ≤ 0.005 M at all maturation times or (ii) = 0.010 M with 4 h of maturation. At higher Tb3+ concentrations, amorphous
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21

Cano Plá, Sandra Maria, Annarita D’Urso, Jorge Fernando Fernández-Sánchez, et al. "Biomimetic Citrate-Coated Luminescent Apatite Nanoplatforms for Diclofenac Delivery in Inflammatory Environments." Nanomaterials 12, no. 3 (2022): 562. http://dx.doi.org/10.3390/nano12030562.

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Luminescent nanoparticles are innovative tools for medicine, allowing the imaging of cells and tissues, and, at the same time, carrying and releasing different types of molecules. We explored and compared the loading/release ability of diclofenac (COX-2 antagonist), in both undoped- and luminescent Terbium3+ (Tb3+)-doped citrate-coated carbonated apatite nanoparticles at different temperatures (25, 37, 40 °C) and pHs (7.4, 5.2). The cytocompatibility was evaluated on two osteosarcoma cell lines and primary human osteoblasts. Biological effects of diclofenac-loaded-nanoparticles were monitored
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22

Hege, Nicole, Andrew T. Poore, Shane S. Galley, et al. "Understanding Europium and Terbium Speciation and Ion Pairing in Carbonate Complexes Using Advanced Spectroscopy Techniques." European Journal of Inorganic Chemistry, July 9, 2024. http://dx.doi.org/10.1002/ejic.202400011.

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Lanthanide (Ln) elements are critical materials that are typically extracted/mined together. Their separation by solvent extraction from acidic media is well known; however, there are few studies in basic media with carbonate anions. We investigated the complexation of Eu(III) and Tb(III) carbonates as solids and solutions in alkaline K2CO3, wherein we sought to access a Tb(IV) carbonate complex through ozonolysis. L3‐edge XANES of Eu and Tb carbonate solids, colorless solutions, and a red‐hued Tb solution (obtained by ozonolysis) all showed Ln(III) cations. The absence of evidence for a Tb(IV
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23

Artes, Ernst, Primiana Cavallo, Tobias Häger, et al. "Influence of carbon dioxide and water concentration on terbium thin films produced by Molecular Plating." Radiochimica Acta, July 16, 2025. https://doi.org/10.1515/ract-2025-0021.

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Abstract Terbium and thulium thin films were produced by Molecular Plating under controlled conditions to elucidate a possible influence of water and carbon dioxide present in the plating solution. Platings were made in a glovebox with variable concentration of residual water and CO2 in a controlled inert atmosphere to study the impact on the quality of the produced thin films and on deposition yields. The morphology of the thin films was analyzed by scanning electron microscopy. The deposition yield was determined by neutron activation analysis at the research reactor TRIGA Mainz. Chemical an
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24

VARLASHKIN, P. G., G. M. BEGUN, and J. R. PETERSON. "ChemInform Abstract: ON THE NATURE OF TETRAVALENT TERBIUM IN CARBONATE-HYDROXIDE SOLUTIONS." Chemischer Informationsdienst 16, no. 47 (1985). http://dx.doi.org/10.1002/chin.198547034.

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25

Shironosova, Galina, and Ilya Prokopyev. "REE Speciation in Fluoride-Carbonate-Chloride Cooling Hydrothermal Fluids in the Presence of Barite and Celestine (Thermodynamic Modeling)." Russian Journal of Earth Sciences, December 30, 2023, 1–16. http://dx.doi.org/10.2205/2023es000859.

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A thermodynamic study was carried out in order to determine the forms of transport for the entire series of lanthanides and their ratio with changing parameters of a hydrothermal fluid of moderate concentrations of chloride, carbonate and fluoride components. Hydrothermal solution, cooling from 500 to 100 ∘C, affected barite and celestine, which are used as a source of sulfate sulfur, monazite as a source of rare earth elements (REE) and phosphorus, and calcite as a source of calcium. It has been established that, under weakly acidic (pH about 4.1) conditions, the equilibrium mineral associati
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26

Sasai, Ryo, Kaoru Ohta, Kohei Makishima, et al. "Mechanism Responsible for Changes in the Luminescence Properties of Terbium (III)–Doped Layered Double Hydroxides During Carbonate/Chloride Exchange." Luminescence 40, no. 4 (2025). https://doi.org/10.1002/bio.70174.

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ABSTRACTLayered double hydroxides (LDHs) have been actively studied as water purification, battery, capacitor, and catalytic materials because they exhibit anion‐exchange capabilities. Furthermore, photoluminescent LDHs are potentially useful as materials capable of detecting toxic anions. These materials can be synthesized using various combinations of divalent and trivalent metal cations. Herein, we investigate the synthesis and photoluminescence (PL) properties of Mg (Al, Tb)‐LDHs with different incorporated interlayer anions, specifically carbonate (CO32−) and chloride (Cl−). The CO32−‐inc
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27

Bian, Zijun, Wei Dong, Zhoushen Ning, Yuexin Song, and Kaijian Hu. "Recovery of terbium by Lysinibacillus sp. DW018 isolated from ionic rare earth tailings based on microbial induced calcium carbonate precipitation." Frontiers in Microbiology 15 (June 3, 2024). http://dx.doi.org/10.3389/fmicb.2024.1416731.

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Microbial induced calcium carbonate precipitation (MICP) is considered as an environmentally friendly microbial-based technique to remove heavy metals. However, its application in removal and recovery of rare earth from wastewaters remains limited and the process is still less understood. In this study, a urease-producing bacterial strain DW018 was isolated from the ionic rare earth tailings and identified as Lysinibacillus based on 16S rRNA gene sequencing. Its ability and possible mechanism to recover terbium was investigated by using X-ray diffraction (XRD), scanning electron microscopy (SE
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28

Bian, Zijun, Wei Dong, Xi Li, et al. "Enrichment of Terbium(III) under synergistic effect of biosorption and biomineralization by Bacillus sp. DW015 and Sporosarcina pasteurii." Microbiology Spectrum, June 25, 2024. http://dx.doi.org/10.1128/spectrum.00760-24.

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ABSTRACT Biosorption and biomineralization are commonly used for the immobilization of metal ions. Biosorption is commonly used as a green method to enrich rare earth ions from wastewater. However, little attention has been paid to the facilitating role of biomineralization in the enrichment of rare earth ions. In this study, a strain of Bacillus sp. DW015, isolated from ion adsorption type rare earth ores and a urease-producing strain Sporosarcina pasteurii were used to enrich rare earth elements (REEs) from an aqueous solution. The results indicate that biomineralization accelerates the enri
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29

Li, Lei-Lei, Yi-Fan Fang, Shuang Liu, Shuang-Shuang Chen, and Wen-Zhen Wang. "A unique terbium-fluoride-oxalate metal-organic framework containing [Tb-F]n chains with bifunctions of luminescent detection of Cr(VI) and catalyzing CO2 conversion to cyclic carbonates." Inorganica Chimica Acta, April 2022, 120979. http://dx.doi.org/10.1016/j.ica.2022.120979.

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