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Relevant bibliographies by topics / Termolecular reaction

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Academic literature on the topic 'Termolecular reaction'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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Journal articles on the topic "Termolecular reaction"

1

Rolletter, Michael, Andreas Hofzumahaus, Anna Novelli, Andreas Wahner, and Hendrik Fuchs. "Kinetics of the reactions of OH with CO, NO, and NO₂ and of HO₂ with NO₂ in air at 1 atm pressure, room temperature, and tropospheric water vapour concentrations." Atmospheric Chemistry and Physics 25, no. 6 (2025): 3481–502. https://doi.org/10.5194/acp-25-3481-2025.

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Abstract. The termolecular reactions of hydroxyl radicals (OH) with carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxides (NO2) and the termolecular reaction of hydroperoxy radicals (HO2) with NO2 greatly impact the atmospheric oxidation efficiency. Few studies have directly measured the pressure-dependent rate coefficients in air at 1 atm pressure and water vapour as third-body collision partners. In this work, rate coefficients were measured with a high accuracy (<5 %) at 1 atm pressure, at room temperature, and in humidified air using laser flash photolysis and detection of the

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Amedro, Damien, Arne J. C. Bunkan, Matias Berasategui, and John N. Crowley. "Kinetics of the OH + NO<sub>2</sub> reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N<sub>2</sub> and O<sub>2</sub> bath gases." Atmospheric Chemistry and Physics 19, no. 16 (2019): 10643–57. http://dx.doi.org/10.5194/acp-19-10643-2019.

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Abstract. The radical terminating, termolecular reaction between OH and NO2 exerts great influence on the NOy∕NOx ratio and O3 formation in the atmosphere. Evaluation panels (IUPAC and NASA) recommend rate coefficients for this reaction that disagree by as much as a factor of 1.6 at low temperature and pressure. In this work, the title reaction was studied by pulsed laser photolysis and laser-induced fluorescence over the pressure range 16–1200 mbar and temperature range 217–333 K in N2 bath gas, with experiments at 295 K (67–333 mbar) for O2. In situ measurement of NO2 using two optical absor

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3

Harada, Kenichi, Hiroki Yamane, Miwa Kubo, Ayumi Ohsaki, and Yoshiyasu Fukuyama. "Construction of Canthin-5,6-diones via Termolecular Condensation Reaction: Studies on Synthesis of Amarastelline A." Natural Product Communications 12, no. 8 (2017): 1934578X1701200. http://dx.doi.org/10.1177/1934578x1701200820.

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A termolecular condensation reaction of harmane, alkyl halide, and dimethyl oxalate has been developed for the construction of a variety of canthin-5,6-diones. The carbon skeleton of amarastelline A, a fluorescent canthin alkaloid, was synthesized in 99.8% yield by applying this procedure.

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Siemieniec, Marta, Hanna Kierzkowska-Pawlak, and Andrzej Chacuk. "Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique." Ecological Chemistry and Engineering S 19, no. 1 (2012): 55–66. http://dx.doi.org/10.2478/v10216-011-0006-y.

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Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique The pseudo-first-order rate constants (kOV) for the reactions between CO2 and diethanolamine have been studied using the stopped-flow technique in an aqueous solution at 293, 298, 303 and 313 K. The amine concentrations ranged from 167 to 500 mol·m-3. The overall reaction rate constant was found to increase with amine concentration and temperature. Both the zwitterion and termolecular mechanisms were applied to correlate the experimentally obtained rate constants. The values of SSE quality

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Prashant, S. Shinge, G. Mallur Shanta, and V. Badami Bharati. "Termolecular one-pot synthesis of symmetrical azines of 4-acetyl-3-arylsydnones. Hydrazone and azine derivatives of 4-acetyl-3-arylsydnones, their spectral characterization and biological properties." Journal of Indian Chemical Society Vol. 82, Jul 2005 (2005): 659–64. https://doi.org/10.5281/zenodo.5830581.

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P.G. Department of Chemistry, Karnatak University, Dharwad-580 003, India <em>E-mail</em> : bbadami @rediffimail.com <em>Manuscript received 9 June 2004. revised 18 December 2004, accepted 22 March 2005</em> Hydrazones of 4-acetyl-3-arylsydnones (2a-o) were prepared by heating 4-acetyl-3-arylsydnones (1a-o) with excess of hydrazine hydrate and the corresponding symmetrical azines (3a-o) were obtained by a termolecular reaction of 4-acetyl-3- arylsydnones with hydrazine hydrate (2 : 1 ratio). Hydrazones and azines were screened for their antimicrobial activity and few of these compounds exhibit

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Forte, Leonard, Min H. Lien, Alan C. Hopkinson, and Diethard K. Bohme. "Carbocationic polymerization in the gas phase: polymerization of acetylene induced by BF2+." Canadian Journal of Chemistry 68, no. 9 (1990): 1629–35. http://dx.doi.org/10.1139/v90-252.

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Gas-phase measurements for the primary reaction of BF2+ with acetylene and the ensuing higher-order reactions with acetylene have been performed at 296 ± 2 K in helium at 0.35 torr using the Selected-Ion Flow Tube (SIFT) technique. The primary reaction was observed to be rapid and to produce two species which both initiated rapid polymerization of acetylene. The major primary product, C2HBF+, was observed to initiate the sequential addition of four molecules of acetylene, most likely by termolecular association reactions. The first few steps in this polymerization were also followed using abin

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7

Olbregts, J. "Termolecular reaction of nitrogen monoxide and oxygen: A still unsolved problem." International Journal of Chemical Kinetics 17, no. 8 (1985): 835–48. http://dx.doi.org/10.1002/kin.550170805.

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8

Gilbert, RG, and MJ McEwan. "The Pressure Dependance of Ion-Molecule Reaction Rate Coefficients: CH3+ + HCN/He." Australian Journal of Chemistry 38, no. 2 (1985): 231. http://dx.doi.org/10.1071/ch9850231.

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Illustrative calculations are presented on the application to termolecular ion-molecule reactions of methods recently developed for the study of fall-off effects in neutral thermal unimolecular reactions. The energy-dependent microscopic reaction rate, k(E), is obtained from RRKM theory with activated complex parameters first estimated by using ab initio and spectroscopic data and then refined to yield the appropriate pressure-saturated rate. The collisional energy transfer probability distribution function, P(E,E′), is obtained by fitting the fall-off data, guided by information from trajecto

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Taylor, Peter R., Andrew Komornicki, and David A. Dixon. "Ab initio CI treatment of the termolecular reaction of 3H2: hexagonal H6." Journal of the American Chemical Society 111, no. 4 (1989): 1259–62. http://dx.doi.org/10.1021/ja00186a016.

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Silver, J. A., M. S. Zahniser, A. C. Stanton, and C. E. Kolb. "Temperature dependent termolecular reaction rate constants for potassium and sodium superoxide formation." Symposium (International) on Combustion 20, no. 1 (1985): 605–12. http://dx.doi.org/10.1016/s0082-0784(85)80549-x.

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Books on the topic "Termolecular reaction"

1

Kerr, J. Alistair. Handbook of Bimolecular and Termolecular Gas Reactions, Volume III, Part A (Handbook on Bimolecular & Termolecular). CRC, 1987.

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Kerr, J. Alistair. Handbook of Bimolecular and Termolecular Gas Reactions, Volume III, Part B. CRC, 1987.

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Book chapters on the topic "Termolecular reaction"

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Mukaiyama, Teruaki. "Dehydration reactions." In Challenges in Synthetic Organic Chemistry. Oxford University PressOxford, 1990. http://dx.doi.org/10.1093/oso/9780198556442.003.0003.

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Abstract Ureas and urethanes dissociate on heating into two components; isocyanates and amines, and isocyanates and alcohols, respectively (eqn (2.1)). Analysis of the rate of these thermal dissociation reactions allows us to conclude that ureas and urethanes dissociate via a ‘termolecular’ reaction mechanism.1 After all, ureas and urethanes can be viewed as addition products of isocyanates with amines and with alcohols, respectively. One of their analogues is a class of amides having an electron-withdrawing substituent at the a-carbon of their carbamoyl group. On heating, these amides are als

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2

Jordan, Robert B. "Rate Law and Mechanism." In Reaction Mechanisms of Inorganic and Organometallic Systems. Oxford University Press, 2007. http://dx.doi.org/10.1093/oso/9780195301007.003.0004.

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Once the experimental rate law has been established, the next step is to formulate a mechanism that is consistent with the rate law. The rate law will not uniquely define the mechanism but will limit the possibilities. The proposed mechanism will lead to predictions of trends in reactivity and other types of experiments that can be done to test the proposal. These aspects will be described in later chapters for specific types of reactions. Except for the simplest cases, the development of the rate law from the mechanism can be a messy exercise. The following sections describe some of the assum

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Conference papers on the topic "Termolecular reaction"

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Versailles, Philippe, Antoine Durocher, Gilles Bourque, and Jeffrey M. Bergthorson. "Effect of High Pressures on the Formation of Nitric Oxide in Lean, Premixed Flames." In ASME Turbo Expo 2019: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/gt2019-91037.

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Abstract Increasingly stringent regulations are imposed on nitrogen oxides emissions due to their numerous negative impacts on human health and the environment. Accurate, experimentally validated thermochemical models are required for the development of the next generation of combustors. This paper presents a series of experiments performed in lean, premixed, laminar, jet-wall stagnation flames at pressures of 2, 4, 8, and 16 atm. To target post-flame temperatures relevant to gas turbine engines, the stoichiometry of the non-preheated methane-air mixture is adjusted to an equivalence ratio of

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Salinas, Jorge S., Akanksha Baranwal, Jacqueline Chen, Swapnil Desai, Yujie Tao, and Alexei Poludnenko. "Non-thermal termolecular reactions effects on hydrogen-air planar detonation." In AIAA SCITECH 2024 Forum. American Institute of Aeronautics and Astronautics, 2024. http://dx.doi.org/10.2514/6.2024-2783.

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Reports on the topic "Termolecular reaction"

1

Continetti, Robert E. Dynamics of Elementary Termolecular Reactions and Cluster Fragmentation. Defense Technical Information Center, 2000. http://dx.doi.org/10.21236/ada376064.

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Continetti, Robert E. Dynamics of Elementary Termolecular Reactions and Cluster Fragmentation. Defense Technical Information Center, 2000. http://dx.doi.org/10.21236/ada387088.

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