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Journal articles on the topic 'Termolecular reaction'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Rolletter, Michael, Andreas Hofzumahaus, Anna Novelli, Andreas Wahner, and Hendrik Fuchs. "Kinetics of the reactions of OH with CO, NO, and NO₂ and of HO₂ with NO₂ in air at 1 atm pressure, room temperature, and tropospheric water vapour concentrations." Atmospheric Chemistry and Physics 25, no. 6 (2025): 3481–502. https://doi.org/10.5194/acp-25-3481-2025.

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Abstract. The termolecular reactions of hydroxyl radicals (OH) with carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxides (NO2) and the termolecular reaction of hydroperoxy radicals (HO2) with NO2 greatly impact the atmospheric oxidation efficiency. Few studies have directly measured the pressure-dependent rate coefficients in air at 1 atm pressure and water vapour as third-body collision partners. In this work, rate coefficients were measured with a high accuracy (<5 %) at 1 atm pressure, at room temperature, and in humidified air using laser flash photolysis and detection of the

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2

Amedro, Damien, Arne J. C. Bunkan, Matias Berasategui, and John N. Crowley. "Kinetics of the OH + NO<sub>2</sub> reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N<sub>2</sub> and O<sub>2</sub> bath gases." Atmospheric Chemistry and Physics 19, no. 16 (2019): 10643–57. http://dx.doi.org/10.5194/acp-19-10643-2019.

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Abstract. The radical terminating, termolecular reaction between OH and NO2 exerts great influence on the NOy∕NOx ratio and O3 formation in the atmosphere. Evaluation panels (IUPAC and NASA) recommend rate coefficients for this reaction that disagree by as much as a factor of 1.6 at low temperature and pressure. In this work, the title reaction was studied by pulsed laser photolysis and laser-induced fluorescence over the pressure range 16–1200 mbar and temperature range 217–333 K in N2 bath gas, with experiments at 295 K (67–333 mbar) for O2. In situ measurement of NO2 using two optical absor

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3

Harada, Kenichi, Hiroki Yamane, Miwa Kubo, Ayumi Ohsaki, and Yoshiyasu Fukuyama. "Construction of Canthin-5,6-diones via Termolecular Condensation Reaction: Studies on Synthesis of Amarastelline A." Natural Product Communications 12, no. 8 (2017): 1934578X1701200. http://dx.doi.org/10.1177/1934578x1701200820.

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A termolecular condensation reaction of harmane, alkyl halide, and dimethyl oxalate has been developed for the construction of a variety of canthin-5,6-diones. The carbon skeleton of amarastelline A, a fluorescent canthin alkaloid, was synthesized in 99.8% yield by applying this procedure.

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4

Siemieniec, Marta, Hanna Kierzkowska-Pawlak, and Andrzej Chacuk. "Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique." Ecological Chemistry and Engineering S 19, no. 1 (2012): 55–66. http://dx.doi.org/10.2478/v10216-011-0006-y.

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Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique The pseudo-first-order rate constants (kOV) for the reactions between CO2 and diethanolamine have been studied using the stopped-flow technique in an aqueous solution at 293, 298, 303 and 313 K. The amine concentrations ranged from 167 to 500 mol·m-3. The overall reaction rate constant was found to increase with amine concentration and temperature. Both the zwitterion and termolecular mechanisms were applied to correlate the experimentally obtained rate constants. The values of SSE quality

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5

Prashant, S. Shinge, G. Mallur Shanta, and V. Badami Bharati. "Termolecular one-pot synthesis of symmetrical azines of 4-acetyl-3-arylsydnones. Hydrazone and azine derivatives of 4-acetyl-3-arylsydnones, their spectral characterization and biological properties." Journal of Indian Chemical Society Vol. 82, Jul 2005 (2005): 659–64. https://doi.org/10.5281/zenodo.5830581.

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P.G. Department of Chemistry, Karnatak University, Dharwad-580 003, India <em>E-mail</em> : bbadami @rediffimail.com <em>Manuscript received 9 June 2004. revised 18 December 2004, accepted 22 March 2005</em> Hydrazones of 4-acetyl-3-arylsydnones (2a-o) were prepared by heating 4-acetyl-3-arylsydnones (1a-o) with excess of hydrazine hydrate and the corresponding symmetrical azines (3a-o) were obtained by a termolecular reaction of 4-acetyl-3- arylsydnones with hydrazine hydrate (2 : 1 ratio). Hydrazones and azines were screened for their antimicrobial activity and few of these compounds exhibit

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6

Forte, Leonard, Min H. Lien, Alan C. Hopkinson, and Diethard K. Bohme. "Carbocationic polymerization in the gas phase: polymerization of acetylene induced by BF2+." Canadian Journal of Chemistry 68, no. 9 (1990): 1629–35. http://dx.doi.org/10.1139/v90-252.

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Gas-phase measurements for the primary reaction of BF2+ with acetylene and the ensuing higher-order reactions with acetylene have been performed at 296 ± 2 K in helium at 0.35 torr using the Selected-Ion Flow Tube (SIFT) technique. The primary reaction was observed to be rapid and to produce two species which both initiated rapid polymerization of acetylene. The major primary product, C2HBF+, was observed to initiate the sequential addition of four molecules of acetylene, most likely by termolecular association reactions. The first few steps in this polymerization were also followed using abin

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7

Olbregts, J. "Termolecular reaction of nitrogen monoxide and oxygen: A still unsolved problem." International Journal of Chemical Kinetics 17, no. 8 (1985): 835–48. http://dx.doi.org/10.1002/kin.550170805.

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8

Gilbert, RG, and MJ McEwan. "The Pressure Dependance of Ion-Molecule Reaction Rate Coefficients: CH3+ + HCN/He." Australian Journal of Chemistry 38, no. 2 (1985): 231. http://dx.doi.org/10.1071/ch9850231.

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Illustrative calculations are presented on the application to termolecular ion-molecule reactions of methods recently developed for the study of fall-off effects in neutral thermal unimolecular reactions. The energy-dependent microscopic reaction rate, k(E), is obtained from RRKM theory with activated complex parameters first estimated by using ab initio and spectroscopic data and then refined to yield the appropriate pressure-saturated rate. The collisional energy transfer probability distribution function, P(E,E′), is obtained by fitting the fall-off data, guided by information from trajecto

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9

Taylor, Peter R., Andrew Komornicki, and David A. Dixon. "Ab initio CI treatment of the termolecular reaction of 3H2: hexagonal H6." Journal of the American Chemical Society 111, no. 4 (1989): 1259–62. http://dx.doi.org/10.1021/ja00186a016.

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10

Silver, J. A., M. S. Zahniser, A. C. Stanton, and C. E. Kolb. "Temperature dependent termolecular reaction rate constants for potassium and sodium superoxide formation." Symposium (International) on Combustion 20, no. 1 (1985): 605–12. http://dx.doi.org/10.1016/s0082-0784(85)80549-x.

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11

Campbell, Mark L. "Kinetics of the Termolecular Insertion Reaction of Ground State Rhodium with Methane." Journal of the American Chemical Society 119, no. 25 (1997): 5984–85. http://dx.doi.org/10.1021/ja9708169.

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12

Mogo, César, João Brandão, Wenli Wang, Daniela Coelho, and Carolina Rio. "Quasiclassical study of a termolecular reaction: Application to the HO2 collisional stabilization process." Computational and Theoretical Chemistry 1209 (March 2022): 113614. http://dx.doi.org/10.1016/j.comptc.2022.113614.

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13

Trolier, M., R. L. Mauldin, and A. R. Ravishankara. "Rate coefficient for the termolecular channel of the self-reaction of chlorine monoxide." Journal of Physical Chemistry 94, no. 12 (1990): 4896–907. http://dx.doi.org/10.1021/j100375a027.

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14

Campbell, Mark L. "Kinetics of the termolecular reaction of gas phase Pd(a1S0) atoms with methane." Chemical Physics Letters 365, no. 3-4 (2002): 361–65. http://dx.doi.org/10.1016/s0009-2614(02)01497-5.

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15

Ozge, Yuksel Orhan. "Catalytic effect of amines on a CO2BOL absorption performance." Journal of Indian Chemical Society Vol. 97, No. 10c, Oct 2020 (2020): 2079–82. https://doi.org/10.5281/zenodo.5665889.

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Department of Chemical Engineering, Hacettepe University, Ankara, Turkey <em>E-mail:</em> oyuksel@hacettepe.edu.tr <em>Manuscript received online 20 October 2020, revised and accepted 31 October 2020</em> In the scope of this work, the kinetic parameters for the reaction between CO<sub>2</sub> and promoted CO<sub>2</sub> BOLs were achieved by using stopped-flow technique. As an organic base DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) and as promoters MEA (monoethanolamine) and morpholine were investigated. Experiments were performed under constant DBU weight percentage by varying promoter concent

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16

Saleh, Sanaa Rabie, and Ahmed Daham Wiheeb. "Kinetic Study of Carbon Dioxide Reaction with Binding Organic Liquids." TJES Vol26 No.1 2019 26, no. 1 (2019): 26–32. http://dx.doi.org/10.25130/tjes.26.1.04.

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Binding organic liquids are a strong base of amidine have been used for CO2 capture. Up to now, there is no known datum on the reaction kinetics of CO2 with 1,5-Diazabicyclo[4.3.0]non-5-ene (DBN). In this paper, Kinetics of reaction between CO2 and DBN/MDEA in 1-Pentanol were performed utilizing the stirred cell reactor with DBN concentration (2 – 2.9 M) and at room temperature. The reaction path was qualified using zwitterion and the termolecular mechanism. From the kinetic datum with DBN concentrations (2 – 2.9 M), it was found that the capturing process happen in a fast reaction system with

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17

Kirkpatrick, Iain, David R. Worrall, Siân L. Williams, Craig J. T. Buck, and Rafael G. Meseguer. "Probing the interplay between factors determining reaction rates on silica gel using termolecular systems." Photochemical & Photobiological Sciences 11, no. 10 (2012): 1585. http://dx.doi.org/10.1039/c2pp25171j.

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18

Liu, Yi, Li-Ming Yang, and Eric Ganz. "First-Principles Investigations of Single Metal Atoms (Sc, Ti, V, Cr, Mn, and Ni) Embedded in Hexagonal Boron Nitride Nanosheets for the Catalysis of CO Oxidation." Condensed Matter 4, no. 3 (2019): 65. http://dx.doi.org/10.3390/condmat4030065.

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We evaluated isolated transition metal atoms (Sc, Ti, V, Cr, Mn, and Ni) embedded in hexagonal-BN as novel single atom catalysts for CO oxidation. We predicted that embedded Ni atoms should have superior performance for this task. Ti, V, and Mn bind CO2 too strongly and so the reaction will not proceed smoothly. We studied the detailed reaction processes for Sc, Cr, and Ni. The Langmuir–Hinshelwood (LH), Eley–Rideal (ER), and the new termolecular Eley–Rideal (TER) processes for CO oxidation were investigated. Sc was not effective. Cr primarily used the ER process, although the barrier was rela

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19

Gabričević, Mario, Gábor Lente, and István Fábián. "Hydrogen Isotope Exchange of Chlorinated Ethylenes in Aqueous Solution: Possibly a Termolecular Liquid Phase Reaction." Journal of Physical Chemistry A 119, no. 51 (2015): 12627–34. http://dx.doi.org/10.1021/acs.jpca.5b10665.

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20

Wu, Yun-Dong, Jeehiun K. Lee, K. N. Houk, and Alessandro Dondoni. "Theoretical Study of a Termolecular Mechanism for the Reaction of (Trimethylsilyl)thiazole with Carbonyl Compounds." Journal of Organic Chemistry 61, no. 6 (1996): 1922–26. http://dx.doi.org/10.1021/jo951758h.

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21

Pilling, Sergio, Geanderson A. Carvalho, and Will R. M. Rocha. "Chemical Evolution of CO₂ Ices under Processing by Ionizing Radiation: Characterization of Nonobserved Species and Chemical Equilibrium Phase with the Employment of PROCODA Code." Astrophysical Journal 925, no. 2 (2022): 147. http://dx.doi.org/10.3847/1538-4357/ac3d8a.

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Abstract Astrophysical ices are being exposed to ionizing radiation in space environments, which trigger new reactions and desorption processes. In the lab, such processing by radiation has revealed the appearance of several new species and complements the study of the chemical evolution of icy astrophysical scenarios. Here, we develop a computational methodology that helps to clarify the chemical evolution of ices investigated experimentally under photolysis/radiolysis processes until reaching chemical equilibrium (CE). Briefly, the code (named PROCODA) solves a system of coupled differential

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22

Krötz, W., A. Ulrich, B. Busch, G. Ribitzki, and J. Wieser. "Third excimer continua in neon and argon." Laser and Particle Beams 11, no. 3 (1993): 521–28. http://dx.doi.org/10.1017/s0263034600005176.

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The emission of the third continuum of argon in the wavelength range between 175 and 250 nm and the vacuum ultraviolet emission of neon (λ < 100 nm) has been studied by timeresolved optical spectroscopy. The target gases at pressures between 2 and 100 kPa were excited with a pulsed beam of 100 MeV 32S9+ ions from the Munich Tandem van de Graaf accelerator. Wavelength spectra recorded in different time windows after the 2-ns beam pulses show that two different components contribute to the third continuum of argon. A radiative lifetime of 5.71 ± 0.08 ns for the Ar22+ molecule and a rate coeff

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23

Pan, James J., Donald J. Arseneau, Masayoshi Senba, et al. "Termolecular kinetics for the Mu+CO+M recombination reaction: A unique test of quantum rate theory." Journal of Chemical Physics 125, no. 1 (2006): 014307. http://dx.doi.org/10.1063/1.2209679.

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24

Makul, Natt. "Towards Computational CO2 Capture and Storage Models." Global Environmental Engineers 8 (December 25, 2021): 55–69. http://dx.doi.org/10.15377/2410-3624.2021.08.5.

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This review is aimed to increase knowledge on computational CO2 capture and storage models that are gradually evolving in the design and development to act as more effective carbon capture agents with acceptable toxicity and costs and complementary adjuncts to experiments for comprehending amino-CO2 reaction mechanisms. Also, the review discussed experimental research of degradation reactions of aqueous organic amines, measurements, kinetics and forecasts of amine pKₐ values and amine-CO2 equilibria. Also, the researcher comprehensively discussed the computational simulation of mechanisms of c

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25

Mahmud, Nafis, Abdelbaki Benamor, Mustafa Nasser, Muftah H. El-Naas, and Paitoon Tontiwachwuthikul. "Reaction Kinetics of Carbon Dioxide in Aqueous Blends of N-Methyldiethanolamine and L-Arginine Using the Stopped-Flow Technique." Processes 7, no. 2 (2019): 81. http://dx.doi.org/10.3390/pr7020081.

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: Reduction of carbon dioxide emission from natural and industrial flue gases is paramount to help mitigate its effect on global warming. Efforts are continuously deployed worldwide to develop efficient technologies for CO2 capture. The use of environment friendly amino acids as rate promoters in the present amine systems has attracted the attention of many researchers recently. In this work, the reaction kinetics of carbon dioxide with blends of N-methyldiethanolamine and L-Arginine was investigated using stopped flow technique. The experiments were performed over a temperature range of 293 t

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26

Diau, Eric Wei Guang, and Yuan Pern Lee. "Termolecular rate coefficients and the standard enthalpy of the reaction hydroxyl + carbon disulfide + M .fwdarw. HOCS2 + M." Journal of Physical Chemistry 95, no. 1 (1991): 379–86. http://dx.doi.org/10.1021/j100154a068.

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27

Bourmada, N., P. Devolder, and L. R. Sochet. "Rate constant for the termolecular reaction of OH+toluene+helium in the fall-off range below 10 Torr." Chemical Physics Letters 149, no. 3 (1988): 339–42. http://dx.doi.org/10.1016/0009-2614(88)85038-3.

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28

von Clarmann, Thomas, and Sören Johansson. "Chlorine nitrate in the atmosphere." Atmospheric Chemistry and Physics 18, no. 20 (2018): 15363–86. http://dx.doi.org/10.5194/acp-18-15363-2018.

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Abstract. This review article compiles the characteristics of the gas chlorine nitrate and discusses its role in atmospheric chemistry. Chlorine nitrate is a reservoir of both stratospheric chlorine and nitrogen. It is formed by a termolecular reaction of ClO and NO2. Sink processes include gas-phase chemistry, photo-dissociation, and heterogeneous chemistry on aerosols. The latter sink is particularly important in the context of polar spring stratospheric chlorine activation. ClONO2 has vibrational–rotational bands in the infrared, notably at 779, 809, 1293, and 1735 cm−1, which are used for

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Amedro, Damien, Matias Berasategui, Arne J. C. Bunkan, Andrea Pozzer, Jos Lelieveld, and John N. Crowley. "Kinetics of the OH + NO<sub>2</sub> reaction: effect of water vapour and new parameterization for global modelling." Atmospheric Chemistry and Physics 20, no. 5 (2020): 3091–105. http://dx.doi.org/10.5194/acp-20-3091-2020.

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Abstract. The effect of water vapour on the rate coefficient for the atmospherically important, termolecular reaction between OH and NO2 was determined in He–H2O (277, 291, and 332 K) and N2–H2O bath gases (292 K). Combining pulsed-laser photolytic generation of OH and its detection by laser-induced fluorescence (PLP-LIF) with in situ, optical measurement of both NO2 and H2O, we were able to show that (in contrast to previous investigations) the presence of H2O increases the rate coefficient significantly. We derive a rate coefficient for H2O bath gas at the low-pressure limit (k0H2O) of 15.9×

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30

Monge-Palacios, M., and Homayoon Rafatijo. "On the role of the termolecular reactions 2O2 + H2 → 2HO2 and 2O2 + H2 → H + HO2 + O2 in formation of the first radicals in hydrogen combustion: ab initio predictions of energy barriers." Physical Chemistry Chemical Physics 19, no. 3 (2017): 2175–85. http://dx.doi.org/10.1039/c6cp07029a.

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31

Sun, Wenyu, Matias Berasategui, Andrea Pozzer, Jos Lelieveld, and John N. Crowley. "Kinetics of OH + SO<sub>2</sub> + M: temperature-dependent rate coefficients in the fall-off regime and the influence of water vapour." Atmospheric Chemistry and Physics 22, no. 7 (2022): 4969–84. http://dx.doi.org/10.5194/acp-22-4969-2022.

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Abstract. The OH-initiated oxidation of SO2 is the dominant, first step in the transformation of this atmospherically important trace gas to particulate sulfate, and accurate rate coefficients for the title reaction under all atmospheric conditions (pressures, temperatures, and humidity) are required to assess its role in, for example, new particle formation. Prior to this study, no temperature-dependent data were available in the fall-off regime for atmospherically relevant bath gases. We thus address an important omission in the kinetic database for this reaction and highlight significant di

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Whitehill, A. R., B. Jiang, H. Guo, and S. Ono. "SO<sub>2</sub> photolysis as a source for sulfur mass-independent isotope signatures in stratospheric aerosols." Atmospheric Chemistry and Physics Discussions 14, no. 16 (2014): 23499–554. http://dx.doi.org/10.5194/acpd-14-23499-2014.

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Abstract. Signatures of sulfur isotope mass-independent fractionation (S-MIF) have been observed in stratospheric sulfate aerosols deposited in polar ice. The S-MIF signatures are associated with stratospheric photochemistry following stratospheric volcanic eruptions, but the exact mechanism responsible for the production and preservation of these signatures is debated. In order to identify the origin and the mechanism of preservation for these signatures, a series of laboratory photochemical experiments were carried out to investigate the effect of temperature and added O2 on S-MIF produced b

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33

Roberts, T. J., L. Jourdain, P. T. Griffiths, and M. Pirre. "Re-evaluating the reactive uptake of HOBr in the troposphere with implications for the marine boundary layer and volcanic plumes." Atmospheric Chemistry and Physics Discussions 14, no. 2 (2014): 2717–71. http://dx.doi.org/10.5194/acpd-14-2717-2014.

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Abstract. The reactive uptake of HOBr onto halogen-rich aerosols promotes conversion of Br−(aq) into gaseous reactive bromine (incl. BrO) with impacts on tropospheric oxidants and mercury deposition. However, experimental data quantifying HOBr reactive uptake on tropospheric aerosols is limited, and reported values vary in magnitude. This study re-examines the reaction kinetics of HOBr across a range of aerosol acidity conditions, focusing on chemistry within the marine boundary layer and volcanic plumes. We highlight that the termolecular approach to HOBr reaction kinetics, used in numerical

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34

Nickolaisen, Scott L., Randall R. Friedl, and Stanley P. Sander. "Kinetics and mechanism of the chlorine oxide ClO + ClO reaction: pressure and temperature dependences of the bimolecular and termolecular channels and thermal decomposition of chlorine peroxide." Journal of Physical Chemistry 98, no. 1 (1994): 155–69. http://dx.doi.org/10.1021/j100052a027.

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35

Noll, Stefan, John M. C. Plane, Wuhu Feng, et al. "Structure, variability, and origin of the low-latitude nightglow continuum between 300 and 1800 nm: evidence for HO₂ emission in the near-infrared." Atmospheric Chemistry and Physics 24, no. 2 (2024): 1143–76. http://dx.doi.org/10.5194/acp-24-1143-2024.

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Abstract. The Earth's mesopause region between about 75 and 105 km is characterised by chemiluminescent emission from various lines of different molecules and atoms. This emission was and is important for the study of the chemistry and dynamics in this altitude region at nighttime. However, our understanding is still very limited with respect to molecular emissions with low intensities and high line densities that are challenging to resolve. Based on 10 years of data from the astronomical X-shooter echelle spectrograph at Cerro Paranal in Chile, we have characterised in detail this nightglow (

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36

Roberts, T. J., L. Jourdain, P. T. Griffiths, and M. Pirre. "Re-evaluating the reactive uptake of HOBr in the troposphere with implications for the marine boundary layer and volcanic plumes." Atmospheric Chemistry and Physics 14, no. 20 (2014): 11185–99. http://dx.doi.org/10.5194/acp-14-11185-2014.

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Abstract. The reactive uptake of HOBr onto halogen-rich aerosols promotes conversion of Br−(aq) into gaseous reactive bromine (incl. BrO) with impacts on tropospheric oxidants and mercury deposition. However, experimental data quantifying HOBr reactive uptake on tropospheric aerosols is limited, and reported values vary in magnitude. This study introduces a new evaluation of HOBr reactive uptake coefficients in the context of the general acid-assisted mechanism. We emphasise that the termolecular kinetic approach assumed in numerical model studies of tropospheric reactive bromine chemistry to

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37

Whitehill, A. R., B. Jiang, H. Guo, and S. Ono. "SO<sub>2</sub> photolysis as a source for sulfur mass-independent isotope signatures in stratospehric aerosols." Atmospheric Chemistry and Physics 15, no. 4 (2015): 1843–64. http://dx.doi.org/10.5194/acp-15-1843-2015.

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Abstract. Signatures of sulfur isotope mass-independent fractionation (S-MIF) have been observed in stratospheric sulfate aerosols deposited in polar ice. The S-MIF signatures are thought to be associated with stratospheric photochemistry following stratospheric volcanic eruptions, but the exact mechanism responsible for the production and preservation of these signatures is debated. In order to identify the origin and the mechanism of preservation for these signatures, a series of laboratory photochemical experiments were carried out to investigate the effect of temperature and added O2 on th

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38

Barbet, Mark C., Kevin McCullough, and Michael P. Burke. "A framework for automatic discovery of chemically termolecular reactions." Proceedings of the Combustion Institute 37, no. 1 (2019): 347–54. http://dx.doi.org/10.1016/j.proci.2018.05.002.

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39

Vaidya, P. D., and E. Y. Kenig. "Termolecular Kinetic Model for CO2-Alkanolamine Reactions: An Overview." Chemical Engineering & Technology 33, no. 10 (2010): 1577–81. http://dx.doi.org/10.1002/ceat.201000050.

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40

Anicich, V. "Termolecular Ion–Molecule Reactions in Titan's Atmosphere III. Clustering of Ions." Icarus 154, no. 2 (2001): 522–30. http://dx.doi.org/10.1006/icar.2001.6696.

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Mohammed, Mohammed A., Klaus H. Ebert, and Hans Joachim Breunig. "Zwischenmolekulare Wechselwirkungen bei RSbCl2 und die Bildung cyclischer Organoantimon(III)-chalkogenide, (RSbE)n [R = (Me3Si)2CH, E = S, Se, Te] / Intermolecular Interactions of RSbCl2 and Formation of Cyclic Organoantimony(III) Chalcogenides, (RSbE)n [R = (Me3Si)2CH, E = S, Se, Te]." Zeitschrift für Naturforschung B 51, no. 1 (1996): 149–52. http://dx.doi.org/10.1515/znb-1996-0128.

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Abstract Alkylantimony Dichloride, Cyclostibane Chalcogenides The crystal structure of the compound (Me3Si)2CHSbCl2 (1) has been determined as obtained from the melt. It contains dimers with in termolecular Sb···Cl distances of 351.8 (1) pm. Reactions of 1 with the corresponding sodium chalcogenides yield the products (RSbS)n (2), (RSbSe)n (3) and (RSbTe)n (4) [R = (Me3Si)2CH], The mass spectra of 2-4 give peaks for the dimers, trimers and tetramers, while the NM R spectra of solutions of 2-4 in CDCl3 show that the trimers are the most abundant species in ring-ring-equilibria.

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Anicich, V. "Termolecular Ion–Molecule Reactions in Titan's Atmosphere, I Principal Ions with Principal Neutrals." Icarus 146, no. 1 (2000): 118–24. http://dx.doi.org/10.1006/icar.2000.6353.

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43

Daly, G. M., M. Meot‐Ner, Y. B. Pithawalla, and M. S. El‐Shall. "Termolecular proton transfer reactions assisted by ionic hydrogen bond formation: Reactions of aromatic cations with polar molecules." Journal of Chemical Physics 104, no. 20 (1996): 7965–73. http://dx.doi.org/10.1063/1.471512.

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Hart, Peter W., and Jude T. Sommerfeld. "Elliptic integral solutions for the kinetics of autocatalytic termolecular reactions with reactive intermediate species." Chemical Engineering Journal 66, no. 3 (1997): 231–34. http://dx.doi.org/10.1016/s1385-8947(97)00008-9.

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Desai, Swapnil, Yujie Tao, Raghu Sivaramakrishnan, Yunchao Wu, Tianfeng Lu, and Jacqueline H. Chen. "Effects of non-thermal termolecular reactions on detonation development in hydrogen (H2)/methane (CH4) - air mixtures." Combustion and Flame 244 (October 2022): 112277. http://dx.doi.org/10.1016/j.combustflame.2022.112277.

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Charlo, David, and David C. Clary. "Quantum-mechanical calculations on termolecular association reactions XY+Z+M→XYZ+M: Application to ozone formation." Journal of Chemical Physics 117, no. 4 (2002): 1660–72. http://dx.doi.org/10.1063/1.1485069.

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Schröder, Detlef, Reuben Brown, Peter Schwerdtfeger, and Helmut Schwarz. "Kinetics of radiative/termolecular associations in the low pressure regime: reactions of bare au+ with benzene." International Journal of Mass Spectrometry 203, no. 1-3 (2000): 155–63. http://dx.doi.org/10.1016/s1387-3806(00)00317-1.

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Chao, Wen, Cangtao Yin, Kaito Takahashi, and Jim Jr-Min Lin. "Hydrogen-Bonding Mediated Reactions of Criegee Intermediates in the Gas Phase: Competition between Bimolecular and Termolecular Reactions and the Catalytic Role of Water." Journal of Physical Chemistry A 123, no. 39 (2019): 8336–48. http://dx.doi.org/10.1021/acs.jpca.9b07117.

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Petrie, Simon. "Basic Atmospheric Chemistry: A Quantum Chemical Study on Hydration of Mesospheric NaOH." Environmental Chemistry 1, no. 1 (2004): 35. http://dx.doi.org/10.1071/en04001.

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Abstract:

Environmental Context.A natural global layer of sodium atoms exists in the mesosphere, 80–95 km above sea level, where it originates—along with lithium, iron, and calcium—from ablation of meteors. Sodium, as its hydroxide, readily associates with free water to form NaOH·(H2O)n clusters. The clusters strongly emit IR radiation and may therefore affect the upper atmosphere’s temperature profile; the clusters are also likely to be a source of nuclei for noctilucent clouds. The same NaOH-based processes may also occur at lower altitudes in the troposphere where water is more abundant than carbon d

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Anicich, Vincent G., Paul Wilson, and Murray J. McEwan. "Termolecular ion-molecule reactions in Titan’s atmosphere. IV. A search made at up to 1 micron in pure hydrocarbons." Journal of the American Society for Mass Spectrometry 14, no. 8 (2003): 900–915. http://dx.doi.org/10.1016/s1044-0305(03)00218-6.

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