Relevant bibliographies by topics / Tertiary carbinol derivatives

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Academic literature on the topic 'Tertiary carbinol derivatives'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Tertiary carbinol derivatives"

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O., P. VIG, L. KAD G., GHOSE J., and SINGH JASVINDER. "Insect Juvenile Hormone Analogues. Part-XVII. Synthesis and Juvenile Hormonal Activity of Undecencyl Ethers and Their Derivatives." Journal of Indian Chemical Society Vol. 62, Aug 1985 (1985): 607–12. https://doi.org/10.5281/zenodo.6321630.

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Department of Chemistry, Punjab University, Chandigarh-160 014 <em>Manuscript received 8 March 1983, revised 26 June 1986, accepted 30 August 1985</em> Four substituted-aromatic ethers with undecenyl chain have been prepared by the alkylation of 2-isopropylphenol, 4-isopropylphenol, 5-isopropyl-2-methylphenol and 6- isopropyl-3-methylppenol with 10-undecenyl-1-bromide. These ethers have been modi&shy;fied at the terminal methylene moiety for the preparation of different analogues. Their Juvenile hormone activity against <em>Dysdercus koenigii </em>Fabricius (red cotton bug) is described.
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2

Wibaut, J. P., and P. Ph H. L. Otto. "Tripyridyl carbinols: A group of tertiary alcohols with amphoteric properties: 104th Communication on pyridine derivatives." Recueil des Travaux Chimiques des Pays-Bas 77, no. 11 (2010): 1048–63. http://dx.doi.org/10.1002/recl.19580771109.

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3

Frichert, Alex, Peter G. Jones, and Thomas Lindel. "Synthesis of eunicellane-type bicycles embedding a 1,3-cyclohexadiene moiety." Beilstein Journal of Organic Chemistry 14 (September 20, 2018): 2461–67. http://dx.doi.org/10.3762/bjoc.14.222.

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The first synthesis of diterpenoid eunicellane skeletons incorporating a 1,3-cyclohexadiene moiety is presented. Key step is a low-valent titanium-induced pinacol cyclization that proved to be perfectly diastereoselective. Determination of the relative configuration of the diol was aided by the conversion to the diastereomer by oxidation and reduction. Conformational analysis of some of the resulting diols obtained under McMurry conditions was complicated by the presence of several conformers of similar energy. The pinacol coupling appears to start at the ketone, as indicated by the selective
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4

Bravo, Pierfrancesco, Massimo Frigerio, Giovanni Fronza, et al. "Stereoselective oxirane formation by reaction of diazomethane on 1-fluoro-3-[(4-methylphenyl)sulfinyl]-3-phenylpropan-2-one." Canadian Journal of Chemistry 72, no. 8 (1994): 1769–79. http://dx.doi.org/10.1139/v94-224.

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(2S, 2′R,RS)-2-(Fluoromethyl)-2-{[(4-methylphenyl)sulfinyl][phenyl]methyl}oxirane (4) was obtained in high chemical yield and with high diastereoselectivity by reacting diazomethane with pure (3R, RS)-1-fluoro-3-[(4-methylphenyl)sulfinyl]-3-phenylpropan-2-one (3), but also with its (3S, RS)-3-diastereoisomer, in the latter case through inversion of the configuration at carbon 3. The corresponding methyl enol ethers 6 were isolated as by-products. NMR experiments and molecular modelling calculations were performed in order to clarify the equilibria in solution and the preferred conformations of
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5

Turdialiev, Murodjon, and Elmurod Pulatov. "SYNTHESIS OF 2-R-AMINO-5,6-ETHYLENE-1,4-DIOXYBENZTHIAZOLANE FROM 6-AMINO-1,4-BENZODIOXANE." BULLETIN OF THE TAJIK NATIONAL UNIVERSITY. SERIES OF ECONOMIC AND SOCIAL SCIENCES 2024, no. 3 (2024). https://doi.org/10.62965/tnu.sns.2024.3.3.

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By reacting 6-amino-1,4-benzodioxane with potassium thiocyanate in an acidic medium and subsequent oxidation with sulfuryl chloride, 2-amino-5,6-ethylenedioxy-1,4 benzothiazole was obtained. Further, in reactions with electrophilic reagents: acetic anhydride and toluenesulfonamide, the corresponding acylamide and toluenesulfonamide derivatives of the latter were obtained.An innovative approach to the synthesis of secondary and tertiary carbinols of the 1,4-benzodioxane series is proposed. A new method for the synthesis of a tricyclic heterocycle, 2-amino-6,7-ethylenedioxybenzthiazole, has been
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Book chapters on the topic "Tertiary carbinol derivatives"

1

Lambert, Tristan H. "Construction of Single Stereocenters." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0037.

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James L. Leighton at Columbia University reported (Nature 2012, 487, 86) that the commercially available allylsilane 2 allylated acetoacetone (1) to furnish the enantioenriched tertiary carbinol 3. Alexander T. Radosevich demonstrated (Angew. Chem. Int. Ed. 2012, 51, 10605) that diazaphospholidine 5 induced the formal reductive insertion of 3,5-dinitrobenzoic acid to α-ketoester 4 to generate adduct 6 enantioselectively. Tehshik P. Yoon at the University of Wisconsin at Madison found (J. Am Chem. Soc. 2012, 134, 12370) that aminoalcohol derivative 9 could be prepared via an asymmetric iron-cat
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