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Journal articles on the topic 'Tetrabutylammonium tribromide'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Bora, Upasana, Mihir K. Chaudhuri, Deepa Dey, and Siddhartha S. Dhar. "Peroxometal-mediated environmentally favorable route to brominating agents and protocols for bromination of organics." Pure and Applied Chemistry 73, no. 1 (2001): 93–102. http://dx.doi.org/10.1351/pac200173010093.

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Higher-valent transition metals react with H2O2 to form peroxometallates, thereby activating the coordinated peroxide. Based on the reaction profiles of peroxometal species, environmentally acceptable newer syntheses of tetrabutylammonium tribromide (TBATB), Bu4NBr3, cetyltrimethylammonium tribromide (CTMATB), cetyl(Me)3NBr3, and tetraethyl-ammonium tribromide (TEATB), Et4NBr3, have been developed from the reactions of the corresponding quaternary ammonium bromides with H2O2 and a catalytic amount of vanadium(V) or molybdenum(VI). Other transition metals capable of activating peroxide give sim

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2

Berthelot, Jacques, Catherine Guette, Paul-Louis Desbène, Jean-Jacques Basselier, Patrick Chaquin, and Daniel Masure. "Bromation régiosélective en série aromatique. I: Monobromation en position para de phénols et d'aminés aromatiques par le tribromure de tétrabutylammonium." Canadian Journal of Chemistry 67, no. 12 (1989): 2061–66. http://dx.doi.org/10.1139/v89-320.

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The reaction of tetrabutylammonium tribromide (TBABr3) with phenols and aromatic amines in aprotic and non-basic solvents at 20 °C gives exclusively the corresponding para-brominated compounds in high yields. A mechanism involving electrophilic substitution by the tribromide anion Br3− itself is suggested to account for the results, especially the regioselective para bromination. Keywords: bromination, tetrabutylammonium tribromide, phenols, aromatic amines.

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3

Berthelot, Jacques, Yamina Benammar, and Bernard Desmazières. "Action of tetrabutylammonium tribromide with para-substituted chalcones in protic and aprotic media." Canadian Journal of Chemistry 73, no. 9 (1995): 1526–30. http://dx.doi.org/10.1139/v95-189.

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Bromination of the double bond of para-substituted chalcones under mild conditions in aprotic solvents is accomplished with high yields using tetrabutylammonium tribromide (TBABr3). In methanol, the main reaction is (α-β) bromomethoxylation. Stereoselectivity, regioselectivity, and chemioselectivity of this bromomethoxylation reaction are described. Keywords: bromination, bromomethoxylation, tetrabutylammonium tribromide, (α-β) dibromodihydrochalcones, α-bromo, β-methoxydihydrochalcones.

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4

Arora, Pragi, Jagdeep Dua, and Jitender Singh. "Synthesis of some new 1,3,5-trisubstituted pyrazoles as antioxidant and antiinflammatory agents." Journal of Drug Delivery and Therapeutics 9, no. 2-s (2019): 343–47. http://dx.doi.org/10.22270/jddt.v9i2-s.2722.

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A series of some new 1,3,5-trisubstituted pyrazoles was synthesized by the reaction of α-β dibromochalcones with phenylhydrazine hydrochloride. α-β-Dibromochalcones were prepared by the regioselective bromination of respective chalcones with tetrabutylammonium tribromide. The synthesized trisubstituted pyrazoles were evaluated for their anti-inflammatory and antioxidant properties. Keywords: α-β-Dibromochalcones, 1,3,5-Trisubstituted pyrazoles, Tetrabutylammonium tribromide, Anti-inflammatory and antioxidant activities

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5

Desbene-Monvernay, Annie, Ouzama Karazoun, Jacques Berthelot, and Paul-Louis Desbene. "Modelisation de la bromation au moyen de TBABr3 de matrices organiques complexes: suivi de la bromation de carbazoles à l'aide de la voltampérométrie et de la chromatographie liquide hautes performances." Canadian Journal of Chemistry 70, no. 3 (1992): 870–76. http://dx.doi.org/10.1139/v92-115.

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To determine the degree of substitution of complex matrices, the bromination of various carbazoles by tetrabutylammonium tribromide has been used as a model of a substitution reaction. This has allowed us to test the validity of the voltamperometric titration of tribromide ions and species formed (Br− and H+ ions). The results obtained for various substrate/reagent ratios are in excellent agreement with those of high performance liquid chromatography. The electrochemical titration can be considered as reliable, fast, and very easy to use. It permits us to follow the bromination kinetics and to

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6

Gogoi, Prasanta, Sukanya Hazarika, and Pranjit Barman. "Tetrabutylammonium tribromide impregnated MCM-48 as a heterogeneous catalyst for selective oxidation of sulfides." RSC Advances 5, no. 48 (2015): 38044–47. http://dx.doi.org/10.1039/c5ra04573h.

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We report here tetrabutylammonium tribromide supported on MCM-48 as a highly efficient heterogeneous catalyst for the selective oxidation of sulfides, in ethanolic medium using hydrogen peroxide as an oxidant.

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7

Srikrishna, Devulapally, and Pramod Kumar Dubey. "PEG-600 mediated one-pot reaction of 3-acetyl-2H-chromen-2-one with heterylthiols and phenylthioureas using tetrabutylammonium tribromide as an efficient green reagent." New Journal of Chemistry 41, no. 12 (2017): 5168–75. http://dx.doi.org/10.1039/c7nj00504k.

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A simple method for the one-pot reaction of 3-acetyl-2H-chromen-2-one with different heterylthiols and phenylthioureas under green conditions using tetrabutylammonium tribromide (TBATB) as an efficient reagent has been described.

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8

Li, Yingqian, Yali Liu, Di Hao, Liang Xu, and Ping Liu. "Regioselective bromination of pyrrolo[1,2-a]quinoxalines." RSC Advances 14, no. 49 (2024): 36488–96. http://dx.doi.org/10.1039/d4ra07358d.

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A novel and efficient method for the regioselective bromination of pyrrolo[1,2-a]quinoxaline using tetrabutylammonium tribromide was developed. A series of highly selective C3-brominated or C1, C3-dibrominated products were obtained in good yields.

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9

Kavitha, Kotthireddy, Devulapally Srikrishna, Pramod Kumar Dubey, and Pasula Aparna. "A Green and Efficient Synthesis of Substituted 2-(4-(2-Oxo-2H-chromen-3- yl)thiazol-2-yl)-3-phenylacrylonitriles Under Environmentally Benign Conditions." Letters in Organic Chemistry 16, no. 8 (2019): 637–42. http://dx.doi.org/10.2174/1570178616666181224112851.

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An efficient and convenient method for the condensation of various aldehydes with 2-(4-(2- oxo-2H-chromen-3-yl)thiazol-2-yl)acetonitrile has been demonstrated via triphenylphosphinecatalyzed Knoevenagel condensation in good to excellent yields. The effect of solvent on this reaction was studied. In addition, a tandem method for the synthesis of 2-(4-(2-oxo-2H-chromen-3-yl)thiazol-2- yl)acetonitrile has been outlined using tetrabutylammonium tribromide as an efficient, green and ecofriendly reagent. Subsequently, the latter was reacted with various aromatic aldehydes in the presence of PEG-600

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10

Jaya, Gosain, and K. Sharma Pradeep. "Kinetics and mechanism of the oxidation of secondary alcohols by tetrabutylammonium tribromide." Journal of Indian Chemical Society Vol. 79, Oct 2002 (2002): 815–18. https://doi.org/10.5281/zenodo.5847740.

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Department of Chemistry, J. N. V. University, Jodhpur-342 005, India <em>Manuscript received 1 January 2002, accepted 19 June 2002</em> Oxidation of several secondary alcohols by tetrabutylammonium tribromide (TBATB) in aqueous acetic acid leads to the formation of corresponding ketones. The reaction is first order with respect to TBATB and the alcohols. The reaction failed to induce polymerization of acrylonitrile. There is no effect of tetrabutylammonium chloride on the reaction rate. The proposed reactive oxidizing species is tribromide ion. The oxidation of benzhydrol-α-ß

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11

V., K. Chouhan, and Sharma Vinita. "Kinetics and mechanism of the oxidation of some thioacids by tetrabutylammonium tribromide." Journal of Indian Chemical Society Vol. 82, Apr 2005 (2005): 302–5. https://doi.org/10.5281/zenodo.5827285.

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Department of Chemistry, J. N. V. University, Jodhpur-342 005, India <em>Manuscript received 18 July 2003, revised 3 November 2004, accepted 9 December 2004</em> The oxidation of sonic thioacids viz. thioglycollic, thiolactic and thiomalic acids by tetrabutylammonium tribromide (TBATB) has been studied in acetic acid. The reaction is first order with respect to TBATB. Michaelis-Menten type of kinetics were observed 'Aid' respect to the reductants. The reaction has been studied in solvents of different compositions of acetic acid and water. The solvent composition effect has b

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12

Naik, Sarala, Rangam Gopinath, and Bhisma K. Patel. "Tetrabutylammonium tribromide (TBATB)-promoted tetrahydropyranylation/depyranylation of alcohols." Tetrahedron Letters 42, no. 43 (2001): 7679–81. http://dx.doi.org/10.1016/s0040-4039(01)01599-4.

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13

Berthelot, J., C. Guette, M. Essayegh, P. L. Desbene, and J. J. Basselier. "Regioselective Monobromination of Aromatic Amines with Tetrabutylammonium Tribromide." Synthetic Communications 16, no. 13 (1986): 1641–45. http://dx.doi.org/10.1080/00397918608056422.

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14

Bellucci, Giuseppe, Cinzia Chiappe, and Felicia D'Andrea. "Diastereoselective bromination of allyl glycosides using tetrabutylammonium tribromide." Tetrahedron: Asymmetry 6, no. 1 (1995): 221–30. http://dx.doi.org/10.1016/0957-4166(94)00378-o.

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15

Berthelot, Jacques, and Michel Fournier. "Bromation stéréosélective d'alcynes par le tribromure de tétrabutylammonium." Canadian Journal of Chemistry 64, no. 3 (1986): 603–7. http://dx.doi.org/10.1139/v86-097.

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The reaction of tetrabutylammonium tribromide (TBABr3) with alkynes (R—C≡C—R′, with R and (or) R′ = H, alkyl, phenyl, carboxyl, carbonyl) in chloroform at 20 °C gives only the corresponding E 1,2-dibromo alkene in high yields. A mechanism involving a cyclic brominated zwitterion is suggested to account for the results, especially the stereospecificity of this E-addition.

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16

Naik, Sarala, Veerababurao Kavala, Rangam Gopinath, and Bhisma K. Patel. "Tetrabutylammonium tribromide mediated condensation of carboxylic acids with alcohol." Arkivoc 2006, no. 1 (2005): 119–27. http://dx.doi.org/10.3998/ark.5550190.0007.114.

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17

Yao, Min-Liang, George W. Kabalka, David W. Blevins, Marepally Srinivasa Reddy, and Li Yong. "Halodeboronation of organotrifluoroborates using tetrabutylammonium tribromide or cesium triiodide." Tetrahedron 68, no. 19 (2012): 3738–43. http://dx.doi.org/10.1016/j.tet.2012.03.016.

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18

Kajigaeshi, Shoji, Takaaki Kakinami, Tsuyoshi Okamoto, and Shizuo Fujisaki. "Synthesis of Bromoacetyl Derivatives by Use of Tetrabutylammonium Tribromide." Bulletin of the Chemical Society of Japan 60, no. 3 (1987): 1159–60. http://dx.doi.org/10.1246/bcsj.60.1159.

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19

Kalantre, V. A., and G. H. Nikam. "Kinetics and mechanism of oxidation of hypophosphite by tetrabutylammonium tribromide." Research Journal of Chemistry and Environment 26, no. 9 (2022): 119–22. http://dx.doi.org/10.25303/2609rjce1190122.

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The reaction between tetrabutylammonium tribromide and hypophosphite was studied in 50% (v/v) acetic acid under second order conditions. The overall order of reaction was found to be two, unity each in both the reactants. The reaction was found to involve direct two electron transfer step as the test for formation of free radicals due to single electron step was negative. The hypophosphorous acid (H3PO2) in aqueous solution dissociates to give H2PO2- and in the present study, as the acetic acid content increases, the rate of the reaction decreases. The plot of 1/ks against [H+] was found to be

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20

Yan, Yunhui, Xiaojuan Yang, and Liqiang Wu. "Facile Synthesis of 1,5-Benzothiazepines in Water Using Tetrabutylammonium Tribromide." Phosphorus, Sulfur, and Silicon and the Related Elements 187, no. 5 (2012): 573–79. http://dx.doi.org/10.1080/10426507.2011.627900.

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21

Kalantre, Vilasrao A., Sanjeev P. Maradur, and Gavisiddappa S. Gokavi. "Kinetics and mechanism of vanadium(IV) oxidation by tetrabutylammonium tribromide." Transition Metal Chemistry 32, no. 2 (2007): 214–18. http://dx.doi.org/10.1007/s11243-006-0149-3.

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22

Naik, Sarala, Rangam Gopinath, and Bhisma K. Patel. "ChemInform Abstract: Tetrabutylammonium Tribromide (TBATB)-Promoted Tetrahydropyranylation/Depyranylation of Alcohols." ChemInform 33, no. 4 (2010): no. http://dx.doi.org/10.1002/chin.200204089.

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23

BELLUCCI, G., C. CHIAPPE, and F. D'ANDREA. "ChemInform Abstract: Diastereoselective Bromination of Allyl Glycosides Using Tetrabutylammonium Tribromide." ChemInform 26, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.199527050.

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24

Berthelot, Jacques, Yamina Benammar, and Catherine Lange. "A mild and efficient sonochemical bromination of alkenes using tetrabutylammonium tribromide." Tetrahedron Letters 32, no. 33 (1991): 4135–36. http://dx.doi.org/10.1016/s0040-4039(00)79884-4.

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25

Gao, Shuang, Travis K. Bethel, Tayeb Kakeshpour, Grace E. Hubbell, James E. Jackson, and Jetze J. Tepe. "Substrate Controlled Regioselective Bromination of Acylated Pyrroles Using Tetrabutylammonium Tribromide (TBABr3)." Journal of Organic Chemistry 83, no. 16 (2018): 9250–55. http://dx.doi.org/10.1021/acs.joc.8b01251.

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26

Baghmar, Manju, and Pradeep K. Sharma. "Kinetics and mechanism of oxidation of aliphatic alcohols by tetrabutylammonium tribromide." Journal of Chemical Sciences 113, no. 2 (2001): 139–46. http://dx.doi.org/10.1007/bf02704186.

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27

Lin, Xu‐Feng, Sun‐Liang Cui, and Yan‐Guang Wang. "Mild and Efficient Synthesis of bis‐Indolylmethanes Catalyzed by Tetrabutylammonium Tribromide." Synthetic Communications 36, no. 21 (2006): 3153–60. http://dx.doi.org/10.1080/00397910600908819.

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28

Yao, Min-Liang, George W. Kabalka, David W. Blevins, Marepally Srinivasa Reddy, and Li Yong. "ChemInform Abstract: Halodeboronation of Organotrifluoroborates Using Tetrabutylammonium Tribromide or Cesium Triiodide." ChemInform 43, no. 44 (2012): no. http://dx.doi.org/10.1002/chin.201244045.

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29

Malo-Forest, Bianca, Jessye-Ann Roy, and Jean-François Paquin. "Bromination/desilicobromination of silylated monofluoroalkenes using tetrabutylammonium tribromide under microwave conditions." Journal of Fluorine Chemistry 145 (January 2013): 77–80. http://dx.doi.org/10.1016/j.jfluchem.2012.10.008.

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30

V., S. Chouhan, Sharma Monica, and Sharma Vinita. "Kinetics and mechanism of the oxidation of substituted benzaldehydes by tetrabutylammonium tribromide." Journal of Indian Chemical Society Vol. 84, Jun 2007 (2007): 582–87. https://doi.org/10.5281/zenodo.5820716.

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Department of Chemistry, J. N. V. University, Jodhpur-342 005, Rajasthan, India Modi Institute of Technology, Kota, Rajasthan, India <em>E-mail</em> : drpkvs27@yahoo.com <em>Manuscript received 27 December 2006, accepted 20 April 2007</em> The oxidation of thirty-six monosubstituted benzaldehydes by tetrabutylammonium tribromide (TBATB), in aqueous acetic acid solution, leads to the formation of the corresponding benzoic acids. The reaction is first order with respect to both TBATB and aldehydes. The reaction failed to induce the polymerization of acrylonitrile. There is no effect of tetrabuty

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31

Yao, Min-Liang, Marepally Srinivasa Reddy, Li Yong, Ingrid Walfish, David W. Blevins, and George W. Kabalka. "Chemoselective Bromodeboronation of Organotrifluoroborates Using Tetrabutylammonium Tribromide: Application in (Z)-Dibromoalkene Syntheses." Organic Letters 12, no. 4 (2010): 700–703. http://dx.doi.org/10.1021/ol9027144.

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32

郑, 明花. "Effects of Lewis Acids on the Reaction of Acetophenone and Tetrabutylammonium Tribromide." Journal of Organic Chemistry Research 02, no. 03 (2014): 39–42. http://dx.doi.org/10.12677/jocr.2014.23006.

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33

Kundu, S. K., S. Islam, A. Hajra, and A. Majee. "Tetrabutylammonium tribromide as efficient catalyst in the synthesis of bis(indolyl)methanes." Russian Journal of Organic Chemistry 46, no. 1 (2010): 126–28. http://dx.doi.org/10.1134/s1070428010010136.

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34

Zhu, Yi-Zhong, and Chun Cai. "Direct synthesis of nitriles from aldehydes using tetrabutylammonium tribromide in aqueous ammonia." Monatshefte für Chemie - Chemical Monthly 141, no. 6 (2010): 637–39. http://dx.doi.org/10.1007/s00706-010-0305-5.

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35

Baghmar, Manju, and Pradeep K. Sharma. "Kinetics and mechanism of the oxidation of aliphatic aldehydes by tetrabutylammonium tribromide." International Journal of Chemical Kinetics 33, no. 6 (2001): 390–95. http://dx.doi.org/10.1002/kin.1033.

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36

Chaudhuri, Mihir K., Abu T. Khan, Bhisma K. Patel, et al. "An environmentally benign synthesis of organic ammonium tribromides (OATB) and bromination of selected organic substrates by tetrabutylammonium tribromide (TBATB)." Tetrahedron Letters 39, no. 44 (1998): 8163–66. http://dx.doi.org/10.1016/s0040-4039(98)01818-8.

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37

Zende, Sunil N., Vilasrao A. Kalantre, and Gavisiddappa S. Gokavi. "Kinetics and mechanism of oxidation of dimethyl and diphenyl sulfoxides by tetrabutylammonium tribromide." Journal of Sulfur Chemistry 29, no. 2 (2008): 171–78. http://dx.doi.org/10.1080/17415990701824398.

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38

Khan, Abu T., Md Musawwer Khan, and Anubendu Adhikary. "Tetrabutylammonium tribromide (TBATB): a mild and efficient catalyst for O-isopropylidenation of carbohydrates." Carbohydrate Research 346, no. 5 (2011): 673–77. http://dx.doi.org/10.1016/j.carres.2010.12.018.

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39

Kumar, Ashok, Pradeep K. Sharma, and Kalyan K. Banerji. "Correlation analysis of reactivity in oxidation of substituted benzyl alcohols by tetrabutylammonium tribromide." Journal of Physical Organic Chemistry 15, no. 10 (2002): 721–27. http://dx.doi.org/10.1002/poc.541.

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40

Lange, C., Y. Benammar, and J. Berthelot. "Behaviour of tetrabutylammonium tribromide under fast-atom bombardment using protic and aprotic matrices." Rapid Communications in Mass Spectrometry 5, no. 8 (1991): 371–73. http://dx.doi.org/10.1002/rcm.1290050809.

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41

Malo-Forest, Bianca, Jessye-Ann Roy, and Jean-Francois Paquin. "ChemInform Abstract: Bromination/Desilicobromination of Silylated Monofluoroalkenes Using Tetrabutylammonium Tribromide under Microwave Conditions." ChemInform 44, no. 24 (2013): no. http://dx.doi.org/10.1002/chin.201324066.

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42

CHAUDHURI, M. K., A. T. KHAN, B. K. PATEL, et al. "ChemInform Abstract: An Environmentally Benign Synthesis of Organic Ammonium Tribromides (OATB) and Bromination of Selected Organic Substrates by Tetrabutylammonium Tribromide (TBATB)." ChemInform 30, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.199903054.

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43

Dai, Pengcheng, and Liang Xu. "Visible-Light-Induced Benzylic C—H Oxygenation Reaction Using Tetrabutylammonium Tribromide as the Catalyst." Chinese Journal of Organic Chemistry 41, no. 12 (2021): 4690. http://dx.doi.org/10.6023/cjoc202106041.

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44

Khan, Abu T., Mohan Lal, and Md Musawwer Khan. "Synthesis of highly functionalized piperidines by one-pot multicomponent reaction using tetrabutylammonium tribromide (TBATB)." Tetrahedron Letters 51, no. 33 (2010): 4419–24. http://dx.doi.org/10.1016/j.tetlet.2010.06.069.

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45

BERTHELOT, J., Y. BENAMMAR, and C. LANGE. "ChemInform Abstract: A Mild and Efficient Sonochemical Bromination of Alkenes (I) Using Tetrabutylammonium Tribromide." ChemInform 23, no. 19 (2010): no. http://dx.doi.org/10.1002/chin.199219108.

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46

Yao, Min-Liang, Marepally Srinivasa Reddy, Li Yong, Ingrid Walfish, David W. Blevins, and George W. Kabalka. "ChemInform Abstract: Chemoselective Bromodeboronation of Organotrifluoroborates Using Tetrabutylammonium Tribromide: Application in (Z)-Dibromoalkene Syntheses." ChemInform 41, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.201027035.

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47

Kundu, S. K., S. Islam, A. Hajra, and A. Majee. "ChemInform Abstract: Tetrabutylammonium Tribromide as Efficient Catalyst in the Synthesis of Bis(indolyl)methanes." ChemInform 41, no. 29 (2010): no. http://dx.doi.org/10.1002/chin.201029139.

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48

Bose, Gopal, Ejabul Mondal, Abu T. Khan, and Manob J. Bordoloi. "An environmentally benign synthesis of aurones and flavones from 2′-acetoxychalcones using n -tetrabutylammonium tribromide." Tetrahedron Letters 42, no. 50 (2001): 8907–9. http://dx.doi.org/10.1016/s0040-4039(01)01938-4.

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49

Berthelot, J., P.-L. Desbène, and A. Desbène-Monvernay. "Use of tetrabutylammonium tribromide for voltametric titration of unsaturation in vegetable oils and fatty acids." Journal of the American Oil Chemists' Society 70, no. 3 (1993): 277–79. http://dx.doi.org/10.1007/bf02545308.

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50

Zende, S. N., V. A. Kalantre, and G. S. Gokavi. "Kinetics and Mechanism of Oxidation of Hydroquinone by Tetrabutylammonium Tribromide Ion in Aqueous Acetic Acid." Journal of Solution Chemistry 39, no. 8 (2010): 1178–86. http://dx.doi.org/10.1007/s10953-010-9567-0.

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