Academic literature on the topic 'Tetraether lipids'

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Journal articles on the topic "Tetraether lipids"

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Chong, Parkson Lee-Gau, Umme Ayesa, Varsha Prakash Daswani, and Ellah Chay Hur. "On Physical Properties of Tetraether Lipid Membranes: Effects of Cyclopentane Rings." Archaea 2012 (2012): 1–11. http://dx.doi.org/10.1155/2012/138439.

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This paper reviews the recent findings related to the physical properties of tetraether lipid membranes, with special attention to the effects of the number, position, and configuration of cyclopentane rings on membrane properties. We discuss the findings obtained from liposomes and monolayers, composed of naturally occurring archaeal tetraether lipids and synthetic tetraethers as well as the results from computer simulations. It appears that the number, position, and stereochemistry of cyclopentane rings in the dibiphytanyl chains of tetraether lipids have significant influence on packing tig
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Zhu, Chun, Travis B. Meador, Wolf Dummann, and Kai-Uwe Hinrichs. "Identification of unusual butanetriol dialkyl glycerol tetraether and pentanetriol dialkyl glycerol tetraether lipids in marine sediments." Rapid Communications in Mass Spectrometry 28 (December 27, 2013): 332–38. https://doi.org/10.1002/rcm.6792.

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RATIONALE: Glycerol serves as the principal backbone moiety bound to various acyl/alkyl chains for membrane lipids of <em>Eukarya</em>, <em>Bacteria</em>, and <em>Archaea</em>. In this study, we report a suite of unusual tetraether lipids in which one of the two conventional glycerol backbones is substituted by butanetriol or pentanetriol. METHODS: Identification of these lipids was achieved via diagnostic fragments and their expected acetylation products using liquid chromatography/mass spectrometry (LC/MS), and their diagnostic ether cleavage products using gas chromatography/mass spectromet
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Kon, Takahide, Naoki Nemoto, Tairo Oshima, and Akihiko Yamagishi. "Effects of a Squalene Epoxidase Inhibitor, Terbinafine, on Ether Lipid Biosyntheses in a Thermoacidophilic Archaeon, Thermoplasma acidophilum." Journal of Bacteriology 184, no. 5 (2002): 1395–401. http://dx.doi.org/10.1128/jb.184.5.1395-1401.2002.

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ABSTRACT The archaeal plasma membrane consists mainly of diether lipids and tetraether lipids instead of the usual ester lipids found in other organisms. Although a molecule of tetraether lipid is thought to be synthesized from two molecules of diether lipids, there is no direct information about the biosynthetic pathway(s) or intermediates of tetraether lipid biosynthesis. In this study, we examined the effects of the fungal squalene epoxidase inhibitor terbinafine on the growth and ether lipid biosyntheses in the thermoacidophilic archaeon Thermoplasma acidophilum. Terbinafine was found to i
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Saracco, Margot, Philippe Schaeffer, Maxime Tourte, et al. "Bilayer-Forming Lipids Enhance Archaeal Monolayer Membrane Stability." International Journal of Molecular Sciences 26, no. 7 (2025): 3045. https://doi.org/10.3390/ijms26073045.

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Archaeal membranes exhibit remarkable stability under extreme environmental conditions, a feature attributed to their unique lipid composition. While it is widely accepted that tetraether lipids confer structural integrity by forming monolayers, the role of bilayer-forming diether lipids in membrane stability remains unclear. Here, we demonstrate that incorporating diethers into archaeal-like lipid assemblies enhances membrane organization and adaptability under thermal stress. Using neutron diffraction, we show that membranes composed of mixed diethers and tetraethers exhibit greater structur
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Bonanno, Alexander, Robert C. Blake, and Parkson Lee-Gau Chong. "Sulfolobus acidocaldarius Microvesicles Exhibit Unusually Tight Packing Properties as Revealed by Optical Spectroscopy." International Journal of Molecular Sciences 20, no. 21 (2019): 5308. http://dx.doi.org/10.3390/ijms20215308.

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In this study, we used optical spectroscopy to characterize the physical properties of microvesicles released from the thermoacidophilic archaeon Sulfolobus acidocaldarius (Sa-MVs). The most abundant proteins in Sa-MVs are the S-layer proteins, which self-assemble on the vesicle surface forming an array of crystalline structures. Lipids in Sa-MVs are exclusively bipolar tetraethers. We found that when excited at 275 nm, intrinsic protein fluorescence of Sa-MVs at 23 °C has an emission maximum at 303 nm (or 296 nm measured at 75 °C), which is unusually low for protein samples containing multipl
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Sprott, G. Dennis, Brian J. Agnew, and Girishchandra B. Patel. "Structural features of ether lipids in the archaeobacterial thermophilesPyrococcus furiosus,Methanopyrus kandleri,Methanothermus fervidus, andSulfolobus acidocaldarius." Canadian Journal of Microbiology 43, no. 5 (1997): 467–76. http://dx.doi.org/10.1139/m97-066.

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The ether lipids of several thermophilic archaea (archaeobacteria) were compared by negative-ion fast atom bombardment mass spectrometry. The major polar lipids in extracts of Pyrococcus furiosus were assigned as archaeol lipids (phosphatidylglycerol diether, m/z 805; phosphatidylinositol diether, m/z 893; and diglycosyl diether, m/z 975) and caldarchaeol lipids (diglycosyl phosphatidylglycerol tetraether, m/z 1778; and diglycosyl phosphatidylinositol tetraether, m/z 1866). The polar lipids of Methanopyrus kandleri were primarily glycolipids consisting of a series of archaeol lipids with one t
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Becker, Kevin W., Felix J. Elling, Marcos Y. Yoshinaga, Andrea Söllinger, Tim Urich, and Kai-Uwe Hinrichs. "Unusual Butane- and Pentanetriol-Based Tetraether Lipids in Methanomassiliicoccus luminyensis, a Representative of the Seventh Order of Methanogens." Applied and Environmental Microbiology 82, no. 15 (2016): 4505–16. http://dx.doi.org/10.1128/aem.00772-16.

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ABSTRACTA new clade of archaea has recently been proposed to constitute the seventh methanogenic order, theMethanomassiliicoccales, which is related to theThermoplasmatalesand the uncultivated archaeal clades deep-sea hydrothermal ventEuryarchaeotagroup 2 and marine group IIEuryarchaeotabut only distantly related to other methanogens. In this study, we investigated the membrane lipid composition ofMethanomassiliicoccus luminyensis, the sole cultured representative of this seventh order. The lipid inventory ofM. luminyensiscomprises a unique assemblage of novel lipids as well as lipids otherwis
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Blöcher, Detlef, Raymund Gutermann, Birgit Henkel, and Klaus Ring. "Physicochemical Characterization of Tetraetherlipids from Thermoplasma acidophilum." Zeitschrift für Naturforschung C 40, no. 9-10 (1985): 606–11. http://dx.doi.org/10.1515/znc-1985-9-1003.

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Abstract By means of differential thermoanalysis, the miscibility of the main polar tetraether lipid of Thermoplasma acidophilum with two ester lipids, dipalmitoyl phosphatidylcholine and dipalmitoyl phosphatidylglycerol, resp., in the presence of excess water was studied. It is shown that with increasing fraction of tetraether lipid in the mixture, the transition range of dipalmitoyl phosphatidylcholine is broadened and the temperature of the maximum heat flow (Tm) is shifted to lower temperatures; furthermore, the enthaply change (ΔH) of the transition declines. Similar results were obtained
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Bonanno, Alexander, and Parkson Lee-Gau Chong. "Certain, but Not All, Tetraether Lipids from the Thermoacidophilic Archaeon Sulfolobus acidocaldarius Can Form Black Lipid Membranes with Remarkable Stability and Exhibiting Mthk Channel Activity with Unusually High Ca2+ Sensitivity." International Journal of Molecular Sciences 22, no. 23 (2021): 12941. http://dx.doi.org/10.3390/ijms222312941.

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Bipolar tetraether lipids (BTL) have been long thought to play a critical role in allowing thermoacidophiles to thrive under extreme conditions. In the present study, we demonstrated that not all BTLs from the thermoacidophilic archaeon Sulfolobus acidocaldarius exhibit the same membrane behaviors. We found that free-standing planar membranes (i.e., black lipid membranes, BLM) made of the polar lipid fraction E (PLFE) isolated from S. acidocaldarius formed over a pinhole on a cellulose acetate partition in a dual-chamber Teflon device exhibited remarkable stability showing a virtually constant
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DeLong, Edward F., Linda L. King, Ramon Massana, et al. "Dibiphytanyl Ether Lipids in Nonthermophilic Crenarchaeotes." Applied and Environmental Microbiology 64, no. 3 (1998): 1133–38. http://dx.doi.org/10.1128/aem.64.3.1133-1138.1998.

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ABSTRACT The kingdom Crenarchaeota is now known to include archaea which inhabit a wide variety of low-temperature environments. We report here lipid analyses of nonthermophilic crenarchaeotes, which revealed the presence of cyclic and acyclic dibiphytanylglycerol tetraether lipids. Nonthermophilic crenarchaeotes appear to be a major biological source of tetraether lipids in marine planktonic environments.
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Dissertations / Theses on the topic "Tetraether lipids"

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Escala, Pascual Marina. "Application of tetraether membrane lipids as proxies for continental climate reconstruction in Iberian and Siberian lakes." Doctoral thesis, Universitat Autònoma de Barcelona, 2009. http://hdl.handle.net/10803/3819.

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Des del 2002, s'han desenvolupat una sèrie de proxies climàtiques basades en biomarcadors derivats d'arquees i bacteris. Aquests biomarcadors són els glicerol dialquil glicerol tetraèters o GDGTs. D'entre aquestes proxies, l'índex TEX86 s'aplica en sediments per tal de reconstruir les temperatures superficials del mar i dels llacs; els índexs MBT i CBT són utilitzats conjuntament per a reconstruir la temperatura superficial de l'aire i l'índex BIT permet avaluar la contribució relativa de material provinent del sòl i material pelàgic en els sediments. A causa del recent desenvolupament d'aques
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Poplawski, Cezary. "Development of a high-throughput technique for screening Archaeal tetraether lipid cores and other alcohols in sediments and microbial cultures." Thesis, University of York, 2017. http://etheses.whiterose.ac.uk/18948/.

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A mild and effective protocol for the derivatisation of Archaeal tetraether lipid cores and other alcohols from cultured and sedimentary material has been developed using N-protected amino acids. The derivatives were prepared in excellent to near quantitative yields in approx. 2 h. The N-Boc and N-Fmoc derivatives exhibit very good chromatographic properties and considerable signal intensity improvement, in MS, of up to two orders of magnitude, relative to the native species. The fluorescence properties of the derivatives containing a strong chromophore (Fmoc), showed excellent detector respon
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Coffinet, Sarah. "Validation and application of lipid biomarkers to reconstruct past environmental changes in East Africa." Thesis, Paris 6, 2015. http://www.theses.fr/2015PA066500/document.

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La Province Volcanique du Rungwe (PVR) en Afrique de l’Est abrite diverses archives continentales (séquence de loess-paléosols, tourbières, lacs) permettant d’étudier les changements environnementaux passés des zones tropicales continentales. Ce travail s’est intéressé à l’applicabilité des alkyl tetraéthers de glycérol (tetraéthers) et des n-alcanes comme biomarqueurs de ces changements passés. Leur analyse le long de transects altitudinaux a permis de rendre compte de la capacité des tetraéthers à enregistrer de faibles changements de température de l’air dans la région. En conséquence, une
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Coffinet, Sarah. "Validation and application of lipid biomarkers to reconstruct past environmental changes in East Africa." Electronic Thesis or Diss., Paris 6, 2015. http://www.theses.fr/2015PA066500.

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La Province Volcanique du Rungwe (PVR) en Afrique de l’Est abrite diverses archives continentales (séquence de loess-paléosols, tourbières, lacs) permettant d’étudier les changements environnementaux passés des zones tropicales continentales. Ce travail s’est intéressé à l’applicabilité des alkyl tetraéthers de glycérol (tetraéthers) et des n-alcanes comme biomarqueurs de ces changements passés. Leur analyse le long de transects altitudinaux a permis de rendre compte de la capacité des tetraéthers à enregistrer de faibles changements de température de l’air dans la région. En conséquence, une
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Véquaud, Pierre. "Développement et application de nouveaux marqueurs d’environnement d’origine bactérienne en milieu terrestre." Electronic Thesis or Diss., Sorbonne université, 2021. http://www.theses.fr/2021SORUS475.

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A ce jour, les seuls biomarqueurs organiques utilisables pour la reconstruction de la température et du pH en milieu terrestre sont les alkyl tetraéthers de glycérol bactériens (GDGTs ramifiés ou brGDGTs). Ce travail de thèse s’est intéressé au développement et à l’application d’autres marqueurs bactériens, les acides gras 3-hydroxylés (3-AGH). L’analyse de l’abondance des 3-AGHs et des brGDGTs dans 49 sols prélevés dans les Alpes françaises a permis de quantifier l'influence de paramètres environnementaux autres que la température sur la distribution des brGDGTs et des 3-AGHs. En parallèle, d
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Zhang, Yige. "Methane Index a tetraether archaeal lipid biomarker proxy for detecting the instability of marine gas hydrates /." 2009. http://purl.galileo.usg.edu/uga%5Fetd/zhang%5Fyige%5F200908%5Fms.

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Book chapters on the topic "Tetraether lipids"

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Gulik, Annette, Vittorio Luzatti, Mario de Rosa, and Agata Gambacorta. "Biradical Tetraether Lipids from Thermoacidophilic Archaebacteria." In Advances in Experimental Medicine and Biology. Springer US, 1988. http://dx.doi.org/10.1007/978-1-4684-7908-9_4.

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Chong, Parkson Lee-Gau, Alexander Bonanno, and Umme Ayesa. "Dynamics and Organization of Archaeal Tetraether Lipid Membranes." In Springer Series in Biophysics. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-66601-3_2.

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Lee-Gau Chong, Parkson. "Physical Properties of Membranes Composed of Tetraether Archaeal Lipids." In Thermophiles. CRC Press, 2007. http://dx.doi.org/10.1201/9781420008852.ch6.

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"Physical Properties of Membranes Composed of Tetraether Archaeal Lipids." In Thermophiles. CRC Press, 2007. http://dx.doi.org/10.1201/9781420008852-12.

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Vidawati, Sri, Udo Bakowsky, Ulrich Rothe, and Nadhifa Safira P. "Langmuir Monolayer Stabilization Characteristics on Tetraether Lipids at the Air-Water Interface with Variance in Dispersion Time." In Novel Aspects on Chemistry and Biochemistry Vol. 8. B P International (a part of SCIENCEDOMAIN International), 2023. http://dx.doi.org/10.9734/bpi/nacb/v8/6156c.

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Freisleben, Hans-Joachim. "Tetraether Lipid Liposomes." In Membrane Structure in Disease and Drug Therapy. CRC Press, 2000. http://dx.doi.org/10.1201/9780203910054.ch8.

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Vidawati, Sri, and Ulrich Rothe. "Study of Langmuir-Blodgett Films of Synthetic Artificial Mimic Molecules Resembling the Following Tetraether Lipids on Silicon Wafers." In Current Topics on Chemistry and Biochemistry Vol. 9. B P International (a part of SCIENCEDOMAIN International), 2023. http://dx.doi.org/10.9734/bpi/ctcb/v9/4300c.

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Śliwińska, K. K., A. Mets, and S. Schouten. "Data report: distribution and sources of tetraether lipids in Oligocene deposits from the western North Atlantic, IODP Sites U1406 and U1411." In Proceedings of the IODP. Integrated Ocean Drilling Program, 2017. http://dx.doi.org/10.2204/iodp.proc.342.205.2017.

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Bianchi, Thomas S., and Elizabeth A. Canuel. "Lipids: Alkenones, Polar Lipids, and Ether Lipids." In Chemical Biomarkers in Aquatic Ecosystems. Princeton University Press, 2011. http://dx.doi.org/10.23943/princeton/9780691134147.003.0011.

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This chapter focuses on several classes of polar lipids, including alkenones, which are di-, tri-, and tetra-unsaturated long-chain ketones. These compounds are produced by a restricted number of species of prymnesiophyte algae (coccolithophorid alga Emiliania huxleyi), living over a wide temperature range. Prymnesiophytes are able to live under different temperature regimes because they are able to regulate the degree of unsaturation of these compounds; as ambient water temperature decreases, unsaturation increases. Long-chain ketones are more stable than most unsaturated lipids and can survi
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Gaines, Susan M., Geoffrey Eglinton, and Jürgen Rullkötter. "Weird Molecules, Inconceivable Microbes, and Unlikely Environmental Proxies: Marine Ecology Revised." In Echoes of Life. Oxford University Press, 2008. http://dx.doi.org/10.1093/oso/9780195176193.003.0014.

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Anaerobic methanotrophs are not the only ecologically important archaea to surprise microbiologists in the last decade. And their isoprenoid ethers are not the only useful lipids—and certainly not the strangest—to have joined the lexicon of microbial biomarkers. Though much of that lexicon is still too generic to be of much use in understanding geologic history, some of these structures have allowed geochemists to transcend biological complexity and garner clues to past climates and environments. In the 1990s, when Stefan Schouten first started finding ring-containing biphytanyl ethers in his
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Conference papers on the topic "Tetraether lipids"

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Welander, Paula V., Zhirui Zeng, Xiaolei Liu, Jeremy H. Wei, and Roger E. Summons. "BIOSYNTHESIS OF TETRAETHER MEMBRANE LIPIDS IN THE ARCHAEON SULFOLOBUS ACIDOCALDARIUS." In GSA Annual Meeting in Indianapolis, Indiana, USA - 2018. Geological Society of America, 2018. http://dx.doi.org/10.1130/abs/2018am-323962.

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Dearing Crampton-Flood, E., D. Smits, G. van der Molen, et al. "Towards Reliable Reconstructions of Pliocene Terrestrial Temperatures Using Branched Tetraether Membrane Lipids." In 29th International Meeting on Organic Geochemistry. European Association of Geoscientists & Engineers, 2019. http://dx.doi.org/10.3997/2214-4609.201902854.

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Harris, Carolynn, Jeemin Rhim, Yujiao Zhang, et al. "Determining controls on hydrogen isotope fractionation in archaeal tetraether lipids in a thermoacidophilic archaeal heterotroph." In Goldschmidt2022. European Association of Geochemistry, 2022. http://dx.doi.org/10.46427/gold2022.10597.

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Zhang, Yige, Tiegang Li, Ronnakrit Rattanasriampaipong, et al. "Methylation index of Overly Branched tetraether lipids (MOB): a proxy for deep ocean (de)oxygenation?" In Goldschmidt 2024. Geochemical Society, 2024. https://doi.org/10.46427/gold2024.24078.

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Keller, Katherine, Jerome Blewett, Isabel Baker, et al. "Constraining the sources of archaeal tetraether lipids in multiple cold seep provinces of the Cascadia Margin." In Goldschmidt 2024. Geochemical Society, 2024. https://doi.org/10.46427/gold2024.24540.

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Śnieżyńska, I. "Archaeal Community Composition in Holocene Methane Pockmarks in the Gulf of GdaŃsk Based on Tetraether Lipids and 16S rRNA." In IMOG 2023. European Association of Geoscientists & Engineers, 2023. http://dx.doi.org/10.3997/2214-4609.202333094.

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Guo, Jingjing, Martin Ziegler, Mike Vreeken, et al. "Reconstructing 130,000 years of East Asian air temperature variability using branched tetraether membrane lipids and clumped isotopes of land snail shells from the Chinese Loess Plateau." In Goldschmidt2021. European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.7044.

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Scott, Wesley, Sergio Contreras, and Josef Werne. "Examining Temperature Proxies Based on Branched Tetraether Membrane Lipid Abundances Derived from Lacustrine Surface Sediments and Modern Lake Temperatures in Central Chile." In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.2328.

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