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Dissertations / Theses on the topic 'Tetranuclear copper(II) complexes'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Reed-Mundell, Joseph Jerome. "Binuclear and tetranuclear copper(II) complexes containing ligands derived from phenol or hydroquinone." Case Western Reserve University School of Graduate Studies / OhioLINK, 1990. http://rave.ohiolink.edu/etdc/view?acc_num=case1058302716.

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2

Tran, Khoa V. "Spectroscopic studies of tetranuclear Pd(II) and Pt(II) macrocyclic square complexes." Virtual Press, 2000. http://liblink.bsu.edu/uhtbin/catkey/1191722.

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Two macrocyclic squares (one with four Pd 21 corners, the other with four Pte+ corners) were synthesized according to literature methods."2 The charge-transfer complexes which formed when each were mixed with a bis(thiol)hydroquinone were then studied by UV-VIS, NMR, and IR spectroscopy. The UV-VIS data obtained indicated a stoichiometric relationship of I mole of molecular square to 2 moles of dithiol and a very large binding constant. Further evidence for the association between each macrocyclic square and the dithiol was observed in the NMR spectrum by the shifting of the proton resonances

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3

Birtles, John. "Solution based studies of tetranuclear (mu₄-oxo)-Cu(II) complexes /." Thesis, Connect to Dissertations & Theses @ Tufts University, 2004.

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Thesis (Ph.D.)--Tufts University, 2004.<br>The [mu] in the title is depicted as a Greek letter mu, followed by a subscript 4. Adviser: Samuel P. Kounaves. Submitted to the Dept. of Chemistry. Includes bibliographical references. Access restricted to members of the Tufts University community. Also available via the World Wide Web;

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4

Ireland, David Rey. "Copper(II) and Ruthenium(II) Complexes from Polydentate Ligands." University of Dayton / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1523008522727672.

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5

Wardhani, Kartika. "Applications of Novel Tetranuclear Polypyridylruthenium(II) Complexes as Highly Selective Phosphorescent Stains for Extracellular Vesicles." Thesis, The University of Sydney, 2021. https://hdl.handle.net/2123/28119.

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It was hypothesised that novel selective phosphorescent RNA stains that consisted of polynuclear polypyridylruthenium(II) complexes could distinguish intact extracellular vesicles (EVs) from cellular debris and other non-EV components. Tetranuclear polypyridylruthenium(II) complexes-based stains, Rubb7-TNL and Rubb7-TL, were confirmed as superior phosphorescent stains for cell biology experiments associated with monocytic and cancer cell EVs, mainly microvesicles (MVs). These novel tetranuclear polypyridylruthenium(II) complexes are remarkably stable in biological media, and act as selective n

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6

Essex, Sarah Jane. "Spectral intensities in planar copper(II) complexes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239622.

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7

Zhang, Yousheng. "Polynuclear magnetic complexes of manganese(II), cobalt(II), nickel(II) and copper(II)." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape2/PQDD_0014/NQ52856.pdf.

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8

Quinlan, D. J. "Hydrogen bonding in N-ligated copper(II) complexes." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262983.

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9

Crowder, Janell M. "Homo- and Heterometallic Bis(Pentafluorobenzoyl)Methanide Complexes of Copper(II) and Cobalt(II)." Thesis, State University of New York at Albany, 2017. http://pqdtopen.proquest.com/#viewpdf?dispub=10680674.

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<p> β-Diketones are well known to form metal complexes with practically every known metal and metalloid. Metal complexes of fluorinated β-diketones generally exhibit increased volatility and thermal stability compared to the non-fluorinated analogues, and thus are used extensively in various chemical vapor deposition (CVD) processes for the deposition of metal, simple or mixed metal oxides, and fluorine-doped metal oxide thin films. Furthermore, the electron-withdrawing nature of the fluorinated ligand enhances the Lewis acidity of a coordinatively unsaturated metal center which faci

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10

Jamadar, Abeda. "Copper(II) and Zinc(II) complexes of aroyl hydrazones as potential antitubercular agents." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/3099/.

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There is a continuing need to make new antitubercular drugs due to development of resistance towards present drugs. To do this, series of pyruvate hydrazones (PVAHs) and their respective Cu(II) complexes and Zn(II) complexes were synthesized and fully characterised. Variable temperature NMR studies of PVAHs indicate the presence of E and Z isomers in the solution. Determination of the obtained single crystal X-ray structures reveals that Cu(II) ion binds to PVAH ligand in 1:1 ratio resulting in square pyramidal geometry in most of the Cu(II) complexes, whereas Zn(II) ion binds to two PVAH liga

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11

Doddridge, Bruce Germein. "Ligand exchange and substitution on five-coordinate complexes of copper (II), nickel (II) and cobalt (II) /." Title page, contents and summary only, 1986. http://web4.library.adelaide.edu.au/theses/09PH/09phd641.pdf.

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12

Chen, Wei. "Studies on immobilized polymer-bound imidazole copper(II) complexes as catalysts." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 1991. http://irs.ub.rug.nl/ppn/293908745.

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13

Oakley, Michael Andrew. "Synthesis, structure and properties of copper(II) complexes and their ligands." Thesis, University of Hull, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.296239.

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14

REIS, ALINE CRUZ DE MORAES. "SYTHESIS AND CHARACTERIZATION OF COPPER (II) AND ZINC (II) COMPLEXES WITH DIPEPTIDES OF BIOLOGICAL INTEREST." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2010. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=16186@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>FUNDAÇÃO DE APOIO À PESQUISA DO ESTADO DO RIO DE JANEIRO<br>Este trabalho descreve a síntese e caracterização de quatro complexos de cobre (II) e quatro complexos de zinco (II), com dipeptídeos, no estado sólido. Os dipeptídeos envolvidos foram: glicil-glicina, glicil-valina, metionil-metionina, metionil-glicina e cisteinil-glicina, cujos aminoácidos fazem parte de algumas proteínas envolvidas em processos de neurodegeneração, mais especificamente na doença de Alzheimer. Embora os mecanismos que desencadeiam esta patologia não es

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15

SZYFMAN, NATALIE WAISSMANN. "STUDY OF COPPER(II) AND ZINC(II) COMPLEXES WITH SOME POLYAMINES AND PHOSPHOCREATINE OR ATP." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2011. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=18244@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>Foram estudados alguns sistemas binários de Cu(II) e Zn(II) formados com as poliaminas (PA= En, Tn, Put, Spd e Spm) e os complexos ternários (MLPA), onde L foi a PCr ou o ATP e PA uma das cinco poliaminas. O estudo foi realizado em solução aquosa por potenciometria, espectroscopia de ultravioleta-visível, Raman, RMN e RPE e cálculos de menor energia de estabilização e modelagem molecular. As constantes de estabilidade foram determinadas pela potenciometria. Os valores das constantes dos complexos com as poliaminas apresentam um c

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16

Gichinga, Moses G. Striegler Susanne. "Synthesis, spectroscopic investigation and immobilization of copper(II) complexes as oxidation catalysts." Auburn, Ala, 2009. http://hdl.handle.net/10415/1857.

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17

TRUDU, FEDERICA. "Studio di complessi di rame (II) e platino (II) con proprietà antitumorali." Doctoral thesis, Università degli Studi di Cagliari, 2015. http://hdl.handle.net/11584/266557.

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Cisplatin is one of the most active drugs in anticancer therapy, and it is currently used for the treatment of a wide range of cancers, in particular advanced ones. After its introduction in clinical therapy, the research in this field has focused on the preparation of new metal complexes with increased activity and lower side-effects. Besides, the use of drug combinations with synergistic effect, i.e. an effect greater than the sum of the effects of the single drugs, has been introduced. This thesis is focused on the preparation of Cu(II) and Pt(II) complexes and on the study of their c

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18

Suksangpanya, Unchulee. "Hydrogen bonded supramolecular architectures of copper (II) complexes of amidino #OMICRON# alkylurea derivatives." Thesis, University of Nottingham, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.273124.

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19

PINTO, LUCIANA DORNELAS. "STUDY OF COPPER(II) COMPLEXES CONTAINING AMINO ACIDS OF INTEREST FOR BRAIN CHEMISTRY." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2010. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=16189@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>Foram sintetizados 16 complexos de cobre(II) coordenados com seis aminoácidos presentes na placa b-amilóide, que está associada à Doença de Alzheimer - ácido aspártico, ácido glutâmico, metionina, glicina, serina e arginina, outros dois aminoácidos também encontrados no cérebro - cisteína e homocisteína, além da L-carnitina e acetil-L-carnitina que vêm sendo utilizados como suplemento alimentar em pacientes com doenças neurodegenerativas. Nosso objetivo foi verificar a afinidade do cobre(II) com estes aminoácidos, uma vez que o e

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20

LeCloux, Daniel D. (Daniel David) 1970. "Synthesis and reactivity of copper(I) and iron(II) carboxylate-bridged dimetallic complexes." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/50411.

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21

Wioppiold, Thomaz Arruda. "Aroilbis(N,N-dietiltioureatos) de cádmio (II) e chumbo (II): síntese e caracterização." Universidade Federal de Santa Maria, 2014. http://repositorio.ufsm.br/handle/1/10586.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior<br>This work introduces the synthesis of two novel ligands belonging to the aroylbis(thiourea) class to study the spacer group influence in the complexes structure. Five membered rings were utilized as spacer groups such as pyrrole and furan. The presence of the hydrogen in the pyrrole s nitrogen restricts the complexes formation while the furan ring, in some cases, can coordinate its oxygen atom to coordination with specific metals. It was synthetized bi-, tri-, tetranuclear complexes with two metal, cadmium and lead. With cadmium th

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22

Walli, Adam. "Biomimetic Copper(I)-Mediated Activation of Dioxygen and Redox Non-Innocence in Copper(II) Complexes of Bis(oxazoline)s." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-9636-9.

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23

Sobola, Abdullahi Owolabi. "Synthesis, characterization and antimicrobial activity of copper (II) complexes of some hydroxybenzaldimines and their derivatives." Thesis, Rhodes University, 2012. http://hdl.handle.net/10962/d1016258.

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This study focuses on the antimicrobial activity of Cu(II) complexes of some orthohydroxybenzaldimines and its derivatives. Four different categories of Schiff base ligands were prepared by condensing salicylaldehyde, o-vanillin, p-vanillin and vanillin with p- and osubstituted anilines; 1-aminonaphthalene; 2- and 3-aminopyridine; 2- and 3- aminomethylpyridine as well as 2-aminobenzimidazole. The last category was prepared from ophenylenediamine and o-vanillin. The Schiff base ligands have been characterized by a combination of elemental analysis and spectral (¹H- and ¹³C-NMR, UV/Visible, infr

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24

Alcacio, Tim. "THE MOLECULAR SCALE NATURE OF COPPER(II) AND ARSENATE BONDING WITH GOETHITE-HUMATE COMPLEXES." NCSU, 2001. http://www.lib.ncsu.edu/theses/available/etd-20010113-190843.

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<p>Alcacio, Tim. The Molecular Scale Nature of Copper(II) and Arsenate Bonding With Goethite-Humate Complexes. In soils, interactions between clay minerals and natural organic matter are known to affect the cycling of heavy metals and anions. Contaminant structures at mineral surfaces that contain adsorbed organic matter will have a significant influence on the bioavailability of the contaminant. The structure of copper(II) and arsenate complexes on goethite in the presence and absence of adsorbed humic acid were studied with extended x-ray absorption fine structure (EXAFS) spectroscopy and wi

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25

Flynn, Elizabeth. "The catalysed decomposition of chlorosulfides." Thesis, Queen Mary, University of London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336343.

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26

Lin, Yongyue, and 林勇躍. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands: structures, spectroscopic properties and applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31243381.

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27

Lin, Yongyue. "Luminescent platinum(II), copper(I), silver(I) and zinc(II) complexes with functional pyridyl and arylacetylide ligands : structures, spectroscopic properties and applications /." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B25155325.

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28

Chen, Tianyu. "Study on the Copper(II)-Lactate Complexes in Cu₂O Electrodeposition Baths：From Determination to Application." Kyoto University, 2020. http://hdl.handle.net/2433/259043.

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29

HOTTES, SUMAIA. "NEW PLATINUM(II) AND COPPER(II) COMPLEXES DERIVED FROM 1,2,3-TRIAZOLIC OXIMES AS POTENTIAL ANTITUMOR AGENTS AND PROTOTYPES OF BIOREDUCTIVE PRODRUGS." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2013. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=24950@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>COORDENAÇÃO DE APERFEIÇOAMENTO DO PESSOAL DE ENSINO SUPERIOR<br>CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>PROGRAMA DE SUPORTE À PÓS-GRADUAÇÃO DE INSTS. DE ENSINO<br>O câncer constitui patologia de grande importância, visto que já corresponde à segunda maior causa de mortes em todo o mundo, havendo perspectiva de crescimento em número de casos para os próximos anos. Os tratamentos quimioterápicos atuais caracterizam-se por um elevado custo e índice terapêutico relativamente reduzido, estando associados a diversos efeit

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30

Lingga, Novalina. "Syntheses and structural studies of polynuclear copper (II) complexes of Schiff-base macrocycles and related ligands." Thesis, University of Canterbury. Chemistry, 1996. http://hdl.handle.net/10092/7315.

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Two diimine-diamine ligands derived from the [2+1] template condensation of 1,3-diaminopropane with 2,6-diformyl-4-R-phenol [R = Me, (L¹)-; R = tBu, (L⁸)-], have been isolated as their dicopper(II) hydroxo-bridged complex cations. The ring-closure condensation reaction of the dicopper complex cation of (L¹)- with 2,5-diformylfuran produced a new asymmetric tetraimine macrocycle, (L³)- as the methoxo-, hydroxo- and ethoxo-bridged dicopper(II) complexes. The hydroxo- and ethoxo-bridged dicopper(II) complexes of (L³)- were isolated from the recrystallisation of the methoxo-bridged analogue using

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31

INCIO, JIMMY LLONTOP. "SPECTROSCOPIC STUDIES OF FLUOROQUINOLONES AND THEIR COPPER(II) COMPLEXES: INTERACTION WITH MICELLES, LIPOSOMES AND GOLD NANOCOMPOSITES." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2018. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=36043@1.

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PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO<br>COORDENAÇÃO DE APERFEIÇOAMENTO DO PESSOAL DE ENSINO SUPERIOR<br>CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>PROGRAMA DE SUPORTE À PÓS-GRADUAÇÃO DE INSTS. DE ENSINO<br>PROGRAMA DE EXCELENCIA ACADEMICA<br>Norfloxacina (NFX) é um antibiótico fluorescente de amplo espectro bacteriológico, membro da família das fluorquinolonas (FQs). A interação das FQs com íons metálicos pode incrementar a ação bactericida e agir contra a resistência das bactérias frente aos antibióticos. Diversos exemplos de complexos mistos de norfloxacin

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32

Cheruiyot, Linnus L. Carleton University Dissertation Chemistry. "Long range antiferromagnetic exchange coupling in dinuclear copper(II) complexes containing 1.4-dicyanamidobenzene dianion bridging ligands." Ottawa, 1994.

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33

Hung, Jun-Teng, and 黃俊騰. "Synthesis and Reactions of Tetranuclear Copper( I ) Complexes." Thesis, 2001. http://ndltd.ncl.edu.tw/handle/99708429584444013177.

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碩士<br>國立成功大學<br>化學系<br>90<br>[Cu2(μ- dppm)2(MeCN)2][PF6]2 reacted with five dicarboxylic acid to produce tetracopper complexes [{Cu2(μ- dppm)2}2(μ4,η4—O2CXCO2)] [PF6]2 ( X = CH2 (2)、CH2CH2 (3)、C6H4 (4)、C6H4C6H4 (5)、trans-CH=CH (6) ). These new complexes were characterized by elemental analysis, IR, and NMR spectra, together with the solid-state structures of 3-6 determined by X-ray diffraction methods. Crystal data：3•3.5acetone, triclinic, Pī, a = 15.1352(3), b = 17.5068(4), c = 22.0689(4) Å, α = 101.843(1), β = 99.789(1), γ = 93.382(1)°, V = 5613.0(2) Å3, Z = 2, R = 0.0479, Rw = 0.1082, base

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34

Chang, Wen-Jwu, and 張順隆. "Tetranuclear copper complexes of 3,6-bis(2'-pyridyl)-pyridazine." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/19654227393404181115.

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碩士<br>淡江大學<br>化學學系<br>84<br>A series of copper(I) and copper(II) complexes has beenprepareed,containing -diimine ligands, PPA and PTA. Thereare ten complexes listed below[Cu4(PPA)4](ClO4)4,,[Cu2(DMP)2(PPA)]( ClO4)2,[Cu4(PPA)4][Cu3Br6][CuBr2], [Cu4I4(PPA)2],[Cu(II)(PPA)2 I]I, [Cu(II)(PPA)2I]ClO4,[Cu4(PPA)4][Cu4Cl8], [Cu4I4(PTA)2], [Cu4Br4(PTA)2] and[Cu4Cl4(PTA)2] ,the front six complexes whose molecularstructures are confirmed by X-ray crystal diffraction. Tosum up, these copper(I) complexes

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35

Cheng, Sheng-Chuan, and 鄭勝權. "Studies of Catecholase-like Model Copper( II ) Complexes." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/38523503391867508457.

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碩士<br>淡江大學<br>化學學系<br>88<br>Title of Thesis: Studies of Catecholase-like Model Copper( II ) Complexes Key word: Copper(II) complex,Magnetic properties, Catecholase-like Name of Institute:Graduate Institute of Chemistry Tamkang University Graduate date: June, 2000 Degree conferred: Master Name of student: Sheng-Chuan Cheng Advisor:Dr. Ho-Hsiang Wei 鄭勝權 Abstract: This thesis essentially has been separated into two parts : Ⅰ. The synthesis of dinuclear copper(II) complexes a

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36

YU, LIN, and 俞琳. "Electrochemistry of copper (II) complexes of diamino diamides." Thesis, 1990. http://ndltd.ncl.edu.tw/handle/96036039770267042153.

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37

Lin, Yung-Chan, and 林永展. "Structures and Kinetics of Nickel(II) and Copper(II) Macrocyclic Complexes." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/946je8.

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博士<br>國立清華大學<br>化學系<br>92<br>The tetraaza-macrocyclic ligands were synthesized by two methods. (1) The protecting group method reported by Richman and Atkins was used for the synthesis of isocyclam. (2) The general organic method with Michael addition reaction was employed to prepare 3-10-C-meso-Me8[14]dieneN4.2HClO4. The structures and components of these ligands were analyzed and identified by NMR, IR, UV-vis, mass, and X-ray studies. The complexes of Ni(II) and Cu(II) were synthesized by using Ni(ClO4)2.6H2O, Ni(OAc)2.4H2O, or Cu(ClO4)2.6H2O in hot methanol solution and recrystallized from

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38

WANG, YUN-MING, and 王雲銘. "COORDINATION CHEMISTRY OF COPPER(II) AND NICKEL(II) COMPLEXES OF DIAZADIOXIMES." Thesis, 1990. http://ndltd.ncl.edu.tw/handle/69153478402852757506.

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39

Kuo-Shen, Chuang, and 莊國昇. "Synthesis and Characterization of Hexaazamacrocyclophane and Cobalt(II),Nickel(II),Copper(II) Complexes." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/07616080849513435027.

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博士<br>淡江大學<br>化學學系<br>87<br>We synthesize a new hexaazamacrocyclic ligand(H2HAPP) and their cobalt(II)、nickel(II)、copper(II) complexes, and the N-substituted methyl derivative(DMHAPP) was also obtained by reactng with methyl iodide. The X-ray stacking structures of i-H2HAPP and H4HAPP(CF3COO)2 show that both ligands exist a type of face-to-face aggregates between macrocyclic molecules and a strong  interaction exists in aggregates according to the distance of plane-to-plane in the aggregates(3.28~3.29 ). The study of aggregate behavior in solution proved the formation of face

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40

Lee, Chen-Shiang, and 李成祥. "Palladium (II), Copper (I), Ruthenium (II) and Platinum (II) N-Heterocyclic Carbene Complexes." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/50020053295025232657.

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博士<br>國立東華大學<br>化學系<br>98<br>This dissertation discusses the synthesis, structural characterizations, related properties and further applications of N-heterocyclic carbene (NHC) complexes of palladium (II), copper (I), ruthenium (II) and platinum (II). In Chapter 1, the basic principles of N-heterocyclic carbene ligand and the related background of their metal complexes are conceptually described. The properties of metal complexes bearing chelate- or pincer-type NHC ligand are introduced. The main ideas of each chapter in this dissertation are illustrated. In Chapter 2, the homoleptic bis-chel

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41

Wu, Chiou-yeh, and 吳秋月. "Studies of Modelling Complexes of Copper Proteins:Syntheses, Structures and Bonding Properties of Tridentate Picolinamido Copper(II) Complexes." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/02297080253961804172.

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博士<br>國立臺灣師範大學<br>化學系<br>84<br>Four series of mixed ligand tridentate picolinamido copper(II) complexeshave been prepared. They are :(1) Cu(pmpa)( L)(X)(H2O)n type, where pmpa stands for N-(2-picolinyl)- picolinamido, and L for imidazole(ImH), N-methylimidazole(NMIm), 4-methylimidazole(4MImH), pyridine(py), 2-methylpyridine(2Mpy), 3-methylpyridine(3Mpy), and 4-methylpyridine(4Mpy), and X for ClO4-, or BF4-,and n = 0, 1 or 2.(2) Cu(pepa)(L)(X)(H2O)n type, where pepa stands for (N-(2-(2''-py

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42

劉育良. "Structural and Kinetic Studies of Copper(II) and Nickel(II) Polyamine Complexes." Thesis, 1992. http://ndltd.ncl.edu.tw/handle/25005470719694984803.

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43

Wu, Shu-Pao, and 吳淑褓. "The Copper(II) Complexes of Glycine and L-Alanine." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/37208790571201430373.

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碩士<br>國立臺灣師範大學<br>化學系<br>84<br>Copper(II) complexes of two types, Cu(A)(LL)(ClO4) and Cu( pa)(L)(ClO4), where A = glycine(gly) and L-alanine(L-ala); pa = N-picolyl-(L)-alanine; LL = 1,10-phenanthroline(phen), 2,2'-bipyridine(bipy), neocuproine(neoc) and ethylenediamine( en); L = N-methylimidazole(NMIm), 4-methylimidazole(4MImH), 4-methylpyridine(4Mpy) and pyridine(py), have been synthesized andcharacterized by elemental analyses, IR, UV-VIS, CD and EPR spectroscopicmeasurements.

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Chiu, Po-Lin, та 邱柏霖. "β-Diketiminato Copper(II)-nitrito Complexes As New Models For Copper Nitrite Reductases". Thesis, 2013. http://ndltd.ncl.edu.tw/handle/44963923225850910846.

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碩士<br>高雄醫學大學<br>醫藥暨應用化學研究所<br>101<br>Copper-containing nitrite reductases active site contains a type II copper catalytic center possessing a (His)3 coordination sphere. A new type asymmetry N,N-substituted ??-diketiminato ligand sets bearing different kinds of arms ( L1H、L2H、L3H、L4H ) are design for the type II coordination environment. The synthesis of lithium complexes ( L1Li、L2Li、L3Li、L4Li ) show the tridentate chelating nature. Asymmetry N,N-substituted ??-diketiminato copper(II) complexes ( L1CuCl、L2CuCl、L3CuCl、L4CuCl ) could be obtained by reaction of the corresponding lithium complex w

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45

ZHONG, YI-ZHEN, and 鐘意鎮. "Kinetics of acid-catalyzed dissociation of copper (II) and nickel (II) hexaazamacrocyclic complexes." Thesis, 1992. http://ndltd.ncl.edu.tw/handle/98245993345245508376.

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Torre, Lorente Laura. "Liquid crystalline copper(II) complexes of poly(propylene imine) dendrimers." 2007. http://opus.ub.uni-bayreuth.de/volltexte/2009/558/.

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WU, DE-XIN, and 伍德馨. "The study of coordination chemistry of copper (II) macrocyclic complexes." Thesis, 1986. http://ndltd.ncl.edu.tw/handle/63640024981323501622.

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Chen, Zhi-Wan, and 陳枝萬. "Stereochemistry of tetraamine macrocyclic complexes of nickel(II); kinetics and mechanisms of tetraamine macrocyclic complexes of copper(II) and nickel(II)." Thesis, 1986. http://ndltd.ncl.edu.tw/handle/63807275128724776095.

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Munro-Leighton, Colleen. "Synthesis and reactivity of copper(I), copper(II), platinum(II) and platinum(IV) complexes with non-dative heteroatomic ligands." 2008. http://www.lib.ncsu.edu/theses/available/etd-08122008-133840/unrestricted/etd.pdf.

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50

Hsiao-Han, Peng, and 彭筱涵. "Liquid Crystalline Properties of Copper(II) and Palladium(II) Complexes Containing 1,3-dialkylimidazolium Salts." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/30152222138914591932.

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碩士<br>輔仁大學<br>化學系<br>88<br>Palladium(II) and copper(II) complexes ([(Cn)2-imyH][MCl4] , n = 8, 10,12, 14, 16, 18 ) were synthesized, and their liquid crystalline properties investigated. Two compounds, [(C12)2-imyH]2[CuCl4] and [(C12)2-imyH]2 [PdCl4] were structurally determined by single crystal X-ray diffraction. Tetra-chloropallate adopts a square-planar geometry while tetrachlorocuprate has a distorted tetrahedral structure. Liquid crystalline behavior of these compounds was studied by differential scanning calorimetry and polarized optical microscopy. The typical fan texture, the spontan

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