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Journal articles on the topic 'Thallium(I) Chelates'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Chandra, D. Dwivedi, N. Munahi Kailash, and K. Dey Arun. "Composition and Stability of the Chelates of Trivalent Gallium, Indium, and Thallium with 3,3'-Bis-NN'-di-(carboxymethyl)aminomethyl -o-cresol Sulphonphthalein (Xylenol Orange)." Journal of Indian Chemical Society` Vol. 43, May 1966 (2022): 301–4. https://doi.org/10.5281/zenodo.6482803.

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Detailed studies on the composition and debility of the metal ohelates<sup>7</sup> of trivalent gallium, indium, and thallium with Xylonol orange., that is, 8,3'-bis-<em>NN'</em>-di-(carboxyrnethyl)aminomethyl-o-orseol emlphonghtlkslein (DCAC) have been made. All the chelates have the composition of 1 :1. ishiwatari <em>el ar. </em>made some observations on the indium chalets only in connection with the spootrophotometrie determination of indium with Xylenol orange. Chelates of gallium, indium, and thallium with DCAC have been studied in the present communication.

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2

Lyczko, Krzysztof, Monika Lyczko, Marzena Banasiewicz, et al. "Thallium(I) Tropolonates: Synthesis, Structure, Spectral Characteristics, and Antimicrobial Activity Compared to Lead(II) and Bismuth(III) Analogues." Molecules 27, no. 1 (2021): 183. http://dx.doi.org/10.3390/molecules27010183.

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Synthesis, single-crystal X-ray determination diffraction and FT-IR, NMR (1H, 13C, 19F and 205Tl), UV–vis, and luminescence spectra characteristics were described for series of thallium(I) compounds: thallium(I) triflate (Tl(OTf)), 1:1 co-crystals of thallium(I) triflate and tropolone (Htrop), Tl(OTf)·Htrop, as well as simple thallium(I) chelates: Tl(trop) (1), Tl(5-metrop) (2), Tl(hino) (3), with Htrop, 5-methyltropolone (5-meHtrop), 4-isopropyltropolone (hinokitiol, Hhino), respectively, and additionally more complex {Tl@[Tl(hino)]6}(OTf) (4) compound. Comparison of their antimicrobial activ

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3

Toma, Monica, Agustín Sánchez, María García-Tasende, et al. "Crystal structure and spectral characterization of dimethylthallium (III) complexes with 2-mercaptonicotinic acid and esters." Open Chemistry 2, no. 3 (2004): 534–52. http://dx.doi.org/10.2478/bf02476206.

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AbstractSynthesis, spectral properties and crystal structure of dimethylthallium(III) complexes with 2-mercaptonicotinic acid (2mna), 2-mercapto-methyl-nicotinate (2mmn), 2-mercapto-ethyl-nicotinate (2men) and 2-mercapto-isopropyl-nicotinate (2min) are reported. The compounds were characterized using IR, multinuclear NMR (1H,13C,205Tl) and mass spectrometry (electrospray, ES-API). The molecular structures of [TlMe2(2mna)]·H2O, (1), [TlMe2(2mmn)], (2), [TlMe2(2men)], (3) and [TlMe2(2min)], (4) were determined by the single-crystal X-ray diffraction. In 1, the monodeprotonate O,S-bidentate ligan

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4

Fatemi, S. J., A. Amiri, M. H. Bazargan, S. Tubafard, and S. N. Fatemi. "Clinical Evaluation of Desferrioxamine (DFO) for Removal of Thallium Ions in Rat." International Journal of Artificial Organs 30, no. 10 (2007): 902–5. http://dx.doi.org/10.1177/039139880703001007.

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An investigation was conducted to evaluate the ability of DFO following the administration of thallium salt in male Wistar rats. Thallium was introduced to several groups of weanling male Wistar rats via different means, through drink, food and intraperitoneal injection. A control group was fed on a diet containing a normal level of iron. After a period of 30 days, all the rats administered thallium were severely anemic and showed toxicity symptoms through loss of hair, an increase in thallium and a decrease in iron levels in the blood. Chelation therapy was carried out to remove the toxic ele

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5

Wang, Jieqi, Masahiko Taniguchi, David F. Bocian, and Jonathan S. Lindsey. "Synthesis of porphyrin triads chelated with thallium(III) for studies of ground-state hole/electron transfer." Journal of Porphyrins and Phthalocyanines 28, no. 08 (2024): 515–26. http://dx.doi.org/10.1142/s1088424624500524.

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Four target all-porphyrin triads have been prepared for fundamental studies of ground-state hole/electron transfer. Each triad contains thallium(III) porphyrins as bookends, which bear mesityl groups at the three non-linking meso-positions. The central porphyrin is a free base or thallium(III) porphyrin bearing mesityl or pentafluorophenyl groups at the two non-linking meso-positions. The linker is a 4,4′-diphenylethyne unit joined at the porphyrin meso-positions. The net spacer between the two bookend thallium(III) porphyrins thus consists of diphenylethyne–porphyrin–diphenylethyne and is des

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6

Aravindu, Kunche, Masahiko Taniguchi, David F. Bocian, and Jonathan S. Lindsey. "Synthesis of (oxo)chlorin dimers chelated with thallium(III)." Journal of Porphyrins and Phthalocyanines 28, no. 08 (2024): 527–35. http://dx.doi.org/10.1142/s1088424624500548.

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Two target dimers have been prepared for fundamental studies of hole/electron transfer. Metalation with thallium(III) enables clocking of the rate of hole/electron transfer between the two macrocycles. Each dimer contains a diphenylethyne linker joining two identical hydroporphyrins (chlorin or oxochlorin). The linker is substituted at the 4,4′-positions whereas each (oxo)chlorin is joined at the 10-position. Each (oxo)chlorin is equipped with a gem-dimethyl group at the 18-position to stabilize the hydroporphyrin chromophore toward adventitious dehydrogenation and a 3,5-di-tert-butyl group at

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7

Safyanova, Inna S., Oksana A. Bondar, Anna V. Pavlishchuk, Iryna V. Omelchenko, Turganbay S. Iskenderov та Valentina A. Kalibabchuk. "Crystal structure of poly[(μ3-4-amino-1,2,5-oxadiazole-3-hydroxamato)thallium(I)]". Acta Crystallographica Section E Crystallographic Communications 76, № 3 (2020): 328–31. http://dx.doi.org/10.1107/s2056989020001577.

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The title compound represents the thallium(I) salt of a substituted 1,2,5-oxadiazole, [Tl(C3H3N4O3)] n , with amino- and hydroxamate groups in the 4- and 3- positions of the oxadiazole ring, respectively. In the crystal, the deprotonated hydroxamate group represents an intermediate between the keto/enol tautomers and forms a five-membered chelate ring with the thallium(I) cation. The coordination sphere of the cation is augmented to a distorted disphenoid by two monodentately binding O atoms from two adjacent anions, leading to the formation of zigzag chains extending parallel to the b axis. T

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8

Stöber, Franziska, Kathrin Baldauf, Iryna Ziabreva, et al. "Single-Cell Resolution Mapping of Neuronal Damage in Acute Focal Cerebral Ischemia Using Thallium Autometallography." Journal of Cerebral Blood Flow & Metabolism 34, no. 1 (2013): 144–52. http://dx.doi.org/10.1038/jcbfm.2013.177.

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Neuronal damage shortly after onset or after brief episodes of cerebral ischemia has remained difficult to assess with clinical and preclinical imaging techniques as well as with microscopical methods. We here show, in rodent models of middle cerebral artery occlusion (MCAO), that neuronal damage in acute focal cerebral ischemia can be mapped with single-cell resolution using thallium autometallography (TlAMG), a histochemical technique for the detection of the K+-probe thallium (Tl+) in the brain. We intravenously injected rats and mice with thallium diethyldithiocarbamate (TlDDC), a lipophil

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9

Kumar, Vinod, Vikram Singh, Ajit N. Gupta, Michael G. B. Drew, and Nanhai Singh. "Intermolecular Tl⋯H–C anagostic interactions in luminescent pyridyl functionalized thallium(i) dithiocarbamates." Dalton Transactions 44, no. 4 (2015): 1716–23. http://dx.doi.org/10.1039/c4dt03032j.

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10

Amano, Ryohei, and Yoshinobu Shiokawa. "A volatile thallium chelate, (2,2,6,6-tetramethyl-3,5-heptanedionato)Tl(I)." Inorganica Chimica Acta 203, no. 1 (1993): 9–10. http://dx.doi.org/10.1016/s0020-1693(00)82897-2.

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11

Amiri, Asghar, S. Jamilaldine Fatemi, and S. Nabilaldine Fatemi. "Removal of thallium by combining desferrioxamine and deferiprone chelators in rats." BioMetals 20, no. 2 (2006): 159–63. http://dx.doi.org/10.1007/s10534-006-9023-1.

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12

Rigby, Alex, George Firth, Charlotte Rivas, et al. "Towards bifunctional chelators for thallium-201 for use in nuclear medicine." Nuclear Medicine and Biology 114-115 (November 2022): S10. http://dx.doi.org/10.1016/s0969-8051(22)02120-5.

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13

Lehman, John T., Ali Bazzi, Todd Nosher, and Jerome O. Nriagu. "Copper inhibition of phytoplankton in Saginaw Bay, Lake Huron." Canadian Journal of Fisheries and Aquatic Sciences 61, no. 10 (2004): 1871–80. http://dx.doi.org/10.1139/f04-129.

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Field surveys and bioassays during 1999 and 2000 demonstrated trace metal effects on the phytoplankton of inner and outer regions of Saginaw Bay, Lake Huron. Addition of as little as 1 µg·L1 copper suppressed algal biomass, measured as particulate chlorophyll a, compared with control treatments, additions of ethylenediaminetetraacetic acid, or additions of carrier water alone. Suppression effects of copper, added alone or in combination with cadmium, lead, and thallium, were evident in inner and outer regions of Saginaw Bay during both spring and summer when phytoplankton communities were com

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14

Musso, Stefano, Giorgio Anderegg, Heinz Ruegger, Carl Wilhelm Schlaepfer, and Volker Gramlich. "Mixed-Ligand Chelate Complexes of Thallium(III), Characterized by Equilibrium Measurements, NMR and Raman Spectroscopy, and X-ray Crystallography." Inorganic Chemistry 34, no. 12 (1995): 3329–38. http://dx.doi.org/10.1021/ic00116a027.

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15

Goldschmidt, Jürgen, Tim Wanger, Achim Engelhorn, et al. "High-resolution mapping of neuronal activity using the lipophilic thallium chelate complex TlDDC: Protocol and validation of the method." NeuroImage 49, no. 1 (2010): 303–15. http://dx.doi.org/10.1016/j.neuroimage.2009.08.012.

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16

Belyaev, B. N., and N. M. Beregovaya. "The influence of culture medium on the quantity of agar, pigments and growth of Gelidium spinosum from the Black Sea." Marine Biological Journal 1, no. 4 (2016): 3–11. http://dx.doi.org/10.21072/mbj.2016.01.4.01.

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The results of researches on the influence of additions of Fe, Mo, Mg and Cu on growth characteristics and maintenance of pigments and agar in the thallus of Gelidium spinosum (Grev.) Born et Thur. (Rodophyta) from the Black Sea are presented. Increasing salinity of Black Sea water to 26 ‰ and enriching it with nitrogen up to 4.8 and phosphorus to 0.8 mg/l (environment A) showed that additions of chelated chloric iron in the amount of 0.5 mg/l (nourishing environment B) not only save viability of Gelidium during of annual cycle but also increase maintenance of agar by 30 %, total carotenoids a

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17

McNeil, Brooke L., Andrew K. H. Robertson, Winnie Fu, et al. "Production, purification, and radiolabeling of the 203Pb/212Pb theranostic pair." EJNMMI Radiopharmacy and Chemistry 6, no. 1 (2021). http://dx.doi.org/10.1186/s41181-021-00121-4.

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Abstract Background Lead-212 (212Pb, t1/2 = 10.6 h) and lead-203 (203Pb, t1/2 = 51.9 h) are an element-equivalent, or a matched theranostic radioisotope pair that show great potential for application in targeted radionuclide therapy (TRT) and single-photon emission computed tomography (SPECT), respectively. At TRIUMF we have produced both 203Pb and 212Pb using TRIUMF’s TR13 (13 MeV) and 500 MeV cyclotrons, and subsequently purified and evaluated both radioisotopes using a series of pyridine-modified DOTA analogues in comparison to the commercially available chelates DOTA (1,4,7,10-tetraazacycl

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18

Narbutt, Jerzy, and Jadwiga Krejzler. "Liquid–liquid distribution studies on moderately labile metal chelates. Kinetics of hydrolysis of tris(thenoyltrifluoroacetonate)thallium(III)." Radiochimica Acta 93, no. 9-10 (2005). http://dx.doi.org/10.1524/ract.2005.93.9-10.627.

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19

Frei, Angelo, Alex Rigby, Thomas T. C. Yue, George Firth, Michelle Ma, and Nicholas J. Long. "To Chelate Thallium(I) - Synthesis and Evaluation of Kryptofix-based Chelators for ²⁰¹Tl." Dalton Transactions, 2022. http://dx.doi.org/10.1039/d2dt01074g.

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While best known for its toxic properties, thallium has also been explored for applications in nuclear diagnostics and medicine. Indeed, [201Tl]TlCl has been used extensively for nuclear imaging in the...

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20

Carey, Jennifer L., and Edward W. Boyer. "Heavy Metals." DeckerMed Emergency Medicine, September 1, 2015. http://dx.doi.org/10.2310/em.4341.

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Heavy metal poisoning may be acute, subacute, or chronic, and it is important for the emergency physician to recognize poisonings that are acutely life threatening. Nearly all parts of the human body are affected by heavy metals, including the cardiovascular, gastrointestinal, renal, hematologic and nervous systems. In many heavy metal poisonings, chelation therapy is the standard of care. This review details the principles of toxicity, immediate stabilization, diagnosis and definitive therapy, and disposition and outcomes for patients who have been exposed to arsenic, chromium, cobalt, lead,

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21

Rigby, Alex, George Firth, Charlotte Rivas, et al. "Toward Bifunctional Chelators for Thallium-201 for Use in Nuclear Medicine." Bioconjugate Chemistry, July 8, 2022. http://dx.doi.org/10.1021/acs.bioconjchem.2c00284.

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22

McNeil, Brooke L., Simona A. Mastroianni, Scott W. McNeil, et al. "Optimized production, purification, and radiolabeling of the 203Pb/212Pb theranostic pair for nuclear medicine." Scientific Reports 13, no. 1 (2023). http://dx.doi.org/10.1038/s41598-023-37313-8.

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AbstractTRIUMF is one of the only laboratories in the world able to produce both lead-203 (203Pb, t1/2 = 51.9 h) and 212Pb (t1/2 = 10.6 h) onsite via its 13 and 500 MeV cyclotrons, respectively. Together, 203Pb and 212Pb form an element-equivalent theranostic pair that potentiate image-guided, personalized cancer treatment, using 203Pb as a single-photon emission computed tomography (SPECT) source, and 212Pb for targeted alpha therapy. In this study, improvements to 203Pb production were accomplished by manufacturing electroplated, silver-backed thallium (Tl) targets to improve target thermal

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23

Suno, Hiroya, Masahiko Machida, Terumi Dohi, and Yoshihito Ohmura. "Quantum chemical calculation studies toward microscopic understanding of retention mechanism of Cs radioisotopes and other alkali metals in lichens." Scientific Reports 11, no. 1 (2021). http://dx.doi.org/10.1038/s41598-021-87617-w.

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AbstractWe evaluate stability of cesium (Cs) and other alkali-metal cation complexes of lichen metabolites in both gas and aqueous phases to discuss why lichens can retain radioactive Cs in the thalli over several years. We focus on oxalic acid, (+)-usnic acid, atranorin, lecanoric acid, and protocetraric acid, which are common metabolite substances in various lichens including, e.g., Flavoparmelia caperata and Parmotrema tinctorum retaining Cs in Fukushima, Japan. By performing quantum chemical calculations, their gas-phase complexation energies and aqueous-solution complexation free energies

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