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Journal articles on the topic 'ThCr2Si2 structure'

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Published: 4 June 2021

Last updated: 1 February 2022

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1

Shatruk, Michael. "ThCr2Si2 structure type: The “perovskite” of intermetallics." Journal of Solid State Chemistry 272 (April 2019): 198–209. http://dx.doi.org/10.1016/j.jssc.2019.02.012.

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2

Ying, J. J., Y. J. Yan, R. H. Liu, et al. "Isotropic superconductivity in LaRu2P2with the ThCr2Si2-type structure." Superconductor Science and Technology 23, no. 11 (2010): 115009. http://dx.doi.org/10.1088/0953-2048/23/11/115009.

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3

Esmailzadeh, Saeid, Rolf-Dieter Hoffmann, and Rainer Pöttgen. "The Modulated Structure of SrAuSn2." Zeitschrift für Naturforschung B 59, no. 11-12 (2004): 1451–57. http://dx.doi.org/10.1515/znb-2004-11-1213.

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The ternary stannide SrAuSn2 was synthesized by induction melting of the elements under an argon atmosphere in a sealed niobium ampoule in a water-cooled sample chamber of a high-frequency furnace. The structure of SrAuSn2 was investigated by X-ray powder and single crystal diffraction. It was found to be favourable to describe as a commensurately modulated structure. The 3+1 dimensional superspace group symmetry P : Cmcm(α, 0, 0) : 0s0 with the unit cell dimensions a = 460.20(14), b = 2038.8(8), c = 460.34(19) pm and the modulation wave vector q =¼ [100]*. The Sn1 atoms were those with the st

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4

Newmark, A. R., G. Huan, M. Greenblatt, and M. Croft. "Magnetic ordering in TlCo2-xNixSe2 with the ThCr2Si2 structure." Solid State Communications 71, no. 11 (1989): 1025–32. http://dx.doi.org/10.1016/0038-1098(89)90584-x.

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5

Horvath, C., and P. Rogl. "Refinement of the crystal structure of HoRu2Si2 (ThCr2Si2-type)." Materials Research Bulletin 20, no. 1 (1985): 35–40. http://dx.doi.org/10.1016/0025-5408(85)90024-8.

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6

Roy, S. B., A. K. Pradhan, and P. Chaddah. "Metastable magnetic response in UT2X2 compounds with ThCr2Si2 structure." Physica B: Condensed Matter 223-224 (June 1996): 198–200. http://dx.doi.org/10.1016/0921-4526(96)00076-2.

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7

Okeeffe, M. "Self-Dual Plane Nets in Crystal Chemistry." Australian Journal of Chemistry 45, no. 9 (1992): 1489. http://dx.doi.org/10.1071/ch9921489.

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A self-dual net is one that is identical to its dual. It is shown that some of the more commonly occurring binary and ternary intermetallic crystal structure types can be very simply described as a stacking of self-dual nets. Common structure types discussed include those of CrB , Cu2Sb (= PbClF ), BaAl4 (=ThCr2Si2) and CoSi2 (= SrMgSi ).

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8

Pfannenschmidt, Ulrike, Ute Ch Rodewald, and Rainer Pöttgen. "Ce13Ir34.4P24– An intergrowth structure of ThCr2Si2, SrPtSb, and CeMg2Si2related slabs." Zeitschrift für Kristallographie 226, no. 3 (2011): 229–35. http://dx.doi.org/10.1524/zkri.2011.1355.

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9

Johrendt, Dirk, Claudia Felser, Ove Jepsen, Ole Krogh Andersen, Albrecht Mewis, and Jean Rouxel. "LMTO Band Structure Calculations of ThCr2Si2-Type Transition Metal Compounds." Journal of Solid State Chemistry 130, no. 2 (1997): 254–65. http://dx.doi.org/10.1006/jssc.1997.7300.

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10

Qiao, Lei, Jian Chen, Baijiang Lv, et al. "Antiferromagnetic Kondo lattice compound Ce2O2Bi with anti-ThCr2Si2-type structure." Journal of Alloys and Compounds 836 (September 2020): 155229. http://dx.doi.org/10.1016/j.jallcom.2020.155229.

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11

Jiao, W. H., I. Felner, I. Nowik, and G. H. Cao. "EuRu2As2: A New Ferromagnetic Metal with Collapsed ThCr2Si2-Type Structure." Journal of Superconductivity and Novel Magnetism 25, no. 2 (2011): 441–45. http://dx.doi.org/10.1007/s10948-011-1287-1.

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12

Sikolenko, V. V., E. V. Pomjakushina, V. Yu Pomjakushin, et al. "Modulated spin-density waves in uranium intermetallic compounds with ThCr2Si2 structure." Physica B: Condensed Matter 350, no. 1-3 (2004): E163—E166. http://dx.doi.org/10.1016/j.physb.2004.03.043.

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13

Hoffmann, Roald, and Chong Zheng. "Making and Breaking Bonds in the Solid State: The ThCr2Si2 Structure." Journal of Physical Chemistry 89, no. 20 (1985): 4175–81. http://dx.doi.org/10.1021/j100266a007.

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14

Kase, Naoki, Hironaga Sasaki, Hiroki Hayamizu, and Jun Akimitsu. "Superconducting State in the Ternary Germanide Y2AlGe3with Related ThCr2Si2-Type Structure." Journal of the Physical Society of Japan 80, no. 1 (2011): 014716. http://dx.doi.org/10.1143/jpsj.80.014716.

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15

Gadjiev, B. R. "Structure genesis and magnetic orderings in compounds of the ThCr2Si2 type." Low Temperature Physics 26, no. 12 (2000): 874–80. http://dx.doi.org/10.1063/1.1334437.

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16

Kadir, K., and D. Noréus. "Structural determination of NaAl2Ga2 intermetallic compound having the ThCr2Si2 type structure." Journal of Alloys and Compounds 477, no. 1-2 (2009): 149–51. http://dx.doi.org/10.1016/j.jallcom.2008.10.035.

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17

Dirken, M. W., R. C. Thiel, and K. H. J. Buschow. "Crystal-field effects in rare earth compounds with the ThCr2Si2 structure." Journal of the Less Common Metals 147, no. 1 (1989): 97–104. http://dx.doi.org/10.1016/0022-5088(89)90152-5.

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18

Greaney, Mark, Guohe Huan, K. V. Ramanujachary, Zeri Teweldemedhin, and Martha Greenblatt. "Antiferro-to-ferromagnetic transition in metallic with the ThCr2Si2 type structure." Solid State Communications 79, no. 10 (1991): 803–10. http://dx.doi.org/10.1016/0038-1098(91)90309-j.

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19

Kunioka, Haruno, Kunihiro Kihou, Daichi Kato, et al. "Thermoelectric Properties of (Ba,K)Zn2As2 Crystallized in the ThCr2Si2-type Structure." Inorganic Chemistry 59, no. 9 (2020): 5828–34. http://dx.doi.org/10.1021/acs.inorgchem.9b02680.

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20

Wenski, Guido, and Albrecht Mewis. "BaAl4-Strukturvarianten bei ARu2X2(A = Ca, Sr, Ba, Eu; X = P, As) und APt2P2—x (A = Ca, Eu) / BaAl4-Denvative Structures of ARu2X2 (A = Ca, Sr, Ba. Eu; X = P, As) and of APt2P2-x (A = Ca, Eu)." Zeitschrift für Naturforschung B 41, no. 1 (1986): 38–43. http://dx.doi.org/10.1515/znb-1986-0108.

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Compounds ARu2P(As)2 (A = Ca, Sr. Ba. Eu) were found to have the ThCr2Si2-type structure (14/mmm). Single crystals of CaRu2P2 (a = 404.6 pm, c = 977.1 pm) and EuRu2P2 (a = 402.9 pm, c = 1077.2 pm) were obtained using tin as a flux. In the case of the Pt compounds, single crystals could be isolated from powder samples. Ca(Eu)Pt2P2-x crystallizes isotypically in a new structure type which can be described as a stacking variation of the CaBe2Ge2-type structure (14/mmm; CaPt2P1.43: a = 409.9 pm, c = 1895.1 pm; EuPt2P1.62: a = 414.3 pm; c = 1912.0 pm). The crystal structures of Ca(Eu)Ru2P2 and Ca(E

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21

Pöttgen, Rainer. "Dy3Co6Sn5 – a New Stannide with an Ordered La3Al11 Type Structure." Zeitschrift für Naturforschung B 50, no. 2 (1995): 175–79. http://dx.doi.org/10.1515/znb-1995-0203.

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The title compound has been obtained by arc-melting of the elemental components and subsequent annealing at 800 °C. It crystallizes in the orthorhombic space group Immm, a = 430.3(1), b = 1235.0(2), c = 967.6(3) pm, V = 0.5142(2) nm3, Z = 2. The structure has been determined from single-crystal X-ray data and refined to R = 0.0181 for 747 F2 values and 28 variables. It is of a new type and can be described as a ternary ordered version of the binary La3Al11-type structure. Dy3Co6Sn5 is built up from DyCo2Sn2 and DyCo2Sn slabs with ThCr2Si2 and Cu3Au-like atomic arrangements, respectively. Its c

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22

Pohlkamp, Marc W., and Wolfgang Jeitschko. "Preparation, Properties, and Crystal Structure of Quaternary Silicide Carbides RCr2Si2C (R = Y, La - Nd, Sm, Gd - Ho)." Zeitschrift für Naturforschung B 56, no. 11 (2001): 1143–48. http://dx.doi.org/10.1515/znb-2001-1108.

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The title compounds were prepared by arc-melting cold-pressed pellets of the elemental components. They crystallize with a tetragonal structure already reported for CeCr2Si2C. It was refined from single-crystal X-ray data of PrCr2S2C: P4/mmm, a - 402.2( 1) pm, c = 535.2(1) pm, Z = 1, R = 0.012 for 252 structure factors and 10 variable parameters. Magnetic susceptibility measurements with a SQUID magnetometer indicate Pauli paramagnetism for YCr2Si2C, while CeC2Si2C shows mixed valent behavior. The carbon atoms in the structure of these compounds are isolated from each other. The silicon atoms

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23

Moze, O., M. Hofmann, and K. H. J. Buschow. "Chromium sublattice magnetic ordering in a compound of the ThCr2Si2 type structure: HoCr2Si2." Journal of Alloys and Compounds 308, no. 1-2 (2000): 60–63. http://dx.doi.org/10.1016/s0925-8388(00)00985-3.

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24

Huan, Guohe, Martha Greenblatt, and K. V. Ramanujachary. "Magnetic ordering in metallic TlCo2−xNixS2 (0 ⪕ x ⪕ 2.0) with the ThCr2Si2 structure." Solid State Communications 71, no. 3 (1989): 221–28. http://dx.doi.org/10.1016/0038-1098(89)90406-7.

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25

Brylak, Markus, and Wolfgang Jeitschko. "Ternary Antimonides LnTSb3 with Ln = La-Nd, Sm and T = V, Cr." Zeitschrift für Naturforschung B 50, no. 6 (1995): 899–904. http://dx.doi.org/10.1515/znb-1995-0611.

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The title compounds were prepared by reaction of the elemental components. They crystallize in a new structure type, which was determined from single-crystal X -ray data of CeCrSb3: Pbcm, a = 1310.8(3), b = 618.4(1), c = 607.9(1) pm, Z = 4, R = 0.029 for 648 structure factors and 32 variable parameters. The structure of the antimonide CeVSb3 is isotypic: a = 1319.0(2), b = 623.92(8), c = 603.03(8) pm , R = 0.041 for 477 structure factors and 32 variables. The transition metal site and one of the three antimony sites were found to have partial occupancies resulting in the exact compositions CeV

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26

Voßwinkel, Daniel, and Rainer Pöttgen. "Synthesis of Ce2Rh3Ge5 Crystals from a Bismuth Flux." Zeitschrift für Naturforschung B 68, no. 3 (2013): 301–5. http://dx.doi.org/10.5560/znb.2013-3015.

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The germanide Ce2Rh3Ge5 was synthesized from the elements in a bismuth flux, and the structure was refined from single-crystal X-ray diffractometer data: U2Co3Si5 type, Ibam, a = 1010:1(2), b = 1210:4(2), c = 599:1(1) pm, wR=0.0596, 760 structure factors, 31 variables. The rhodium and germanium atoms build up a three-dimensional [Rh3Ge5] network (242 - 269 pm Rh-Ge; 300 pm Rh-Rh; 266 pm Ge-Ge) in which the cerium atoms fill cavities. Each cerium atom has coordination number 17 by ten germanium (302 - 331 pm) and seven rhodium (320 - 355 pm) neighbors. The crystal-chemical relation of the Ce2Rh

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27

Reehuis, M., T. Vomhof, and W. Jeitschko. "Magnetic properties of UCo2P2 with CaBe2Ge2 type structure and LnNi2P2 (Ln ≡ Gd-Tb) with ThCr2Si2 type structure." Journal of the Less Common Metals 169, no. 1 (1991): 139–45. http://dx.doi.org/10.1016/0022-5088(91)90242-v.

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28

Liu, Han Yuan, Li Fu, and Yong Quan Guo. "Structural, Magnetic and Electrical Transport Properties of Ternary Compound LaCo₂Ge₂." Applied Mechanics and Materials 455 (November 2013): 148–53. http://dx.doi.org/10.4028/www.scientific.net/amm.455.148.

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Ternary compound LaCo2Ge2 was synthesized and characterized by means of XRD, magnetic and electrical measurements. Rietveld structure refinements of powder XRD patterns confirm that LaCo2Ge2 compound crystallizes with a body-centered tetragonal structure of ThCr2Si2-type (space group I4/mmm) with the unit lattice parameters a=4.105(6) Å and c=10.264(7) Å. Nd, Co and Ge occupy 2a, 4d and 4e crystal positions, respectively. Magnetism measurements show that LaCo2Ge2 is nearly temperature-impendent Pauli paramagnetic down to 100 K, whereas orders diamagnetic at elevated temperatures. The (T) mea

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29

Seidel, Stefan, and Rainer Pöttgen. "SrPdGa3 type gallides RERhGa3 with RE=La, Ce and Pr." Zeitschrift für Kristallographie - Crystalline Materials 235, no. 3 (2020): 53–57. http://dx.doi.org/10.1515/zkri-2019-0059.

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AbstractThe ternary rare earth gallides RERhGa3 with RE = La, Ce and Pr were synthesized by arc-melting and subsequent annealing in a muffle furnace. The gallides were characterized through Guinier powder patterns and the structure of LaRhGa3 was refined from single-crystal X-ray diffraction data: SrPdGa3 type, Cmcm, a = 639.2(2), b = 1030.9(2), c = 589.3(2) pm, wR2 = 0.0964, 416 F2 values and 19 variables. The rhodium and gallium atoms build up a three-dimensional polyanionic network [RhGa3] which is stabilized through Rh–Ga (245–251 pm) and Ga–Ga (267–295 pm) bonds and filled by the lanthanu

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30

Huhnt, C., W. Schlabitz, A. Wurth, A. Mewis, and M. Reehuis. "First- and second-order phase transitions in ternary europium phosphides with ThCr2Si2-type structure." Physica B: Condensed Matter 252, no. 1-2 (1998): 44–54. http://dx.doi.org/10.1016/s0921-4526(97)00904-6.

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31

Zhao, J. T., and E. Parthé. "Sc3Ni2Si3 with Hf3Ni2Si3-type structure, an intergrowth of CrB-, ThCr2Si2- and W-type slabs." Acta Crystallographica Section C Crystal Structure Communications 45, no. 12 (1989): 1853–56. http://dx.doi.org/10.1107/s0108270189002490.

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32

Jeitschko, W., and M. Reehuis. "Magnetic properties of CaNi2P2 and the corresponding lanthanoid nickel phosphides with ThCr2Si2 type structure." Journal of Physics and Chemistry of Solids 48, no. 7 (1987): 667–73. http://dx.doi.org/10.1016/0022-3697(87)90157-0.

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33

Albering, Jörg H., and Wolfgang Jeitschko. "Quaternary Thorium Transition Metal Pnictide Oxides: ThCu1-xPO, ThCuAsO, and Th2Ni3-xP3O." Zeitschrift für Naturforschung B 51, no. 2 (1996): 257–62. http://dx.doi.org/10.1515/znb-1996-0215.

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Abstract The new compounds ThCu1-xPO and ThCuAsO with ZrCuSiAs-type structure were prepared in well crystallized form by chemical vapor transport reactions. Th2Ni3-xP3O with a new structure type was obtained by reaction of ThO2 with the other elemental components in an alumina crucible at high temperatures. The crystal structures of the three compounds were determined from single-crystal X-ray data. ThCu1-xPO: P4/nmm, a = 389.43(4), c -828.3(1) pm, R = 0.024 for 13 variable parameters and 338 structure factors; ThCuAsO: P4/ nmm, a = 396.14(5), c = 844.0(1) pm, R = 0.028 (13 variables and 379

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34

Quebe, Peter, and Wolfgang Jeitschko. "The Arsenides LnPd3As2 (Ln = La-Nd, Sm, Gd) and Structure Refinement of CePd2-xAs2 with the ThCr2Si2 Structure." Journal of Solid State Chemistry 115, no. 1 (1995): 37–42. http://dx.doi.org/10.1006/jssc.1995.1099.

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35

Stüβer, N., Z. Zolnierek, and X. Hu. "Magnetic neutron powder diffraction on some UCu2-xGa2+y ternaries of the ThCr2Si2-type structure." Journal of Magnetism and Magnetic Materials 177-181 (January 1998): 815–16. http://dx.doi.org/10.1016/s0304-8853(97)00723-3.

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36

Moze, O., M. Hofmann, and K. H. J. Buschow. "ChemInform Abstract: Chromium Sublattice Magnetic Ordering in a Compound of the ThCr2Si2 Type Structure: HoCr2Si2." ChemInform 31, no. 49 (2000): no. http://dx.doi.org/10.1002/chin.200049010.

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37

Huan, Guohe, and Martha Greenblatt. "Antiferromagnetic-to-ferromagnetic transition in metallic Tl1−xKxCo2Se2 (0 ⩽ x ⩽ 1.0) with ThCr2Si2-type structure." Journal of the Less Common Metals 156, no. 1-2 (1989): 247–57. http://dx.doi.org/10.1016/0022-5088(89)90423-2.

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38

Kranenberg, Christian, Dirk Johrendt, Albrecht Mewis, et al. "New Compounds of the ThCr2Si2-Type and the Electronic Structure of CaM2Ge2 (M: Mn–Zn)." Journal of Solid State Chemistry 167, no. 1 (2002): 107–12. http://dx.doi.org/10.1006/jssc.2002.9626.

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39

REEHUIS, M., T. VOMHOF, and W. JEITSCHKO. "ChemInform Abstract: Magnetic Properties of UCo2P2 with CaBe2Ge2 Type Structure and LnNi2P2 (Ln: Gd-Tm) with ThCr2Si2 Type Structure." ChemInform 22, no. 28 (2010): no. http://dx.doi.org/10.1002/chin.199128018.

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40

Imre, Anette, and Albrecht Mewis. "Synthese und Kristallstrukturen von Seltenerdmetall-Antimoniden des Palladiums / Synthesis and Crystal Structures of Antimonides of Rare-Earth Metals and Palladium." Zeitschrift für Naturforschung B 61, no. 1 (2006): 17–22. http://dx.doi.org/10.1515/znb-2006-0104.

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The new compounds Pr3Pd6Sb5 (a = 13.442(3), b = 4.442(1), c = 9.994(2) Å ), Nd3Pd6Sb5 (a = 13.412(3), b = 4.431(1), c = 9.962(2) Å), and Gd3Pd6Sb5 (a = 13.293(2), b = 4.397(1), c = 9.881(2) Å) are isotypic and crystallize with the Ce3Pd6Sb5 type structure (Pmmn; Z = 2). The rare-earth metal atoms are arranged in form of three pseudo-body-centered subcells, whereas Pd and Sb atoms form a three-dimensional arrangement derived from the well-known ThCr2Si2 and CaBe2Ge2 structures. GdPdSb (a = 4.566(1), c = 7.444(1) Å) and DyPdSb (a = 4.545(1), c = 7.354(1) Å) crystallize with an ordered variant of

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41

Oledzka, M., K. V. Ramanujachary, and M. Greenblatt. "Synthesis and Characterization of New Quaternary Selenides with ThCr2Si2-Type Structure: ACuMnSe2 (A = K, Rb, Cs)." Materials Research Bulletin 33, no. 6 (1998): 855–66. http://dx.doi.org/10.1016/s0025-5408(98)00066-x.

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42

Kiselyova, N. N., O. V. Sen’ko, D. A. Kropotov, and A. A. Dokukin. "Computer-aided design of AD 2 X 2 intermetallics with a ThCr2Si2-type of crystal structure." Russian Metallurgy (Metally) 2012, no. 7 (2012): 644–53. http://dx.doi.org/10.1134/s0036029512070087.

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43

Dünner, J., and A. Mewis. "BaCu6P2 and BaCu6As2 — two compounds with a periodic intergrowth of ThCr2Si2 and Cu structure-type segments." Journal of Alloys and Compounds 221, no. 1-2 (1995): 65–69. http://dx.doi.org/10.1016/0925-8388(94)01431-0.

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44

Pfannenschmidt, Ulrike, Ute Ch Rodewald, and Rainer Pöttgen. "The Metal-rich Phosphide Ce4Ir13.55P9." Zeitschrift für Naturforschung B 66, no. 1 (2011): 7–13. http://dx.doi.org/10.1515/znb-2011-0102.

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Needle-shaped crystals of the metal-rich phosphide Ce4Ir13.55P9 were synthesized from the elements in a lead flux (starting composition 1 : 2 : 2 : 60) at 1370 K followed by slow cooling. Ce4Ir13.55P9 crystallizes with a new orthorhombic structure type: Pnma, a = 1269.1(2), b = 399.1(1), c = 3349.9(7) pm, wR2 = 0.0722, 2025 F2 values and 139 variables. Two of the 14 crystallographic iridium sites show small defects. All phosphorus atoms have slightly distorted tricapped trigonal prismatic metal coordination by cerium and iridium. The iridium and phosphorus atoms build up a threedimensional [Ir

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45

Reehuis, Manfred, and Wolfgang Jeitschko. "Structure and magnetic properties of the phosphides CaCo2P2 and LnT2P2 with ThCr2Si2 structure and LnTP with PbFCl structure (Ln = Lanthanoids, T = Fe, Co, Ni)†." Journal of Physics and Chemistry of Solids 51, no. 8 (1990): 961–68. http://dx.doi.org/10.1016/0022-3697(90)90039-i.

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46

Kawasoko, Hideyuki, Kenji Ohoyama, Ryosuke Sei, et al. "Investigation of magnetism and magnetic structure of anti-ThCr2Si2-type Tb2O2Bi by magnetization and neutron diffraction measurements." AIP Advances 9, no. 11 (2019): 115301. http://dx.doi.org/10.1063/1.5126399.

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47

Mörsen, E., B. D. Mosel, W. Müller-Warmuth, M. Reehuis, and W. Jeitschko. "Mössbauer and magnetic susceptibility investigations of strontium, lanthanum and europium transition metal phosphides with ThCr2Si2 type structure." Journal of Physics and Chemistry of Solids 49, no. 7 (1988): 785–95. http://dx.doi.org/10.1016/0022-3697(88)90030-3.

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48

Lin, Shi Dong, Xiao Long Chen, Jiang Wang, et al. "Magnetic Properties and Magnetocaloric Effect of Nd_0.7Gd_0.3Mn₂Si₂ Alloy." Advanced Materials Research 1142 (January 2017): 47–52. http://dx.doi.org/10.4028/www.scientific.net/amr.1142.47.

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In this work, crystal structure, magnetic properties and magnetocaloric effect of Nd0.7Gd0.3Mn2Si2 alloy were studied by X-ray diffraction (XRD), Physical Property Measurement System (PPMS) and Differential Scanning Calorimetry (DSC). Nd0.7Gd0.3Mn2Si2 crystallizes in ThCr2Si2-typed structure with space group I4/mmm, in which the Nd, Gd, Mn and Si atoms occupy 2a (0, 0, 0), 2a (0, 0, 0), 4d (0, 1/2, 1/4) and 4e (0, 0, 0.38261) position, respectively. The Curie temperature (Tc) of Nd0.7Gd0.3Mn2Si2 alloy is 42 K, while the spin reorientation temperature (TSR) is 26 K and the Nel temperature (TN)

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DUENNER, J., and A. MEWIS. "ChemInform Abstract: BaCu6P2 and BaCu6As2, Two Compounds with a Periodic Intergrowth of ThCr2Si2 and Cu Structure-Type Segments." ChemInform 26, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199539014.

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Vinokur, Anastasiya, and Daniel Fredrickson. "The new phase GdFe0690Si1940as a structural intermediate of GdSi2and GdFe2Si2." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1776. http://dx.doi.org/10.1107/s2053273314082230.

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Abstract:

Intermetallic phases are solid state compounds formed between metals that exhibit a wide structural variety and a myriad of important properties such as magnetism, catalysis, and superconductivity. Developing their properties requires an ability to control or guide their crystal structures, which can be wildly elaborate, involving thousands of atoms per unit cell. One principle for approaching this problem is the recognition that many of the most complex phases encountered in intermetallics can be understood in terms of fragments of simpler structures. The challenge of tailoring of intermetall

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