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Relevant bibliographies by topics / The asymmetric Mannich reaction

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Academic literature on the topic 'The asymmetric Mannich reaction'

Author: Grafiati

Published: 24 April 2022

Last updated: 30 July 2025

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Journal articles on the topic "The asymmetric Mannich reaction"

1

Singh, Girija S. "Greener Approaches to Selected Asymmetric Addition Reactions Relevant to Drug Development." Current Organic Chemistry 25, no. 13 (2021): 1497–522. http://dx.doi.org/10.2174/1385272825666210519100457.

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Asymmetric organic synthesis is of paramount importance in the development of drugs. Asymmetric addition reactions such as aldol reaction, Michael addition, and Mannich addition reactions are important carbon-carbon bond-forming reactions and have been employed in the synthesis of a broad range of biologically important molecules. Many of these reactions have been developed under solvent-free conditions or in greener solvents like water. Several reactions have been developed at room temperature or by using a non-conventional energy source such as microwave irradiation. Several greener catalyst

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2

Sodeoka, Mikiko, and Yoshitaka Hamashima. "Synthesis of optically active heterocyclic compounds using Pd-catalyzed asymmetric reactions as a key step." Pure and Applied Chemistry 80, no. 4 (2008): 763–76. http://dx.doi.org/10.1351/pac200880040763.

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Highly enantioselective Pd(II)-catalyzed Michael addition, Mannich-type reaction, aldol reaction, fluorination, conjugate addition of amine, and conjugate reduction have been developed. Asymmetric synthesis of biologically interesting heterocyclic compounds, calycotomine, BMS-204352, torcetrapib, and warfarin, was achieved by using these Pd-catalyzed asymmetric reactions as a key step.

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Lee, Hyo-Jun, Natarajan Arumugam, Abdulrahman Almansour, Raju Kumar, and Keiji Maruoka. "Design of New Amino Tf-Amide Organocatalysts: Environmentally Benign Approach to Asymmetric Aldol Synthesis." Synlett 30, no. 04 (2018): 401–4. http://dx.doi.org/10.1055/s-0037-1610408.

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A new type of optically pure primary amino aromatic Tf-amide organocatalyst can be easily prepared from 8-amino-1-tetralone, and its chemical behavior was investigated in the context of asymmetric aldol and Mannich reactions. Most notably, the asymmetric aldol reaction proceeded smoothly in brine.

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Bagheri, Ilnaz, Leila Mohammadi, Vahideh Zadsirjan, and Majid M. Heravi. "Organocatalyzed Asymmetric Mannich Reaction: An Update." ChemistrySelect 6, no. 5 (2021): 1008–66. http://dx.doi.org/10.1002/slct.202003034.

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Córdova, Armando. "The Direct Catalytic Asymmetric Mannich Reaction." Accounts of Chemical Research 37, no. 2 (2004): 102–12. http://dx.doi.org/10.1021/ar030231l.

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Dudek, Agata, and Jacek Mlynarski. "Iron-Catalyzed Asymmetric Nitro-Mannich Reaction." Journal of Organic Chemistry 82, no. 20 (2017): 11218–24. http://dx.doi.org/10.1021/acs.joc.7b01786.

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Chen, Jianfeng, Xing Gong, Jianyu Li, et al. "Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction." Science 360, no. 6396 (2018): 1438–42. http://dx.doi.org/10.1126/science.aat4210.

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Chiral amines are widely used as catalysts in asymmetric synthesis to activate carbonyl groups for α-functionalization. Carbonyl catalysis reverses that strategy by using a carbonyl group to activate a primary amine. Inspired by biological carbonyl catalysis, which is exemplified by reactions of pyridoxal-dependent enzymes, we developed an N-quaternized pyridoxal catalyst for the asymmetric Mannich reaction of glycinate with aryl N-diphenylphosphinyl imines. The catalyst exhibits high activity and stereoselectivity, likely enabled by enzyme-like cooperative bifunctional activation of the subst

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Nomura, Miku, Zubeda Begum, Chigusa Seki та ін. "Thiourea fused γ-amino alcohol organocatalysts for asymmetric Mannich reaction of β-keto active methylene compounds with imines". RSC Advances 13, № 6 (2023): 3715–22. http://dx.doi.org/10.1039/d2ra08317e.

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Catalytic functionality of new optically active thiourea fused γ-amino alcohols was examined in the asymmetric Mannich reaction of β-keto active methylene compounds with imines to afford chiral Mannich products, β-amino keto compounds..

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Rachwalski, Michał, Aleksandra Buchcic-Szychowska, and Stanisław Leśniak. "Recent Advances in Selected Asymmetric Reactions Promoted by Chiral Catalysts: Cyclopropanations, Friedel–Crafts, Mannich, Michael and Other Zinc-Mediated Processes—An Update." Symmetry 13, no. 10 (2021): 1762. http://dx.doi.org/10.3390/sym13101762.

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The main purpose of this review article is to present selected asymmetric synthesis reactions in which chemical and stereochemical outcomes are dependent on the use of an appropriate chiral catalyst. Optically pure or enantiomerically enriched products of such transformations may find further applications in various fields. Among an extremely wide variety of asymmetric reactions catalyzed by chiral systems, we are interested in: asymmetric cyclopropanation, Friedel–Crafts reaction, Mannich and Michael reaction, and other stereoselective processes conducted in the presence of zinc ions. This pa

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Yoshida, Yasushi, Maho Aono, Takashi Mino та Masami Sakamoto. "Asymmetric synthesis of β-amino cyanoesters with contiguous tetrasubstituted carbon centers by halogen-bonding catalysis with chiral halonium salt". Beilstein Journal of Organic Chemistry 21 (12 березня 2025): 547–55. https://doi.org/10.3762/bjoc.21.43.

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β-Amino cyanoesters are important scaffolds because they can be transformed into useful chiral amines, amino acids, and amino alcohols. Halogen bonding, which can be formed between halogen atoms and electron-rich chemical species, is attractive because of its unique interaction in organic synthesis. Chiral halonium salts have been found to have strong halogen-bonding-donor abilities and work as powerful asymmetric catalysts. Recently, we have developed binaphthyl-based chiral halonium salts and applied them in several enantioselective reactions, which formed the corresponding products in high

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Dissertations / Theses on the topic "The asymmetric Mannich reaction"

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Howell, Gareth P. "A general, asymmetric nitro-Mannich reaction for the synthesis of 1,2-diamines." Thesis, University of Nottingham, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.416417.

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Yeste, Sonia Lozano. "Boron-BINOL catalysed asymmetric Mannich and aldol type reaction : novel boronate esters." Thesis, University of Bath, 2007. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.516904.

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McLaren, Andrew B. "Studies towards asymmetric aziridine synthesis via aza-darzens reaction of (2S)-N-bromoacyl camphorsultam." Thesis, University of Reading, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.340028.

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Rowland, Emily Bretherick. "Enantioselective Brønsted Acid-Catalyzed Reaction Methodology Part A: Enantioselective Mannich Reaction Part B: Enantioselective Desymmetrization of meso-Aziridines." [Tampa, Fla] : University of South Florida, 2008. http://purl.fcla.edu/usf/dc/et/SFE0002613.

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Homma, Chihiro. "Development of Amine-Catalyzed Asymmetric Reactions of Aldehydes with Alkynyl Z-Ketimines." Doctoral thesis, Kyoto University, 2021. http://hdl.handle.net/2433/263497.

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Bibi, Ahtaram [Verfasser]. "Primary Amine Containing Bifunctional Catalysts for Asymmetric Aldol and Mannich Reactions / Ahtaram Bibi." Bremen : IRC-Library, Information Resource Center der Jacobs University Bremen, 2012. http://d-nb.info/1035220229/34.

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Fini, Francesco <1979&gt. "Organocatalytic asymmetric mannich-type reactions: an easy approach to optically active amine derivatives." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2008. http://amsdottorato.unibo.it/1047/1/Tesi_Fini_Francesco.pdf.

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The topics I came across during the period I spent as a Ph.D. student are mainly two. The first concerns new organocatalytic protocols for Mannich-type reactions mediated by Cinchona alkaloids derivatives (Scheme I, left); the second topic, instead, regards the study of a new approach towards the enantioselective total synthesis of Aspirochlorine, a potent gliotoxin that recent studies indicate as a highly selective and active agent against fungi (Scheme I, right). At the beginning of 2005 I had the chance to join the group of Prof. Alfredo Ricci at the Department of Organic Chemistry of

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Fini, Francesco <1979&gt. "Organocatalytic asymmetric mannich-type reactions: an easy approach to optically active amine derivatives." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2008. http://amsdottorato.unibo.it/1047/.

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The topics I came across during the period I spent as a Ph.D. student are mainly two. The first concerns new organocatalytic protocols for Mannich-type reactions mediated by Cinchona alkaloids derivatives (Scheme I, left); the second topic, instead, regards the study of a new approach towards the enantioselective total synthesis of Aspirochlorine, a potent gliotoxin that recent studies indicate as a highly selective and active agent against fungi (Scheme I, right). At the beginning of 2005 I had the chance to join the group of Prof. Alfredo Ricci at the Department of Organic Chemistry of

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Sakamoto, Ryu. "Development of Amine-catalyzed Asymmetric Reactions Using Hetero-functionalized Acetaldehydes as Nucleophiles." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/188503.

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Plas, Aurélie. "Synthèse stéréosélective de bispidines : vers la conception de nouvelles molécules antalgiques." Phd thesis, Université Blaise Pascal - Clermont-Ferrand II, 2011. http://tel.archives-ouvertes.fr/tel-00683624.

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Les bispidines sont des diamines polycycliques chirales régulièrement utilisées comme ligand pour réaliser de l'induction asymétrique. La bispidine HZ2 est connue pour être agoniste et sélective des récepteurs κ-opioïdes, récepteurs impliqués dans le mécanisme douloureux. Ce travail décrit la mise au point d'une méthode générale de synthèse asymétrique et flexible du squelette bispidine, permettant des modifications structurales, afin d'évaluer le potentiel pharmacologique des analogues synthétisés. Tout d'abord, nous avons synthétisé des pipéridines 2,3,6-trisubstituées grâce à une réaction d

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Books on the topic "The asymmetric Mannich reaction"

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Mahrwald, Rainer. Enantioselective Organocatalyzed Reactions II: Asymmetric C-C Bond Formation Processes. Springer Science+Business Media B.V., 2011.

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Teerawutgulrag, Aphiwat. Asymmetric induction in Lewis acid promoted reaction of some d- and e-(Alkyloxyallyl)stannanes and aldehydes. University of Manchester, 1993.

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Mahrwald, Rainer. Enantioselective Organocatalyzed Reactions I: Enantioselective Oxidation, Reduction, Functionalization and Desymmetrization. Springer Science+Business Media B.V., 2011.

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Theoretical Studies in the Mannich Reaction. Creative Media Partners, LLC, 2011.

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Theoretical Studies in the Mannich Reaction. Creative Media Partners, LLC, 2023.

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Fernandez, Jack E. Theoretical Studies in the Mannich Reaction. Creative Media Partners, LLC, 2018.

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Theoretical Studies in the Mannich Reaction. Creative Media Partners, LLC, 2023.

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Theoretical Studies in the Mannich Reaction. Creative Media Partners, LLC, 2015.

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9

Papageorgiou, George. Aspects of the chemistry of the Mannich reaction. 1990.

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10

Kawasaki, Tsuneomi, Kenso Soai, and Arimasa Matsumoto. Asymmetric Autocatalysis: The Soai Reaction. Royal Society of Chemistry, The, 2022.

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Book chapters on the topic "The asymmetric Mannich reaction"

1

Hoekman, Steven, Jorge M. M. Verkade, and Floris P. J. T. Rutjes. "Organocatalyzed Asymmetric Mannich Reactions." In Enantioselective Organocatalyzed Reactions II. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-90-481-3867-8_5.

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Córdova, Armando. "Examples of Metal-Free Direct Catalytic Asymmetric Mannich-Type Reactions Using Aminocatalysis." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch04.

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3

Tsubogo, Tetsu, Yasuhiro Yamashita, and Shū Kobayashi. "Chiral Ca-, Sr-, and Ba-Catalyzed Asymmetric Direct-Type Aldol, Michael, Mannich, and Related Reactions." In Alkaline-Earth Metal Compounds. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-36270-5_7.

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4

Li, Jie Jack. "Mannich reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_183.

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Gooch, Jan W. "Mannich Reaction." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_7176.

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Li, Jie Jack. "Mannich reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_162.

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Li, Jie Jack. "Mannich reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_172.

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Li, Jie Jack. "Mannich reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_150.

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Li, Jie Jack. "Mannich Reaction." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_87.

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Nakagawa, Kazumichi. "Asymmetric Reaction, Absolute." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-27833-4_6-2.

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Conference papers on the topic "The asymmetric Mannich reaction"

1

Pinappu, Sai Reddy, Kwadwo Sarpong, Corina Sandu, and Zhenning Gu. "Fast On-Site Quantification and Monitoring of Monoethanolamine in Crude Oils Using Field Asymmetric Ion Mobility Spectrometry." In CORROSION 2015. NACE International, 2015. https://doi.org/10.5006/c2015-05630.

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Abstract Triazine-based hydrogen sulfide (H2S) scavengers are the most commonly used additives in the oil and gas industry. One of the reaction products of the scavenging process is an organic amine. The organic amine by-product, together with amines in slop oil and the desalter wash water, are collectively referred to as “tramp amines.” The most-common tramp amines from the H2S scavenging process are mono-ethanolamine (MEA) and methylamine (MA). These tramp amines have the potential to react with hydrochloric acid (HCl) to form corrosive amine hydrochloride salts in the crude atmospheric dist

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Fiorot, R. G., J. F. Allochio Filho, S. G. Greco, V. Lacerda Jr., R. B. dos Santos, and E. V. R. de Castro. "Multicomponent catalytic Mannich Reaction: a methodological study with lawsone." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013915222817.

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Naimi-Jamal, Mohammad, Ali Sharifi, and Amene Yaghoubi. "One-pot three-component Mannich-type reaction catalyzed by functionalized ionic liquid." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00458.

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Aftrid, Zera Helga Vuvida Irgani, and Antonius Herry Cahyana. "Synthesis of carbazole derivative compound with the Mannich reaction and antioxidant activity." In THE 2ND UNIVERSITAS LAMPUNG INTERNATIONAL CONFERENCE ON SCIENCE, TECHNOLOGY, AND ENVIRONMENT (ULICoSTE) 2021. AIP Publishing, 2022. http://dx.doi.org/10.1063/5.0104131.

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Gonçalves, Vanessa P., Rodrigo M. S. Justo, and Giovanni W. Amarante. "Chiral Brønsted Acid Catalyzed Highly Stereoselective Mannich-type reaction of Azlactone with Aldimines." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_20139216537.

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Yousif, Ola B., Dhafer S. Zinad, M. S. Ali, and Ayad Tariq Mahmood. "Synthesis and antibacterial screening of novel benzene sulfonamide derivatives through multicomponent Mannich reaction." In 4TH INTERNATIONAL CONFERENCE ON INNOVATION IN IOT, ROBOTICS AND AUTOMATION (IIRA 4.0). AIP Publishing, 2025. https://doi.org/10.1063/5.0255227.

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Naimi-Jamal, Mohammad Reza, razieh davoudvandi, and Leila Panahi. "CMC Catalyzed Multicomponent Mannich Reaction for Synthesis of Lawsone Family Pigments." In The 20th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-a002.

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Dotsenko, Victor, Elena Chigorina, Ivan Bushmarinov, Alexander Goloveshkin, and Sergey Krivokolysko. "Mannich-type reaction of tetrahydropyridine-2-thiolates with primary amines and α-substituted propanals." In The 20th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-a061.

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Alegre-Requena, Juan Vicente, Raquel P. Herrera, Isaac G. Sonsona, Eugenia Marqués-López, and M. Concepción Gimeno. "Asymmetric aza-Henry reaction of hydrazones." In The 24th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2020. http://dx.doi.org/10.3390/ecsoc-24-08411.

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Carmona, Rafaela C., and Carlos Roque D. Correia. "Asymmetric Arylation of Indenes via Heck-Matsuda Reaction." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201381992939.

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