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Dissertations / Theses on the topic 'The Photochemistry Of 4-Aminophenylazides'

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1

Voskresenska, Valentyna D. "Photoaffinity Labeling Via Nitrenium Ion Chemistry: The Photochemistry of 4-aminophenylazides." Bowling Green State University / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1293135363.

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2

Cowley, Nicholas John. "The mechanistic photochemistry of 4-hydroxybenzophenone." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq20620.pdf.

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3

Durand, Anne Pascale Yvette. "The aqueous photochemistry of 4-chlorophenol." Thesis, University of Central Lancashire, 1994. http://clok.uclan.ac.uk/19058/.

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The photochemistry of 4-chlorophenol has been studied in aqueous solution as a function of pH, 4-chiorophenol concentration and oxygen concentration. Solutions of 4-chlorophenol in the concentration range around 5 x 10-4 mol dm-3 have been photolysed by being subjected to a series of microsecond white light flashes and the result of the photolysis analysed by HPLC. In aerated solution, para-benzoquinone is the main photoproduct together with smaller amounts of para-hydroquinone and 2-hydroxy-1,4-benzoquinone. The latter is found to be the dominant photoproduct at pH values above the pKa of 4-c
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4

Hostetler, Katherine J. "The photochemistry and 1,3-dipolar cycloadditions of 4-azidopyridine-N-oxide." Virtual Press, 2005. http://liblink.bsu.edu/uhtbin/catkey/1328115.

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We have investigated the chemistry of 4-azidopyridine-N-oxide. One aspect of this thesis involved the photolysis of this azido heteroaromatic-N-oxide, to generate highly reactive nitrene intermediates. We have studied these intermediates and determined that the intermediates vary significantly in structure and reactivity from those of simpler phenyl and pyridyl systems. This study yields new insight into the structure, bonding, and energetics of nitrene species.The nitrene intermediate originating from this azide has features which could in the future help in synthetic practices and photoaffin
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5

Borg, Anders. "Theoretical Photochemistry : Halogenated Arenes, Phytochromobilin, Ru(II)polypyridyl complexes and 6-4 photoadducts." Doctoral thesis, Uppsala universitet, Kvantkemi, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-8469.

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This thesis presents Quantum Chemical calculations on the Photochemistry of Halogenated benzenes, Phytochromobilin, Ruthenium Polypyridyl complexes and 6-4 photoadducts in DNA. The work is focused on improving the understanding of a number of experimentally observed photochemical processes in these systems. New results regarding the mechanism of photodissociation of halogenated arenes, photointerconversion of phytochromobilin are presented, as well as of the photoprocesses of Ruthenium Polypyridyl complexes and new mechanistic insights in the repair of 6-4 photoadducts in DNA.
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6

Moiseev, Andrey G. "Synthesis and photochemistry 3,5-dialkyl-3,5-dihydro--3,5-diphenyl-4H-pyrazol-4-ones." Bowling Green, Ohio : Bowling Green State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=bgsu1134948701.

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7

Dixon, Stephen R. "Studies on the photochemistry of 2-dimethylamino-5,6-dimethypyimidin-4-OL and related compounds." Thesis, Kingston University, 1985. http://eprints.kingston.ac.uk/20498/.

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8

Cohen, Terry Suzanne. "Synthesis and photophysics of 3, 4, 9, 10 perylene tetracarboxylic diimide dendrimers /." Full text (PDF) from UMI/Dissertation Abstracts International, 2000. http://wwwlib.umi.com/cr/utexas/fullcit?p3004240.

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9

Chan, Kwok-wai Queenie. "Synthesis and photophysical properties of oligo (arylene-ethynylene)s, osmium(II) diimine and platinum(II) calix[4] arene complexes and their applications as sensory materials." Click to view the E-thesis via HKUTO, 2008. http://sunzi.lib.hku.hk/hkuto/record/B40988107.

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10

Chan, Kwok-wai Queenie, and 陳幗慧. "Synthesis and photophysical properties of oligo (arylene-ethynylene)s,osmium(II) diimine and platinum(II) calix[4] arene complexes and theirapplications as sensory materials." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2008. http://hub.hku.hk/bib/B40988107.

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11

Chhabra, Radhika. "Photochemistry and bio-evaluation of 1, 4- disubstituted tetrazolethiones and synthesis of 2-(2-(phenylimino) vinyl)benzonitrile." Thesis, Manhattan, Kan. : Kansas State University, 2007. http://hdl.handle.net/2097/525.

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12

Sturley, Garry Graham. "Photochemistry of 3,3',4',5 - tetrachlorosalicylanilide and 3,4',5 - tribromosalicylanilide and their interactions with human serum albumin." Thesis, Loughborough University, 1998. https://dspace.lboro.ac.uk/2134/25614.

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Many substituted salicylanilides, particularly halogenated salicylanilides have strong anti-bacterial properties and in the past have been employed as bactericides in soaps. However, this has led to photoallergy causing serious adverse skin reactions. Although most photoallergens will elicit a response in only a small fraction of the people exposed 3,3',4',5-tetrachlorosalicylanilide (T₄CS-H) is unusual in inducing photoallergy in a high fraction of those exposed and displays a high specificity towards serum albumin. The proposed mechanism of the protein-photoallergen binding is thought to pro
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13

Derstine, Brenden Paul. "PHOTOCHEMICAL AND TITANIUM (II) MEDIATED METHODS FOR THE SYNTHESIS OF COMPLEX MOLECULAR SCAFFOLDS." Diss., Temple University Libraries, 2018. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/497266.

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Chemistry<br>Ph.D.<br>Development of therapeutics is an extensive process, consuming significant amounts of time and requiring herculean synthetic efforts. A new therapeutic is most often designed from a previously commercialized scaffold, to increase the chance of success. Designing new molecular scaffolds can be extremely high risk and time consuming, yet at the same time the reward can be substantial. Accessing new molecular scaffolds, with efficient and “green” methods, is important in modern medicinal chemistry to diversify chemical space for therapeutic targets. There may be significant
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14

Holanda, Alda Karine Medeiros. "SÃntese, caracterizaÃÃo e estudo da liberaÃÃo fotoquÃmica de Ãxido nÃtrico por nitrosilo complexos de Ru e Fe e pelo composto [cyclam(NO)4]." Universidade Federal do CearÃ, 2006. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=1343.

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Conselho Nacional de Desenvolvimento CientÃfico e TecnolÃgico<br>Neste trabalho à apresentada a sÃntese, caracterizaÃÃo e o estudo da liberaÃÃo fotoquÃmica de Ãxido nÃtrico pelos nitrosilo complexos trans-[Fe(cyclam)(NO+)Cl]Cl2 e trans-[Ru(NH3)4L(NO)]Cl3, onde L=Imidazol, Benzoimidazol, CafeÃna e Teofileno, bem como pelo novo composto [cyclam(NO)4]. AtravÃs de uma nova rota sintÃtica, obteve-se o composto trans-[Fe(cyclam)(NO+)Cl]Cl2, o qual apresenta o ligante Ãxido nÃtrico coordenado ao Ãtomo de ferro na sua forma linear (NO+), &#957;NO=1888 cm-1, com um Ãngulo de ligaÃÃo Fe-NO igual a 177,4
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15

Wu, Yanlin. "Application of Fe(III)-EDDS complex in advanced oxidation processes : 4-ter-butylphenol degradation." Thesis, Clermont-Ferrand 2, 2014. http://www.theses.fr/2014CLF22455/document.

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Dans cette étude, un nouveau complexe de fer est utilisé dans des processus d’oxydation avancée pour la dégradation de polluants organiques présents dans l’eau. Le fer ferrique (Fe(III)) et l’acide éthylène diamine-N,N’-disuccinique (EDDS) forment un complexe Fe(III)-EDDS dont la structure a été mise en évidence durant ce travail. Les propriétés photochimiques du complexe ont ensuite été évaluées en fonction de différents paramètres physico-chimiques dont le pH qui est apparu comme un paramètre clé pour l’efficacité des processus testés. Ensuite nous avons donc travaillé sur l’utilisation de c
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16

Casale, Mariana Romano Camilo. "Desenvolvimento de processos químicos seguindo os princípios adotados pela química verde: redução e conversão de CO2 usando compostos de Mn(I)." Universidade Federal de São Carlos, 2014. https://repositorio.ufscar.br/handle/ufscar/6319.

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Made available in DSpace on 2016-06-02T20:34:56Z (GMT). No. of bitstreams: 1 6264.pdf: 6241491 bytes, checksum: c10b9312872f17d86e9c24ccd25b2508 (MD5) Previous issue date: 2014-10-09<br>Universidade Federal de Minas Gerais<br>Due to its versatile chemistry and ability to stabilize metals with low oxidation states, carbonyl compounds of transition metals play an important role in various fields of organometallic chemistry. In our research group, we have studied carbonyl compounds of manganese (I) over time and investigated their photochemical and spectroscopic properties. We carried out studi
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17

Yao-Ming, He, and 何曜名. "Synthesis and study on photochemistry of 4, 4-dimethoxy -5-(4-substituted phenyl)-cyclohex-2-enones." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/58314252506879507911.

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碩士<br>臺北市立教育大學<br>自然科學系碩士班<br>99<br>This thesis deals with the synthesis of 4, 4-dimethoxy-5-(4-substituted- phenyl)-cyclohex-2-enones 58, 59, 60 via 1, 4-addition of Grignard reagents to 4, 4-dimethoxycyclohexa-2, 5-dienone 46. These compounds 58, 59, 60 are irradiated in trifluoroethanol (0.01M) with light of 352 nm to give cyclopentanone derivatives 61, 62, 63, 64, 66, 67. However, irradiation of 4, 4-dimethoxy- 5- (4-methoxyphenyl)-cyclohex-2-enone60 gives a mixture cyclobutanone derivative 65a+65b as well.
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18

Tantillo, Anthony William. "The photochemistry of 3-hydroxy-1, 4-pentadiene derivatives." 1987. http://catalog.hathitrust.org/api/volumes/oclc/18089547.html.

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19

沈純琦. "Synthesis and Photochemistry of 1-Benzyl-4, 5, 6-trihydroindazole." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/73950895240195778958.

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碩士<br>靜宜大學<br>應用化學研究所<br>85<br>Direct photolysis of the l-benzyl-4,5,6-trihydromdazole (21b) in acetonitrile produces 2-benzyl-4,5,6-trihydroindazole (22b, 2.6%), 4,5,6-trihydroindazole (24, 2.5%), and compound 28 (1.3%) respectively. The mechanism of this reaction is suggested that the first step is the C-N bond cleavage into the two radical species, 24a and 24b. Then the radical 24a can be in the resonance form of 24c and the consequence of the reaction of the diradicals 24c and 24b, the 2-benzyl-4,5,6-trihydroindazole (22b) can be formed. On the other hand if the hydrogen atom abstrac
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20

Chang, Ya-Ho, and 張雅合. "Studies on the photochemistry andthe fluorescence sensing behavior of trans-4-aminomethylstilbene derivative." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/04166370716876759447.

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碩士<br>國立中央大學<br>化學研究所<br>93<br>This thesis reports the synthesis and fluorescence properties of three compounds series (1-3). We are particularly interested in the structural dependence of dual fluorescence behavior of 1-3 in polar solvents. Because of the ionophoric nature of the dipyridylamino (dpa) group in 2OMe, 2CN, 3H and 3CN, their fluoroionophoric behavior was also investigated. The fluorescence spectra of 1EE as well as 1OMe, 2CN, and 3CN show dual fluorescence in acetonitrile, which indicates that both arylamino and alkylamino electron donors can lead to intramolecular charge transf
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21

St, Clair Jerry Dale. "Electronic and steric control of photochemical migratory aptitudes the photochemistry of 4-(1-naphthyl)-4-(2-naphthyl)-2-cyclohexenone /." 1988. http://catalog.hathitrust.org/api/volumes/oclc/19586851.html.

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22

Moses, Julianne Ives. "I. Phase Transformations and the Spectral Reflectance of Solid Sulfur: Possible Metastable Sulfur Allotropes on Io's Surface. II. Photochemistry and Aerosol Formation in Neptune's Atmosphere." Thesis, 1991. https://thesis.library.caltech.edu/2993/4/Moses_ji_1991.pdf.

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<p>This thesis consists of two independent papers:</p> <p>PAPER I:</p> <p>The spectral reflectance of elemental sulfur is examined in a set of laboratory experiments to determine the factors that affect the transformation rate of monoclinic (β) sulfur and various other sulfur allotropes into orthorhombic (α) sulfur. The laboratory data have implications for the spectral variation and physical behavior of freshly solidified sulfur, if any exists, on Jupiter's satellite Io. Depending on its thermal history, molten sulfur on Io would initially solidify into a glassy solid or a monoclinic cr
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23

Chen, Yu-Jen, and 陳俞臻. "(1) Temperature and Matrix Effects Dependence on the Triplet Radical Pairs Generated from Photolysis of N-Tosylpyrrole Derivatives, (2) Photochemistry of Heteroaromatic Fused ??-1,2,3-Triazoline Derivatives, (3) Application of Tetrazole Modified Calix[4]a." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/54411936287525538177.

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博士<br>國立交通大學<br>應用化學研究所<br>98<br>In part 1, the photolysis (230-325 nm) of N-tosyl pyrrole 37, 2-phenyl-N-tosyl pyrrole 72, 2,5-diphenyl-N-tosyl pyrrole 73, and N-(2-naphthyl)-sulfonyl pyrrole 75 in a 2-methyltetrahydrofuran glassy matrix at 4 K gives electron paramagnetic resonance (EPR) spectra with triplet characteristics; the zero-field-splitting (zfs) parameters D' for the corresponding radical pairs (RPs) 93, 94, 95, and 96 are 0.0239, 0.0190, 0.0174, and 0.0241 cm-1, respectively. Irradiation of 37 at RT allows the isolation of two rearranged products 38 and 39 and a polymeric material
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