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Dissertations / Theses on the topic 'The photochemistry of aryl azides'

Author: Grafiati

Published: 4 June 2021

Last updated: 9 February 2022

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1

Leyva-Ramos, Elisa. "The temperature dependent photochemistry of aryl azides and aryl diazo compounds /." The Ohio State University, 1986. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487267024997622.

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2

Zhai, Hongbin. "Exploratory photochemistry of polyfluorinated aryl azides in neutral and acidic media /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487864986612072.

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3

Panov, Maxim S. "Early Events in Photochemistry of Aryl Azides Used as Photoaffinity Labeling Agents." Bowling Green State University / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1321571677.

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4

Li, Qian. "Characterizing triplet azo biradical and corannulene- halogen complexes by laser flash photolysis." University of Cincinnati / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1352403404.

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5

Jadhav, Abhijit V. "Crosslinking of polyaniline with aryl azides and the photolysis of vinyl azides and azidopropanones." University of Cincinnati / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1204666531.

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6

Porter, Thomas Carl. "Studies in the chemistry of #omicron#-substituted aryl-azides." Thesis, University of Salford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308217.

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7

Stocker, A. W. "The synthesis of heterocycles by assisted decomposition of aryl azides." Thesis, University of Salford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.353977.

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8

Hostetler, Katherine J. "The photochemistry and 1,3-dipolar cycloadditions of 4-azidopyridine-N-oxide." Virtual Press, 2005. http://liblink.bsu.edu/uhtbin/catkey/1328115.

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We have investigated the chemistry of 4-azidopyridine-N-oxide. One aspect of this thesis involved the photolysis of this azido heteroaromatic-N-oxide, to generate highly reactive nitrene intermediates. We have studied these intermediates and determined that the intermediates vary significantly in structure and reactivity from those of simpler phenyl and pyridyl systems. This study yields new insight into the structure, bonding, and energetics of nitrene species.The nitrene intermediate originating from this azide has features which could in the future help in synthetic practices and photoaffin

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9

Klima, Rodney F. "Triplet Alkyl Nitrene Intermediates: Photolysis of Alkyl Azides with Intermolecular and Intramolecular Triplet Sensitization." Cincinnati, Ohio : University of Cincinnati, 2004. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=ucin1100710601.

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10

Shields, Dylan J. "Photochemistry of Organic Azides, Quinones, and Peroxides in Solution, Crystals, Super Molecular Complexes and Cryogenic Matrices." University of Cincinnati / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=ucin157441745178423.

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11

Gatlin, DeVonna M. M. S. "Characterization and Photodynamics of Reactive Intermediates for Various Carbonyl-Based Systems: Alkyl Azides, Vinyl Azides, and Beta-Ketoester Moieties." University of Cincinnati / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1535380770508755.

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12

Payton, John L. PhD. "The Photophysical Behavior of Aryl-diphosphenes and Aryl-phosphaalkenes: A Theoretical Study." Cleveland, Ohio : Case Western Reserve University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=case1270488297.

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Thesis (Doctor of Philosophy)--Case Western Reserve University, 2010<br>Department of Chemistry Title from PDF (viewed on 2010-05-25) Includes abstract Includes bibliographical references and appendices Available online via the OhioLINK ETD Center

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13

Mandel, Sarah M. "Photolysis of alkyl azides containing an aryl ketone chromophore in solution and the solid state." Cincinnati, Ohio : University of Cincinnati, 2004. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=ucin1099539420.

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14

Mandel, Sarah Marie. "Photolysis of Alkyl Azides Containing an Aryl Ketone Chromophore in Solution and the Solid-state." University of Cincinnati / OhioLINK, 2004. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1099539420.

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15

Barcus, Robert L. "Kinetic studies of Aryl carbenes and nitrile ylids by laser flash photolysis /." The Ohio State University, 1985. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487262825076232.

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16

Banerjee, Upasana. "Mechanistic Investigations into the Photoreactivity of Organic Azides in Solution, Crystals and Cryogenic Matrices." University of Cincinnati / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1623250627543686.

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17

Ong, Shing-yau, and 王承祐. "Time-resolved resonance raman investigation of selected arylnitrenes and their reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B31227740.

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18

Thenna, Hewa Kosala R. S. "Applications Focused Synthetic Modification on Photoremovable Protecting Groups (PRPG) & Photochemical Analysis on Organic Azides and Isoxazoles." University of Cincinnati / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1511858669354976.

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19

Xue, Jiadan, and 薛佳丹. "Time-resolved resonance raman and density functional theory studies ofselected arylnitrenium ions and their reactions with guanosinederivatives and aryl azides." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2008. http://hub.hku.hk/bib/B41290914.

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20

Osisioma, Onyinye. "Understanding the Factors That Control Increased Photo-reactivity and Selectivity Of Vinylic And Aromatic Azides." University of Cincinnati / OhioLINK, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1595848489564813.

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21

Xue, Jiadan. "Time-resolved resonance raman and density functional theory studies of selected arylnitrenium ions and their reactions with guanosine derivatives and aryl azides." Click to view the E-thesis via HKUTO, 2008. http://sunzi.lib.hku.hk/hkuto/record/B41290914.

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22

Xie, Sheng. "Perfluroaryl azides : Reactivities, Unique Reactions and their Applications in the Synthesis of Theranostic Agents." Doctoral thesis, KTH, Organisk kemi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-172950.

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The work centersaround perfluoroaryl azides (PFAAs), and theirability to undergo certain fast and robusttransformations. The chemistry was furtherappliedfor biomedical applications. The first section focuses on the azide-aldehyde-amine cycloaddition using PFAAs. Experimental and computational investigations uncovered a fast azide-enamine cycloaddition to form triazolines, which spontaneously rearrange into stable amidine products. In addition, this transformation was explored in the formulation of pure nanodrugs. Because this reaction can introduce a phenyl and a perfluoroaryl moiety enabling

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23

Heiden, Arthur Paul van der. "Polymeric biomaterials with phosphorylcholine groups at the surface on the photochemical surface modification of polyurethanes using aryl azides with a phosphorylcholine endgroup to improve hemocompatibility /." Maastricht : Maastricht : Universiteit Maastricht ; University Library, Maastricht University [Host], 1998. http://arno.unimaas.nl/show.cgi?fid=6054.

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24

Liu, Shwu-Huey. "Part I. Photoaffinity labeling of chymotrypsin with polyfluorinated aryl azides ; Part II. The determination of dextran average chain length and bonding specificity during dextransucrase catalyzed formation of dextran /." The Ohio State University, 1990. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487685204968245.

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25

Polshakov, Dmitrii Arkadyevich. "Ultrafast spectroscopy and dynamics of nitrenes and carbenes." Columbus, Ohio : Ohio State University, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1130968887.

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26

Weigand, Kevin, Neeraj Singh, Manfred Hagedorn, and Klaus Banert. "Direct observation and characterisation of 3-azido-2H-azirines: postulated, but highly elusive intermediates." Universitätsbibliothek Chemnitz, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-222768.

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For the first time, successful synthesis of an unknown class of compounds, 3-azido-2H-azirines, which are implicated as highly reactive intermediates in the thermolysis of the corresponding 1,1-diazidoethenes, has been performed. These elusive heterocycles have been detected and characterised by low-temperature NMR and in situ IR spectroscopy. Even the parent compound, 3-azido-2H-azirine, has been observed via low-temperature photolysis of 1,1-diazidoethene, as a highly reactive species with a half-life period of only 12 min at −40 °C<br>Dieser Beitrag ist aufgrund einer (DFG-geförderten) Alli

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27

Kerbal, Abdelali. "Cycloaddition de diarylnitrilimines et d'azides sur diverses énones et énamines dérivées d'indadones et de tétralones : Regiochimie, diasteréochimie et transformation des cycloadduits." Besançon, 1988. http://www.theses.fr/1988BESA2038.

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La cycloaddition dipolaire-1,3 des diarylnitrilimines sur diverses enones a double-liaison dipolarophile juxtacyclique est regiospecifique. Lorsque le dipolarophile présente deux faces diastereotopiques, l'approche dipole-dipolarographie se fait du côté le moins encombré : - de façon diastereospecifique sur les enones dérivées de l'indanone-1 substituée ou de la tetralone-1 substituée lorsque ces dernières portent en -3 ou -4 un substituant occupant une position axiale - de facon diastereoselective sur les enones dérivées de la tetralone-1 portant un substituant en -4 qui peut adopter une disp

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28

Luo, Yun-Wen, and 羅云彣. "Surface Photochemical Synthesis of Azoarenes from Aryl Azides." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/w8dz55.

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碩士<br>國立中山大學<br>化學系研究所<br>106<br>Thermal, photochemical and metal-facilitated routes to aryl nitrenes via the extrusion of dinitrogen from 4-methoxyphenyl azide adsorbed on a single crystal Cu(100) surface have been investigated using reflection-absorption infrared spectroscopy and temperature-programmed desorption in ultrahigh high vacuum. Only by irradiation with UV light can an N=N double bond be made, rendering azoarene. The azido precursors are transparent to the 365 nm and 405 nm photons employed in our experiments; therefore, the observed wavelength-dependent N-N2 bond dissociation rate

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29

Nuss, John Mark. "Photochemical 1,4 aryl migrations ; Photochemistry of 1,1,3,3-tetraarylpropene derivatives." 1986. http://catalog.hathitrust.org/api/volumes/oclc/14367499.html.

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30

Wang, Keyan. "Asymmetric induction in the photochemistry of α-oxoamides and bicycle aryl ketones". Thesis, 2004. http://hdl.handle.net/2429/16152.

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Enantioselective photochemical synthesis of a β-lactam (methyl 4-[3-hydroxy-2,2- dimethyl-l-(l-methylethyl)-4-oxo-3-azetidinyl]benzoate) was investigated via the ionic chiral auxiliary method. Solid state photolysis of the chiral salts formed from optically pure amines and the achiral α-oxoamide reactant containing a carboxylic acid functional group gave variable results, but through the use of a number of auxiliaries it was possible to achieve a high degree of enantioselectivity in the β-lactam (up to 99 % ee at 99 % conversion of the starting α-oxoamide). Suspension of the prolinamide

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31

Senapati, Dulal. "Photodissociation Dynamics Of Mixed Halogenated Alkyl And Aryl Halides." Thesis, 2004. http://etd.iisc.ernet.in/handle/2005/1221.

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32

張瓅心. "Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/26605075301300238627.

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碩士<br>臺北市立教育大學<br>自然科學系碩士班<br>99<br>This study on the synthesis of 5-aryl-4,4-dimethoxy-2-cyclohexeones that 4,4-dimethoxy-2,5-cyclohex-di-enones be chelated carbonyl group by Lewis acid, MAD [methyl aluminium bis(2,6-di-tert-butyl-4-methyl phenoxide)],and then executed 1,4-addition with prepared aryl grignard reagent, prepare as 0.01 M in trifluoroacetic ethanol respectively and carry out photochemistry reaction using 350 nm wavelength light. The results show that aromatic group is toluene causing the main skeleton of product is cyclopentanone on the other hand that aromatic group is thiophen

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33

Parisien-Collette, Shawn. "Développement de réactions photochimiques pour la synthèse d’hétérocycles azotés en chimie en flux continu." Thesis, 2019. http://hdl.handle.net/1866/24769.

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Cette thèse portera sur le développement de nouvelles méthodologies photochimiques utilisant la chimie en flux continu. Les travaux présentés au chapitre 2 décrivent l’utilisation d’un photocatalyseur à base de fer(II) pour la synthèse de carbazoles substitués. La cyclisation de diaryles et triarylamines a été effectuée en utilisant le système catalytique [Fe(phen)3](NTf2)2/O2 avec des rendements variants entre 63 et 91 %. La technologie de chimie en flux continu a permis d’entreprendre l’étude de l’agrandissement d’échelle de cette réaction photochimique. La technique de « numbering-up » a pe

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