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Dissertations / Theses on the topic 'Thermotropic Liquid Crystalline Polymers'

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1

Scribben, Eric Christopher. "Selection of Thermotropic Liquid Crystalline Polymers for Rotational Molding." Diss., Virginia Tech, 2004. http://hdl.handle.net/10919/11251.

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Thermotropic liquid crystalline polymers (TLCPs) possess a number of physical and mechanical properties such as: excellent chemical resistance, low permeability, low coefficient of thermal expansion, high tensile strength and modulus, and good impact resistance, which make them desirable for use in the storage of cryogenic fluids. Rotational molding was selected as the processing method for these containers because it is convenient for manufacturing large storage vessels from thermoplastics. Unfortunately, there are no reports of successful TLCP rotational molding in the technical literature
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2

Chen, Hongyan. "Simulations of Shearing Rheology of Thermotropic Liquid Crystalline Polymers." University of Akron / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=akron1210991980.

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3

Shiwaku, Toshio. "Ordered structures formed by thermotropic nematic liquid crystalline polymers." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/144861.

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4

Wilson, David James. "Diffraction measurements of crystalline morphology in thermotropic random copolyesters." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241169.

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5

Pickles, Adrian Philip. "The rheology, properties and morphology of thermotropic liquid crystalline polymers." Thesis, University of Liverpool, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317227.

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6

Ishida, Hiroyuki. "Studies on Structure and Dynamics of Thermotropic Liquid Crystalline Polymers." 京都大学 (Kyoto University), 2002. http://hdl.handle.net/2433/149788.

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7

Jenkins, Shawn Eric. "Synthesis and spinning of a new thermotropic liquid crystallinepolymers : characterization of fiber morphology and mechanical properties." Thesis, Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/8557.

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8

Zhang, Heping. "Structure and properties of oriented thermotropic liquid crystalline polyesters and polyamides." Thesis, University of Leeds, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.305812.

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9

Bai, Yiqun. "Structure and properties of linear and star-like thermotropic liquid crystalline polymeric fibers." Thesis, Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/9976.

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10

Done, Dinshong. "Studies on the rheology and morphology of thermotropic liquid crystalline polymers." Diss., Virginia Polytechnic Institute and State University, 1987. http://hdl.handle.net/10919/77792.

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It is known that the physical properties of as-processed liquid crystalline polymers are highly dependent on the thermal and deformation histories of the materials experienced. The purpose of this study has been to examine the effect of thermal history on the rheology and morphological texture for several thermotropic liquid crystalline polymers. These include two copolyesters of para-hydroxybenzoic acid and polyethylene terephthalate and a copolymer of para-hydroxy benzoic acid and 6-hydroxy-2-naphthoic acid. For all three systems, it was found that the viscosities at temperatures below the n
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11

Tang, Youhong. "Microrheological study on polyethylene/thermotropic liquid crystalline polymer/layered silicates nanocomposites /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CENG%202007%20TANG.

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12

Wilson, Thomas Stephen. "The rheology and structure of thermotropic liquid crystalline polymers in extensional flow." Diss., This resource online, 1991. http://scholar.lib.vt.edu/theses/available/etd-05222007-091333/.

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13

Romo-Uribe, Angel. "Main-chain thermotropic liquid crystalline polymers under shear : a dynamic scattering study." Thesis, University of Cambridge, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243155.

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14

Dimitriades, Klisthenis. "Characterisation, processing and mechanical modelling of a thermotropic main-chain liquid crystalline polymer." Thesis, Queen Mary, University of London, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266210.

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15

Chuah, Siew Peng. "In-situ fibre formation & management of thermotropic liquid crystalline polymers in thermoplastic matrices." Thesis, Brunel University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295188.

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16

Collier, Monty C. "Reclamation and Reprocessing of Thermotropic Liquid Crystalline Polymer from Composites of Polypropylene Reinforced with Liquid Crystalline Polymer." Thesis, Virginia Tech, 1998. http://hdl.handle.net/10919/36859.

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The composites industry can be positively influenced by composite materials that are processed faster, are lighter in weight, are higher in stiffness and strength, and that are more recyclable. There has been considerable interest in the use of thermotropic liquid crystalline polymers (TLCPs) to reinforce thermoplastic materials. In a novel process developed by Baird and coworkers, wholly thermoplastic composites are produced via a patented, dual extrusion process. This unique process yields a fiber which consists of numerous continuous fibrils of the liquid crystalline polymer encased in a
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17

Blizard, Kent G. "A study of processing methods for producing biaxial orientation in thermotropic liquid crystalline polymers." Diss., Virginia Polytechnic Institute and State University, 1988. http://hdl.handle.net/10919/54318.

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Four methods of biaxial deformation were considered in an attempt to obtain biaxial orientation and properties in two thermotropic copolyesters: hydroxybenzoic acid-co-polyethylene terephthalate (HBA/PET) and hydroxybenzoic acid/2, 6 hydroxynaphthoic acid (HBA/HNA). They consisted of solid phase forming, extrusion blow molding, biaxial stretching, and film blowing. Some measure of biaxial properties and orientation was obtainable in all four processes, from the layered structure apparent in the blow molded bottles to the uniplanar orientation in the stretched film. Tensile and flexural propert
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18

Gray, Robert Williamson IV. "The Effects of Processing Conditions on Thermoplastic Prototypes Reinforced with Thermotropic Liquid Crystalline Polymers." Thesis, Virginia Tech, 1997. http://hdl.handle.net/10919/46512.

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This work is concerned with preliminary studies on developing thermoplastic composite materials suitable for use in fused deposition modeling (FDM). Polypropylene (PP) strands reinforced with continuous thermotropic liquid crystalline polymer (TLCP) fibrils were generated in a novel dual extruder process. Strands were then re-extruded to form short fiber composite monofilaments that were used as feed stock in the FDM 1600 rapid prototyping system. Prototypes containing 40 wt% Vectra A were shown to have tensile properties twice those of parts built using acrylonitrile bu
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19

Murakami, Miwa. "Studies on the structure formation and dynamics of main-chain thermotropic liquid crystalline polymers." 京都大学 (Kyoto University), 2004. http://hdl.handle.net/2433/145341.

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20

Arrighi, Valeria. "Chain conformation of a main-chain thermotropic liquid crystalline polymer." Thesis, Imperial College London, 1991. http://hdl.handle.net/10044/1/46651.

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21

Qian, Chen. "Linking the Rheological Behavior to the Processing of Thermotropic Liquid Crystalline Polymers in the Super-cooled State." Diss., Virginia Tech, 2016. http://hdl.handle.net/10919/75005.

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Thermotropic liquid crystalline polymers (TLCPs) have attracted great interest because of the combination of their promising properties, which includes high stiffness and strength, excellent processability, and outstanding chemical resistance. TLCPs exhibit inherently low viscosity relative to many other conventional thermoplastics. The low melt viscosity is detrimental to processes requiring high melt strength, such as extrusion blow molding, film blowing, thermoforming and multilayer coextrusion. Our laboratory has developed a unique method to increase the viscosity of TLCPs by first raising
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22

Jacob, Sunny. "Synthesis and characterization of low-melting thermotropic liquid crystalline poly(ester-imide)s /." Online version of thesis, 1994. http://hdl.handle.net/1850/11881.

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23

Zhou, Weijun Kornfield Julia A. Kornfield Julia A. "Dynamics and shear alignment behavior of a model thermotropic liquid crystalline polymer /." Diss., Pasadena, Calif. : California Institute of Technology, 2001. http://resolver.caltech.edu/CaltechETD:etd-08292008-110129.

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24

Robertson, Christopher G. "Processing of composite fibers based on polypropylene and a thermotropic liquid crystalline polymer." Thesis, Virginia Tech, 1995. http://hdl.handle.net/10919/40661.

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25

Erdogan, Selahattin. "Synthesis Of Liquid Crystalline Copolyesters With Low Melting Temperature For In Situ Composite Applications." Phd thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613306/index.pdf.

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The objective of this study is to synthesize nematic-thermotropic liquid crystalline polymers (LCP) and determine their possible application areas. In this context, thirty different LCP&rsquo<br>s were synthesized and categorized with respect to their fiber formation capacity, melting temperature and mechanical properties. The basic chemical structure of synthesized LCP&rsquo<br>s were composed of p-acetoxybenzoic acid (p-ABA), m-acetoxybenzoic acid (m-ABA), hydroquinone diacetate (HQDA), terephthalic acid (TPA) and isophthalic acid (IPA) and alkyl-diacids monomers. In addition to mentioned mo
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26

Sabol, Edward A. "The development of a dual extrusion blending process and composites based on thermotropic liquid crystalline polymers and polypropylene." Thesis, Virginia Tech, 1994. http://hdl.handle.net/10919/40650.

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27

Ozturk, Hale Bahar. "Mechanical And Thermal Properties Of Thermotropic Liquid Crystalline Copolyester (tlcp) And Its Mixtures With Poly(ethyleneterephthalate) And Denture Base Poly(methyl Methacrylate)." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605205/index.pdf.

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In this study, the thermal and mechanical properties of poly(ethylenetheraphthalate) (PET)-thermotropic liquid crystal polyester (TLCP), mixtures and poly(methyl methacrylate) (PMMA)-TLCP mixtures were studied. The curing of PMMA-TLCP mixtures was done by heat, gamma radiation and microwave. The amount of TLCP in mixtures was % 0.5, 2 and 5 TLCP by weight. TLCP was synthesized by melt-acidolysis system, and PET-TLCP mixtures were prepared by using lab scale batch mixer. PMMA samples were prepared according to denture manufacturer&rsquo<br>s procedure. The characterization of polymer samples a
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28

Handlos, Agnita A. "The processing of microcomposites based on polypropylene and two thermotropic liquid crystalline polymers in injection molding, sheet extrusion, and extrusion blow molding." Diss., This resource online, 1994. http://scholar.lib.vt.edu/theses/available/etd-06062008-164735/.

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29

Zhao, Feng D. "The processing of thermotropic liquid crystalline polymers within a polypropylene matrix for the production of oriented thermo-reversible blends." Thesis, University of Cambridge, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338073.

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30

Ansari, Mubashir Qamar. "Generation of Thermotropic Liquid Crystalline Polymer (TLCP)-Thermoplastic Composite Filaments and Their Processing in Fused Filament Fabrication (FFF)." Diss., Virginia Tech, 2019. http://hdl.handle.net/10919/99885.

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One of the major limitations in Fused Filament Fabrication (FFF), a form of additive manufacturing, is the lack of composites with superior mechanical properties. Traditionally, carbon and glass fibers are widely used to improve the physical properties of polymeric matrices. However, the blending methods lead to fiber breakage, preventing generation of long fiber reinforced filaments essential for printing load-bearing components. Our approach to improve tensile properties of the printed parts was to use in-situ composites to avoid fiber breakage during filament generation. In the filaments ge
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31

Severing, Kirsten. "A biaxial nematic phase in a thermotropic liquid crystalline side-chain polymer a deuterium NMR study /." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=976850222.

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32

Zhou, Ming. "Synthesis, Phase Transition, Morphology, and Rheology of Combined Main−Chain and Side−Chain Liquid−Crystalline Polymers in Both Thermotropic and Lyotropic States." University of Akron / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=akron1143515132.

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33

Chen, Tianran. "Generation of Recyclable Liquid Crystalline Polymer Reinforced Composites for Use in Conventional and Additive Manufacturing Processes." Diss., Virginia Tech, 2021. http://hdl.handle.net/10919/103439.

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The application of glass fiber reinforced composites has grown rapidly due to their high strength-to-weight ratio, low cost, and chemical resistance. However, the increasing demand for fiber reinforced composites results in the generation of more composite wastes. Mechanical recycling is a cost-effective and environmentally-friendly recycling method, but the loss in the quality of recycled glass or carbon fiber composite hinders the wide-spread use of this recycling method. It is important to develop novel composite materials with higher recyclability. Thermotropic liquid crystalline polymers
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34

Wesselingh, Marjan. "Processing and properties of composites based on high density polyethylene and thermotrophic liquid crystalline polymers." Thesis, This resource online, 1995. http://scholar.lib.vt.edu/theses/available/etd-12172008-063352/.

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35

Liang, Hua. "The in-situ formation and management of fibres in moulded composites of polypropylene and a thermotropic liquid crystalline polymer." Thesis, Brunel University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241574.

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36

McLeod, Michael Allen. "Injection Molding of Pregenerated Microcomposites." Diss., Virginia Tech, 1997. http://hdl.handle.net/10919/28844.

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One portion of this work was concerned with injection molding pregenerated microcomposites composed primarily of poly(ethylene terephthalate) (PET) as the matrix and HX1000 as the thermotropic liquid crystalline polymer (TLCP). Several factors were examined to maximize the mechanical properties of these composites, including injection molding temperature, matrix viscosity, and nozzle tip exit diameter. In addition, concentrated strands of HX1000/PET (50/50 wt%) were diluted using both an injection molding grade of PET and an injection molding grade of PBT. From this work, it was determined
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37

Cracknell, Steven J. "Assessment of some novel thermotropic liquid crystalline phthalocyanines." Thesis, University of East Anglia, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.303554.

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38

Aragrag, Najib. "Synthesis and characterisation of thermotropic liquid crystalline elastomers." Thesis, University of Reading, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.541980.

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39

Arai, Yuko. "Volume phase transition of thermotropic liquid crystalline gels." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/144885.

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40

Almasri, Moayad. "Liquid crystalline conducting polymers." Thesis, Kingston University, 2008. http://eprints.kingston.ac.uk/20393/.

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Side chain liquid crystal polypyrroles have been synthesised and investigated in order to study their liquid crystallinity and its possible effect on their electronic conductivity. The synthesis ofN-substituted dithienylpyrrole was studied using a number of methods. Firstly, there was the synthesis of a side chain which consisted of a mesogenic group and nine units of methylene as a spacer. This synthesis was followed by the preparation of the N-substituted monomer, its polymerisation and the characterisation of both the low molecular weight compounds and the polymer. The next stage was the hy
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41

Onwumere, Fidelis C. "The synthesis and characterization of thermotropic liquid crystalline copolyesters." DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 1985. http://digitalcommons.auctr.edu/dissertations/3267.

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The synthesis of polyesters and copolyesters containing the bicycl o[2. 2.2]octane ring and 1,4-cycl ohexanedi acetic acid and 1,4-cyclohexanedimethanol spacers are discussed. The following homopolyesters were synthesized: poly[oxy(2-methyll, 4-phenylene)oxycarbonyl-l,4-bicyclo[2.2.2]octylenecarbonyl] I; and poly[oxy(2-chloro-l,4-phenylene)oxycarbonyl-l,4-bicyclo[2.2.2]octy-1 enecarbonyl] II. The following copolyesters were synthesized: poly[oxy (2-chl oro- 1,4-phenyl ene )oxycarbonyl-l ,4-bi cycl o[2. 2. 2]octyl enecarbonyl-co-oxy- (2-chloro-1,4-phenylene)oxysebacoyl] III; poly[oxy(2-methyl-l
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42

Bogdanowicz, Krzysztof Artur. "Liquid Crystalline Polymers for Smart Applications." Doctoral thesis, Universitat Rovira i Virgili, 2015. http://hdl.handle.net/10803/321835.

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Polímers cristall-líquids (PCL) posseeixen propietats que són una combinació entre sòlids cristal·lins i fluids. Actualment, PCL que incorporen elements actius en l'estructura (pe, grups de foto-sensibles, dendrons, etc.) condueixen a un material selectivament sensible. S'informa que els polímers es poden aplicar en diversos sistemes pe com materials amb memòria de forma, sensors o pantalles foto-òptiques. Els nostres estudis se centren en dues aplicacions diferents: microcàpsules fotosensibles per a sistemes de lliurament controlat i les membranes autoacoblades conductores de protons per a la
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43

Lovell, Christopher Stewart. "High performance bioresorbable liquid crystalline polymers." Thesis, University of Leeds, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.511134.

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44

Hinchcliffe, Trevor Thomas. "Chiral side chain liquid crystalline polymers." Thesis, Heriot-Watt University, 1993. http://hdl.handle.net/10399/1404.

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45

Baxter, Gillian Margaret. "Amphotropic side-chain liquid crystalline polymers." Thesis, University of Strathclyde, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366930.

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46

Nicholson, Timothy Michael. "Anisotropic structure in liquid crystalline polymers." Thesis, University of Cambridge, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293821.

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47

Kawasumi, Masaya. "Liquid crystalline polymers with complex architectures." Case Western Reserve University School of Graduate Studies / OhioLINK, 1993. http://rave.ohiolink.edu/etdc/view?acc_num=case1060626491.

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48

Nandu, Mahendra P. "Thermotropic liquid crystalline copolyesters containing the bicycl0[2.2.2]0ctane ring system." DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 1987. http://digitalcommons.auctr.edu/dissertations/3744.

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The syntheses of polyesters and copolyesters containing the bicyclo[2.2.2]octane ring and spacers such as sebacoyl chloride, ethyleneglycol, 1,4-butanediol, and 1,8-octanediol are discussed. The following homopolyesters were synthesized: poly(oxy-trans-1.4- cyclohexyleneoxycarbonyl-1,4-bicyclo[2.2.2]octylenecarbonyl) I; poly[(oxy-2-bromo-l,4-phenylene)oxycarbonyl-l,4-bicyclo[2.2.2]octy-lenecarbonyl] III; and poly[oxy(2-phenyl-1,4-pheny1ene)oxycarbonyl-1.4- bicyclo[2.2.2]octylenecarbonyl] V. The following copolyesters were synthesized: poly(oxy-trans-1,4-cycl ohexyleneoxycarbonyl-l,4-bicyclo[2.
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49

Brannum, Michelle T. "Functional Performance of Liquid Crystalline Elastomers." Case Western Reserve University School of Graduate Studies / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=case1549025445138734.

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50

Lau, Richard Yiu-Ting. "Surface segregation of amorphous, semi-crystalline and liquid crystalline polymers /." View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?CENG%202006%20LAUR.

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