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Journal articles on the topic 'Thianthrene'

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1

May, Bonnie L., Henry Yee, and Donald G. Lee. "Oxygen transfer reactions. 2. A comparison of the reactions of ruthenium tetroxide, chromyl chloride, and permanganate with thianthrene 5-oxide." Canadian Journal of Chemistry 72, no. 11 (1994): 2249–54. http://dx.doi.org/10.1139/v94-286.

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Products obtained from the oxidation of thianthrene 5-oxide, SSO, have been used to compare oxygen transfer mechanisms for three high-valent transition metals. Oxidation of SSO by benzyltriethylammonium permanganate in methylene chloride gives the corresponding sulfone, thianthrene 5,5-dioxide (SSO2), as the exclusive product. Oxidation of SSO by ruthenium tetroxide also gives SSO2 as the predominant product along with minor amounts of the disulfoxide, thianthrene 5,10-dioxide (SOSO). However, the converse is observed when chromyl chloride is used as the oxidant; SOSO is the major product. It
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2

Zhao, Wenyi, and Henry J. Shine. "Primary and secondary 5-(alkyloxy)thianthrenium perchlorates. Characterization with 1H NMR spectroscopy, reactions with iodide and bromide ion, and thermal decomposition in solution." Canadian Journal of Chemistry 76, no. 6 (1998): 695–702. http://dx.doi.org/10.1139/v98-010.

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A series of 5-(alkyloxy)thianthrenium perchlorates has been made in which the alkyl group is primary (1a-1p) and secondary (2a-2g). Preparations were carried out by reaction of the corresponding alkanol with thianthrene cation radical perchlorate in CH2Cl2 solution followed by precipitation of the perchlorate salt with dry ether. 1H NMR spectroscopy reveals that the presence of a stereogenic center in the alkyl group causes inequivalence in the ordinarily paired protons (e.g., H-4, H-6) of the thianthrenium ring. Reaction of iodide and bromide ion with primary alkyl-group compounds (e.g., meth
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3

Ueda, Masafumi, Moe Isozaki, and Yasuhiro Mazaki. "Synthesis, Structure, and Characterization of Thiacalix[4]-2,8-thianthrene." Molecules 28, no. 14 (2023): 5462. http://dx.doi.org/10.3390/molecules28145462.

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Sulfur-containing macrocycles have attracted substantial interest because they exhibit unique characteristics due to their polygonal ring-shaped skeleton. In this study, a thianthrene-based cyclic tetramer with the sulfur linker, thiacalix[4]-2,8-thianthrene (TC[4]TT), was successfully prepared from a cyclo-p-phenylenesulfide derivative using acid-induced intramolecular condensation. Single crystal X-ray diffraction revealed that TC[4]TT adopts an alternative octagonal form recessed to the inner side. Its internal cavity included small solvents, such as chloroform and carbon disulfide. Due to
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4

Swager, Timothy, Wen Ong, Federico Bertani, and Enrico Dalcanale. "Redox Switchable Thianthrene Cavitands." Synthesis 50, no. 23 (2018): 4697. http://dx.doi.org/10.1055/s-0037-1610833.

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5

Swager, Timothy, Wen Ong, Federico Bertani, and Enrico Dalcanale. "Redox Switchable Thianthrene Cavitands." Synthesis 49, no. 02 (2016): 358–64. http://dx.doi.org/10.1055/s-0036-1588659.

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6

Beck, Johannes, Thomas Bredow, and Rachmat Triandi Tjahjanto. "Thianthrene Radical Cation Hexafluorophosphate." Zeitschrift für Naturforschung B 64, no. 2 (2009): 145–52. http://dx.doi.org/10.1515/znb-2009-0201.

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In the presence of [NBu4][PF6] as the electrolyte, thianthrene (TA) is transformed by electrochemical oxidation to thianthrenium hexafluorophosphate containing the TA•+ radical cation. The reactions were performed in CH2Cl2, H3CCN, and liquid SO2 as solvents. In CH2Cl2, TA[PF6] is sparingly soluble and is deposited directly in crystalline form on the platinum electrode. In H3CCN and liquid SO2, TA[PF6] is highly soluble and gives dark blue solutions from which it can be crystallized upon concentration of the solutions. The air sensitive crystals are black with bronze metallic luster. They belo
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7

Plater, M. John, and William T. A. Harrison. "Chiral Thianthrenes." International Journal of Molecular Sciences 25, no. 8 (2024): 4311. http://dx.doi.org/10.3390/ijms25084311.

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The absolute configuration and stability of two thianthrene chiral sulfoxides has been determined by means of X-ray single-crystal structure determinations. The analyses and configurations allow verification that the diastereomeric sulfoxides are stable in solution and are not interconverting, which has been suggested in some studies of sulfoxides. The two thianthrene sulfoxides have slightly different Rf values, which allowed their separation using flash chromatography on silica. The spots run back-to-back, which posed a challenge for their separation. The pure, separated compounds in solutio
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8

WOO, H. G., S. Y. KIM, L. Y. HONG, H. G. KANG, H. S. HAM, and W. G. KIM. "ChemInform Abstract: Thianthrene. Cationic Polymerization of Vinyl Monomers Initiated by Thianthrene Cation Radical." ChemInform 27, no. 8 (2010): no. http://dx.doi.org/10.1002/chin.199608047.

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9

Liu, Haichao, Yu Gao, Jungang Cao, et al. "Efficient room-temperature phosphorescence based on a pure organic sulfur-containing heterocycle: folding-induced spin–orbit coupling enhancement." Materials Chemistry Frontiers 2, no. 10 (2018): 1853–58. http://dx.doi.org/10.1039/c8qm00320c.

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10

Yamashita, Masataka, Hironobu Hayashi, Mitsuharu Suzuki, et al. "Bisanthra-thianthrene: synthesis, structure and oxidation properties." RSC Advances 6, no. 74 (2016): 70700–70703. http://dx.doi.org/10.1039/c6ra13036d.

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11

MITCHELL, S. C., and R. H. WARING. "Fate of thianthrene in rat." Xenobiotica 28, no. 1 (1998): 93–101. http://dx.doi.org/10.1080/004982598239786.

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12

Speer, Martin E., Martin Kolek, Jean Jacques Jassoy, et al. "Thianthrene-functionalized polynorbornenes as high-voltage materials for organic cathode-based dual-ion batteries." Chemical Communications 51, no. 83 (2015): 15261–64. http://dx.doi.org/10.1039/c5cc04932f.

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13

Schaefer, Ted, Rudy Sebastian, and Christian Beaulieu. "Molecular orbital and 1H nuclear magnetic resonance studies of the inversion potentials of thianthrene and thioxanthene." Canadian Journal of Chemistry 69, no. 6 (1991): 927–33. http://dx.doi.org/10.1139/v91-137.

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The inversion potentials, obtained from STO-3G, STO-3G(*), 3-21G, 3-21G(*), and 4-31G basis sets, are reported for thianthrene and thioxanthene, molecules in which both or only one of the methylene groups have been replaced by sulfur in 9,10-dihydroanthracene. Comparison with the available experimental data suggests that the split-valence bases lead to an overestimate, possibly by about 10 kJ/mol, of the inversion barrier in the crystal, whereas the STO-3G and STO-3G* basis sets underestimate this barrier. It appears that the inversion barrier for thianthrene is much lower in solution than in
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14

Chen, Xiao-Yue, Xiao-Xue Nie, Yichen Wu, and Peng Wang. "para-Selective arylation and alkenylation of monosubstituted arenes using thianthrene S-oxide as a transient mediator." Chemical Communications 56, no. 37 (2020): 5058–61. http://dx.doi.org/10.1039/d0cc00641f.

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Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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15

Bock, H., B. Hierholzer, and P. Rittmeyer. "Radikalionen, 81. ENDOR-spektroskopische Untersuchungen an Radikalkationen aromatischer Organoschwefel-Verbindungen / Radical Ions, 81. ENDOR Spectroscopic Investigations of Radical Cations of Aromatic Organosulfur Compounds." Zeitschrift für Naturforschung B 44, no. 2 (1989): 187–204. http://dx.doi.org/10.1515/znb-1989-0216.

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Conditions for ENDOR measurem ents of organosulfur radical cations are discussed and tested. The one electron oxidation of a variety of aromatic sulfur com pounds comprising benzene-1,2-dithiole, 1,4-dithiine, thianthrene and diphenylsulfide derivatives as well as 33S isotope-marked bis(2,5-dimethoxyphenyl)disulfide is accomplished using the oxygen-free, powerful and selective AlCl3/H2CCl2 reagent. Partly with substantial structural changes, paramagnetic M⊕ species of 1,2-benzodithiete, 1,4-dithiine, thianthrene and diphenyl sulfide result. Their temperature-dependent ENDOR signal patterns pro
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16

Fujita, Tomoyuki, Tetsuo Maeda, Byung Ju Kim, et al. "Photolytic aziridination by thianthrene sulfilimine derivatives." Journal of Sulfur Chemistry 29, no. 5 (2008): 459–65. http://dx.doi.org/10.1080/17415990802183868.

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17

Mitchell, Steve C., and Rosemary H. Waring. "Fate of thianthrene in biological systems." Xenobiotica 47, no. 8 (2016): 731–40. http://dx.doi.org/10.1080/00498254.2016.1222107.

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18

González-Núñez, María Elena, Rossella Mello, Jorge Royo, et al. "Conformational Mobility of Thianthrene-5-oxide." Journal of Organic Chemistry 70, no. 9 (2005): 3450–57. http://dx.doi.org/10.1021/jo048802q.

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19

Lynch, V. M., S. H. Simonsen, B. E. Davis, et al. "1,4,6,9-Tetraazathianthrene: a planar thianthrene, C8H4N4S2." Acta Crystallographica Section C Crystal Structure Communications 50, no. 9 (1994): 1470–72. http://dx.doi.org/10.1107/s0108270194002234.

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20

Holzer, W., A. Penzkofer, A. Lux, H. H. Hörhold, and E. B. Kley. "Photo-physical and lasing characterisation of neat films of a thianthrene-substituted distyrylbenzene dye (Thianthrene-DSB)." Synthetic Metals 145, no. 2-3 (2004): 119–27. http://dx.doi.org/10.1016/j.synthmet.2004.04.027.

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21

Dötze, Marc, Hendrik Czepat, Jens Kudnig, and Günter Klar. "Elementorganische Verbindungen mit o-Phenylenresten, XXXI [1]. Charge-transfer-Komplexe von 2,3,7,8-Tetrakis(methylthio)chalkogenanthrenen mit 7,7,8,8-Tetracyanchinodimethan und Tetracyanethen / Organometalloidal Compounds with o-Phenylene Substituents, Part XXXI [1]. Charge-transfer Complexes of 2,3,7,8-Tetrakis(methylthio)chalkogenanthrenes with 7,7,8,8-Tetracyanoquinodimethane and Tetracyanoethene." Zeitschrift für Naturforschung B 53, no. 11 (1998): 1316–22. http://dx.doi.org/10.1515/znb-1998-1114.

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The title compounds are prepared by slow evaporation of dilute solutions of the components. 2,3,7,8-Tetrakis(methylthio)thianthrene and -selenanthrene give isostructural 2:1 complexes with 7,7,8,8-tetracyanoquinodimethane (TCNQ) built up by donor/acceptor/donor units in which the TCNQ molecule is inserted into the cavity formed by two of the folded, oppositely arranged chalcogenanthrene molecules. These units are connected to chains by S -S contacts via the methylthio groups. From 2,3,7,8-tetrakis(methylthio)thianthrene and tetracyanoethene again a 2:1 complex is obtained, however, with a colu
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22

Triandi, Rachmat, and Johannes Beck. "Synthesis and Crystal Structures of Silver Thianthrene Complexes with Weakly Coordinating Anions." Zeitschrift für Naturforschung B 62, no. 10 (2007): 1291–97. http://dx.doi.org/10.1515/znb-2007-1010.

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Two novel silver complexes with thianthrene (TA) as a ligand have been synthesized in the poorly coordinating solvent liquid sulfur dioxide, using silver salts with weakly coordinating anions [BF4]− and [SbF6]−. Both colorless compounds contain discrete molecular entities and SO2 molecules included in the crystal structure. Selection of crystals and the diffraction data collection were performed at low temperatures (123 K). The tris(μ-thianthrene-κ2S)disilver(I) bis(hexafluoroantimonate) sulfur dioxide solvate [Ag2(TA)3][SbF6]2·5SO2 (1) (monoclinic, P21/c, a = 21.644(3), b = 12.4216(4), c = 21
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23

Hinrichs, Winfried, Peer Berges, and Günter Klar. "Elementorganische Verbindungen mit ö-Phenylenresten, XI [1] 3:l-Komplexe von Hexachlor-dibenzo-p-dioxin-2,3-chinon mit 2,3,7,8-Tetramethoxythianthren und -selenanthren / Organometallic Compounds with o-Phenylene Substituents, Part XI [1] 3:1 Complexes of Hexachloro-dibenzo-p-dioxin-2,3-quinone with 2,3,7,8-Tetram ethoxythianthrene and Selenanthrene." Zeitschrift für Naturforschung B 41, no. 9 (1986): 1133–41. http://dx.doi.org/10.1515/znb-1986-0913.

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Abstract The title com pounds can be isolated from concentrated solutions of 2,3,7,8-tetramethoxy thianthrene or selenanthrene and tetrachloro-o-benzoquinone as dark blue crystals. Bond distances and bond and folding angles of the components indicate these com pounds to be charge transfer complexes in which the tetramethoxy thianthrene or selenanthrene molecules act as donors (D), the hexachloro-dibenzo-p-dioxin-2,3-quinone molecules as acceptors (A). In the asymmetric units of the two isostructural complexes an acceptor, a donor and another acceptor molecule are arranged parallel to each othe
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24

Świst, Agnieszka, Jadwiga Sołoducho, Przemysław Data, and Mieczysław Łapkowski. "Thianthrene-based oligomers as hole transporting materials." Arkivoc 2012, no. 3 (2012): 193–209. http://dx.doi.org/10.3998/ark.5550190.0013.315.

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25

Bizzarri, Paolo Costa, and Carlo Delia Casa. "Synthesis and Conductivity of Thianthrene-Type Polymers." Molecular Crystals and Liquid Crystals 118, no. 1 (1985): 245–48. http://dx.doi.org/10.1080/00268948508076218.

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26

Boduszek, Bogdan, and Henry J. Shine. "Preparation of solid thianthrene cation radical tetrafluoroborate." Journal of Organic Chemistry 53, no. 21 (1988): 5142–43. http://dx.doi.org/10.1021/jo00256a042.

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27

Nakai, Takeo, Masatoshi Kozaki, Kazunobu Sato, et al. "Exchange Interaction of Some Thianthrene-Derived Dications." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 334, no. 1 (1999): 139–48. http://dx.doi.org/10.1080/10587259908023311.

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28

Sabbah, Raphaël, and Lahcen El Watik. "Etude thermodynamique de la molecule de thianthrene." Thermochimica Acta 138, no. 2 (1989): 241–47. http://dx.doi.org/10.1016/0040-6031(89)87260-0.

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29

Johnson, Randy A., and Lon J. Mathias. "Synthesis and Characterization of Thianthrene-Based Polyamides." Macromolecules 28, no. 1 (1995): 79–85. http://dx.doi.org/10.1021/ma00105a009.

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30

Shin, Seung Rim, and Henry J. Shine. "Reactions of phenols with thianthrene cation radical." Journal of Organic Chemistry 57, no. 9 (1992): 2706–10. http://dx.doi.org/10.1021/jo00035a031.

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31

Steele, W. V., R. D. Chirico, S. E. Knipmeyer, and A. Nguyen. "The thermodynamic properties of thianthrene and phenoxathiin." Journal of Chemical Thermodynamics 25, no. 8 (1993): 965–92. http://dx.doi.org/10.1006/jcht.1993.1093.

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32

Sugimoto, Yukihiro, Francis J. Derbyshire, and Alan W. Scaroni. "The effect of sulfur evolution on the properties of high-temperature carbons—I. Thianthrene and thianthrene-anthracene precursors." Carbon 23, no. 4 (1985): 411–16. http://dx.doi.org/10.1016/0008-6223(85)90034-x.

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33

Edson, Joseph B., and Daniel M. Knauss. "Thianthrene as an activating group for the synthesis of poly(aryl ether thianthrene)s by nucleophilic aromatic substitution." Journal of Polymer Science Part A: Polymer Chemistry 42, no. 24 (2004): 6353–63. http://dx.doi.org/10.1002/pola.20464.

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34

Hoque, A. K. M. M., Henry J. Shine, and T. Krishnan Venkatachalam. "Reaction of Thianthrene Cation Radical with Diarylmercurials. Search for Single Electron Transfer Is Elusive." Collection of Czechoslovak Chemical Communications 58, no. 1 (1993): 82–88. http://dx.doi.org/10.1135/cccc19930082.

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Diarylmercurials (Ar2Hg) with Ar = p-tolyl Ib, o-tolyl Ic, p-anisyl Id and 2-allyloxy-4,5-dimethylphenyl Ie, reacted with thianthrene cation radical perchlorate (Th.+ClO4-) in two stoichiometric ratios: 2 : 1 and 4 : 1 (Th.+ClO4-/Ar2Hg). In the 2 : 1 ratio the products were the 5-arylthianthreniumyl perchlorates IIb - IIe, thianthrene (Th) and ArHg+ClO4- (assayed as ArHgCl, III) in quantitative yields. In the 4 : 1 ratio reaction with ArHg+ occurred, too, and the products were IIb - IIe, Th, the complex Th3Hg(ClO4)2 and HgO (after workup). In contrast, Ph2Hg (Ia) did not react beyond the 2 : 1
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35

Liu, Meng, Zhiqiang Yang, Zhe Feng, et al. "Combining Functional Units to Design Organic Materials with Dynamic Room-Temperature Phosphorescence under Continuous Ultraviolet Irradiation." Molecules 29, no. 11 (2024): 2621. http://dx.doi.org/10.3390/molecules29112621.

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Developing materials with dynamic room-temperature phosphorescence (RTP) properties is crucial for expanding the applications of organic light-emitting materials. In this study, we designed and synthesized two novel RTP molecules by combining functional units, incorporating the folded unit thianthrene into the classic luminescent cores thioxanthone or anthraquinone to construct TASO and TA2O. In this combination, the TA unit contributes to the enhancement of spin–orbit coupling (SOC), while the luminescent core governs the triplet energy level. After the strategic manipulation of SOC using the
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36

Okamura, Haruyuki, Ryosuke Matsumori, and Masamitsu Shirai. "I-Line Sensitive Photoacid Generators Having Thianthrene Skeleton." Journal of Photopolymer Science and Technology 17, no. 1 (2004): 131–34. http://dx.doi.org/10.2494/photopolymer.17.131.

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37

Ternay, A. L., Bobbie E. South, R. Mckellar, and W. W. Lam. "RING FLATTENING IN THIANTHRENE SULFONIUM BIS(CARBOMETHOXY)METHYLIDES." Phosphorus, Sulfur, and Silicon and the Related Elements 73, no. 1-4 (1992): 63–66. http://dx.doi.org/10.1080/10426509208034432.

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38

Shine, Henry J., and Wang Yueh. "Reaction of thianthrene cation radical with alcohols: Cyclohexanols." Tetrahedron Letters 33, no. 44 (1992): 6583–86. http://dx.doi.org/10.1016/s0040-4039(00)60991-7.

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39

Soroka, Miroslaw, and Henry J. Shine. "Reaction of thianthrene cation radical with grignard reagents." Tetrahedron 42, no. 22 (1986): 6111–21. http://dx.doi.org/10.1016/s0040-4020(01)88071-6.

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40

Ahmad, Abrar, Ashok Kumar Chauhan, Saleem Javed, and Ashwani Kumar. "Desulfurization of thianthrene by a Gordonia sp. IITR100." Biotechnology Letters 36, no. 11 (2014): 2209–14. http://dx.doi.org/10.1007/s10529-014-1606-2.

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41

Sheikh, Md, Toshiaki Yoshimura, Hiroyuki Morita, et al. "Synthesis of Thianthrene Derivatives Linked by Carbon Chains." Synthesis 46, no. 01 (2013): 42–48. http://dx.doi.org/10.1055/s-0033-1338550.

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42

Prema, S., and M. Srinivasan. "Preparation and properties of polyamides containing thianthrene units." European Polymer Journal 23, no. 11 (1987): 897–903. http://dx.doi.org/10.1016/0014-3057(87)90065-6.

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43

Friedrich, Reiner, Silvia Janietz, and Armin Wedel. "Synthesis and characterization of new thianthrene-containing polymers." Macromolecular Chemistry and Physics 200, no. 4 (1999): 731–38. http://dx.doi.org/10.1002/(sici)1521-3935(19990401)200:4<731::aid-macp731>3.0.co;2-a.

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44

LYNCH, V. M., S. H. SIMONSEN, B. E. DAVIS, et al. "ChemInform Abstract: 1,4,6,9-Tetraazathianthrene: A Planar Thianthrene, C8H4N4S2." ChemInform 26, no. 11 (2010): no. http://dx.doi.org/10.1002/chin.199511055.

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45

Schreiner, Roger P., S. Edward Stevens, and Ming Tien. "Oxidation of Thianthrene by the Ligninase of Phanerochaete chrysosporium." Applied and Environmental Microbiology 54, no. 7 (1988): 1858–60. http://dx.doi.org/10.1128/aem.54.7.1858-1860.1988.

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46

Abboud, K. A., V. M. Lynch, S. H. Simonsen, A. Piórko та R. G. Sutherland. "Structure of (η5-cyclopentadienyl)(η6-thianthrene)iron(II) hexafluorophosphate". Acta Crystallographica Section C Crystal Structure Communications 46, № 6 (1990): 1018–22. http://dx.doi.org/10.1107/s0108270189010437.

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47

Shine, Henry J. "Oxygen Transfer From Alcohols to the Thianthrene Cation Radical." Phosphorus, Sulfur, and Silicon and the Related Elements 95, no. 1-4 (1994): 429–30. http://dx.doi.org/10.1080/10426509408034264.

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48

Yus, Miguel, Francisco Foubelo, and José V. Ferrández. "Thianthrene as a source of the 1,2-benzene dianion." Tetrahedron Letters 43, no. 40 (2002): 7205–7. http://dx.doi.org/10.1016/s0040-4039(02)01661-1.

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49

Yang, L., J. Fang, N. Meichin, K. Tanaka, H. Kita, and K. Okamoto. "Gas permeation properties of thianthrene-5,5,10,10-tetraoxide-containing polyimides." Polymer 42, no. 5 (2001): 2021–29. http://dx.doi.org/10.1016/s0032-3861(00)00500-0.

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50

Du, Naiying, Gilles P. Robertson, Ingo Pinnau, and Michael D. Guiver. "Polymers of Intrinsic Microporosity with Dinaphthyl and Thianthrene Segments†." Macromolecules 43, no. 20 (2010): 8580–87. http://dx.doi.org/10.1021/ma101930x.

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