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1

Bostick, B. C., S. Fendorf, and G. E. Brown. "In situ analysis of thioarsenite complexes in neutral to alkaline arsenic sulphide solutions." Mineralogical Magazine 69, no. 5 (2005): 781–95. http://dx.doi.org/10.1180/0026461056950288.

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AbstractThe solubility of arsenic in anoxic soil and sediment pore waters is strongly influenced by complexation with dissolved sulphide. Despite their importance in arsenic chemistry, thioarsenite complexes have not been well characterized, and considerable questions remain regarding their structure, protonation state, and relative stabilities. Here we use X-ray absorption spectroscopy to examine the type and structure of aqueous arsenic-sulphur complexes in sulphidic solutions under neutral to alkaline pH. Arsenic formed a variety of thioarsenites, including AsS(SH)(OH)—, As(SH)S22—, AsS33—a
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2

Rader, Kevin J., Paul M. Dombrowski, Kevin J. Farley, John D. Mahony, and Dominic M. Di Toro. "EFFECT OF THIOARSENITE FORMATION ON ARSENIC(III) TOXICITY." Environmental Toxicology and Chemistry 23, no. 7 (2004): 1649. http://dx.doi.org/10.1897/03-443.

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3

Wilkin, Richard T., Robert G. Ford, Lisa M. Costantino, Randall R. Ross, Douglas G. Beak, and Kirk G. Scheckel. "Thioarsenite Detection and Implications for Arsenic Transport in Groundwater." Environmental Science & Technology 53, no. 20 (2019): 11684–93. http://dx.doi.org/10.1021/acs.est.9b04478.

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4

SERVES, S. V., D. N. SOTIROPOULOS, P. V. IOANNOU, and M. K. JAIN. "ChemInform Abstract: One-Pot Synthesis of Arsonolipids via Thioarsenite Precursors." ChemInform 24, no. 52 (2010): no. http://dx.doi.org/10.1002/chin.199352282.

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5

Wang, Ying, Xi Wu, Shaofeng Wang, et al. "The adsorption behavior of thioarsenite on magnetite and ferrous sulfide." Chemical Geology 492 (August 2018): 1–11. http://dx.doi.org/10.1016/j.chemgeo.2018.05.030.

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6

Planer-Friedrich, Britta. "Comment on “Thioarsenite Detection and Implications for Arsenic Transport in Groundwater”." Environmental Science & Technology 54, no. 12 (2020): 7730–31. http://dx.doi.org/10.1021/acs.est.0c01641.

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7

Tossell, J. A. "Computing the Properties of the Copper Thioarsenite Complex, CuAsS(SH)(OH)." Inorganic Chemistry 40, no. 25 (2001): 6487–92. http://dx.doi.org/10.1021/ic0105157.

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8

Liu, Xiandong, Mengjia He, Xiancai Lu, and Rucheng Wang. "Structures and acidity constants of arsenite and thioarsenite species in hydrothermal solutions." Chemical Geology 411 (September 2015): 192–99. http://dx.doi.org/10.1016/j.chemgeo.2015.07.015.

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9

Wilkin, Richard T., Robert G. Ford, Lisa M. Costantino, et al. "Response to Comment on “Thioarsenite Detection and Implications for Arsenic Transport in Groundwater”." Environmental Science & Technology 54, no. 12 (2020): 7732–33. http://dx.doi.org/10.1021/acs.est.0c02771.

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10

Suess, Elke, Andreas C. Scheinost, Benjamin C. Bostick, Broder J. Merkel, Dirk Wallschlaeger, and Britta Planer-Friedrich. "Discrimination of Thioarsenites and Thioarsenates by X-ray Absorption Spectroscopy." Analytical Chemistry 81, no. 20 (2009): 8318–26. http://dx.doi.org/10.1021/ac901094b.

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11

Tian, Lei, LinQing Huang, Jiacong Xu, Xiaoqiang Yu, and Zhifeng Xu. "Study on the solvent extraction of thioarsenite in alkaline solutions with transformed quaternary ammonium salt." Hydrometallurgy 199 (February 2021): 105528. http://dx.doi.org/10.1016/j.hydromet.2020.105528.

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12

Sun, Jianliang, Yaowu Hong, Jiahua Guo, et al. "Arsenite removal without thioarsenite formation in a sulfidogenic system driven by sulfur reducing bacteria under acidic conditions." Water Research 151 (March 2019): 362–70. http://dx.doi.org/10.1016/j.watres.2018.12.027.

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13

Wang, Ying, Jinru Lin, Shaofeng Wang, et al. "Adsorption and transformation of thioarsenite at hematite/water interface under anaerobic condition in the presence of sulfide." Chemosphere 222 (May 2019): 422–30. http://dx.doi.org/10.1016/j.chemosphere.2019.01.157.

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14

Zakaznova-Herzog, Valentina P., and Terry M. Seward. "A spectrophotometric study of the formation and deprotonation of thioarsenite species in aqueous solution at 22°C." Geochimica et Cosmochimica Acta 83 (April 2012): 48–60. http://dx.doi.org/10.1016/j.gca.2011.12.022.

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15

Clarke, Michelle B., and George R. Helz. "Metal−Thiometalate Transport of Biologically Active Trace Elements in Sulfidic Environments. 1. Experimental Evidence for Copper Thioarsenite Complexing." Environmental Science & Technology 34, no. 8 (2000): 1477–82. http://dx.doi.org/10.1021/es990134g.

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16

Tossell, J. A. "Metal−Thiometalate Transport of Biologically Active Trace Elements in Sulfidic Environments. 2. Theoretical Evidence for Copper Thioarsenite Complexing." Environmental Science & Technology 34, no. 8 (2000): 1483–88. http://dx.doi.org/10.1021/es9901359.

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17

Tossell, J. A., and M. D. Zimmermann. "Calculation of the structures, stabilities, and vibrational spectra of arsenites, thioarsenites and thioarsenates in aqueous solution." Geochimica et Cosmochimica Acta 72, no. 21 (2008): 5232–42. http://dx.doi.org/10.1016/j.gca.2008.08.013.

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18

Mereiter, Kurt. "Trilithium thioarsenate octahydrate." Acta Crystallographica Section E Structure Reports Online 69, no. 5 (2013): i30—i31. http://dx.doi.org/10.1107/s1600536813010921.

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19

Zhou, Jian, Rong-Qing Zhao, Tao Yang, et al. "A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates." Dalton Transactions 44, no. 16 (2015): 7203–12. http://dx.doi.org/10.1039/c4dt03912b.

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A series of new lanthanoid thioarsenates were prepared and they would be helpful for gaining insights into the influence of lanthanide contraction on the formation of other new lanthanoid thioarsenates.
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20

Zhou, Jian, Xing Liu, Rong Li, et al. "The syntheses, structures and properties of three new lanthanoid thioarsenates: the only example of thioarsenate acting as a ligand to a lanthanide complex." Dalton Transactions 42, no. 31 (2013): 11155. http://dx.doi.org/10.1039/c3dt50858g.

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21

Vater, Viola, та William S. Sheldrick. "SolvatothermaleDarstellung und Struktur von [Me4N]2[As6S10] und [Me4N]2[As4S7], dem ersten Thioarsenat(III) mit Ψ -AsS4trigonalen Bipyramiden / Solvatothermal Synthesis and Structure of the Thioarsenates(III) [Me4N]2[As6S10] and [Me4N]2[As4S7], the First Thioarsenate(III) with Ψ-AsS4 Trigonal Bipyramids". Zeitschrift für Naturforschung B 52, № 9 (1997): 1119–24. http://dx.doi.org/10.1515/znb-1997-0917.

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The tetramethylammonium thioarsenate(III) [Me4N]2[As6S10] (1) has been prepared together with the minor product [Me4N]2[As4S7] (2) by reaction of [Me4N]Cl with As2S3 and Na2S in acetonitrile at 115 °C. The polymeric anion of 1 consists of adjacent 1∞[As3S5-] chains linked together into a 1∞[As6S102-] double chain through planar As2S2 rings involving As atoms of every second constituent ring-shaped As3S6 building unit. A relatively undistorted Ψ-AsS4 trigonal bipyramidal geometry is observed for the participating As atoms. Individual As3S6 units are linked by bridging AsS3 pyramids into the zwe
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22

Vater, Viola, and William S. Sheldrick. "Solventothermal Synthesis and Structure of the Polymerie Thioarsenates(III) (Et4N)2As6S10 and (Et4N)2As8S13." Zeitschrift für Naturforschung B 53, no. 11 (1998): 1259–64. http://dx.doi.org/10.1515/znb-1998-1103.

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Reaction of (Et4N)Cl with AS2S3 and Na2S in acetonitrile at 110°C affords the polymeric thioarsenate(III) (Et4N)2As6S10 in which the cyclic [As3S6]3- and chainlike [As3S7]5- trinuclear molecular building units are linked together through common sulphur atoms into infinite double chains. In contrast, reaction of the same starting materials at higher temperatures (180°C) in water leads to formation of a markedly denser phase (Et4N)2As8S13, whose thioarsenate(III) 1∞ [As8S132-] anions exhibit a higher condensation grade. These likewise double chains are composed of cyclic [AS3S6]3- and dinuclear
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23

VATER, V., та W. S. SHELDRICK. "ChemInform Abstract: Solvatothermal Synthesis and Structure of the Thioarsenates(III) (Me4N) 2(As6S10) and (Me4N)2(As4S7), the First Thioarsenate(III) with ψ- AsS4 Trigonal Bipyramids." ChemInform 28, № 51 (2010): no. http://dx.doi.org/10.1002/chin.199751031.

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24

Kassem, M., A. Sokolov, A. Cuisset, et al. "Mercury Sulfide Dimorphism in Thioarsenate Glasses." Journal of Physical Chemistry B 120, no. 23 (2016): 5278–90. http://dx.doi.org/10.1021/acs.jpcb.6b03382.

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25

Stauder, S., B. Raue, and F. Sacher. "Thioarsenates in Sulfidic Waters." Environmental Science & Technology 39, no. 16 (2005): 5933–39. http://dx.doi.org/10.1021/es048034k.

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26

Zhao, Rong-Qing, Xing Liu, Jian Zhou, et al. "The first examples of 1-D organic hybrid lanthanoid thioarsenates based on two [AsVS4]3− linkage modes." Dalton Transactions 45, no. 14 (2016): 6015–22. http://dx.doi.org/10.1039/c5dt02188j.

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27

Sheldrick, W. S., and J. Kaub. "Ein isoliertes cyclisches Thioarsenat(III)-Anion. Darstellung und Struktur von (enH2)3 (As3S6)2 · 6en / An Isolated Cyclic Thioarsenate(III) Anion. Preparation and Structure of (enH2)3(As3S6)2·6en." Zeitschrift für Naturforschung B 40, no. 1 (1985): 19–21. http://dx.doi.org/10.1515/znb-1985-0106.

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The thioarsenate(III) (enH2)3(As3S6)2 · 6en 1 (en = ethylenediamine) has been prepared by the reaction of ethylenediamine with As2S3 and its structure established by X-ray structural analysis. 1 contains discrete cyclic As3S63- anions with a six-membered As3S3-ring in the chair conformation. The As atoms display a ψ-tetrahedral coordination
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28

Zhou, Jian, Xiao-Feng Tan, Xing Liu, Miao Qing, Rong-Qing Zhao, and Qiuling Tang. "A series of new manganese thioarsenates(v) based on different unsaturated [Mn(amine)x]2+complexes." Dalton Transactions 44, no. 37 (2015): 16430–38. http://dx.doi.org/10.1039/c5dt02910d.

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Different unsaturated [Mn(amine)<sub>x</sub>]<sup>2+</sup>complexes have a significant structure directing effect on the structures of manganese thioarsenates(v) under similar solvothermal conditions.
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29

Sheldrick, W. S., and J. Kaub. "Darstellung und Struktur von Cs2As8S13 / Preparation and Structure of Cs2As8S13." Zeitschrift für Naturforschung B 40, no. 5 (1985): 571–73. http://dx.doi.org/10.1515/znb-1985-0501.

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Abstract The thioarsenate(III) Cs2As8S13 has been prepared by the reaction of Cs2CO3 with As2S3 in aqueous solution under pressure at 180 °C. Its structure has been established by X-ray structural analysis. The polymeric anion (As8S132-)n is composed of individual As4S4 -rings, which are each connected to three further eight-membered rings via As-S-As bridges, so giving rise to an infinite layer structure.
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30

SIEWERT, B., and U. MUELLER. "ChemInform Abstract: Tetraphenylphosphonium Heptathiacyclo Thioarsenate(III), PPh4(SAsS7)." ChemInform 22, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199139036.

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31

WENDEL, K., and U. MUELLER. "ChemInform Abstract: The Cyclic Thioarsenate(III) (PPh4)2As2S6." ChemInform 26, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199540025.

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32

Kassem, Mohammad, Sohayb Khaoulani, Arnaud Cuisset, David Le Coq, Pascal Masselin, and Eugene Bychkov. "Mercury thioarsenate glasses: a hybrid chain/pyramidal network." RSC Adv. 4, no. 90 (2014): 49236–46. http://dx.doi.org/10.1039/c4ra07811j.

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Mercury thioarsenate glasses (HgS)<sub>x</sub>(As<sub>2</sub>S<sub>3</sub>)<sub>1−x</sub>, 0.0 ≤x≤ 0.5, form a hybrid (HgS<sub>2/2</sub>)<sub>n</sub>chain/AsS<sub>3/2</sub>pyramidal network, highly unusual for metal chalcogenide glasses. This network is evidenced by Raman spectroscopy and DFT modelling and consistent with thermal properties. Nevertheless we cannot exclude completely the presence of a small fraction of HgS<sub>4/4</sub>tetrahedral units.
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33

Suess, Elke, and Britta Planer-Friedrich. "Thioarsenate formation upon dissolution of orpiment and arsenopyrite." Chemosphere 89, no. 11 (2012): 1390–98. http://dx.doi.org/10.1016/j.chemosphere.2012.05.109.

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34

Wallschläger, D., and C. J. Stadey. "Mass spectrometric investigation of thioarsenate formation in waters." Geochimica et Cosmochimica Acta 70, no. 18 (2006): A684. http://dx.doi.org/10.1016/j.gca.2006.06.1489.

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35

Han, Jingyu, Yun Liu, Chunying Tang, et al. "Thioarsenate anions acting as ligands: Solvothermal syntheses, crystal structures and characterizations of transition metal complexes of thioarsenate and polyethyleneamine ligands." Inorganica Chimica Acta 444 (April 2016): 36–42. http://dx.doi.org/10.1016/j.ica.2016.01.027.

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36

Yan, Dongming, Yu Xiao, Chang Liu, et al. "Two new members in the quaternary Cs–Ag–As–S family with different arrangements of Ag–S and As–S asymmetric building units: syntheses, structures, and theoretical studies." Dalton Transactions 49, no. 28 (2020): 9743–50. http://dx.doi.org/10.1039/d0dt01375g.

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Two novel quaternary layered thioarsenates(iii), Cs<sub>2</sub>Ag<sub>2</sub>As<sub>2</sub>S<sub>5</sub> (I) and Cs<sub>3</sub>AgAs<sub>4</sub>S<sub>8</sub> (II), with different arrangements of Ag–S and As–S asymmetric building units are reported.
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37

Siewert, Bright, and Ulrich M�ller. "Tetraphenylphosphonium-Heptathiacyclo-thioarsenat(III), PPh4[SAsS7]." Zeitschrift f�r anorganische und allgemeine Chemie 595, no. 1 (1991): 211–15. http://dx.doi.org/10.1002/zaac.19915950120.

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38

Wendel, Karin, and Ulrich M�ller. "Das cyclische Thioarsenat(III) (PPh4)2As2S6." Zeitschrift f�r anorganische und allgemeine Chemie 621, no. 6 (1995): 979–81. http://dx.doi.org/10.1002/zaac.19956210614.

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39

Planer-Friedrich, Britta, Tanja Kühnlenz, Dipti Halder, et al. "Thioarsenate Toxicity and Tolerance in the Model SystemArabidopsis thaliana." Environmental Science & Technology 51, no. 12 (2017): 7187–96. http://dx.doi.org/10.1021/acs.est.6b06028.

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40

Planer-Friedrich, Britta, Doreen Franke, Broder Merkel, and Dirk Wallschläger. "ACUTE TOXICITY OF THIOARSENATES TO VIBRIO FISCHERI." Environmental Toxicology and Chemistry 27, no. 10 (2008): 2027. http://dx.doi.org/10.1897/07-633.1.

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41

Wallschläger, Dirk, and Christopher J. Stadey. "Determination of (Oxy)thioarsenates in Sulfidic Waters." Analytical Chemistry 79, no. 10 (2007): 3873–80. http://dx.doi.org/10.1021/ac070061g.

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42

Suess, Elke, Dirk Wallschläger, and Britta Planer-Friedrich. "Stabilization of thioarsenates in iron-rich waters." Chemosphere 83, no. 11 (2011): 1524–31. http://dx.doi.org/10.1016/j.chemosphere.2011.01.045.

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43

Hinrichsen, Sinikka, Franziska Geist, and Britta Planer-Friedrich. "Inorganic and Methylated Thioarsenates Pass the Gastrointestinal Barrier." Chemical Research in Toxicology 28, no. 9 (2015): 1678–80. http://dx.doi.org/10.1021/acs.chemrestox.5b00268.

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44

Liu, Xing, and Jian Zhou. "Solvothermal Syntheses and Crystal Structures of Two Thioarsenate Metal Complexes [Co(dien)2]3[As3S6]2 and [Mn(teta)]2As2S5." Zeitschrift für Naturforschung B 66, no. 4 (2011): 366–70. http://dx.doi.org/10.1515/znb-2011-0405.

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Two thioarsenates [Co(dien)2]3[As3S6]2 (1, dien = diethylenetriamine) and [Mn(teta)]2As2S5 (2, teta = triethylenetetramine) have been solvothermally synthesized and structurally characterized. 1 consists of isolated cyclic [As3S6]3− anions in a chair-conformation and two different isomeric [Co(dien)2]2+ cations, while 2 consists of neutral [Mn(teta)]2As2S5 moieties built up from saddlelike As2S5 anions as a tetradentate ligand connecting two [Mn(teta)]2+ groups via terminal S atoms. The optical absorption spectrum of 1 is described.
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45

Sheldrick, W. S., and J. Kaub. "Darstellung und Struktur von Rb2As8S13·H2O und (NH4)2As8S13·H2O / Preparation and Structure of Rb2As8S13·H2O and (NH4)2As8S13·H2O." Zeitschrift für Naturforschung B 40, no. 9 (1985): 1130–33. http://dx.doi.org/10.1515/znb-1985-0906.

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The rubidium and ammonium thioarsenates(III) Rb2As8S13·H2O and (NH4)2As8S13·H2O have been prepared by the reaction of the alkali carbonates with As2S3 in aqueous solution in sealed ampoules at respective temperatures of 200 °C and 220 °C. The structure of Rb2As8S13·H2O has been established by X-ray structural analysis. The polymeric anion (As8S132-)n is composed of individual As3S3-rings, which are connected to one another via bridging AsS3-pyramids, so giving rise to infinite loop-branched dreier double chains. (NH4)2As8S13·H2O is isotypic with Rb2As8S13·H2O.
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46

Yang, Dan-Dan, Ying Song, Bo Zhang, et al. "Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates." Crystal Growth & Design 18, no. 5 (2018): 3255–62. http://dx.doi.org/10.1021/acs.cgd.8b00495.

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47

Li, Yanhua, Xuedan Song, Yiping Zhong, et al. "Temperature controlling valance changes of crystalline thioarsenates and thioantimonates." Journal of Alloys and Compounds 872 (August 2021): 159591. http://dx.doi.org/10.1016/j.jallcom.2021.159591.

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48

Colina Blanco, Andrea E., Carolin F. Kerl, and Britta Planer-Friedrich. "Detection of Thioarsenates in Rice Grains and Rice Products." Journal of Agricultural and Food Chemistry 69, no. 7 (2021): 2287–94. http://dx.doi.org/10.1021/acs.jafc.0c06853.

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49

Bannikov, Leonid, Anna Smirnova, and Serhiy Nesterenko. "Interpretation of Salts Influence on the Regeneration Process of Rich Thioarsenate Solution by Oxidative Reduction Potential Measurement." Chemistry & Chemical Technology 10, no. 1 (2016): 67–72. http://dx.doi.org/10.23939/chcht10.01.067.

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50

Wang, Jiajia, Dipti Halder, Laura Wegner, et al. "Redox Dependence of Thioarsenate Occurrence in Paddy Soils and the Rice Rhizosphere." Environmental Science & Technology 54, no. 7 (2020): 3940–50. http://dx.doi.org/10.1021/acs.est.9b05639.

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