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Journal articles on the topic 'Thiocyanate complex'

Author: Grafiati

Published: 5 June 2025

Last updated: 15 July 2025

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1

Wang, Hui-Ting, and Lin Zhou. "A one-dimensional CdIIcoordination polymer constructed from 4-(dimethylamino)pyridinium-1-acetate ligands and thiocyanate coordination bridges." Acta Crystallographica Section C Structural Chemistry 71, no. 7 (2015): 549–53. http://dx.doi.org/10.1107/s2053229615011298.

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A new cadmium–thiocyanate complex, namelycatena-poly[1-carboxymethyl-4-(dimethylamino)pyridinium [cadmium(II)-tri-μ-thiocyanato-κ4N:S;κ2S:N] [[[4-(dimethylamino)pyridinium-1-acetate-κ2O,O′]cadmium(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]], {(C9H13N2O2)[Cd(NCS)3][Cd(NCS)2(C9H12N2O2)]}n, was synthesized by the reaction of 4-(dimethylamino)pyridinium-1-acetate, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, two types of CdIIatoms are observed in distorted octahedral coordination environments. One type of CdIIatom is coordinated by two O atoms from

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2

Zhou, Lin, and Hui-Ting Wang. "A two-dimensional cadmium(II) polymer based on nicotinic acid and thiocyanate ligands." Acta Crystallographica Section C Structural Chemistry 71, no. 9 (2015): 820–23. http://dx.doi.org/10.1107/s2053229615015156.

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A cadmium–thiocyanate complex, poly[[bis(nicotinic acid-κN)di-μ-thiocyanato-κ2N:S;κ2S:N-cadmium(II)] monohydrate], {[Cd(NCS)2(C6H5NO2)2]·H2O}n, was synthesized by the reaction of nicotinic acid, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, each CdIIcation is in a distorted octahedral coordination environment, coordinated by the N and S atoms of nicotinic acid and thiocyanate ligands. Neighbouring CdIIcations are linked together by thiocyanate bridges to form a two-dimensional network. Hydrogen-bond interactions between the uncoordinated

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3

Wang, Hui-Ting, Qiang Li, and Lin Zhou. "A two-dimensional cadmium(II) coordination polymer based on 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane and thiocyanate ligands." Acta Crystallographica Section C Structural Chemistry 71, no. 9 (2015): 763–67. http://dx.doi.org/10.1107/s205322961501431x.

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A cadmium–thiocyanate complex, poly[(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κ4N)octakis-μ2-thiocyanato-κ8N:S;κ8S:N-tricadmium(II)], [Cd3(C8H14N3)2(NCS)8]n, was synthesized by the reaction of 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, there are two independent types of CdIIcation (one on a centre of inversion and one in a general position) and both are in distorted octahedral coordination environments, coordinated by N and S atoms from different ligands. Neighbouring C

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4

Wang, Hui-Ting, and Xiao-Li Wang. "A new two-dimensional anionic cadmium(II) polymer constructed through thiocyanate coordination bridges." Acta Crystallographica Section C Structural Chemistry 71, no. 4 (2015): 318–21. http://dx.doi.org/10.1107/s2053229615005239.

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A new cadmium–thiocyanate complex, poly[4-(dimethylamino)pyridin-1-ium [di-μ-thiocyanato-κ2N:S;κ2S:N-thiocyanato-κN-cadmium(II)]], {(C7H11N2)[Cd(NCS)3]}n, was synthesized by the reaction of cadmium thiocyanate and 4-(dimethylamino)pyridine hydrochloride in aqueous solution. In the crystal structure, each CdIIion is square-pyramidally coordinated by three N and two S atoms from five different thiocyanate ligands, four of which are bridging. The thiocyanate ligands play different roles in the build up of the structure; one role results in the formation of [Cd2(NCS)2] building blocks, while the o

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5

Mariyam, Dewi, I. Wayan Dasna, Husni Wahyu Wijaya, and Danar. "Synthesis, Characterization and Antibacterial Properties of Complex [Ag(SCN)(2-NH2py)]." E3S Web of Conferences 473 (2024): 03006. http://dx.doi.org/10.1051/e3sconf/202447303006.

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The reaction of AgSCN with 2-aminopyridine in ammonia solution produces the colorless crystal of catena-poly [Ag(SCN))(C6H5N2)]n. The crystals were characterized by FTIR analysis and single crystal X-Ray diffraction. The silver(I) ion bind to one N atom of 2-aminopyridine, one N atom of thiocyanate and two S atoms of two thiocyanates to form a pseudo-tetrahedral complex. The presence of thiocyanates bridge ligand give an one-dimensional polymer. Complex [Ag(SCN)(2-NH2py)] crystallizes in monoclinic lattice and P21 space group with a=9,122(3) Å, b=4,1506(15) Å, c=11,269(4) Å, α= γ= 90°, β= 109,

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6

Ozawa, Yoshiki, Misa Kim та Koshiro Toriumi. "A one-dimensional platinum mixed-valence complex with bridging thiocyanate S atoms: [[PtII(en)2](μ-SCN)[PtIV(en)2](μ-SCN)](ClO4)4(en is ethane-1,2-diamine)". Acta Crystallographica Section C Crystal Structure Communications 69, № 2 (2013): 146–49. http://dx.doi.org/10.1107/s0108270113000541.

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A new one-dimensional platinum mixed-valence complex with nonhalogen bridging ligands, namelycatena-poly[[[bis(ethane-1,2-diamine-κ2N,N′)platinum(II)]-μ-thiocyanato-κ2S:S-[bis(ethane-1,2-diamine-κ2N,N′)platinum(IV)]-μ-thiocyanato-κ2S:S] tetrakis(perchlorate)], {[Pt2(SCN)2(C2H8N2)4](ClO4)4}n, has been isolated. The PtIIand PtIVatoms are located on centres of inversion and are stacked alternately, linked by the S atoms of the thiocyanate ligands, forming an infinite one-dimensional chain. The PtIV—S and PtII...S distances are 2.3933 (10) and 3.4705 (10) Å, respectively, and the PtIV—S...PtIIangl

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7

Kreaunakpan, Janjira, Kittipong Chainok, Nathan R. Halcovitch, Edward R. T. Tiekink, Teerapong Pirojsirikul, and Saowanit Saithong. "Crystal and molecular structures of a binuclear mixed ligand complex of silver(I) with thiocyanate and 1H-1,2,4-triazole-5(4H)-thione." Acta Crystallographica Section E Crystallographic Communications 76, no. 1 (2020): 42–47. http://dx.doi.org/10.1107/s2056989019016359.

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The complete molecule of the binuclear title complex, bis[μ-1H-1,2,4-triazole-5(4H)-thione-κ2 S:S]bis{(thiocyanato-κS)[1H-1,2,4-triazole-5(4H)-thione-κS]silver(I)}, [Ag2(SCN)2(C2H3N3S)4], is generated by crystallographic inversion symmetry. The independent triazole-3-thione ligands employ the exocyclic-S atoms exclusively in coordination. One acts as a terminal S-ligand and the other in a bidentate (μ2) bridging mode to provide a link between two AgI centres. Each AgI atom is also coordinated by a terminal S-bound thiocyanate ligand, resulting in a distorted AgS4 tetrahedral coordination geome

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8

Tsitsishvili, Vladimer, and Koba Amirkhanashvili. "Application, structure, salts and complexes of lidocaine: a review. Part VI. Thiocyanate complexes." InterConf, no. 46(205) (June 19, 2024): 387–406. http://dx.doi.org/10.51582/interconf.19-20.06.2024.037.

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The review focuses on lidocaine (2-(diethylamino)-N-(2,6-dimethylphenyl)acetamide), one of the most popular and widely used painkillers. This part of the review is an introduction to our results from studying the structure of two thiocyanate complexes of lidocaine. The properties of the thiocyanate group, the use of infrared spectroscopy to study the structure of lidocaine-containing compounds, and the infrared spectra of thiocyanates are considered. The work on studying the structure of thiocyanate and other lidocaine complexes, carried out in the 1990s by a group of researchers from the Univ

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9

Plyuta, Nataliya, Olga Yu Vassilyeva, Vladimir N. Kokozay, Iryna Omelchenko, and Svitlana Petrusenko. "A binuclear CuII/CaII thiocyanate complex with a Schiff base ligand derived from o-vanillin and ammonia." Acta Crystallographica Section E Crystallographic Communications 76, no. 3 (2020): 423–26. http://dx.doi.org/10.1107/s205698902000211x.

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The new heterometallic complex, aqua-1κO-bis(μ2-2-iminomethyl-6-methoxyphenolato-1κ2 O 1,O 6:2κ2 O 1,N)bis(thiocyanato-1κN)calcium(II)copper(II), [CaCu(C8H8NO2)2(NCS)2(H2O)], has been synthesized using a one-pot reaction of copper powder, calcium oxide, o-vanillin and ammonium thiocyanate in methanol under ambient conditions. The Schiff base ligand (C8H9NO2) is generated in situ from the condensation of o-vanillin and ammonia, which is released from the initial NH4SCN. The title compound consists of a discrete binuclear molecule with a {Cu(μ-O)2Ca} core, in which the Cu...Ca distance is 3.4275

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10

Md., Munsur Rahman. "Mechanistic studies on the reactions of iodopentaammineruthenium(III) complex cation and thiocyanate ion in aqueous solution." Journal of Indian Chemical Society Vol. 76, Apr 1999 (1999): 188–90. https://doi.org/10.5281/zenodo.5848183.

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Department of Chemistry, University of Kalyani, Kalyani-741 235, India <em>Manuscript received 14 July 1998, accepted 8 December 1998</em> The substitution of iodide ion by thiocyanate ion in the iodopentaammineruthenium(III) complex cation in aqueous solution has been investigated at 35-50º. Rate increases linearly with thiocyanate ion concentration having a positive intercept on the rate axis. The intercept gives the aquation rate constant of the iodo complex, and the slope represents thiocyanate anation rate. The rate was compared with the thiocyanate anation rate of the aqua complex b

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11

Sudha, A. G., and T. N. Ramesh. "Competitive Ligand Binding and Photosensitivity Studies of Iron(III)-thiocyanate in presence of Glutamate ion." Research Journal of Chemistry and Environment 25, no. 7 (2021): 79–85. http://dx.doi.org/10.25303/257rjce7921.

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Addition of a chelating ligand (glutamate ion) to [Fe(SCN)]2+ solution leads to change in the colour. On increasing the glutamate ion concentration in iron thiocyanate complex solution, the colour of [Fe(SCN)]2+ disappears with the emergence of a new peak at lower wavelength due to the formation of [Fe(Glu)]2+complex. The conductance of [Fe(SCN)]2+ complex ion in solution is high while on addition of different concentrations of glutamate ion to iron thiocyanate complex, their conductance value decreases due to formation of [Fe(Glu)]2+. Photosensitivity studies of a series of solutions prepared

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12

Mariyam, Dewi, Nani Farida, Husni Wahyu Wijaya, and I. Wayan Dasna. "Studi Karakterisasi dan Aktivitas Antibakteri Senyawa Kompleks dari Zink(II) Klorida, Kalium Tiosianat dan 2-Aminopiridina." Jurnal Riset Kimia 13, no. 1 (2022): 100–110. http://dx.doi.org/10.25077/jrk.v13i1.465.

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The development of complex compounds as antibacterial continues to be carried out to overcome cases of microbial resistance. One of them is the development of complex compounds with thiocyanate and aminopyridine ligands which show good potential as antibacterial. Complex compound of zinc(II) chloride with thiocyanate and 2-aminopyridine ligands was successfully synthesized. The synthesis was carried out by mixing the reactants with ratio of Zn2+: 2-aminopyridine: SCN 1:2:2 under heating and stirring continuously for 6 hours. The Obtained beam-shaped colorless crystals were characterized using

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13

Kuramochi, Yusuke, Shunsuke Sayama, and Akiharu Satake. "Solvoluminescence of Cerium(III) Thiocyanate Complex." Chemistry – A European Journal 25, no. 52 (2019): 12042–45. http://dx.doi.org/10.1002/chem.201901528.

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14

R. Labhade, Shivaji, and Kailas R. Labhade. "MONO-THIOCYANATO MERCURY (II) CHLORIDE: A NOVEL REAGENT FOR SPECTROPHOTOMETRIC DETERMINATION OF CHLORIDE IN BEERS." Rasayan Journal of Chemistry 14, no. 04 (2021): 2834–44. http://dx.doi.org/10.31788/rjc.2021.1446539.

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The mono-thiocyanato mercuric (II) chloride [Hg(SCN)Cl] reagent was prepared synthetically and implemented for spectrophotometric determination of chloride in beers. In determining chloride, a known aliquot of beer sample was added into Hg(SCN)Cl reagent. The displaced thiocyanate ions were subsequently used to form the red-colored ferric-thiocyanate complex. The absorbance of which was measured at 455-nm was found directly proportional to the concentration of chloride in the beer sample. The experiment was performed by the standard addition method using beer sample and reagent at a time, and

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15

Faqih, Khoirul, Rong Cao, Saeed Ahmad, and Muntholib Muntholib. "Synthesis and Characterization of Complex Compounds of Cadmium (II) Nitrate, Potassium Thiocyanate, and 2,2-Bipyridine Ligand." Frontier Advances in Applied Science and Engineering 1, no. 2 (2024): 73–81. http://dx.doi.org/10.59535/faase.v1i2.181.

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A complex compound of a central atom of cadmium(II), potassium thiocyanate, and a 2,2'-bipy ligand with a stoichiometric ratio of 1:2:2 has never been reported. The aim of this research is to determine the coordination pattern of the 2,2'-bipy ligand and thiocyanate ion and the stability of the compounds formed. Synthesis of complex compounds was carried out using the direct reaction method, characterization of the complex compounds produced using the melting point test, FTIR analysis, SEM-EDX analysis, DHL test, thiocyanate ion qualitative test, and Gaussian 09W analysis. This synthesis produ

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16

Khoirul, Rong Cao, and Antonio Zucca. "Synthesis and Characterization of Complex Compounds of Cadmium (II) Nitrate, Potassium Thiocyanate, and 2,2-Bipyridine Ligand." Frontier Advances in Applied Science and Engineering 2, no. 1 (2024): 46–56. http://dx.doi.org/10.59535/faase.v2i1.179.

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A complex compound of a central atom of cadmium(II), potassium thiocyanate, and a 2,2'-bipy ligand with a stoichiometric ratio of 1:2:2 has never been reported. The aim of this research is to determine the coordination pattern of the 2,2'-bipy ligand and thiocyanate ion and the stability of the compounds formed. Synthesis of complex compounds was carried out using the direct reaction method, characterization of the complex compounds produced using the melting point test, FTIR analysis, SEM-EDX analysis, DHL test, thiocyanate ion qualitative test, and Gaussian 09W analysis. This synthesis produ

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17

Kozyrev, Yuriy N., Andrey S. Mendkovich, Vladimir A. Kokorekin, Victor B. Luzhkov, and Alexander I. Rusakov. "Integrated Study of the Thiocyanate Anion Electrooxidation by Electroanalytical and Computational Methods." Journal of The Electrochemical Society 168, no. 12 (2021): 125501. http://dx.doi.org/10.1149/1945-7111/ac39d4.

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The mechanism of the electrochemical oxidation of thiocyanate anion in acetonitrile was studied by cyclic voltammetry, chronoamperometry, electrolysis, digital simulations and quantum chemical calculations. The experimental data indicated complex character of the reaction mechanism, which includes reactions of thiocyanate anion with the products of its oxidation, thiocyanate radical and thiocyanogen. It was proposed that the last reaction takes place in the reduction of thiocyanogen as well. The DFT PCM-SMD M06–2X/aug-CC-pVQZ calculations show that the reaction of thiocyanate anion with thiocy

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18

Basavaiah, Kanakapura, and Bankavadi Chikkaswamy Somashekar. "Argentimetric assay of ranitidine in bulk drug and in dosage forms." Ecletica Quimica 32, no. 1 (2007): 19–26. http://dx.doi.org/10.26850/1678-4618eqj.v32.1.2007.p19-26.

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Two simple, rapid and cost-effective methods based on titrimetric and spectrophotometrictechniques are described for the assay of RNH in bulk drug and in dosage forms using silver nitrate, mer-cury(II)thiocyanate and iron(III)nitrate as reagents. In titrimetry, an aqueous solution of RNH is treatedwith measured excess of silver nitrate in HNO 3 medium, followed by determination of unreacted silvernitrate by Volhard method using iron(III) alum indicator. Spectrophotometric method involve the addi-tion a known excess of mercury(II)thiocyanate and iron(III)nitrate to RNH, followed by the measurem

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19

Suckert, Stefan, Inke Jess та Christian Näther. "Crystal structure of bis(3,5-dimethylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)". Acta Crystallographica Section E Crystallographic Communications 72, № 12 (2016): 1824–26. http://dx.doi.org/10.1107/s2056989016018326.

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The asymmetric unit of the title complex, [Co(NCS)2(C7H9N)2(CH3OH)2], comprises of one CoIIcation located on a centre of inversion, one thiocyanate ligand, one methanol ligand and one 3,5-dimethylpyridine ligand. The CoIIcation is octahedrally coordinated by two terminal N-bonding thiocyanate anions, two methanol molecules and two 3,5-dimethylpyridine ligands into a discrete complex. The complex molecules are linked by intermolecular O—H...S hydrogen bonding into chains that elongate in the direction parallel to thebaxis.

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20

Qian, Wei, Zibo Wang, Jingfeng Xia, et al. "Synthesis, Structural Characterization, EPR Analysis and Antimicrobial Activity of a Copper(II) Thiocyanate Complex Based on 3,7-Di(3-pyridyl)-1,5-dioxa-3,7-diazacyclooctane." Symmetry 17, no. 5 (2025): 791. https://doi.org/10.3390/sym17050791.

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The reaction of bipyridine 3,7-di(3-pyridyl)-1,5-dioxa-3,7-diazacyclooctane (L) with copper thiocyanate produces a discrete metallamacrocycle [Cu(L)(SCN)2(DMF)]2 (1). In complex 1, two cis-coordinated ligands combine with two copper ions to form an unabridged 24-membered macrocycle. Each copper ion is five-coordinated with two nitrogens from separate ligands, two nitrogens from thiocyanates and one oxygen from the dimethylformamide (DMF) solvent. Complex 1 has been characterized using single-crystal X-ray diffraction, optical and thermal analyses and antimicrobial activity measurements. The so

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21

Kratochvíl, Bohumil, Jan Ondráček, Jaroslav Maixner, Josef Macíček, and Václav Haber. "Structure of a palladium(II) complex with a non-symmetrical tetradentate Schiff base, [Pd(C14H20N3O)]NCS." Collection of Czechoslovak Chemical Communications 56, no. 9 (1991): 1900–1907. http://dx.doi.org/10.1135/cccc19911900.

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The structure of (1-phenyl-3-{2-[(2-aminoethyl)amino]ethylimino}-1-buten-1-olato-O,N,N’,N”) palladium(II) thiocyanate, [Pd(baden)]NCS, was solved by heavy-atom method and refined anisotropically ro R = 0.026 for 2 851 unique observed reflections. The title complex crystallizes in the Pc21b space group with a = 11.919(2), b = 14.061(2), c = 19.769(3)Å, Z = 8. The structure contains two symmetrical-independent molecules, each includes the palladium complex cation and thiocyanate anion. The cation formed by the baden ligand consists of one six-membered and two five-membered chelate rings and the

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22

Mahmoud, Joe, Matthew Higginson, Christopher Gilligan, Paul Thompson, Francis Livens, and Scott L. Heath. "Rapid americium separations from complex matrices using commercially available extraction chromatography resins." Journal of Radioanalytical and Nuclear Chemistry 331, no. 3 (2022): 1353–60. http://dx.doi.org/10.1007/s10967-022-08190-8.

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AbstractA method for rapid separation of americium from complex matrices by use of two commercially available extraction chromatography resins is reported. TRU resin is capable of purifying americium/lanthanides together from Group 1, Group 2 and transition metals. TRU resin tolerated high loadings of iron, aluminium, calcium sodium and potassium. TEVA resin purified americium/lanthanides by elution with ammonium thiocyanate. Decontamination factors > 20,000 were achieved within one working day. The affinity of TEVA resin for americium, curium and lanthanides as a function of ammonium thioc

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23

Chow, MY, and TCW Mak. "A Mononuclear Cobalt(II) Complex Containing Pyridine Betaine and Thiocyanate Ligands: Triaquabis(pyridinioacetato-O)(thiocyanato-N)cobalt(1+) Tetra(thiocyanato-N)cobaltate(2-)." Australian Journal of Chemistry 45, no. 8 (1992): 1307. http://dx.doi.org/10.1071/ch9921307.

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The cobalt(II) complex [Co(C5H5NCH2CO2)2(NCS)(H2O)3]2 [Co(NCS)4] has been synthesized, and characterized by X-ray crystallography. The complex comprises distorted octahedral [CO(C5H5NCH2CO2)2(NCS)(H2O)3]+ cations, in which the cobalt atom is surrounded by two trans monodentate pyridine betaine ligands, one N-bonded thiocyanate ligand and three aqua ligands, as well as distorted tetrahedral [CO(NCS)4]2- anions. Two-thirds of the aqua ligands form intra- and inter-molecular hydrogen bonds with the coordinated and uncoordinated carboxylate oxygens , linking the cations into a one-dimensional poly

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24

Munadhiroh, Asmi, Husni Wahyu Wijaya, Nani Farida, Stéphane Golhen, and I. Wayan Dasna. "Synthesis, Characterization, and Preliminary Study of [Co(2- aminopyridine)2(NCS)2] or bis(2-aminopyridine)dithiocyanato cobalt(II) as An Antibacterial." Jurnal Kimia Valensi 8, no. 1 (2022): 23–29. http://dx.doi.org/10.15408/jkv.v8i1.22685.

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This study aims to synthesize complex compounds from the Co(II) ion with mixed ligands of 2-aminopyridine and thiocyanate ions. The complexes obtained have Co(II) : 2-aminopyridine: thiocyanate ratio of 1:2:2 based on preliminary analysis by SEM-EDX, DHL, and FTIR. The complex in the form of a blue needle crystal is stable at room temperature and melts at 169 °C. Characterization shows that the complex formed is neutral. The antibacterial activity test was carried out using the diffusion method and show that the resulting complex compounds could inhibit the growth of S. typhi and S. aureus bac

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25

Jiang, Bin, Shaojing Zhong, Hongliang Yu, et al. "Aqueous Two-Phase System–Ion Chromatography for Determination of Thiocyanate in Raw Milk." Separations 8, no. 11 (2021): 212. http://dx.doi.org/10.3390/separations8110212.

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Thiocyanate could effectively inhibit bacteria in milk and extend the shelf life of milk. However, excessive addition will lead to health risks. Therefore, the determination of thiocyanate in raw milk has received a lot of attention, but the determination could be interfered with by other components in raw milk and the pre-treatment of raw milk is complex. In this study, a new pretreatment method combined with ion chromatography (IC) for rapid and sensitive determination of thiocyanate is proposed. An acetonitrile/(NH4)2SO4 aqueous two-phase system (ATPS) was developed for the separation and e

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26

Sonia, Nain, Agnihotri N., and R. Kakkar L. "Microdetermination of palladium using benzildioxime and thiocyanate." Journal of Indian Chemical Society Vol. 83, Jul 2006 (2006): 707–8. https://doi.org/10.5281/zenodo.5824515.

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Department of Chemistry, Kurukshetra University, Kurukshetra-136 119, Haryana, India <em>Manuscript received 7 April 2006, accepted 20 April 2006</em> Palladium(II) forms a light yellow 1 : 1 :2 complex with benzildioxime in presence of thiobyanate at 0.10-1.00 mol L<sup>-1</sup> HCI.The complex is non-extractable in nature and shows absorption maximum at 363-368 nm.The molar absorptivity of the complex is 3.088 x 10<sup>3</sup> L mol<sup>-1</sup> cm<sup>-1 </sup>with a Beer's law range of 0-15.5 μg ml<sup>-1 </sup>The method Is quite simple and rapid and has been satisfa

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27

Sridhar, M. A., A. Indira, G. Nagendrappa, and J. Shashidhara Prasad. "Crystal structure of lignocaine hydrochloride-palladium thiocyanate complex." Acta Crystallographica Section A Foundations of Crystallography 49, s1 (1993): c222. http://dx.doi.org/10.1107/s0108767378093770.

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28

Indira, A., M. A. Sridhar, G. Nagendrappa, and J. Shashidhara Prasad. "Crystal structure of lignocaine hydrochloride-nickel thiocyanate complex." Acta Crystallographica Section A Foundations of Crystallography 49, s1 (1993): c222. http://dx.doi.org/10.1107/s0108767378093782.

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29

Brewster, Timothy P., Wendu Ding, Nathan D. Schley, Nilay Hazari, Victor S. Batista, and Robert H. Crabtree. "Thiocyanate Linkage Isomerism in a Ruthenium Polypyridyl Complex." Inorganic Chemistry 50, no. 23 (2011): 11938–46. http://dx.doi.org/10.1021/ic200950e.

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30

Doyle, Declan A., and B. A. Wallace. "Crystal structure of the Gramicidin/Potassium thiocyanate complex." Journal of Molecular Biology 266, no. 5 (1997): 963–77. http://dx.doi.org/10.1006/jmbi.1996.0837.

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31

Krebs, Christoph, Inke Jess, and Christian Näther. "Crystal structures of two Co(NCS)₂ urotropine coordination compounds with different Co coordinations." Acta Crystallographica Section E Crystallographic Communications 78, no. 3 (2022): 264–69. http://dx.doi.org/10.1107/s2056989022001037.

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The reaction of Co(NCS)2 with urotropine in ethanol leads to the formation of two different compounds, namely, bis(ethanol-κO)bis(hexamethylenetetramine-κN)bis(thiocyanato-κN)cobalt(II)–diaqua-κ 2O-bis(hexamethylenetetramine-κN)bis(thiocyanato-κN)cobalt(II)–ethanol–hexamethylenetetramine (1.2/0.8/1.6/4), [Co(NCS)2(C6H12N4)2(C2H6O)2]1.2·[Co(NCS)2(C6H12N4)2(H2O)2]0.8·1.6C2H6O·4C6H12N4, 1, and tris(ethanol-κO)(hexamethylenetetramine-κN)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H12N4)(C2H6O)3], 2. In the crystal structure of compound 1, two crystallographically independent discrete complexes are

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32

Haque, M. Rezaul, and J. Howard Bradbury. "Simple Method for Determination of Thiocyanate in Urine." Clinical Chemistry 45, no. 9 (1999): 1459–64. http://dx.doi.org/10.1093/clinchem/45.9.1459.

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Abstract Background: It would be useful to develop a simple kit method for determination of thiocyanate in urine, which could be used to monitor cyanide overload in cassava-consuming populations. Methods: The method was based on the quantitative oxidation of thiocyanate in acid permanganate at room temperature in a closed vial with liberation of HCN, which reacted with a picrate paper. For semiquantitative analysis in the field, the colored picrate paper was matched with a color chart prepared using known amounts of KSCN. In the laboratory, a more accurate result was obtained by elution of the

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33

Rodrigue, André, John W. Bovenkamp, Benoit V. Lacroix, Robert A. B. Bannard, and Gerald W. Buchanan. "Complexes of 18-crown-6 macrocyclic ethers obtained from ethereal solvents. Complexes of potassium and sodium salts with host:guest ratios of 1:2 and 1:3." Canadian Journal of Chemistry 64, no. 4 (1986): 808–15. http://dx.doi.org/10.1139/v86-133.

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This paper describes the synthesis, in ethereal solvents, of the complexes of 18-crown-6, the cis–syn–cis and the cis–anti–cis isomers of dicyclohexano-18-crown-6, and dibenzo-18-crown-6 with the potassium and sodium salts of phenoxide and thiocyanate (as well as some potassium oximate salts). In general, the macrocycles break down the aggregates of the potassium salts so that the complexes of the contact ion pairs are isolated. The complex of the cis–anti–cis isomer of dicyclohexano-18-crown-6, however, which has a low stability constant, complexes the dimer of potassium phenoxide to give a c

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Neumann, Tristan, Inke Jess та Christian Näther. "Crystal structure of bis(isonicotinamide-κN1)bis(thiocyanato-κN)zinc". Acta Crystallographica Section E Crystallographic Communications 72, № 7 (2016): 922–25. http://dx.doi.org/10.1107/s2056989016008963.

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The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn2+cation located on a twofold rotation axis, as well as of one thiocyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+cation is tetrahedrally coordinated into a discrete complex by the N atoms of two symmetry-related thiocyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by intermolecular C—H...O and N—H...O, and weak intermolecular N—H...S hydrogen-bonding interactions into a three-dimensional network.

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35

Bowmaker, Graham A., and John V. Hanna. "IR Spectroscopy of Two Polymorphs of Copper(I) Thiocyanate and of Complexes ofCopper(I) Thiocyanate with Thiourea and Ethylenethiourea." Zeitschrift für Naturforschung B 64, no. 11-12 (2009): 1478–86. http://dx.doi.org/10.1515/znb-2009-11-1231.

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Syntheses and infrared spectroscopic studies are reported for two different polymorphs of copper( I) thiocyanate and for adducts of copper(I) thiocyanate with thiourea (‘tu’) and ethylenethiourea (‘etu’ = imidazolidine-2-thione; (CH2NH)2CS)). These include the previously reported complex CuSCN/etu (1 : 2), which has a trigonal monomeric structure, and CuSCN/etu (1 : 1), which has a three-dimensional polymeric structure. A mechanochemical/infrared study of the CuSCN: tu (1 : 2) system showed that no 1 : 2 complex exists in this case, the product being a mixture of a 1 : 3 complex and a novel 1

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Lee, Jie Yie, Sanliang Ling, Stephen P. Argent, Mark S. Senn, Laura Cañadillas-Delgado, and Matthew J. Cliffe. "Controlling multiple orderings in metal thiocyanate molecular perovskites Ax{Ni[Bi(SCN)6]}." Chemical Science 12, no. 10 (2021): 3516–25. http://dx.doi.org/10.1039/d0sc06619b.

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37

Singh, Ashok Kumar, Udai P. Singh, Sameena Mehtab, and Vaibhave Aggarwal. "Thiocyanate selective sensor based on tripodal zinc complex for direct determination of thiocyanate in biological samples." Sensors and Actuators B: Chemical 125, no. 2 (2007): 453–61. http://dx.doi.org/10.1016/j.snb.2007.02.056.

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38

Kavlentis, E. "Spectrophotometric analysis of the sulphide-thiocyanate and cyanide-thiocyanate mixtures using the copper(II)-DPGH complex." Mikrochimica Acta 88, no. 3-4 (1986): 239–43. http://dx.doi.org/10.1007/bf01196616.

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39

Ndoye, Cheikh, Gregory Excoffier, Gorgui Awa Seck та ін. "Crystal structures of bis[1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)cobalt(III)-tetra(thiocyanato-κN) cobalt(II) methanol solvate, bis{1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O}nickel(II) bis(thiocyanate) and (1-(1-hydroxypropan-2-ylidene)thiosemicarbazide-κ3S,N,O)bis(thiocyanato-κN)zinc(II)". European Journal of Chemistry 13, № 2 (2022): 196–205. http://dx.doi.org/10.5155/eurjchem.13.2.196-205.2253.

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The reactions of Schiff base 1-(1-hydroxypropan-2-ylidene)thiosemicarbazide (H2L), with salt of thiocyanate metal (II) (Co, Ni, or Zn), provided one dinuclear and two new mononuclear complexes, formulated respectively as {[Co(LH)2]2·[Co(NCS)4] ·2(MeOH)} (1), {[Ni(H2L)2]·[(NCS)2]} (2) and [Zn(H2L)(NCS)2] (3). These compounds have been studied and characterized by elemental analysis, infrared, and ultraviolet-visible (UV-vis) spectroscopies. The structures of the three complexes have been resolved by X-ray crystallography technique. The dinuclear complex 1 crystallizes in the orthorhombic space

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40

Chowdhury, B., R. Nandy, N. Ch Jana, P. Brandão, and A. Panja. "THE FIRST STRUCTURAL CHARACTERIZATION OF A NI(NCS)64– BRIDGED HOMOMETALLIC NI(II) CHAIN DERIVED FROM A N3O DONOR SCHIFF BASE LIGAND." Журнал структурной химии 65, no. 8 (2024): 130269. http://dx.doi.org/10.26902/jsc_id130269.

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Thiocyanate bridged homometallic Ni(II) chains have potential applications in areas such as molecular magnetism and spintronics due to their tunable magnetic properties. The magnetic properties of these chains are of particular interest and can lead to intriguing magnetic behaviors, such as antiferromagnetic or ferromagnetic interactions. In this context, we have successfully synthesized a Ni(NCS)64– bridge Ni(II) chain complex [Ni2(H2L)2(m1,3-NCS)2(NCS)4]n∙2nCH3CN (1), derived from a tetradentate N3O donor Schiff base ligand (HL). It has been thoroughly characterized by the help of elemental

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Lin, Shuang-Yan, Chao Wang, Lang Zhao, Jianfeng Wu, and Jinkui Tang. "Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue." Dalton Transactions 44, no. 1 (2015): 223–29. http://dx.doi.org/10.1039/c4dt02889a.

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A rare series of enantiopure mononuclear lanthanide complex pairs were obtained by using a chiral macrocyclic ligand and thiocyanate. The Dy complex was revealed to be a rare seven-coordinated lanthanide-based SIM encapsulated in a macrocyclic ligand.

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Radha, K., G. Aravamudan, A. Rajalakshmi, GC Rout, and M. Seshasayee. "Synthesis and Properties of Tris[Bis(2-Hydroxy-Ethyl)Dithiocarbamato]Haloditellurium(II) (Halo = Scn-, Br-, I-) and the Crystal-Structure of the Thiocyanato-S Complex, [Te-2((Hoch2ch2)2ncs2)3scn]." Australian Journal of Chemistry 39, no. 6 (1986): 847. http://dx.doi.org/10.1071/ch9860847.

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Mixed halo dithiocarbamate complexes of TeII were synthesized for the first time. Complexes of the general formula Te2L3X (X = SCN-, Br- and I-) were obtained from the parent compound TeL2[L = bis (2- hydroxyethyl ) dithiocarbamate ] and potassium thiocyanate or halides in acetic acid medium. Their chemical and physical properties were studied and the crystal structure of the thiocyanate compound determined. The crystals of the thiocyanate complex are monoclinic, with space group P21/n, a 14.056(3), b 9.599(2), c 22.519(6) Ǻ, β 105.71(2)°, V 2924.8 Ǻ3, Z 4, F(000) 1672, the final R and Rw valu

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El Hamdani, H., M. El Amane та C. Duhayon. "Crystal structure of the tetraaquabis(thiocyanato-κN)cobalt(II)–caffeine–water (1/2/4) co-crystal". Acta Crystallographica Section E Crystallographic Communications 73, № 7 (2017): 980–82. http://dx.doi.org/10.1107/s2056989017008180.

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In the structure of the title compound [systematic name: tetraaquabis(thiocyanato-κN)cobalt(II)–1,3,7-trimethyl-1,2,3,6-tetrahydro-7H-purine-2,6-dione–water (1/2/4)], [Co(NCS)2(H2O)4]·2C8H10N4O2·4H2O, the cobalt(II) cation lies on an inversion centre and is coordinated in a slightly distorted octahedral geometry by the oxygen atoms of four water molecules and two N atoms of twotrans-arranged thiocyanate anions. In the crystal, the complex molecules interact with the caffeine molecules through O—H...N, O—H...O and C—H...S hydrogen bonds and π–π interactions [centroid-to-centroid distance = 3.47

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44

Shaikh, Aaliya, Rhea Thomas, and Sara Khan. "Estimation of Thiocyanate Content from Selected Cruciferous Vegetables." Biosciences Biotechnology Research Asia 20, no. 4 (2023): 1395–405. http://dx.doi.org/10.13005/bbra/3185.

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ABSTRACT: As per the studies conducted by the Indian Thyroid Society, it is suggested that one out of ten people in India suffer from hypothyroidism and these figures are likely to increase in the near future. According to the survey, women in the post-menopausal age group are more affected in comparison to men. Globally, the prevalence of hypothyroidism is 4-5%. Taking the same into consideration, a comparative study was undertaken to estimate the thiocyanate content in cruciferous vegetables such as Raphanus sativus (radish), Brassica rapa (turnip), Brassica okracea var. botrytis (cauliflowe

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45

Chrimatopoulos, Christoforos, Kalliopi Papadopoulou, Theodora Tsilouli, and Vasilios Sakkas. "Exploring Salivary Thiocyanate as a Novel Biomarker of Physical Activity Response." Molecules 30, no. 11 (2025): 2476. https://doi.org/10.3390/molecules30112476.

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Salivary thiocyanate (SCN−) has long been recognized for its role in mucosal defense and antioxidant function, yet its behavior during physical activity remains unexplored. This study aimed to investigate salivary thiocyanate as a novel salivary biomarker responsive to exercise. A standard Vis–photometric method (thiocyanatoiron-complex formation) was utilized and validated for the rapid quantification of thiocyanate in saliva. The method was applied to two experimental setups: (i) a controlled treadmill protocol involving incremental running intensities (20%, 60%, and 90% VO2max-mL/kg/min), a

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Mikhailov, G. P. "Tetramer structure of a lithium thiocyanate complex in triethylamine." Russian Journal of Inorganic Chemistry 62, no. 6 (2017): 790–94. http://dx.doi.org/10.1134/s0036023617060158.

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47

Bi, Jian-Hong, and Hua-Ze Dong. "Crystal Structural of Phenanthroline and Thiocyanate Copper(II) Complex." Asian Journal of Chemistry 25, no. 14 (2013): 8241–42. http://dx.doi.org/10.14233/ajchem.2013.15354b.

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48

Chiumia, Godfrey C., Donald C. Craig, David J. Phillips, A. David Rae, and F. M. Zafar Kaifi. "Terminal S-coordinated thiocyanate in a nickel(II) complex." Inorganica Chimica Acta 285, no. 2 (1999): 297–300. http://dx.doi.org/10.1016/s0020-1693(98)00340-5.

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Kononova, O. N., N. G. Goryaeva, and Yu S. Kononov. "The sorption of thiocyanate ions on complex-forming ionites." Russian Journal of Physical Chemistry A 85, no. 6 (2011): 1041–46. http://dx.doi.org/10.1134/s0036024411060197.

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50

Vinogradova, Elena A., Olga Yu Vassilyeva, Volodymyr N. Kokozay, and Brian W. Skelton. "Polymeric Double [Cu(NCS)] Chains in the Crystal Structure of [Cu2(Me2Ea)2(SCN)2]∞ (HMe2Ea = 2-Dimethylaminoethanol) (NewP olymorph) and the Dimeric Structure of its DMSO Adduct." Zeitschrift für Naturforschung B 57, no. 3 (2002): 319–22. http://dx.doi.org/10.1515/znb-2002-0310.

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AbstractA new polymorph of the copper(II) thiocyanate complex with 2-dimethylaminoethanol, [Cu2(Me2Ea)2(NCS)2]∞ (HMe2Ea = 2-dimethylaminoethanol, HL) 1, was isolated in the attempted synthesis of a mixed-metal complex from zerovalent copper, cadmium oxide and ammonium thiocyanate in CH3CN solution of HL in air. [Cu2(Me2Ea)2(NCS)2(DMSO)2] 2 is a product of recrystallization of 1 from DMSO. X-ray analysis carried out on single crystals for both compounds revealed that 1 is a rare example of a 1D coordination polymer consisting of two chains in which the metallic centres are connected through sin

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