Academic literature on the topic 'Thioether complexes'

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Journal articles on the topic "Thioether complexes"

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Boeré, René T., and Christopher J. Willis. "Complexes of hybrid ligands. Pd2+ and Pt2+ complexes of new fluoro-alcohol thioether ligands; the use of thioether inversions to make structural assignments." Canadian Journal of Chemistry 63, no. 12 (1985): 3530–36. http://dx.doi.org/10.1139/v85-579.

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The fluorinated alcohol–thioethers RSCH2C(CF3)2OH (R = Me, Ph) have been synthesized by the reaction of RSCH2Li with (CF3)2CO. By ionization of the fluoroalcohol group, these may act as bidentate, uninegative, ligands L−. The presence of the soft thioether function in the hybrid ligand stabilizes the bond to the harder fluoro-alkoxy group, and complexes with soft transition metals are formed. Neutral complexes PdL2 and PtL2 have been synthesized, and, by the use of nmr, the geometry of the complexes is assigned as cis for Pt complexes, while both cis and trans are observed for Pd.The barrier t
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Wang, Hai Ming, та Gerhard Wenz. "Topochemical control of the photodimerization of aromatic compounds by γ-cyclodextrin thioethers in aqueous solution". Beilstein Journal of Organic Chemistry 9 (12 вересня 2013): 1858–66. http://dx.doi.org/10.3762/bjoc.9.217.

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The formation of soluble 1:2 complexes within hydrophilic γ-cyclodextrin (γ-CD) thioethers allows to perform photodimerizations of aromatic guests under controlled, homogenous reaction conditions. The quantum yields for unsubstituted anthracene, acenaphthylene, and coumarin complexed in these γ-CD thioethers were found to be up to 10 times higher than in the non-complexed state. The configuration of the photoproduct reflected the configuration of the dimeric inclusion complex of the guest. Anti-parallel orientation of acenaphthylene within the CD cavity led to the exclusive formation of the an
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Sellmann, Dieter, Peter Lechner, and Matthias Moll. "Übergangsmetallkomplexe mit Schwefelliganden, LXXII / Transition Metal Complexes with Sulfur Ligands, LXXII." Zeitschrift für Naturforschung B 46, no. 11 (1991): 1459–69. http://dx.doi.org/10.1515/znb-1991-1103.

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Racemic [Ru(ClH)(PPh3)′S4'] · CH2Cl2 (′S4'2-= 1,2-bis(2-mercaptophenylthio)ethane(2—)) reacts with monodentate sulfur ligands L to yield diastereospecifically yellow adducts [Ru(L)(PPh3)′S4']. Asymmetric achiral thioethers (L = SPhMe, CH3SSCH3) give only one of two potentially possible pairs of enantiomers, chiral thioethers and thiols (L = N-Acetyl-(L)-Methionin, N-Acetyl-(L)Methionin-methylester, S-Methyl-(L)Cystein, N-Acetyl-(L)Cystein) only two of four potentially possible diastereomers in the ratio 1:1.These results prove that the diastereospecifity is related to the coordinated thioether
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Smolyaninov, Ivan V., Georgy K. Fukin, Nadezhda T. Berberova, and Andrey I. Poddel’sky. "Triphenylantimony(V) Catecholates of the Type (3-RS-4,6-DBCat)SbPh3-Catechol Thioether Derivatives: Structure, Electrochemical Properties, and Antiradical Activity." Molecules 26, no. 8 (2021): 2171. http://dx.doi.org/10.3390/molecules26082171.

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A new series of triphenylantimony(V) 3-alkylthio/arylthio-substituted 4,6-di-tert-butylcatecholates of the type (3-RS-4,6-DBCat)SbPh3, where R = n-butyl (1), n-hexyl (2), n-octyl (3), cyclopentyl (4), cyclohexyl (5), benzyl (6), phenyl (7), and naphthyl-2 (8), were synthesized from the corresponding catechol thioethers and Ph3SbBr2 in the presence of a base. The crystal structures of 1, 2, 3, and 5 were determined by single-crystal X-ray analysis. The coordination polyhedron of 1–3 is better described as a tetragonal pyramid with a different degree of distortion, while that for 5- was a distor
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Muravev, Anton, Ayrat Yakupov, Tatiana Gerasimova, et al. "Thiacalixarenes with Sulfur Functionalities at Lower Rim: Heavy Metal Ion Binding in Solution and 2D-Confined Space." International Journal of Molecular Sciences 23, no. 4 (2022): 2341. http://dx.doi.org/10.3390/ijms23042341.

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Sulfur-containing groups preorganized on macrocyclic scaffolds are well suited for liquid-phase complexation of soft metal ions; however, their binding potential was not extensively studied at the air–water interface, and the effect of thioether topology on metal ion binding mechanisms under various conditions was not considered. Herein, we report the interface receptor characteristics of topologically varied thiacalixarene thioethers (linear bis-(methylthio)ethoxy derivative L2, O2S2-thiacrown-ether L3, and O2S2-bridged thiacalixtube L4). The study was conducted in bulk liquid phase and Langm
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Wang, Hai Ming, та Gerhard Wenz. "Molecular solubilization of fullerene C60 in water by γ-cyclodextrin thioethers". Beilstein Journal of Organic Chemistry 8 (28 вересня 2012): 1644–51. http://dx.doi.org/10.3762/bjoc.8.188.

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Various hydrophilic γ-cyclodextrin (CD) thioethers, containing neutral or ionic side arms were found to form molecular disperse solutions of C60 in water reaching concentrations of 15 mg/L. Equilibrium state was approached after seven days without the use of organic cosolvents. The 1:2 stoichiometry of the C60/γ-CD thioether complexes was demonstrated by a parabolic phase-solubility diagram. In contrast, native γ-CD forms nanoparticles with C60. Particle sizes of C60 were determined by dynamic light scattering.
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Lucas, C. Robert. "Thioether complexes of tungsten hexacarbonyl." Canadian Journal of Chemistry 64, no. 9 (1986): 1758–63. http://dx.doi.org/10.1139/v86-290.

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The preparation of a series of organic and organometallic thioethers R3MSR′ (M = C, Si, Ge, or Sn) is reported. From these, several new compounds of type 1 are synthesized, some of which contain para-substituted aryl functions for R′ and R. In hexane solution in the carbonyl stretching region of the ir and in the uv there is evidence for a degree of multiple bonding, at least in the M—S—W—CO portion of these molecules. Multiple bonding extending into aromatic R or R′ is small or non-existent and cannot be assessed precisely because of spontaneous decomposition of the complexes. All the complex
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Čubrilo, Jadranka, Ingo Hartenbach, Falk Lissner, Thomas Schleid, Mark Niemeyer, and Rainer F. Winter. "p-Cymene ruthenium thioether complexes." Journal of Organometallic Chemistry 692, no. 7 (2007): 1496–504. http://dx.doi.org/10.1016/j.jorganchem.2006.11.046.

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Wu, Huikang, and C. Robert Lucas. "Stereochemical nonrigidity in thioether complexes." Inorganic Chemistry 31, no. 12 (1992): 2354–58. http://dx.doi.org/10.1021/ic00038a012.

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Cooper, Stephen R., Simon C. Rawle, JudithAnn R. Hartman, Eric J. Hintsa, and Gary A. Admans. "Crown thioether chemistry: homoleptic hexakis(thioether) complexes of nickel(II)." Inorganic Chemistry 27, no. 7 (1988): 1209–14. http://dx.doi.org/10.1021/ic00280a023.

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Dissertations / Theses on the topic "Thioether complexes"

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Sullivan, Martin J. "Studies on thioether macrocyclic complexes." Thesis, University of Edinburgh, 1993. http://hdl.handle.net/1842/14515.

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An introduction to macrocyclic chemistry, with particular emphasis on [9]aneS<SUB>3</SUB> (1,4,7 - trithiacyclononane) and thioether macrocyclic transition metal complexes of groups VIII and IX is presented. The reaction of [RuC1<SUB>2</SUB>(PPh<SUB>3</SUB>)([9]aneS<SUB>3</SUB>)] with TIPF<SUB>6</SUB> in CH<SUB>2</SUB>C1<SUB>2</SUB> at 298K results in the formation of a mixture of complexes, [Ru(PPh<SUB>3</SUB>)([9]aneS<SUB>3</SUB>)(μ-C1)]<SUB>2</SUB>(PF<SUB>6</SUB>)<SUB>2</SUB> and [Ru(PPh<SUB>3</SUB>)([9]aneS<SUB>3</SUB>)(μ-C1)<SUB>2</SUB>T1]<SUB>2</SUB>(PF<SUB>6</SUB>)<SUB>2</SUB>, which ha
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Mullen, Gregory E. D. "Thioether complexes of rhenium and technetium." Thesis, University of Kent, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.264628.

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Taylor, Anne. "Studies of transition metal thioether macrocyclic complexes." Thesis, University of Edinburgh, 1991. http://hdl.handle.net/1842/14528.

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Chapter 1: A general discussion of macrocyclic co-ordination chemistry is given, with particular emphasis on the biological and catalytic relevance of macrocyclic systems. Chapter 2: Reproducible high yield synthesis of [Au ([9]aneS<SUB>3</SUB>)<SUB>2</SUB>](PF<SUB>6</SUB>) and [Au([9]aneS<SUB>3</SUB>)<SUB>2</SUB>](BF<SUB>4</SUB>)<SUB>2</SUB> have been established. [Au([9]aneS<SUB>3</SUB>)<SUB>2</SUB>]<SUP>2</SUP>+ undergoes a one-electron oxidation to Au(III) and an irreversible reduction to Au(I). The solution e.p.r. spectrum of [Au([9]aneS<SUB>3</SUB>)<SUB>2</SUB>]<SUP>2</SUP>+ shows an iso
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Mozol, Vivian Janet. "Utilising thioether-bridged ditungsten (III) complexes for metalloligand syntheses." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ31056.pdf.

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Reeves, GorDan T. Addison Anthony W. "Ruthenium(II) complexes of multidentate thioether and amine ligands /." Philadelphia, Pa. : Drexel University, 2009. http://hdl.handle.net/1860/3000.

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DuPont, Julie A. "The coordination chemistry of thioether-supported, low-valent cobalt complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file 3.92 Mb., 165 p, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&res_dat=xri:pqdiss&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&rft_dat=xri:pqdiss:3200521.

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Matondo, Simba Oliver Caleb. "Synthesis and characterisation of thioether containing ligands and their complexes." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259968.

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Bailey, Daniel. "High pressure studies of d-block thioether co-ordination complexes." Thesis, University of Nottingham, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.594819.

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Gibson, Alexander. "Syntheses and studies on transition metal complexes involving phosphine and thioether ligands." Thesis, University of Southampton, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243147.

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Mock, Michael T. "Synthesis and reactivity of thioether-supported organoiron and low-valent iron complexes and cyanide-bridged binuclear complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 282 p, 2008. http://proquest.umi.com/pqdweb?did=1481668291&sid=19&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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Book chapters on the topic "Thioether complexes"

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Cabral, M. F., J. O. Cabral, W. G. Haanstra, W. L. Driessen, and J. Reedijk. "Cyclic Voltammetric Behaviour of Some Copper Complexes with a BIS(Pyrazole)BIS(Thioether)Ligand." In Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1628-2_16.

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Blake, A. J., R. O. Gould, A. J. Holder, et al. "Redox-Structural Correlations in Metal Thioether Macrocyclic Complexes: The Stabilisation of Mononuclear Silver(II) and Gold(II)." In Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1628-2_13.

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Schenk, W. A., M. Dürr, B. Steinmetz, W. Adam, and C. R. Saha-Möller. "Enantioselective Oxidation of Thioethers Using Ruthenium Complexes as Chiral Auxiliaries." In Selective Reactions of Metal-Activated Molecules. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-662-00975-8_36.

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Blake, Alexander J., and Martin Schröder. "Chemistry of Thioether Macrocyclic Complexes." In Advances in Inorganic Chemistry. Elsevier, 1990. http://dx.doi.org/10.1016/s0898-8838(08)60160-9.

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Jagtap, Rahul A., and Benudhar Punji. "Copper(I) complexes of ether- and thioether-based phosphines." In Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles. Elsevier, 2019. http://dx.doi.org/10.1016/b978-0-12-815052-8.00010-5.

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Gaunt, A. J., J. H. Matonic, B. L. Scott, and M. P. Neu. "5f Element Complexes with ‘Soft’ Donor Atom Ligands: Eight Coordinate Pu(III) Pyrazinyl and Thioether Complexes." In Recent Advances in Actinide Science. The Royal Society of Chemistry, 2006. http://dx.doi.org/10.1039/bk9780854046782-00183.

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Pratim Das, Partha. "CHEMISTRY OF MACRO CYCLES CONTAINING ONLY SULFUR DONORS; SOME NOTEWORTHY RESULTS." In Futuristic Trends in Chemical Material Sciences & Nano Technology Volume 3 Book 1. Iterative International Publishers, Selfypage Developers Pvt Ltd, 2024. http://dx.doi.org/10.58532/v3bdcs1ch14.

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Thiamacrocycless how rich Coordination chemistry, producing isolated as well as polymeric metallo-supra molecular frameworks. Thia-donor networks' attraction towards soft metal ions and their capacity to help stabilising uncommon oxidation states for some metals are what define the way they interact. It is seen that thioether sulphur employed in a flexible macrocyclic framework will adopt a combination of an endo- and an exo- positioning with regard to that macrocyclic cavity, providing the development of endocyclic as well as exocyclic metal complexes. Additionally, the existence of exo-orien
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Stogniy, Marina Yu, Sergey V. Timofeev, Igor B. Sivaev, and Vladimir I. Bregadze. "Carborane-based Thioethers and Complexes Thereof." In Handbook of Boron Science. WORLD SCIENTIFIC (EUROPE), 2018. http://dx.doi.org/10.1142/9781786344649_0002.

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Quindt, Matías I., and Sergio M. Bonesi. "Photooxidation of thioethers: preparative and mechanistic investigations (2018–2022)." In Photochemistry. Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781837672301-00257.

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The photooxidation of thioethers under visible-light heterogeneous and homogeneous photocatalysis methodologies is reported dealing with preparative and mechanistic viewpoints of the photoreactions. The heterogeneous photocatalytic reactions involve the use of different metal–organic frameworks containing a wide variety of metals (Zr, Bi, Ru, VO2+, In, Ag, Sn, among others) providing outstanding photocatalytic performances. On the other hand, the homogeneous photocatalytic oxidation reactions of thioethers are based on visible-light photocatalytic and photoorganocatalytic methodologies. Photoc
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Whitehead, M. A. "The Self-Interaction Corrected Local Spin Density Approximation with Vosko, Wilk and Nusair Correlation and Full Relativistic Corrections: Application to Molecules, Cyclopropellanes, Ethers, Thioethers, Crown-Thioethers and their Ni, Co, Fe, and Cu Complexes." In Recent Advances in Density Functional Methods. WORLD SCIENTIFIC, 1997. http://dx.doi.org/10.1142/9789812819468_0007.

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Conference papers on the topic "Thioether complexes"

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Kesić, Ana S., Snežana Radisavljević, and Biljana V. Petrović. "SUBSTITUTION REACTIONS OF THE MONOFUNCTIONAL GOLD(III) COMPLEX AND SULPHUR-DONOR BIOLOGICALLY IMPORTANT LIGANDS." In 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.391k.

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Gold(III) complexes have found application in catalysis, materials science and medical inorganic chemistry. Considering that the right choice of inert ligands in the structure of Au(III) complexes is crucial for their properties and reactivity toward biomolecules, we have studied the substitution reactions between monofunctional Au(III) complex, [Au(Cl-Ph-tpy)Cl]Cl2 (Cl- Ph-tpy = 4′-(4-chlorophenyl)-2,2′:6′, 2″-terpyridine) and sulfur-donor biomolecules, glutathione (GSH) and L-methionine (L-Met), in 25 mM Hepes buffer (pH = 7.2) and 40 mM NaCl. The reactions were followed under the pseudo-fir
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Reports on the topic "Thioether complexes"

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Werst, D. W. Arene-thioether mixed complex radical cations. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10132711.

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