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Dissertations / Theses on the topic 'Thioether complexes'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Sullivan, Martin J. "Studies on thioether macrocyclic complexes." Thesis, University of Edinburgh, 1993. http://hdl.handle.net/1842/14515.

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An introduction to macrocyclic chemistry, with particular emphasis on [9]aneS<SUB>3</SUB> (1,4,7 - trithiacyclononane) and thioether macrocyclic transition metal complexes of groups VIII and IX is presented. The reaction of [RuC1<SUB>2</SUB>(PPh<SUB>3</SUB>)([9]aneS<SUB>3</SUB>)] with TIPF<SUB>6</SUB> in CH<SUB>2</SUB>C1<SUB>2</SUB> at 298K results in the formation of a mixture of complexes, [Ru(PPh<SUB>3</SUB>)([9]aneS<SUB>3</SUB>)(μ-C1)]<SUB>2</SUB>(PF<SUB>6</SUB>)<SUB>2</SUB> and [Ru(PPh<SUB>3</SUB>)([9]aneS<SUB>3</SUB>)(μ-C1)<SUB>2</SUB>T1]<SUB>2</SUB>(PF<SUB>6</SUB>)<SUB>2</SUB>, which ha

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2

Mullen, Gregory E. D. "Thioether complexes of rhenium and technetium." Thesis, University of Kent, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.264628.

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3

Taylor, Anne. "Studies of transition metal thioether macrocyclic complexes." Thesis, University of Edinburgh, 1991. http://hdl.handle.net/1842/14528.

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Chapter 1: A general discussion of macrocyclic co-ordination chemistry is given, with particular emphasis on the biological and catalytic relevance of macrocyclic systems. Chapter 2: Reproducible high yield synthesis of [Au ([9]aneS<SUB>3</SUB>)<SUB>2</SUB>](PF<SUB>6</SUB>) and [Au([9]aneS<SUB>3</SUB>)<SUB>2</SUB>](BF<SUB>4</SUB>)<SUB>2</SUB> have been established. [Au([9]aneS<SUB>3</SUB>)<SUB>2</SUB>]<SUP>2</SUP>+ undergoes a one-electron oxidation to Au(III) and an irreversible reduction to Au(I). The solution e.p.r. spectrum of [Au([9]aneS<SUB>3</SUB>)<SUB>2</SUB>]<SUP>2</SUP>+ shows an iso

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4

Mozol, Vivian Janet. "Utilising thioether-bridged ditungsten (III) complexes for metalloligand syntheses." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ31056.pdf.

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5

Reeves, GorDan T. Addison Anthony W. "Ruthenium(II) complexes of multidentate thioether and amine ligands /." Philadelphia, Pa. : Drexel University, 2009. http://hdl.handle.net/1860/3000.

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6

DuPont, Julie A. "The coordination chemistry of thioether-supported, low-valent cobalt complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file 3.92 Mb., 165 p, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&res_dat=xri:pqdiss&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&rft_dat=xri:pqdiss:3200521.

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7

Matondo, Simba Oliver Caleb. "Synthesis and characterisation of thioether containing ligands and their complexes." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259968.

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8

Bailey, Daniel. "High pressure studies of d-block thioether co-ordination complexes." Thesis, University of Nottingham, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.594819.

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9

Gibson, Alexander. "Syntheses and studies on transition metal complexes involving phosphine and thioether ligands." Thesis, University of Southampton, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243147.

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10

Mock, Michael T. "Synthesis and reactivity of thioether-supported organoiron and low-valent iron complexes and cyanide-bridged binuclear complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 282 p, 2008. http://proquest.umi.com/pqdweb?did=1481668291&sid=19&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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11

Connolly, Julie Christine. "Synthesis and studies on transition metal complexes incorporating thioether, selenoether and phosphine ligands." Thesis, University of Southampton, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284650.

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12

Cheu, Elizabeth Lai Shuen. "Thioether and sulfoxide complexes of ruthenium : preliminary in vitro studies of water-soluble species." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0020/NQ48618.pdf.

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13

Maresca, von Beckh Widmanstetter Carlo Alessandro. "Palladium and Ruthenium complexes of some bidentate thioether ligands synthesis, characterization and application in homogeneous catalysis." Thesis, University of Oxford, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.509991.

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14

SWANSON, DALE DORSETT. "ELECTROCHEMICAL AND SPECTROSCOPIC STUDIES OF THIOETHER COORDINATION COMPLEXES (CYCLIC VOLTAMMETRY, OCTAHEDRAL LOW-SPIN METALS, BLUE COPPER PROTEINS, ELECTRON PARAMAGNETIC RESONANCE)." Diss., The University of Arizona, 1985. http://hdl.handle.net/10150/188102.

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The bis 1,4,7-trithiacyclononane (1,4,7-TTCN) complexes of iron, cobalt, nickel and copper are reported in this work. Their properties have been examined using computer-controlled electrochemical and spectroscopic techniques. These TTCN complexes form readily, are unusually symmetrical and support electron transfer reactions at the metal center. The cobalt(II) complex is octahedral, low spin and symmetrical. Four oxidation states of cobalt-TTCN complex are observed; two one-electron transfer processes are reversible. Copper (II) bis 1,4,7-TTCN is unusually symmetrical evidenced by both solid p

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15

Cao, Zhen. "Functional gold and silver complexes and supramolecules based on 9,10-diphenylanthracenes : photoactivity, catalysis and chiroptical properties." Thesis, Bordeaux, 2020. http://www.theses.fr/2020BORD0142.

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Cette thèse décrit principalement la conception de ligands et la synthèse de leurs complexes d’or fonctionnels pour la catalyse. Des ligands thioéther ont été développés pour accéder aux complexes d'or (III) chlorure qui peuvent être photoréduits en l’or (I), en utilisant la lumière UV ou visible. Ces deux espèces d'or ont été exploitées en catalyse homogène en tant qu’acides de Lewis, lors d’une réaction ‘one pot’ de cyclisation en cascade conduisant à une composé polyhétéroaromatique fusionné. Des ligands de phosphine ont aussi été élaborés puis les complexes d'or(I) chlorure correspondants

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16

Sutton, Liam Richard. "Studies on functionalised crown thioethers." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285639.

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17

Gaudillat, Quentin. "Polymères de coordination et métallopolymères pour l'élaboration de matériaux et surfaces antibactériens." Electronic Thesis or Diss., Bourgogne Franche-Comté, 2024. http://indexation.univ-fcomte.fr/nuxeo/site/esupversions/5a9d8965-7f4d-4c00-b84c-1c53c0e9e067.

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L’objectif de cette thèse était d’élaborer des matériaux antibactériens en utilisant la chimie de coordination. Pour ce faire, ce travail a été mené selon trois axes de recherche distincts. Dans une première partie, nous avons synthétisé des polymères de coordination (CP) par auto-assemblage de ligands dithioéthers avec des sels d’argent(I). Cette approche se démarque de travaux précédents par l’utilisation d’une combinaison acide de Lewis faible/ligand donneur mou. Outre la caractérisation structurale de ces CPs, ce travail présente une étude approfondie de leur activitié antibactérienne et d

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18

NECHAB, BELKACEM. "Catalyse par les complexes du palladium, sous irradiation micro-ondes (heck, hydrogenolyse), par les materiaux hybrides (heck) et les zeolites (synthese de thioethers d'enols) : etude de la selectivite de forme." Caen, 1997. http://www.theses.fr/1997CAEN2039.

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La recherche de nouveaux modes d'activation des reactions est un domaine qui interesse les chimistes organiciens. L'application des micro-ondes a la reaction de heck permet de reduire considerablement les temps de reaction et de realiser ainsi de grandes economies. Le deroulement de cette reaction en milieu aqueux necessite l'usage d'une phosphine hydrosoluble. Nous avons prepare une nouvelle phosphine d'acide phosphonique qui donne de meilleurs resultats que les phosphines classiques. Ce mode d'activation par micro-ondes a ete aussi applique, avec les memes resultats que precedemment, a la re

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19

Hirsch, Jeffrey. "The inorganic and bioinorganic chemistry of copper thioether complexes." 2001. http://www.library.wisc.edu/databases/connect/dissertations.html.

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20

Pacheco-Olivella, Arsenio A. "The reaction of bis(thioether) complexes of (octaethylporphyrinato)ruthenium(II) with dioxygen, and the catalyzed O₂-oxidation of thioethers." Thesis, 1992. http://hdl.handle.net/2429/2383.

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This thesis describes a detailed study of the reactivity of Ru(OEP)(RR'S)₂ complexes (where OEP ≋ the dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin, R ≋ methyl, ethyl or decyl, and R' ≋ methyl or ethyl) with 0₂, in various solvents. Exposure to O₂ (or air) of a benzene, toluene or methylene chloride solution containing PhCOOH and Ru(OEP)(RR’S)₂ at ambient conditions, results in the selective oxidation of the axial ligand(s) on the metalloporphyrin complex to the corresponding sulfoxide(s). For a CD₂Cl₂ solution containing ≈ 20 mM of Ru(OEP)(dms)₂ (dms ≋ dimethylsulfide) and ≈ 12 mM PhCOO

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21

Kuo, Tai-Heng, and 郭泰亨. "Synthesis and Catalysis of Thioether- and Sulfoxide- Functionalized N-Heterocyclic Carbene Platinum Complexes." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/07008366270047661151.

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碩士<br>國立臺灣大學<br>化學研究所<br>101<br>Two series of (Thioether-NHC-R)Pt(ɳ3-CH2C(Me)CH2)X and (Sulfoxide-NHC-R)Pt(ɳ3-CH2C(Me)CH2)X (R = Me, Ph, and X = Cl, PF6) complexes have been successfully synthesized as well and characterized by NMR spectroscopy and X-ray crystallography. All of the allylplatinum(II) complexes have exo/endo isomers. In the S-NHC Pt complexes, the signals of backbone and NHC ligand which showed broad signals were observed in 1H NMR spectra. The exo-endo exchange cross peaks of the allylic group were also observed in 2D NMR spectra. But in the SO-NHC Pt complexes, the signals

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22

Yu, Chi-Ying, and 余祈瑩. "The Study of Rhodium and Silver Complexes with Thioether- and Sulfoxide-Functionalized N-HeterocyclicCarbene Ligands." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/90083317770271409897.

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碩士<br>國立臺灣大學<br>化學研究所<br>102<br>We have synthesized a series of thioether- and sulfoxide-functionalized NHCs (S-NHC and SO-NHC) ligands and investigated their complexes of rhodium(I) and silver(I). All synthesized complexes [(S-NHC)Rh(COD)]X, [(SO-NHC)Rh(COD)]X (X = Cl or BF4), (S-NHC)-AgCl and [(SO-NHC)2Ag]+AgCl2- have been fully characterized by detailed NMR studies and molecular structures of some of these complexes were elucidated by X-ray crystallography. In rhodium complexes, competing coordination with metal center between sulfur atom and chloride ion was found in neutral complexes with

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23

陳佳慧. "Conversion of Nitriles with (2-Mercaptophenyl)phosphines to Phosphine Thioether Heterocycle in the Presence of Nickel (2-Mercaptophenyl)phosphine Complexes." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/75769649938662405378.

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碩士<br>國立臺灣師範大學<br>化學系<br>95<br>Abstract Two ligands, P(C6H5)(o-C6H4SH)2 (PS2) and P(C6H5)2(o-C6H4SH) (PS1), were employed to react with [Ni(CH3CN)6](ClO4)2 in acetonitrile or propionitrile to form three nickel complexes, [Ni(P(C6H5)(o-C6H4S)(o- C6H4SC(CH3)NH2)2)](ClO4)2 (1), [Ni(P(C6H5)(o-C6H4S)(o-C6H4SC(CH3- CH2)NH2)2)](ClO4)2 (2), and [Ni2(P(C6H5)(o-C6H4S)2)] (4), and a heterocycle phosphine of (P((o-C6H4SC(CH3)NH3)(C6H5)2))(ClO4)2 (5). The conversion of acetonitrile or propionitrile to thioimino ester on the mercapto phosphine ligands of nickel complexes 1 and 2 were observed. The resulti

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24

Todd, Erin Kathleen. "Polyaromatic ethers and thioethers coordinated to cyclopentadienyliron complexes." 2003. http://hdl.handle.net/1993/20017.

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25

Wang, Chia-Ching, and 王嘉慶. "Synthesis and Catalysis of Thioethers-Functionalized N-Heterocyclic Carbene Palladium Complexes." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/05553396663289040170.

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碩士<br>國立臺灣大學<br>化學研究所<br>100<br>The hemilability of six- and seven- membered ring metallacycle of thioether-functionalized NHC palladium complexes were observed in solution; therefore, the five-membered ring metallacycle complexes which were constituted by the methyl- tethered thioether-NHC lgands could also exhibit hemilabile behavior in solution. The methyl- and ethyl-tethered thioether(S)-imidazolium salts have been successfully synthesized and employed to afford the N-heterocyclic carbene (NHC) silver derivatives as carbene precursors of transmetallation. The resulting (S-NHC)PdCl2 complex

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