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Journal articles on the topic 'Thioether complexes'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Boeré, René T., and Christopher J. Willis. "Complexes of hybrid ligands. Pd2+ and Pt2+ complexes of new fluoro-alcohol thioether ligands; the use of thioether inversions to make structural assignments." Canadian Journal of Chemistry 63, no. 12 (1985): 3530–36. http://dx.doi.org/10.1139/v85-579.

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The fluorinated alcohol–thioethers RSCH2C(CF3)2OH (R = Me, Ph) have been synthesized by the reaction of RSCH2Li with (CF3)2CO. By ionization of the fluoroalcohol group, these may act as bidentate, uninegative, ligands L−. The presence of the soft thioether function in the hybrid ligand stabilizes the bond to the harder fluoro-alkoxy group, and complexes with soft transition metals are formed. Neutral complexes PdL2 and PtL2 have been synthesized, and, by the use of nmr, the geometry of the complexes is assigned as cis for Pt complexes, while both cis and trans are observed for Pd.The barrier t

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2

Wang, Hai Ming, та Gerhard Wenz. "Topochemical control of the photodimerization of aromatic compounds by γ-cyclodextrin thioethers in aqueous solution". Beilstein Journal of Organic Chemistry 9 (12 вересня 2013): 1858–66. http://dx.doi.org/10.3762/bjoc.9.217.

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The formation of soluble 1:2 complexes within hydrophilic γ-cyclodextrin (γ-CD) thioethers allows to perform photodimerizations of aromatic guests under controlled, homogenous reaction conditions. The quantum yields for unsubstituted anthracene, acenaphthylene, and coumarin complexed in these γ-CD thioethers were found to be up to 10 times higher than in the non-complexed state. The configuration of the photoproduct reflected the configuration of the dimeric inclusion complex of the guest. Anti-parallel orientation of acenaphthylene within the CD cavity led to the exclusive formation of the an

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3

Sellmann, Dieter, Peter Lechner, and Matthias Moll. "Übergangsmetallkomplexe mit Schwefelliganden, LXXII / Transition Metal Complexes with Sulfur Ligands, LXXII." Zeitschrift für Naturforschung B 46, no. 11 (1991): 1459–69. http://dx.doi.org/10.1515/znb-1991-1103.

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Racemic [Ru(ClH)(PPh3)′S4'] · CH2Cl2 (′S4'2-= 1,2-bis(2-mercaptophenylthio)ethane(2—)) reacts with monodentate sulfur ligands L to yield diastereospecifically yellow adducts [Ru(L)(PPh3)′S4']. Asymmetric achiral thioethers (L = SPhMe, CH3SSCH3) give only one of two potentially possible pairs of enantiomers, chiral thioethers and thiols (L = N-Acetyl-(L)-Methionin, N-Acetyl-(L)Methionin-methylester, S-Methyl-(L)Cystein, N-Acetyl-(L)Cystein) only two of four potentially possible diastereomers in the ratio 1:1.These results prove that the diastereospecifity is related to the coordinated thioether

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4

Smolyaninov, Ivan V., Georgy K. Fukin, Nadezhda T. Berberova, and Andrey I. Poddel’sky. "Triphenylantimony(V) Catecholates of the Type (3-RS-4,6-DBCat)SbPh3-Catechol Thioether Derivatives: Structure, Electrochemical Properties, and Antiradical Activity." Molecules 26, no. 8 (2021): 2171. http://dx.doi.org/10.3390/molecules26082171.

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A new series of triphenylantimony(V) 3-alkylthio/arylthio-substituted 4,6-di-tert-butylcatecholates of the type (3-RS-4,6-DBCat)SbPh3, where R = n-butyl (1), n-hexyl (2), n-octyl (3), cyclopentyl (4), cyclohexyl (5), benzyl (6), phenyl (7), and naphthyl-2 (8), were synthesized from the corresponding catechol thioethers and Ph3SbBr2 in the presence of a base. The crystal structures of 1, 2, 3, and 5 were determined by single-crystal X-ray analysis. The coordination polyhedron of 1–3 is better described as a tetragonal pyramid with a different degree of distortion, while that for 5- was a distor

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5

Muravev, Anton, Ayrat Yakupov, Tatiana Gerasimova, et al. "Thiacalixarenes with Sulfur Functionalities at Lower Rim: Heavy Metal Ion Binding in Solution and 2D-Confined Space." International Journal of Molecular Sciences 23, no. 4 (2022): 2341. http://dx.doi.org/10.3390/ijms23042341.

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Sulfur-containing groups preorganized on macrocyclic scaffolds are well suited for liquid-phase complexation of soft metal ions; however, their binding potential was not extensively studied at the air–water interface, and the effect of thioether topology on metal ion binding mechanisms under various conditions was not considered. Herein, we report the interface receptor characteristics of topologically varied thiacalixarene thioethers (linear bis-(methylthio)ethoxy derivative L2, O2S2-thiacrown-ether L3, and O2S2-bridged thiacalixtube L4). The study was conducted in bulk liquid phase and Langm

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6

Wang, Hai Ming, та Gerhard Wenz. "Molecular solubilization of fullerene C60 in water by γ-cyclodextrin thioethers". Beilstein Journal of Organic Chemistry 8 (28 вересня 2012): 1644–51. http://dx.doi.org/10.3762/bjoc.8.188.

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Various hydrophilic γ-cyclodextrin (CD) thioethers, containing neutral or ionic side arms were found to form molecular disperse solutions of C60 in water reaching concentrations of 15 mg/L. Equilibrium state was approached after seven days without the use of organic cosolvents. The 1:2 stoichiometry of the C60/γ-CD thioether complexes was demonstrated by a parabolic phase-solubility diagram. In contrast, native γ-CD forms nanoparticles with C60. Particle sizes of C60 were determined by dynamic light scattering.

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7

Lucas, C. Robert. "Thioether complexes of tungsten hexacarbonyl." Canadian Journal of Chemistry 64, no. 9 (1986): 1758–63. http://dx.doi.org/10.1139/v86-290.

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The preparation of a series of organic and organometallic thioethers R3MSR′ (M = C, Si, Ge, or Sn) is reported. From these, several new compounds of type 1 are synthesized, some of which contain para-substituted aryl functions for R′ and R. In hexane solution in the carbonyl stretching region of the ir and in the uv there is evidence for a degree of multiple bonding, at least in the M—S—W—CO portion of these molecules. Multiple bonding extending into aromatic R or R′ is small or non-existent and cannot be assessed precisely because of spontaneous decomposition of the complexes. All the complex

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8

Čubrilo, Jadranka, Ingo Hartenbach, Falk Lissner, Thomas Schleid, Mark Niemeyer, and Rainer F. Winter. "p-Cymene ruthenium thioether complexes." Journal of Organometallic Chemistry 692, no. 7 (2007): 1496–504. http://dx.doi.org/10.1016/j.jorganchem.2006.11.046.

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9

Wu, Huikang, and C. Robert Lucas. "Stereochemical nonrigidity in thioether complexes." Inorganic Chemistry 31, no. 12 (1992): 2354–58. http://dx.doi.org/10.1021/ic00038a012.

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10

Cooper, Stephen R., Simon C. Rawle, JudithAnn R. Hartman, Eric J. Hintsa, and Gary A. Admans. "Crown thioether chemistry: homoleptic hexakis(thioether) complexes of nickel(II)." Inorganic Chemistry 27, no. 7 (1988): 1209–14. http://dx.doi.org/10.1021/ic00280a023.

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11

Basab, Adhikari, Pramanik Shuvam, Ghorui Tapas, Roy Sima, Das Ujjwal, and Pramanik Kausikisankar. "Pyridyl-imine-thioether complexes of ruthenium(II) : Synthesis, structure and optoelectronic and electron transfer properties." Journal of Indian Chemical Society Vol. 92, Dec 2015 (2015): 1903–12. https://doi.org/10.5281/zenodo.5600044.

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Department of Chemistry, Inorganic Chemistry Section, Jadavpur University, Kolkata-700 032, India <em>E-mail </em>: kpramanik@hotmail.com Reactions of alkyl/aryl (2-pyridylimine)phenyl thioether (L<sup>SR</sup>) with RuCl<sub>2</sub> (PPh<sub>3</sub> )<sub>3</sub> in ethanolic medium afford thioether complexes of type [Ru(L<sup>SR</sup>)Cl(PPh<sub>3</sub> )<sub>2</sub> ]PF<sub>6</sub> (R = benzyl, phenyl). The ligands behave as tridentate neutral N<sub>py</sub>N<sub>imine</sub>S<sub>thioether</sub> donor retaining the C-S bond and bind to the metal atom in meridional fashion. The complexes wer

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12

Fritz, Thorsten, Gunther Steinfeld, and Berthold Kersting. "Preparation and Characterization of Mononuclear Ni Complexes of Tetradentate Amine-thioether and Amine-thiolate Ligands." Zeitschrift für Naturforschung B 62, no. 4 (2007): 508–18. http://dx.doi.org/10.1515/znb-2007-0404.

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A short route for the preparation of tetradentate amine-thioether and amine-thiolate ligands derived from thiosalen is reported. The ligating properties of several of the synthesized ligands towards Ni(II) has been examined. The diamine-dithiophenolate ligands (L6)2− [H2L6 = N,N′-dimethyl-N,N;-di(2- mercaptobenzyl)-ethane-1,2-diamine] and (L7)2− [H2L7 = N,N′-di(2-mercaptobenzyl)-piperazine] support the formation of four-coordinate NiIIN2S2 complexes [NiII(L6)] (10) and [NiII(L7)] (11). By contrast, the amine-thioethers 2 [N′,N″-bis(2-(tert-butylthio)benzyl)ethane-1,2-diamine], L2 [8,11- diaza-

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13

Ulm, Franck, Amalia I. Poblador-Bahamonde, Sabine Choppin та ін. "Synthesis, characterization, and catalytic application in aldehyde hydrosilylation of half-sandwich nickel complexes bearing (κ1-C)- and hemilabile (κ2-C,S)-thioether-functionalised NHC ligands". Dalton Transactions 47, № 47 (2018): 17134–45. http://dx.doi.org/10.1039/c8dt03882a.

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14

Sellmann, Dieter, Helmut Schillinger, and Falk Knoch. "Übergangsmetallkomplexe mit Schwefelliganden, LXXXVI. Säure-Base- und Redox-Reaktionen von [Ni(′MeS2′)2] mit H+, PMe3, NO+ und NO. Röntgenstrukturanalyse von [Ni(PMe3)(′MeS2′)2] (′MeS2′ = o-(Methylthio)thiophenolat(1–)) / Transition-Metal Complexes with Sulfur Ligands, LXXXVI. Acid-Base and Redox Reactions of [Ni(′MeS2')2] with H+, PMe3, NO+ and NO. X-Ray Structure Determination of [Ni(PMe3)(′MeS2′)2] (′MeS2′ = o-(methylthio)thiophenolate(1–))." Zeitschrift für Naturforschung B 47, no. 5 (1992): 748–54. http://dx.doi.org/10.1515/znb-1992-0523.

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In order to elucidate specific properties of nickel-sulfur complexes, addition and substitution reactions of [Ni(′MeS2′)2] (1) were investigated. 1 is rapidly hydrolyzed by aqueous HCl yielding ′MeS2′–H and Ni(II) ions. 1 coordinates phosphines as coligands, thioether donors decoordinate, however, simultaneously. The monophosphine complex [Ni(PMe3)(′MeS2′ )2] (2) was characterized by X-ray structure determination. It contains a square-planar NiS3P unit and one decoordinated thioether group. Redox reactions of 1 occur with NO+ and NO, yielding the binuclear nitrosyl complexes cis- and trans-[Ni

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15

Hanzl, Lukáš, Jaromír Vinklárek, Libor Dostál, Ivana Císařová, Miroslava Litecká, and Jan Honzíček. "Stabilization of propene molybdenum and tungsten half–sandwich complexes by intramolecular coordination of a thioether function." RSC Advances 13, no. 29 (2023): 19746–56. http://dx.doi.org/10.1039/d3ra03383j.

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16

Goh, Lai Yoong, Ming Ern Teo, Soo Beng Khoo, Weng Kee Leong, and Jagadese J. Vittal. "Cyclic thioether and acyclic thioether–thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)." Journal of Organometallic Chemistry 664, no. 1-2 (2002): 161–69. http://dx.doi.org/10.1016/s0022-328x(02)01977-0.

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17

Stewart, Jack, Martin Fuchs, Jack Payne, et al. "Simple Zn(ii) complexes for the production and degradation of polyesters." RSC Advances 12, no. 3 (2022): 1416–24. http://dx.doi.org/10.1039/d1ra09087a.

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18

Dierkes, Peter, Gerlinde Frenzen, Sigrid Wocadlo, et al. "Komplexe des Typs [MCl4(SEt2)2] mit M = Mo und W. Kristallstrukturen, NMR-Spektren und magnetisches Verhalten/[MCl4(SEt2)2] Complexes with M = Mo and W. Crystal Structures, NMR Spectra, and Magnetic Behaviour." Zeitschrift für Naturforschung B 50, no. 2 (1995): 159–67. http://dx.doi.org/10.1515/znb-1995-0201.

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The crystal structures of the thioether complexes [MCl4(SEt2)2] with M = Mo and W have been solved by X-ray methods. Both compounds crystallize isotypically in the triclinic space group P1̄ with two formula units per cell unit. The metal atoms are octahedrally coordinated by four chlorine atoms and by the two sulfur atoms of the thioether molecules in transposition (symmetry Ci) with bond lengths (average): Mo-Cl 233.1, Mo-S 253.4, W-Cl 233.1, and W-S 251.7 pm. Both complexes were also characterized by 1H and 13C NMR spectroscopy as well as by measurement of the magnetic susceptibilities in th

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19

Azpeitia, S., U. Prieto, E. San Sebastián, A. Rodríguez-Diéguez, M. A. Garralda та M. A. Huertos. "Alkene-alkyl interconversion: an experimental and computational study of the olefin insertion and β-hydride elimination processes". Dalton Transactions 47, № 19 (2018): 6808–18. http://dx.doi.org/10.1039/c8dt00448j.

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20

Schenk, Wolfdieter A., Bernhard Steinmetz, Michael Hagel, Waldemar Adam, and Chantu R. Saha-Möller. "Oxyfunctionalization of Allyl Thioether Ruthenium Complexes with Dimethyldioxirane." Zeitschrift für Naturforschung B 52, no. 11 (1997): 1359–71. http://dx.doi.org/10.1515/znb-1997-1114.

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Abstract Allyl thioether complexes [CpRu(P-P)(SRR′)]PF6 (P-P = Ph2PCH2PPh2 (dppm), Ph2PC2H4PP2 (dppe), R = Me, Et, Ph, R′ = 3-propenyl, 3-cyclohexenyl, 2-methyl-2-buten-4-yl) and [CpRu(chir)(SRR′)]PF6 (chir = (S,S)-Ph2PCHMeCHMePPh2, R = Me, CH2Ph, R′ = 2-methyl-2-buten-4-yl) are obtained from the corresponding thiolate complexes by reaction with the appropriate allyl bromide. Careful oxidation with dimethyldioxirane (DMD) gave the allyl sulfoxide complexes [CpRu(P-P)(MeS(O)CH2CH=CH2)]PF6 (P-P = dppm, dppe). Double oxidation to the corresponding sulfinylmethyl epoxide complexes can be readily a

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21

Chen, Weiguang, Julien Egly, Amalia I. Poblador-Bahamonde, Aline Maisse-Francois, Stéphane Bellemin-Laponnaz та Thierry Achard. "Synthesis, characterization, catalytic and biological application of half-sandwich ruthenium complexes bearing hemilabile (κ2-C,S)-thioether-functionalised NHC ligands". Dalton Transactions 49, № 10 (2020): 3243–52. http://dx.doi.org/10.1039/c9dt04825a.

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22

Lucas, C. Robert, and S. Liu. "Macrocylic thioether-esters and thioether-thioesters and their palladium, platinum and silver complexes." Inorganica Chimica Acta 230, no. 1-2 (1995): 133–38. http://dx.doi.org/10.1016/0020-1693(94)04310-r.

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23

Boeré, René T., and Christopher J. Willis. "Complexes of hybrid ligands. Some Pd2+ and Pt2+ complexes of fluoro-alkoxy thioether ligands; the measurement of the trans-effect of phosphines on thioether inversion." Canadian Journal of Chemistry 64, no. 3 (1986): 492–99. http://dx.doi.org/10.1139/v86-078.

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The hybrid ligands R—S—CH2—C(CF3)2—O− (R = CH3 or C6H5) have been used in conjunction with the other donors to prepare complexes of Pt2+ and Pd2+. Five-membered chelate rings are formed by coordination through the hard alkoxy and the soft thioether donor sites. Products are of two types: neutral MCl{RSCH2C(CF3)2O}(PR3) or cationic [M{RSCH2C(CF3)2O}(PR3)2]+, and their geometry is assigned. Variable temperature nmr measurements are used to follow the inversion of the thioether function in the hybrid chelate ring, and values of ΔG‡ are calculated. From a comparison of the barrier to inversion in

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24

Lichtenberg, Crispin, Jan Bloch, Thomas L. Gianetti, Torsten Büttner, Jens Geier, and Hansjörg Grützmacher. "Diolefins with an ether/thioether functionality as ligands in the coordination sphere of Ni and Rh." Dalton Transactions 44, no. 46 (2015): 20056–66. http://dx.doi.org/10.1039/c5dt03279b.

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A diolefin ether, trop<sub>2</sub>O, and a diolefin thioether, trop<sub>2</sub>S, were prepared and coordinated to Ni(0) or Rh(i). A comparison of the electrochemical data with corresponding amine diolefin complexes reveal the differences in stabilizing various oxidation states of these complexes.

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25

Prasad, Rajendra, Anil Kumar, Elisa Murguly та Neil Branda. "Coordination complexes of β-thioether appended tetraazaporphyrin". Inorganic Chemistry Communications 4, № 5 (2001): 219–22. http://dx.doi.org/10.1016/s1387-7003(01)00146-0.

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26

Dahcheh, Fatme, and Douglas W. Stephan. "Ruthenium and Rhodium Complexes of Thioether-Alkynylborates." Organometallics 31, no. 8 (2012): 3222–27. http://dx.doi.org/10.1021/om300075r.

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27

Cao, Zhen, Aline Lacoudre, Cybille Rossy, and Brigitte Bibal. "Self-assembled coordination thioether silver(I) macrocyclic complexes for homogeneous catalysis." Beilstein Journal of Organic Chemistry 15 (October 17, 2019): 2465–72. http://dx.doi.org/10.3762/bjoc.15.239.

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The bis-ortho-thioether 9,10-bis[(o-methylthio)phenyl]anthracene was synthesized as a syn-atropisomer, as revealed by X-ray diffraction. This alkylaryl thioether ligand (L) formed different macrocyclic complexes by coordination with silver(I) salts depending on the nature of the anion: M2L2 for AgOTf and AgOTFA, M6L4 for AgNO3. A discrete M2L complex was obtained in the presence of bulky PPh3AgOTf. These silver(I) complexes adopted similar structures in solution and in the solid state. As each sulfur atom in the ligand is prochiral, macrocycles L2M2 were obtained as mixtures of diastereoisomer

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28

Lucas, C. Robert, Shuang Liu, Michael J. Newlands, and Eric J. Gabe. "X-ray structural and nuclear magnetic resonance study of open chain and macrocyclic thioether complexes." Canadian Journal of Chemistry 68, no. 8 (1990): 1357–63. http://dx.doi.org/10.1139/v90-208.

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Preparations of the thiophenophane and open chain thioether complexes MX2•BBTE(M = Pd; X = Cl, I)(M = Pt; X = Cl) (BBTE = 1,2-bis(benzylthio)ethane) and MX2•L (M = Pd; X = Cl, Br, I, SCN) (M = Pt; X = Cl) (L = 2,5,8-trithia[9](2,5)thiophenophane) are described. The molecular structure of PdBr2•L which contains a weak thiophene-sulfur-to-palladium interaction has been determined: space group P21/n, a = 8.3569(3), b = 16.3254(15), c = 11.1462(3) Å, β = 92.833(4)°, Z = 4, Rf = 0.060, Rw = 0.058. The electronic, low frequency ir, and 13C nmr spectra are described. Variable temperature 1H nmr spect

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29

Mattia, Veronelli, Kindermann Nicole, Dechert Sebastian, and Meyer Franc. "Palladium(II) complexes of pyrazolate ligands with thioether chelate arms." Journal of Indian Chemical Society Vol. 92, Dec 2015 (2015): 1973–80. https://doi.org/10.5281/zenodo.5602449.

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Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstr. 4, D-37077 Göttingen, Germany <em>E-mail</em> : franc.meyer@chemie.uni-goettingen.de Two 3,5-disubstituted pyrazole derivatives with one (HL<sup>1</sup> ) or two (HL<sup>2</sup> ) thioether functions per side arm have been used as ligands towards Ag<sup>I</sup> and Pd<sup>II</sup> ions. Both form the metallamacrocylic complexes [AgL<sup>1/2</sup>]<sub>3</sub> (1, 3) with a common [Ag(µ-pz)]<sub>3</sub> core. In the presence of excess AgI in acetone solution, 3 converts into hexametallic

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30

Anufriev, Sergei A., Maria V. Zakharova, Marina Yu Stogniy, Igor B. Sivaev, and Vladimir I. Bregadze. "Novel sulfur containing derivatives of carboranes and metallacarboranes." Pure and Applied Chemistry 90, no. 4 (2018): 633–42. http://dx.doi.org/10.1515/pac-2017-0908.

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AbstractA series of newcloso- andnido-carborane based functional derivatives 1-X(CH2)nS-1,2-C2B10H11(X=COOH, N3, CH(NH2)COOH) and [7-X(CH2)nS-7,8-C2B9H11]−(X=COOH, N3, NH2, CH(NH2)COOH) was prepared by alkylation of 1-mercapto-ortho-carborane. Dialkylsulfonium derivatives ofnido-carborane 9-R(Me)S-7,8-C2B9H11and 10-R(Me)S-7,8-C2B9H11with boron-sulfur bond were prepared by alkylation of the corresponding methyl-carboranyl thioether. New types of intramolecular B–H···X and B–H···π(C≡C) interactions were found innido-carborane alkylmethyl sulfonium derivatives 9-XCH2S(Me)S-7,8-C2B9H11and 10-RC≡CC

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31

Kuipers, Anneke, Jenny Meijer-Wierenga, Rick Rink, Leon D. Kluskens, and Gert N. Moll. "Mechanistic Dissection of the Enzyme Complexes Involved in Biosynthesis of Lacticin 3147 and Nisin." Applied and Environmental Microbiology 74, no. 21 (2008): 6591–97. http://dx.doi.org/10.1128/aem.01334-08.

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ABSTRACT The thioether rings in the lantibiotics lacticin 3147 and nisin are posttranslationally introduced by dehydration of serines and threonines, followed by coupling of these dehydrated residues to cysteines. The prepeptides of the two-component lantibiotic lacticin 3147, LtnA1 and LtnA2, are dehydrated and cyclized by two corresponding bifunctional enzymes, LtnM1 and LtnM2, and are subsequently processed and exported via one bifunctional enzyme, LtnT. In the nisin synthetase complex, the enzymes NisB, NisC, NisT, and NisP dehydrate, cyclize, export, and process prenisin, respectively. He

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32

Blake, A. J., L. M. Gilby, R. O. Gould, V. Lippolis, S. Parsons, and M. Schröder. "Macrocyclic Thioether Complexes of Palladium with Dibromoiodide Anions." Acta Crystallographica Section C Crystal Structure Communications 54, no. 3 (1998): 295–98. http://dx.doi.org/10.1107/s0108270197014212.

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33

Wong, H. L. S., A. J. Blake, J. McMaster, M. Schröder, and D. R. Allan. "Study of palladium thioether complexes at high pressure." Acta Crystallographica Section A Foundations of Crystallography 67, a1 (2011): C44. http://dx.doi.org/10.1107/s0108767311099004.

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34

Ehweiner, Madeleine A., Carina Vidovič, Ferdinand Belaj, and Nadia C. Mösch-Zanetti. "Bioinspired Tungsten Complexes Employing a Thioether Scorpionate Ligand." Inorganic Chemistry 58, no. 12 (2019): 8179–87. http://dx.doi.org/10.1021/acs.inorgchem.9b00973.

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35

Reeves, GorDan T., Anthony W. Addison, Matthias Zeller, and Allen D. Hunter. "Ru(II) thioether complexes with dangling pyridine ligands." Polyhedron 68 (January 2014): 70–75. http://dx.doi.org/10.1016/j.poly.2013.10.001.

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36

Prushan, Michael J., Anthony W. Addison, Raymond J. Butcher, and Laurence K. Thompson. "Copper(II) complexes of tetradentate thioether-oxime ligands." Inorganica Chimica Acta 358, no. 12 (2005): 3449–56. http://dx.doi.org/10.1016/j.ica.2005.04.038.

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37

Chakraborty, Partha, Swapan Kumar Chandra, and Animesh Chakravorty. "Hexacoordinated complexes of bivalent zinc incorporating thioether binding." Inorganica Chimica Acta 229, no. 1-2 (1995): 477–81. http://dx.doi.org/10.1016/0020-1693(94)04273-x.

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38

Wallenstein, Joachim Hedberg, Jonas Sundberg, Christine J. McKenzie, and Maria Abrahamsson. "Emissive Ruthenium-Bisdiimine Complexes with Chelated Thioether Donors." European Journal of Inorganic Chemistry 2016, no. 6 (2016): 897–906. http://dx.doi.org/10.1002/ejic.201501256.

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39

Sellmann, D., H. Schillinger, and F. Knoch. "Übergangsmetallkomplexe mit Schwefelliganden, LXXXV. / Transition-Metal Complexes with Sulfur Ligands, LXXXV." Zeitschrift für Naturforschung B 47, no. 5 (1992): 645–55. http://dx.doi.org/10.1515/znb-1992-0507.

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Abstract:

Ni(II) salts and the tetradentate thioether-thiolate ligand ′S4-C2′2- (= 1,2-bis(2-mercaptophenylthio)ethane(2-)) yield [Ni(′S4-C2′)]x (1), that also forms when Na2[Ni(′S2′ )2] (′S22-′ = o-benzenedithiolate(2-)) is alkylated by 1,2-dibromoethane. In boiling pyridine 1 adds two solvent molecules and gives pseudooctahedral [Ni(pyr)2(′S4-C2′ )] (2) which was characterized by X-ray structure determination. Reaction of 1 with PMe3 yields [Ni(PMe3)(′S4-C2′)] (4). X-ray structure determination of 4 showed that the Ni center is surrounded by one P and four S atoms in a distorted tetragonal pyramid in

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40

Smith, Danielle E., Victoria K. Greenacre, Andrew L. Hector, et al. "Thioether complexes of WSCl4, WOCl4 and WSCl3 and evaluation of thiochloride complexes as CVD precursors for WS2 thin films." Dalton Transactions 49, no. 8 (2020): 2496–504. http://dx.doi.org/10.1039/d0dt00068j.

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Thioether complexes of WECl<sub>4</sub> and WECl<sub>3</sub> (E = S, O) are prepared and characterised; the dinuclear [(WSCl<sub>4</sub>)<sub>2</sub>{<sup>i</sup>PrS(CH<sub>2</sub>)<sub>2</sub>S<sup>i</sup>Pr}] is shown to be an effective single source precursor for low pressure CVD of WS<sub>2</sub> thin films.

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41

Adams, Richard D., and Joseph Kiprotich. "Coordination chemistry of thioether-carboranes in polynuclear metal carbonyl cluster complexes. B-H activation of thioether-carboranes by dirhenium carbonyl complexes." Journal of Organometallic Chemistry 865 (June 2018): 23–28. http://dx.doi.org/10.1016/j.jorganchem.2017.09.004.

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42

Pietzsch, Hans-Juergen, Hartmut Spies, Peter Leibnitz, and Guenter Reck. "Technetium and rhenium complexes with thioether ligands—IV. Synthesis and structural characterization of binuclear oxorhenium(V) complexes with bidentate thioether coordination." Polyhedron 14, no. 13-14 (1995): 1849–53. http://dx.doi.org/10.1016/0277-5387(94)00470-y.

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43

Chang, Yao-Pang, Andrew L. Hector, William Levason, Gillian Reid, and Joshua Whittam. "Synthesis and properties of MoCl4complexes with thio- and seleno-ethers and their use for chemical vapour deposition of MoSe2and MoS2films." Dalton Transactions 47, no. 7 (2018): 2406–14. http://dx.doi.org/10.1039/c7dt04352j.

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Abstract:

A new series of Mo(iv) chloride complexes with thioether and seleneoether ligands is reported; [MoCl<sub>4</sub>(<sup>n</sup>Bu<sub>2</sub>E)<sub>2</sub>] (E = S, Se) function as single source precursors for the CVD of MoE<sub>2</sub>thin films.

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44

Rosen, Mari S., Charlotte L. Stern, and Chad A. Mirkin. "Heteroligated PtII Weak-Link Approach complexes using hemilabile N-heterocyclic carbene–thioether and phosphino–thioether ligands." Chemical Science 4, no. 11 (2013): 4193. http://dx.doi.org/10.1039/c3sc51557e.

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45

Cressy, Derek, Cristian Zavala, Anthony Abshire, William Sheffield, and Ampofo Darko. "Tuning Rh(ii)-catalysed cyclopropanation with tethered thioether ligands." Dalton Transactions 49, no. 44 (2020): 15779–87. http://dx.doi.org/10.1039/d0dt03019h.

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46

Chang, Yao-Pang, Andrew L. Hector, William Levason, and Gillian Reid. "Chalcogenoether complexes of Nb(v) thio- and seleno-halides as single source precursors for low pressure chemical vapour deposition of NbS2 and NbSe2 thin films." Dalton Transactions 46, no. 30 (2017): 9824–32. http://dx.doi.org/10.1039/c7dt01911d.

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A series of thioether complexes of NbSCl<sub>3</sub> has been prepared and selected examples demonstrated as precursors to 3R-NbS<sub>2</sub> films; deposition of 2H-NbSe<sub>2</sub> from [NbSe<sub>2</sub>Cl<sub>3</sub>(Se<sup>n</sup>Bu<sub>2</sub>)] is also reported.

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47

Gushchin, Artem L., Nikita Y. Shmelev, Svetlana F. Malysheva, et al. "Hemilability of phosphine-thioether ligands coordinated to trinuclear Mo3S4 cluster and its effect on hydrogenation catalysis." New Journal of Chemistry 42, no. 21 (2018): 17708–17. http://dx.doi.org/10.1039/c8nj03720e.

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Phosphine-thioether ligands were coordinated to the Mo<sub>3</sub>S<sub>4</sub> cluster to afford [Mo<sub>3</sub>S<sub>4</sub>Cl<sub>3</sub>(PS)<sub>3</sub>]<sup>+</sup> complexes. Their catalytic activity in nitrobenzene reduction reflects the different hemilabile behaviours of PS1, PS2 and PS3.

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Gilbert, Jayakumar G., Anthony W. Addison, Alexander Y. Nazarenko, and Raymond J. Butcher. "Copper(II) complexes of new unsymmetrical NSN thioether ligands." Inorganica Chimica Acta 324, no. 1-2 (2001): 123–30. http://dx.doi.org/10.1016/s0020-1693(01)00564-3.

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49

Kim, Jang Sub, Joseph H. Reibenspies, and Marcetta Y. Darensbourg. "Lightinduced sulfur-dealkylation of phosphino-thioether nickel(0) complexes." Inorganica Chimica Acta 250, no. 1-2 (1996): 283–94. http://dx.doi.org/10.1016/s0020-1693(96)05237-1.

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50

Famengo, Alessia, Dalice Pinero, Olivier Jeannin, Thierry Guizouarn, and Marc Fourmigué. "Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination." Dalton Trans. 41, no. 5 (2012): 1441–43. http://dx.doi.org/10.1039/c1dt12028j.

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