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1

Chayajarus, Kampanart, and Antony J. Fairbanks. "Efficient synthesis of carbohydrate thionolactones." Tetrahedron Letters 47, no. 21 (2006): 3517–20. http://dx.doi.org/10.1016/j.tetlet.2006.03.104.

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2

Iwasa, Seiji, Makoto Yamamoto, Shigeo Kohmoto, and Kazutoshi Yamada. "Synthesis of thionolactones from homoallylic xanthates." Journal of the Chemical Society, Perkin Transactions 1, no. 5 (1991): 1173. http://dx.doi.org/10.1039/p19910001173.

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3

Wang, Wendong, Pornpun Rattananakin, and Peter G. Goekjian. "Synthesis of N‐Glycoside Analogs via Thionolactones." Journal of Carbohydrate Chemistry 22, no. 7-8 (2003): 743–51. http://dx.doi.org/10.1081/car-120026472.

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4

IWASA, S., M. YAMAMOTO, S. KOHMOTO, and K. YAMADA. "ChemInform Abstract: Synthesis of Thionolactones from Homoallylic Xanthates." ChemInform 22, no. 33 (2010): no. http://dx.doi.org/10.1002/chin.199133165.

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5

Wilkinson, Brendan L., and Antony J. Fairbanks. "One-pot synthesis of carbohydrate thionolactones from 1-thiosugars." Tetrahedron Letters 49, no. 33 (2008): 4941–43. http://dx.doi.org/10.1016/j.tetlet.2008.05.145.

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6

Bringmann, Gerhard, Andreas Wuzik, Jörg Kümmel, and Wolfdieter A. Schenk. "Atropo-Enantioselective Ring Cleavage of Lewis Acid Modified Biaryl Thionolactones†,‡." Organometallics 20, no. 8 (2001): 1692–94. http://dx.doi.org/10.1021/om001040e.

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7

Milewska, Maria J., Maria Gdaniec, and Tadeusz Poloński. "Synthesis, stereochemistry, and chiroptical spectra of cyclopropyl lactones and thionolactones." Tetrahedron: Asymmetry 7, no. 11 (1996): 3169–80. http://dx.doi.org/10.1016/0957-4166(96)00419-3.

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8

Lee, Hyeon Kyu, Jia Kim, and Chwang Siek Pak. "Reaction of thionolactones with zinc enolate: new synthesis of vinylogous carbonates." Tetrahedron Letters 40, no. 34 (1999): 6267–70. http://dx.doi.org/10.1016/s0040-4039(99)01231-9.

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9

Filippi, Jean-Jacques, Xavier Fernandez, and Elisabet Duñach. "Lewis acid-catalysed isomerisation of thionolactones to thiolactones: inversion of configuration." Tetrahedron Letters 47, no. 34 (2006): 6067–70. http://dx.doi.org/10.1016/j.tetlet.2006.06.104.

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10

Beck, Thomas, та Armin Mosandl. "γ(δ)-Thionolactones - Enantioselective Capillary GC and Sensory Characteristics of Enantiomers". Journal of High Resolution Chromatography 22, № 2 (1999): 89–92. http://dx.doi.org/10.1002/(sici)1521-4168(19990201)22:2<89::aid-jhrc89>3.0.co;2-e.

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11

Jang, Doo Ok, and Seong Ho Song. "ChemInform Abstract: Organotin Hydride Catalyzed Radical Desulfurization of Thionoesters and Thionolactones." ChemInform 31, no. 40 (2000): no. http://dx.doi.org/10.1002/chin.200040050.

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12

Nicolaou, K. C., D. G. McGarry, P. K. Somers, et al. "Synthesis of medium-sized ring ethers from thionolactones. Applications to polyether synthesis." Journal of the American Chemical Society 112, no. 17 (1990): 6263–76. http://dx.doi.org/10.1021/ja00173a013.

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13

Nicolaou, Kyriacos C., Mitsunobu Sato, Emmanuel A. Theodorakis, and Neil D. Miller. "Conversion of thionoesters and thionolactones to ethers; a general and efficient radical desulfurisation." Journal of the Chemical Society, Chemical Communications, no. 15 (1995): 1583. http://dx.doi.org/10.1039/c39950001583.

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14

Lee, Hyeon Kyu, Jia Kim, and Chwang Siek Pak. "ChemInform Abstract: Reaction of Thionolactones with Zinc Enolate: New Synthesis of Vinylogous Carbonates." ChemInform 30, no. 45 (2010): no. http://dx.doi.org/10.1002/chin.199945081.

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15

Jang, Doo Ok, Seong Ho Song, and Dae Hyan Cho. "Conversion of esters and lactones to ethers via thionoesters and thionolactones using reductive radical desulfurization." Tetrahedron 55, no. 11 (1999): 3479–88. http://dx.doi.org/10.1016/s0040-4020(98)01156-9.

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16

NICOLAOU, K. C., M. SATO, E. A. THEODORAKIS, and N. D. MILLER. "ChemInform Abstract: Conversion of Thionoesters and Thionolactones to Ethers; a General and Efficient Radical Desulfurization." ChemInform 26, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.199549062.

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17

Huang, Ya-Qing, Xiong-Zhi Huang, and Pei-Qiang Huang. "Synthesis of 5-(1-Alkoxyalkylidene)tetronates by Direct Condensation Reactions of Tetronates with Thionolactones and Thionoesters." Journal of Organic Chemistry 86, no. 3 (2021): 2359–68. http://dx.doi.org/10.1021/acs.joc.0c02502.

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18

Yuan, Pengjun, Yangyang Sun, Xiaowei Xu, Yi Luo, and Miao Hong. "Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones." Nature Chemistry 14, no. 3 (2021): 294–303. http://dx.doi.org/10.1038/s41557-021-00817-9.

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19

Nicolaou, K. C., D. G. McGarry, P. K. Somers, C. A. Veale, and G. T. Furst. "Nucleophilic additions to thionolactones. New synthetic technology for the construction of medium and large ring ethers." Journal of the American Chemical Society 109, no. 8 (1987): 2504–6. http://dx.doi.org/10.1021/ja00242a041.

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20

Schenk, W. A., T. Beucke, J. Kummel, et al. "ChemInform Abstract: Stereo- and Enantioselective Reactions of Thioaldehydes, Thioketones, Thioketenes, and Thionolactones Mediated by Ruthenium Complexes." ChemInform 33, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.200215276.

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21

MILEWSKA, M. J., M. GDANIEC, and T. POLONSKI. "ChemInform Abstract: Synthesis, Stereochemistry, and Chiroptical Spectra of Cyclopropyl Lactones (cf. (V)) and Thionolactones (cf. (VI))." ChemInform 28, no. 12 (2010): no. http://dx.doi.org/10.1002/chin.199712098.

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22

Zaorska, Ewelina, Marta Gawryś-Kopczyńska, Ryszard Ostaszewski, Marcin Ufnal, and Dominik Koszelewski. "Evaluation of thionolactones as a new type of hydrogen sulfide (H2S) donors for a blood pressure regulation." Bioorganic Chemistry 108 (March 2021): 104650. http://dx.doi.org/10.1016/j.bioorg.2021.104650.

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23

Bachi, Mario D., and Eric Bosch. "Free radical cyclization of thionocarbonic acid derivatives of 4-phenyl-3-butenol. A new route to thionolactones." Journal of Organic Chemistry 54, no. 6 (1989): 1234–36. http://dx.doi.org/10.1021/jo00267a002.

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24

Jang, Doo Ok, Seong Ho Song, and Dae Hyan Cho. "ChemInform Abstract: Conversion of Esters and Lactones to Ethers via Thionoesters and Thionolactones Using Reductive Radical Desulfurization." ChemInform 30, no. 30 (2010): no. http://dx.doi.org/10.1002/chin.199930065.

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25

Bingham, Nathaniel M., and Peter J. Roth. "Degradable vinyl copolymers through thiocarbonyl addition–ring-opening (TARO) polymerization." Chemical Communications 55, no. 1 (2019): 55–58. http://dx.doi.org/10.1039/c8cc08287a.

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26

Schenk, Wolfdieter A., Jörg Kümmel, Irene Reuther, et al. "Enantioselective Organic Syntheses Using Chiral Transition Metal Complexes, 9 Atropo-Diastereoselective Ring Opening of Biaryl Thionolactones Using [CpRu{(S,S)-CHIRAPHOS}]+ as a Chiral Auxiliary." European Journal of Inorganic Chemistry 1999, no. 10 (1999): 1745–56. http://dx.doi.org/10.1002/(sici)1099-0682(199910)1999:10<1745::aid-ejic1745>3.0.co;2-1.

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27

Takano, Seiichi, Shun’ichi Tomita, Michiyasu Takahashi, and Kunio Ogasawara. "Thionolactone Claisen Rearrangement." Chemistry Letters 16, no. 7 (1987): 1379–80. http://dx.doi.org/10.1246/cl.1987.1379.

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28

Stojanović, Marija, Ljiljana Šćepanović, Olivera Bosnić, et al. "Effects of Acute Administration of D,L-Homocysteine Thiolactone on the Antioxidative Status of Rat Intestine and Liver." Acta Veterinaria 66, no. 1 (2016): 26–36. http://dx.doi.org/10.1515/acve-2016-0002.

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AbstractOxidative stress appears to play a role in the pathogenesis of several inflammatory gastrointestinal diseases. Increased homocysteine levels may play a role in the pathogenesis of Chron’s disease and ulcerative colitis. The aim of this study was to examine the influence of homocysteine on the antioxidant status of rat intestine and liver. The levels of thiobarbituric acid reactive substances (TBARS), activity of catalase (CAT) and total antioxidant status (TAS) were investigated in the isolated gut and liver of young male rats in the control group (8 rats) and after 3-hоur incubation i
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29

Bringmann, G., B. Schöner, O. Schupp, et al. "Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes." Journal of Organometallic Chemistry 472, no. 1-2 (1994): 275–84. http://dx.doi.org/10.1016/0022-328x(94)80213-0.

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30

Iwasa, Seiji, Makoto Yamamoto, Shigeo Kohmoto, and Kazutoshi Yamada. "Tandem radical cyclization of acyclic homoallylic xanthates: cyclopentannulated .gamma.-thionolactone and .gamma.-lactones." Journal of Organic Chemistry 56, no. 8 (1991): 2849–53. http://dx.doi.org/10.1021/jo00008a048.

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31

IWASA, S., M. YAMAMOTO, S. KOHMOTO та K. YAMADA. "ChemInform Abstract: Tandem Radical Cyclization of Acyclic Homoallylic Xanthates: Cyclopentannulated γ-Thionolactone and γ-Lactones." ChemInform 22, № 41 (2010): no. http://dx.doi.org/10.1002/chin.199141137.

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32

Peters, Karl, Eva-Maria Peters, Gerhard Bringmann, and Olaf Schupp. "Notizen:1,3-Dimethoxy-6H- benzo[b]naphtho[1,2-d]pyran-6-thione, a Thionolactone-Bridged Axially Prostereogenic Biaryl." Zeitschrift für Naturforschung B 51, no. 3 (1996): 431–32. http://dx.doi.org/10.1515/znb-1996-0320.

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Abstract The title compound was prepared from the cor­responding “ordinary” oxolactone bridged biaryl using Lawesson’s reagent. It crystallizes from dichloromethane / petroleum ether in the mono­clinic system, space group P21/a; a = 1115.7(2),b = 1383.9(2), c = 1042.0(1) pm and β = 106.67(1)°.
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33

Bringmann, Gerhard, Andreas Wuzik, Olaf Schupp, Karl Peters, and Eva-Maria Peters. "1,3-Di-terf-butyl-6H-benzo[b]naphtho[1,2-d]pyran-6-thione, a Severely Helically Distorted Thionolactone-Bridged Biaryl." Zeitschrift für Naturforschung B 52, no. 3 (1997): 355–58. http://dx.doi.org/10.1515/znb-1997-0310.

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Abstract The title compound 2c, a potentially useful synthetic intermediate in stereoselective biaryl synthesis, has been prepared from the oxolactone 1c, by treatment with Lawesson′s reagent. An X-ray structure analysis reveals its strongly helically distorted structure, the overall molecular distortion even slightly exceeding that of the corresponding oxo compound 1c.
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34

BRINGMANN, G., A. WUZIK, O. SCHUPP, K. PETERS, and E. M. PETERS. "ChemInform Abstract: Novel Concepts in Direct Biaryl Synthesis. Part 60. 1,3-Di-tert-butyl- 6H-benzo(b)naphtho(1,2-d)pyran-6-thione, a Severely Helically Distorted Thionolactone-Bridged Biaryl." ChemInform 28, no. 35 (2010): no. http://dx.doi.org/10.1002/chin.199735150.

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35

Zheng, Shaoqiu, Shu-Sen Chen, Yang-Yang Li, et al. "Monomer Design Enables Mechanistic Mapping of Anionic Ring‐Opening Polymerization of Aromatic Thionolactones." Angewandte Chemie International Edition, January 22, 2025. https://doi.org/10.1002/anie.202500581.

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Degradable chalcogenide polyesters, e.g., polythioesters (PTEs), typically exhibit improved thermal, mechanical, and optical properties. Anionic ring‐opening polymerization (ROP) of thionolactones, an intrinsically promising yet underexplored approach to accessing PTEs, however, is still limited by: intolerance of metal catalysts, inadequate control over chain growth, and the absence of aromatic system. Monomer design‐boosted mechanistic studies may address the above challenges. Here, we present a new and highly reactive thionolactone synthesized from 1,1′‐binaphthyl‐2,2′‐diol (BINOL). Our inv
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36

Zheng, Shaoqiu, Shu-Sen Chen, Yang-Yang Li, et al. "Monomer Design Enables Mechanistic Mapping of Anionic Ring‐Opening Polymerization of Aromatic Thionolactones." Angewandte Chemie, January 22, 2025. https://doi.org/10.1002/ange.202500581.

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Degradable chalcogenide polyesters, e.g., polythioesters (PTEs), typically exhibit improved thermal, mechanical, and optical properties. Anionic ring‐opening polymerization (ROP) of thionolactones, an intrinsically promising yet underexplored approach to accessing PTEs, however, is still limited by: intolerance of metal catalysts, inadequate control over chain growth, and the absence of aromatic system. Monomer design‐boosted mechanistic studies may address the above challenges. Here, we present a new and highly reactive thionolactone synthesized from 1,1′‐binaphthyl‐2,2′‐diol (BINOL). Our inv
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37

Chayajarus, Kampanart, and Antony J. Fairbanks. "Efficient Synthesis of Carbohydrate Thionolactones." ChemInform 37, no. 35 (2006). http://dx.doi.org/10.1002/chin.200635209.

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38

Ivanchenko, Oleksandr, Stéphane Mazières, Rinaldo Poli, Simon Harrisson, and Mathias Destarac. "Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate." Polymer Chemistry, 2022. http://dx.doi.org/10.1039/d2py01153k.

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The radical ring-opening copolymerisation (rROcoP) of unsubstituted thionolactones of different ring sizes, namely γ-thionobutyrolactone (TBL), δ-thionovalerolactone (TVL), ε-thionocaprolactone (TCL) and ω-thionopentadecalactone (TPDL), with vinyl pivalate has been mechanistically investigated. The...
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39

Wang, Wendong, Pornpun Rattananakin, and Peter G. Goekjian. "Synthesis of N-Glycoside Analogues via Thionolactones." ChemInform 35, no. 14 (2004). http://dx.doi.org/10.1002/chin.200414226.

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40

"Organotin Hydride Catalyzed Radical Desulfurization of Thionoesters and Thionolactones." Synlett 2000, no. 06 (2000): 0811–12. http://dx.doi.org/10.1055/s-2000-6723.

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41

Wilkinson, Brendan L., and Antony J. Fairbanks. "ChemInform Abstract: One-Pot Synthesis of Carbohydrate Thionolactones from 1-Thiosugars." ChemInform 39, no. 47 (2008). http://dx.doi.org/10.1002/chin.200847198.

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42

Filippi, Jean-Jacques, Xavier Fernandez, and Elisabet Dunach. "Lewis Acid Catalyzed Isomerization of Thionolactones to Thiolactones: Inversion of Configuration." ChemInform 37, no. 48 (2006). http://dx.doi.org/10.1002/chin.200648125.

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43

Yuan, Pengjun, Yongliang Xia, Xi Zhang, Yangyang Sun, Yifeng Chen, and Miao Hong. "A Library of Stereoregular Polythioesters for Stereocomplex Formation Enabled by Isomerization‐Driven Cationic Ring‐Opening Polymerization." Angewandte Chemie International Edition, June 3, 2025. https://doi.org/10.1002/anie.202501485.

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Supramolecular stereocomplexation is an important tool to advance sustainable polymers, and oxygen‐containing polymers represent the most widely studied materials for stereocomplexation. However, the sulfur‐containing analogues, a newly emerged class of sustainable polymers, remain essentially unexplored because of a significant challenge encountered in the synthesis of stereoregular polymers and relatively low supramolecular interaction. In this contribution, by the utilization of [Et3O]+[B(C6F5)4]– as a metal‐free cationic initiator, controlled isomerization‐driven ring‐opening polymerizatio
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44

Yuan, Pengjun, Yongliang Xia, Xi Zhang, Yangyang Sun, Yifeng Chen, and Miao Hong. "A Library of Stereoregular Polythioesters for Stereocomplex Formation Enabled by Isomerization‐Driven Cationic Ring‐Opening Polymerization." Angewandte Chemie, June 3, 2025. https://doi.org/10.1002/ange.202501485.

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Supramolecular stereocomplexation is an important tool to advance sustainable polymers, and oxygen‐containing polymers represent the most widely studied materials for stereocomplexation. However, the sulfur‐containing analogues, a newly emerged class of sustainable polymers, remain essentially unexplored because of a significant challenge encountered in the synthesis of stereoregular polymers and relatively low supramolecular interaction. In this contribution, by the utilization of [Et3O]+[B(C6F5)4]– as a metal‐free cationic initiator, controlled isomerization‐driven ring‐opening polymerizatio
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45

Kalana, U. L. D. Inush, Partha P. Datta, Rukshika S. Hewawasam, Elizabeth T. Kiesewetter, and Matthew K. Kiesewetter. "Organocatalytic ring-opening polymerization of thionolactones: anything O can do, S can do better." Polymer Chemistry, 2021. http://dx.doi.org/10.1039/d0py01393e.

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46

NICOLAOU, K. C., D. G. MCGARRY, P. K. SOMERS, et al. "ChemInform Abstract: Synthesis of Medium-Sized Ring Ethers from Thionolactones. Applications to Polyether Synthesis." ChemInform 21, no. 49 (1990). http://dx.doi.org/10.1002/chin.199049319.

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47

Ivanchenko, Oleksandr, Stéphane Mazières, Simon Harrisson, and Mathias Destarac. "On-Demand Degradation of Thioester/Thioketal Functions in Vinyl Pivalate-Derived Copolymers with Thionolactones." Macromolecules, June 1, 2023. http://dx.doi.org/10.1021/acs.macromol.3c00312.

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48

Rix, Matthew F. I., Kyle Collins, Samuel J. Higgs, et al. "Insertion of Degradable Thioester Linkages into Styrene and Methacrylate Polymers: Insights into the Reactivity of Thionolactones." Macromolecules, November 30, 2023. http://dx.doi.org/10.1021/acs.macromol.3c01811.

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49

Luzel, Bastien, Lucas Raggio, Eytan Benharrous, et al. "Closer Look at the Substituent Effects on the Copolymerization of Thionolactones by Radical Ring-Opening Polymerization." Macromolecules, April 30, 2025. https://doi.org/10.1021/acs.macromol.5c00448.

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50

NICOLAOU, K. C., D. G. MCGARRY, P. K. SOMERS, C. A. VEALE, and G. T. FURST. "ChemInform Abstract: Nucleophilic Additions to Thionolactones. New Synthetic Technology for the Construction of Medium- and Large-Ring Ethers." ChemInform 18, no. 35 (1987). http://dx.doi.org/10.1002/chin.198735251.

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