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1

Thomas, Mary Solly. "Complexes of thiophene derivatives as potential metallomesogens." Thesis, Pretoria : [s.n.], 2006. http://upetd.up.ac.za/thesis/available/etd-12072006-171634.

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2

Weddell, Derek Alexander. "Synthesis, structure determination and mechanism in thiophene derivatives." Thesis, Nottingham Trent University, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343542.

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3

Alaviuhkola, T. (Terhi). "Aromatic borate anions and thiophene derivatives for sensor applications." Doctoral thesis, University of Oulu, 2007. http://urn.fi/urn:isbn:9789514286575.

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Abstract This study was part of a project targeted at developing chemical sensors for organic cations and metal ions by exploiting the interactions between cations and anionic borate derivatives. As well, the chemical synthesis of thiophene monomers with charged or neutral ion-recognition sites was investigated. The primary task in the first part of the work was to prepare anionic receptor molecules based on synthesized borate derivatives and study their complexation with N-heteroaromatic and tropylium cations. The complexation was studied in solution by 1H NMR and ESIMS techniques and in so
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4

Cannon, Benjamin Tyree. "Thiophene and Derivatives for Use in Pyridazines and Thiapentalenes." TopSCHOLAR®, 2015. http://digitalcommons.wku.edu/theses/1476.

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This thesis introduces the idea of Band Theory and how it can be used to describe a solid-state materials ability to carry an electrical charge. Next, this thesis defines what makes a material a conductor, semiconductor, or insulator. Semiconductors are attracting interest in chemistry, as well as in the manufacturing of consumer electronics, because of their ability to carry a charge, without the risk of short-circuiting like traditional conductors.1,4 Organic semiconductors, which behave differently than traditional semiconductors, are of particular interest because they offer mechanical fle
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5

Tirkes, Seha. "Synthesis, Characterization, And Polymerization Of Polyether Bridged Thiophene And Aniline Derivatives." Phd thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609399/index.pdf.

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New compounds consisting of 3-thienyl and aniline units linked by polyether bridges have been synthesized and their electrochemical polymerization was performed via constant potential electrolysis and cyclic voltammetry. In the case of 3-thienyl derivatives two compounds, 1,12-di-3-thienyl-2,5,8,11-tetraoxadodecane (MI) and 1,15-di-3-thienyl-2,5,8,11,14-pentaoxapentadecane (MII) were synthesized utilizing literature methods and their corresponding polymers, poly(I) and poly(II) were prepared in an electrolytic solution containing 0.1 M terabutylammonium hexafluorophosphate (TBAPF6) dissolved i
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6

Hunziker, Christoph. "Crystalline thiophene and phenolic polyene derivatives for organic electronic and photonic applications /." Zürich : ETH, 2008. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=18032.

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7

Asil, Demet. "A Glow In The Dark: Synthesis And Electropolymerization Of Chemiluminescent Thiophene Derivatives." Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609863/index.pdf.

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ABSTRACT A GLOW IN THE DARK: SYNTHESIS AND ELECTROPOLYMERIZATION OF CHEMILUMINESCENT THIOPHENE DERIVATIVES Asil, Demet M.Sc., Department of Chemistry Supervisor : Prof. Dr. Ahmet M. &Ouml<br>nal Co-Supervisor: Assist. Prof. Dr. Atilla Cihaner September 2008, 63 Pages Two novel chemiluminescent monomers, 2,3-dihydrothieno(3,4-d)pyridazine-1,4-dione (T-Lum) and 5,7-di-thiophen-2-yl-2,3-dihydro-thieno[3,4-d]pyridazine-1,4-dione (TTT-Lum), were synthesized. The reaction between T-Lum and TTT-Lum in alkaline solution with H2O2 gave chemiluminescence which can be catalyzed using Fe(III)
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8

Dang, Xuan Dung. "Electrosynthesis and characterization of thin copolymer films based on pyrrole and thiophene derivatives." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2005. http://nbn-resolving.de/urn:nbn:de:swb:14-1125491701029-31683.

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Die Copolymerisation wurde mit dem Ziel untersucht, polymere Materialien zu synthetisieren, die die individuellen Eigenschaften der entsprechenden Homopolymere kombinieren. Die Dissertation konzentrierte sich auf die Elektrosynthese und Charakterisierung von leitfähigen Copolymerfilmen auf Basis von Pyrrol- und Thiophenderivaten. Mit einer Reihe von elektrochemischen, spektroskopischen und mikroskopischen Untersuchungsmethoden (Zyklovoltammetrie, elektrochemische Impedanz-spektroskopie, photoelektrochemische Spektroskopie, Elektrospray- Ionisations-Massenspektroskopie, Festkörper- NMR, Raman-S
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9

Aslan, Evren. "Characterization Of Conducting Polymers Of Ester Linkage Containing Thiophene Derivatives Via Mass Spectroscopy." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605704/index.pdf.

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ABSTRACT CHARACTERIZATION OF CONDUCTING POLYMERS OF ESTER LINKAGE CONTAINING THIOPHENE DERIVATIVES VIA MASS SPECTROSCOPY Aslan, Evren M.Sc., Department of Chemistry Supervisor: Prof. Dr. Levent Toppare Co-Supervisor: Prof.Dr. Jale Hacaloglu December 2004, 86 pages In order to investigate the thermal and structural characteristics of terepthalic acid bis-(2-thiophen-3-yl-ethyl)ester (TATE), decanedioic acid bis-(2-thiophen-3-yl- ethyl) ester (DATE) and octanoic acid 2-thiophen-3-yl-ethyl ester (OTE), their corresponding homopolymers, copolymers with thiophene and polythiophene, pyroly
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10

Chen, Qiao. "The chemistry of benzoate, 3-thiophene carboxylate, nitrobenzene and its derivatives on Cu(110) surface." Thesis, University of Liverpool, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366270.

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11

Williams, Gwion Owain. "Conducting polymers for use in supercapacitors : an electrochemical and spectroelectrochemical investigation into low bandgap thiophene derivatives." Thesis, Bangor University, 1999. https://research.bangor.ac.uk/portal/en/theses/conducting-polymers-for-use-in-supercapacitors--an-electrochemical-and-spectroelectrochemical-investigation-into-low-bandgap-thiophene-derivatives(08b98553-6f0c-42ad-9d48-1fc6274f2bbd).html.

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The following low bandgap conducting polymers have been prepared by electrochemical polymerisation of the corresponding monomers: poly-4Hcyclopenta[2,1-b; 3,4-b']dithiophene-4-one, (PCDT), poly-4-dicyanomethylene-4Hcyclopenta[2,1-b: 3,4-b']dithiophene (PCDM) and 6,8-di(2-cyano-2(2- thienyl))ethenyl-4(ethylenedioxy)-4H-cyclopenta[2,1-b; 3,4-b' ]dithiophene (PCET). The polymers were characterised by cyclic voltammetry, spectroelectrochemical studies and impedance measurements in order to assay their suitability as active materials in high power supercapacitors. The redox switching of the polymer
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12

Yang, Florent. "Electrochemical modification of Si surfaces by methyl groups (CH 3, CD 3), ethynyl derivatives, pyrrole and thiophene." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2009. http://dx.doi.org/10.18452/16034.

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Silizium (Si) wird für eine breite Palette von Anwendungen wie z.B. in Solarzellen, Mikroelektronik, Biochips und so weiter eingesetzt. In dieser Arbeit wurden neue Hybridsysteme aus Si und organischen Molekülen, bezüglich der Oberflächenpassivierung des Halbleiters und der resultierenden elektronischen Eigenschaften untersucht. Insbesondere wurden Methyl-Gruppen (CH3 und CD3), Ethynyl-Derivate (H−C≡C-, CH3−C≡C-, und C6H5−C≡C-), sowie Pyrrol und Thiophen aus Grignardlösungen untersucht. Bezüglich Stabilität und Defektkonzentration konnte gezeigt werden, dass organisch modifizierte Si-Oberfläch
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13

Mari, Giacomo. "Synthesis of various and interesting heterocycles included berberino derivatives." Doctoral thesis, Urbino, 2018. http://hdl.handle.net/11576/2656415.

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14

Rebourt, Eymard. "Vers des polymères conducteurs tridimensionnels : préparation et caractérisation de poly(n-octyl-3-thiophènes) réticulés totalement conjugués." Université Joseph Fourier (Grenoble), 1994. http://www.theses.fr/1994GRE10182.

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Il nous a paru interessant de jouer sur la dimensionnalite des polymeres conducteurs electroniques afin d'obtenir des materiaux dont les proprietes (notamment la conductivite) seraient particulieres. D'ou l'idee de preparer des structures totalement conjuguees de dimension fractale voire tridimensionnelles. Pour obtenir ces structures, nous avons reticule des chaines de poly(n-octyl-3-thiophene) avec quatre types de trithienylbenzenes prealablement prepares et caracterises: le tri(thienyl-2)-1,3,5-benzene, le tri(thienyl-2)-1,2,4-benzene, le tri(thienyl-3)-1,3,5-benzene et le tri(thienyl-3)-1,
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15

Berg, Keimpe Jan van den. "Heterocyclic analogs of o-xylylene a study of the synthesis and reactivity of dimethylene derivatives of thiophene and pyrrole /." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 1990. http://irs.ub.rug.nl/ppn/292990278.

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16

Ak, Metin. "Synthesis Of Polythiophene And Polypyrrole Derivatives And Their Application In Electrochromic Devices." Phd thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/12608070/index.pdf.

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Different substituted thiophene and pyrrole monomers namely hexamethylene (bis-3-thiopheneacetamide) (HMTA), N-(4-(3-thienylmethylene)-oxycarbonylphenyl)maleimide (MBThi), 2,4,6-Tris-(4-pyrrol-1-yl-phenoxy)-[1,3,5]triazine (TriaPy), 2,4,6-Tris-(thiophen-3-ylmethoxy)-[1,3,5] triazine (TriaTh), and N-(2-(thiophen-3-yl)methylcarbonyloxyethyl) maleimide (NMT) were synthesized. The chemical structures of the monomers were characterized by Nuclear Magnetic Resonance (1H-NMR and 13C-NMR) and Fourier Transform Infrared (FTIR) Spectroscopies. Electrochemical behavior of the monomers in the presence and
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17

Peay, Miya Alethea. "Investigations into Ligand Substitutions of Rhenium and Molybdenum d4 Hexanuclear Clusters and the Synthesis and Characterization of Aurated Pyrene and Thiophene Derivatives." Case Western Reserve University School of Graduate Studies / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=case1307731363.

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18

Abdel, Fattah Mohamed Assem Omar [Verfasser], Jochen [Akademischer Betreuer] Lehmann, Gerhard [Akademischer Betreuer] Scriba, and Stefan [Akademischer Betreuer] Laufer. "Modulating dopamine receptors subtype selectivity by thiophene and benzothiophene based derivatives / Mohamed Assem Omar Abdel Fattah. Gutachter: Jochen Lehmann ; Gerhard Scriba ; Stefan Laufer." Jena : Thüringer Universitäts- und Landesbibliothek Jena, 2013. http://d-nb.info/1043957812/34.

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19

Roncali, Jean. "Polymères organiques conducteurs fonctionnalisés." Paris 13, 1989. http://www.theses.fr/1989PA132014.

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Etude de la cinétique de la polymérisation électrolytique de dérivés du chiophène et amélioration de son efficacité et de sa sélectivité en vue d'obtenir la meilleure conductivité électrique possible; relation entre la conductivité et les propriétés spectroscopiques et électrochimiques des polymères. Modification des polythiophènes par voie électrochimique et greffage covalent de groupes fonctionnels sur le monomère; étude des facteurs stériques et électroniques associés aux differents substituants en vue de conserver les propriétés conductrices du polymère. Préparation électrochimique de poly
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20

Perakis, Nikolaos. "Separation et detection selective des composes soufres dans les fractions lourdes des petroles : geochimie des benzo (b) thiophenes." Université Louis Pasteur (Strasbourg) (1971-2008), 1986. http://www.theses.fr/1986STR13093.

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Analyse et dosage des composes soufres presents dans une coupe lourde du petrole aramco 90 par chromatographie gazeuse avec detection soit par photometrie de flamme soit par spectrometrie de masse haute resolution. Etude comparative des methodes d'analyse. Etude des composes soufres dans des echantillons de petrole de rozel point et de schiste bitumineux de timahdit grace a l'identification par synthese de nouvelles familles d'alkylbenzo (b) thiophenes
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21

Soucy-Breau, Chantal. "Synthesis of naturally occurring phototoxic thiophenes and their derivatives." Thesis, University of Ottawa (Canada), 1990. http://hdl.handle.net/10393/5712.

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Analogues and derivatives of naturally occurring $\alpha$-terthienyl 3 have been synthesized by using the nickel-catalyzed Grignard-Wurtz cross-coupling reaction. This method has proven useful for the introduction of non-polar substituents on 2-bromothiophene which upon subsequent cross-coupling with 5-iodo-$\alpha$-dithienyl 185 led to a successful variety of 5-substituted $\alpha$-terthienyls. Derivatives of $\alpha$-terthienyl bearing polar functional groups were synthesized either by: (1) introduction of electron-withdrawing and electron-donating at C-5 and C-5$\sp{\prime\prime}$; or (2) c
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22

Primak, Alexiy. "Clay-catalyzed thiomethylation of thiophenes and preparation of some tetrathiafulvalene derivatives." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ34694.pdf.

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23

Berkaoui, M'hamed. "Réactivité énaminique de β-aminothiophènes vis-à-vis de divers électrophiles. Accès à des hétérocycles thiophéniques azotés". Rouen, 1998. http://www.theses.fr/1998ROUES015.

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Le fort caractère énaminique des 3-aminothiophènes est responsable de la grande réactivité de la position 2 de l'hétérocycle vis-à-vis des réactifs électrophiles et des acides. L'action d'un aldéhyde en présence de sélénophénol, comme réducteur, et de traces acides, ouvre une voie d'accès aux 2-alkyl 3-aminothiophènes et à leurs dérivés acétamides et carbamates. Le mécanisme de cette réaction de C-alkylation suppose la formation d'un carbocation pseudo-benzylique intermédiaire mis en évidence par capture avec le thiophénol ou le pyrrole. En absence de réducteur, on observe une double alkylatio
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24

Yigitsoy, Basak. "Synthesis Of A New Thiophene Derivative And Its Uses As An Electrochromic Device Component." Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/12607305/index.pdf.

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2,5-Di(thiophen-2-yl)-1-p-tolyl-1H-pyrrole (DTTP) was synthesized via reaction of 1,4-di(2-thienyl)-1,4-butanedione with p-toluidine in the presence of catalytical amount of p-toluenesulfonic acid (PTSA). Homopolymer P(DTTP) was achieved both by chemical and electrochemical techniques. Chemical polymerization of the monomer yielded a soluble polymer. The average molecular weight was determined by gel permeation chromatography (GPC) as Mn: 2.5x103 g/mol. The monomer was electrochemically polymerized in the presence of LiClO4, NaClO4 (1:1) as the supporting electrolyte in acetonitrile. Copolyme
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25

Odom, Susan A. "Electron transfer and delocalization in mixed-valence monocations of bis- and tris-(diarylamino) derivatives." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26609.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2009.<br>Committee Chair: Marder, Seth; Committee Member: Bredas, Jean-Luc; Committee Member: Collard, David; Committee Member: Kippelen, Bernard; Committee Member: Tolbert, Laren. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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26

Brisset, Hugues. "La rigidification : une nouvelle stratégie de contrôle des propriétés électroniques des systèmes conjugués linéaires." Angers, 1996. http://www.theses.fr/1996ANGE0029.

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Ce travail porte sur l'élaboration de nouveaux systèmes conjugués linéaires à faible bande interdite au moyen d'une stratégie originale basée sur la rigidification du système conjugué. Apres un premier chapitre consacre à un bref rappel des différentes approches de la synthèse de polymères conjugues à faible bande interdite, le second chapitre est consacré à l'élaboration de nouveaux polymères conjugués obtenus par électropolymérisation de précurseurs synthétisés à partir de deux structures de bases: le cyclopentadithiophène et le 6,6'-bis(4,5-dihydro-6h-cyclopentabthienylidene). L'analyse str
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27

Silva, Sheyla Welma Duarte. "Estudos cristaloquímicos e químico-quânticos de seis derivados tiofênicos 2-[(arilideno)-amino]-4,5-cocloalquil-tiofeno-3-carbonitrila." Universidade Federal de Alagoas, 2016. http://www.repositorio.ufal.br/handle/riufal/1864.

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This work consists in carrying out a crystalochemical and quantum chemical study of six tiofênicos derivative 2 - [(arylidene) amino] -4,5-cycloalkyl-thiophene-3-carbonitrile (LPSF / SB). This class of compounds is considered of fundamental importance for the study and design of new drugs, since they exhibit a wide range of pharmacological properties, such as antibacterial, antifungal, analgesic, anti-inflammatory, antioxidant, antitumor and anesthetic. In this context, the present work was to study structural and electronic parameters of the above-mentioned compounds, in order to assess and u
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28

Coutterez, Claire. "Synthèse, caractérisation et étude des propriétés d'oligomères et polymères hétéroarylène vinylènes." Grenoble INPG, 1998. http://www.theses.fr/1998INPG0163.

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Le travail de cette these a concerne la synthese, la caracterisation et l'etude de proprietes d'usage de structures oligomeres et polymeres conjuguees. L'originalite de ces travaux reside d'une part dans l'utilisation d'heterocycles furaniques et thiopheniques comme elements constitutifs des chaines et d'autre part, dans le fait que de nombreux composes oligomeres ont ete cibles, isoles et caracterises. Les possibilites d'application de ces materiaux dans les domaines touchant a l'electronique (conducteurs ou semi-conducteurs), a l'optique (cristaux liquides) et a la luminescence photo- et ele
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29

Patriota, Yuri Basílio Gomes. "Desenvolvimento, caracterização e avaliação de atividade antimicrobiana in vitro de microemulsão contendo derivado tiofênico para administração oral." Universidade Estadual da Paraíba, 2015. http://tede.bc.uepb.edu.br/tede/jspui/handle/tede/2682.

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Submitted by Jean Medeiros (jeanletras@uepb.edu.br) on 2016-12-02T12:49:44Z No. of bitstreams: 1 PDF - Yuri Basílio Gomes Patriota.pdf: 955612 bytes, checksum: 03ba9e97932ba281d6427913b6fc9361 (MD5)<br>Approved for entry into archive by Secta BC (secta.csu.bc@uepb.edu.br) on 2016-12-06T19:13:13Z (GMT) No. of bitstreams: 1 PDF - Yuri Basílio Gomes Patriota.pdf: 955612 bytes, checksum: 03ba9e97932ba281d6427913b6fc9361 (MD5)<br>Made available in DSpace on 2016-12-06T19:13:14Z (GMT). No. of bitstreams: 1 PDF - Yuri Basílio Gomes Patriota.pdf: 955612 bytes, checksum: 03ba9e97932ba281d6427913b6fc93
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Mota, Clélia de Alencar Xavier. "Efeito antinociceptivo e antiinflamatório do 2-[(4-nitro-benzilideno)-amino]-4,5,6,7-tetraidro-benzo[b]tiofeno-3-carbonitrila (6CN10) em camundongos." Universidade Federal da Paraí­ba, 2012. http://tede.biblioteca.ufpb.br:8080/handle/tede/6775.

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Made available in DSpace on 2015-05-14T12:59:49Z (GMT). No. of bitstreams: 1 arquivototal.pdf: 2233780 bytes, checksum: 36fd18af67f2bd8e2c76af844131f20c (MD5) Previous issue date: 2012-08-27<br>Coordenação de Aperfeiçoamento de Pessoal de Nível Superior<br>Heterocyclic compounds are the biggest sources of synthetic drugs and have grown exponentially with important applications in the pharmaceutical industry. Amongst the heterocyclic compounds, it has been highlighted the thiophenes category and its derivatives, which call attention for presenting important pharmacological actions, especially
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31

Enee, Véronique. "Synthèse d'oligo(3-octylthiophènes) régioréguliers : briques moléculaires pour l'élaboration de polymères conjugués incluant des complexes de métaux de transition." Université Joseph Fourier (Grenoble), 1997. http://www.theses.fr/1997GRE10012.

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Le but de ce travail consiste en la synthese d'un polymere conjugue a complexes organometalliques, afin de creer un materiau original jouissant des proprietes du polymere et du complexe organometallique. Ainsi, selon la longueur des bras espaceurs conjugues de la matrice polymere, un couplage entre sites metalliques voisins pourra se produire ou non. De plus, (et cela constitue notre objectif majeur), les proprietes intrinseques du polymere pourraient se coupler a celles du complexe: il serait alors possible de modifier les proprietes du polymere, en agissant sur celles du metal (ou inversemen
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32

Salhi, Fouad. "Les tétrathiapentalènes disubstitués : nouvelle classe d'hétérocycles soufrés pour l'obtention de polymères conducteurs à motifs TTF." Université Joseph Fourier (Grenoble), 1999. http://www.theses.fr/1999GRE10034.

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L'elaboration d'une nouvelle classe d'heterocycles soufres 2 12, bases sur le motif tetrathiapentalenes (ttp) est decrite. La synthese des tetrathiapentalenes disubstitues se deroule en une seule etape par couplage de la thiapendione avec dix differents aldehydes (rcho, r = phenyle, thienyle, furyle, etc) dans le phosphite de triethyle. Les monomeres sont caracterises par leurs proprietes spectroscopiques : uv-visible, ir, rmn, rpe, spectroscopie de masse, et leur proprietes electrochimiques. Excepte pour le compose 10, l'oxydation electrochimique des composes 2 12 conduit a la formation de po
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33

Mabboux, Pierre-Yves. "Relaxation nucléaire dans les polymères conducteurs : application à l'étude de la conduction microscopique et développements théoriques." Grenoble INPG, 1996. http://www.theses.fr/1996INPG0172.

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Cette etude porte sur les proprietes de conduction des polymeres conducteurs et notamment sur la dynamique des excitations elementaires, polarons, au niveau microscopique. Le mouvement des polarons est etudie localement par l'intermediaire des spins nucleaires fixes #1h disposes le long des chaines polymeres. Observes par resonance magnetique nucleaire, la relaxation nucleaire #1h est proportionnelle a la densite spectrale du mouvement des spins electroniques mobiles (dynamique de spin). Nous tirons des mesures du temps de relaxation t#1 en fonction de la frequence de larmor les coefficients d
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34

Hajlaoui, Riadh. "Effet de la structure sur les propriétés électriques et optiques d'oligomères conjugués semi-conducteurs. Application à la réalisation de transistors à effet de champ et de diode électroluminescentes." Rouen, 1995. http://www.theses.fr/1995ROUES005.

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L'étude structurale des polymères conjugués montre que leur désordre moléculaire et structural limite la qualité de leurs propriétés électroniques, et restreint donc leur éventuelle application à des composants électroniques. L'utilisation de systèmes moléculaires structuralement bien définis devrait par contre permettre de s'affranchir de ces défauts chimiques et physiques, et d'améliorer ainsi l'efficacité du transport de charges dans ces matériaux semi-conducteurs. Cette démarche est illustrée ici par l'étude du sexithiophène (6T) et de ses dérivés substitués. La première partie est consacr
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35

Fabre, Bruno. "Synthèse et étude de films de polymères conducteurs électroniques dopés par des hétéropolyanions : application à la réduction électrocatalytique de NO2- et à la détection du NO in vivo." Université Joseph Fourier (Grenoble ; 1971-2015), 1994. http://www.theses.fr/1994GRE10158.

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Ce travail est consacre a la synthese, la caracterisation physico-chimique et l'application de films de polymeres conducteurs electroniques (pce) incluant des heteropolyanions (hpa). Ces entites minerales, connues pour leurs remarquables proprietes redox, sont immobilisees en tant qu'anion dopant lors de la synthese electrochimique des pce. Dans un premier temps, nous montrons qu'une electrode modifiee par un film de poly(3-methyl thiophene) dope par un hpa de structure de keggin xm#1#2o#4#0#n#- (x = p, si ; m = w, mo et n = 3, 4) presente l'electroactivite des deux partenaires. La reponse ele
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36

Sixou, Bruno. "Proprietes de transport dans les polymeres conducteurs electroniques." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10271.

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Ce travail est consacre a l'etude des proprietes de transport, conductivite et pouvoir thermoelectrique, de plusieurs polymeres conducteurs electroniques. Le suivi de l'evolution de ces proprietes en fonction d'un seul parametre de structure, a savoir: le desordre cree par le vieillissement dans le polypyrrole ou dans la polyaniline protonee a l'acide camphre sulfonique, le taux de reticulation dans des reseaux a base de polyoctylthiophene, ou la composition dans des composites polyaniline-nafion ou polyaniline-polyoxyde d'ethylene, nous a permis de preciser la nature du processus de conductio
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37

Bourque, Alex N. "Photophysical Investigations of Thiophene Azomethine Derivatives." Thèse, 2009. http://hdl.handle.net/1866/3565.

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Une série de dimères composés de thiophène-aniline encombrée stériquement a été synthétisée. Les différents processus de désactivation de l’état singulet excité ont été étudiés par UV-visible, fluorescence, phosphorescence, photolyse par impulsion laser et calculs théoriques. Les graphiques de Stern-Volmer obtenus à partir des expériences de désactivation des états singulet et triplet ont démontré l’efficacité de l’azométhine à désactiver les fluorophores. Les calculs semi-empiriques AM1 examinant l’effet des substituants encombrés ont démontrés que les groupements tert-butyls sur l’aniline o
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Wu, Jin-Ti, and 吳進益. "Study on Photochemistry of Furan and Thiophene Derivatives." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/54640388557788524634.

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博士<br>國立臺灣大學<br>化學研究所<br>87<br>A novel photochemical rearrangement of this work is from a series of 2-(4’-alkylstyryl)furan or thiophene to 5-(3-alkylbutadienyl)benzo[b]-furan or thiophene with good yields. The starting materials were prepared from 2-furaldehyde and the corresponding benzyl chloride or bromide using Wittig reaction, the UV absorption is at 330 nm. The styrylfuran or styrylthiophene is known to undergo photochemical isomerization and in the presence of oxygen or iodine to afford cyclized products, but the skeletal rearrangement is occurred only when photolysis is carried out in
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LIANG, LAN-CHANG, and 梁蘭昌. "Studies of thiophene coordination via the reaction of lmine derivatives of thiophene and diiron monacrbonyl." Thesis, 1992. http://ndltd.ncl.edu.tw/handle/86843709795238911449.

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SUN, PEI-JUN, and 孫培鈞. "Studies on copolymers based on dicarbazole derivatives and thiophene derivatives in electrochromic devices." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/bxuzcb.

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碩士<br>國立高雄科技大學<br>化學工程與材料工程系<br>107<br>Copolymers based on 5-[3,5-di(carbazol-9-yl)phenyl]benzene-1,3-dicarbonitrile (dCzCN) and four bithiophene derivatives (2,2'-bithiophene (bTP), 2-(2-thienyl)furan (TF), 4H-cyclopenta[2,1-b:3,4b’]dithiophene (CPDT), and cyclopentadithiopheneketone (CPDTK)) are electrochemically synthesized on ITO electrodes. The spectroelectrochemical properties of four copolymer films are investigated by UV-Vis spectra and cyclic voltammetry (CV). Spectroelectrochemical studies indicated that P(dCzCN-co-bTP) film is brown, green, and blue in the neutral, oxidation, and h
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Lai, Chu-Haw, and 賴俊華. "Reaction of Thiophene Imine Derivatives with Palladium (II) Complexes." Thesis, 1995. http://ndltd.ncl.edu.tw/handle/49335274449723060858.

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42

Yang, Huei-Ru, and 楊惠如. "Synthesis and properties of indane[2,1-b]thiophene derivatives." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/4qr865.

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碩士<br>國立臺灣科技大學<br>高分子系<br>94<br>In this study, ethyl(1-indanylidene)-cyanoacetate(3) has been synthesized by the reaction of 1-indanone with Ethylcyanoacetate, followed by the cyclization with sulfur to given ethyl–2–amino– 8H-indanone[2,1-b]thiophanone-3–carboxylate(5). Compound(5) reacted with acetic anhydride to yield ethyl 2–acetyl-8H-indanone[2,1-b]thiophene-3-carboxylate(7)and with aldehy- des to yield azomethine dyes (C=N) (9) and methine dye(10) and (11), respectively. These compounds were determined by elemental and spectral analysis(FT-IR、1H-NMR and Mass). The solvatochromic behavior
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Liang, Chu-Hua, and 梁琡華. "Synthesis of Thiophene Derivatives as Potential Radiosensitizers and Antiinflammatory Agents." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/67817143543394589582.

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碩士<br>國防醫學院<br>藥學研究所<br>94<br>Our laboratory previously carried out the design and synthesis of a series of benzothieno[2,3-c]quinolone derivatives to develop novel anticancer drugs in our laboratories. After screening of the radiosensitizer/radioprotectant, the results showed that benzothiophene intermediates had strong potency to enhance the activity of radiation. On the other hand, literatures indicated that some thiophene derivatives possess significant antiinflammatory activity. Therefore, we further designed and synthesized a series of benzothiophene and thiophene derivatives to develop
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Huang, Chih-Hong, та 黃志弘. "Synthesis of Thiophene Derivatives as π-conjugated linker Photosensitized Dyes". Thesis, 2010. http://ndltd.ncl.edu.tw/handle/233yrn.

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碩士<br>國立臺北科技大學<br>有機高分子研究所<br>98<br>In this thesis, several triphenylamine dyes, containing high hole mobility of thienothiophene , bithiophene and n-hexyl-substituted thienothiophene as π-conjugated linker, were synthesized . The organic dyes with the structure of donor-conjugated chain-acceptor have been synthesized for dye sensitized solar cell (DSSC). The effects of both the length of the π-conjugated unit and of the alkyl chain up on the photophysical, electrochemical and photovoltaic properties of the dyes were studied. All of these compounds were characterized by UV/VIS spectrophotom
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Koong, Shyang-Ing, and 孔祥櫻. "Pyrolytic Study of 2-Azidomethylbenzo [b] thiophene and its Derivatives." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/13823346485881499687.

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碩士<br>國立中山大學<br>化學系<br>87<br>When we put 2-Azidomethylbenzo [b] thiophene and its Derivatives in the Frash Vacuum Pyrolysis(FVP) instrument, we set the temp = 450-650, pressure = 0.02 torr, we can get the trimer product, di-2-benzo[b]thienylmethylidene-N,N'-2-benzo[b]thienylmethel amine.
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LU, TI-YI, and 呂緹儀. "Preparation and characterization of metal complexes of thiophene imine derivatives." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/82078819571146648251.

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WANG, DONG-LIANG, and 王東亮. "Reaction of thiophene and it's derivatives with palladium (II) complexes." Thesis, 1990. http://ndltd.ncl.edu.tw/handle/16791104899385532200.

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48

Wang, Lian Yi, and 王聯議. "Formation and structure of diiron carbonyl complexes of thiophene imine derivatives." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/61502539631501799385.

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49

Wang, Lennie, and 王聯議. "Formation and Structure of Diiron Carbonyl Complexes of Thiophene Imine Derivatives." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/90147298764374709120.

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50

Feng, Tsai Ming, and 蔡銘峰. "Synthesis and Characterization of Poly (alkyl-thiophene) Derivatives for Optoelectronic Applications." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/67308496980099068422.

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碩士<br>國立高雄應用科技大學<br>化學工程與材料工程系<br>98<br>A novel series of soluble alternating conjugated copolymers: regioregularity Poly(3-alkylthiophene)s (rr-P3AT)s , Poly[(alkylthiophene)-co-(thiophene)]s (PATThs) and Poly[(alkylthiophene)-co-(3,4-ethylenedioxythiophene)] (PATEs) were synthesized by Ni-catalyzed Kumada coupling reaction. The systems of polymers with different alkyl side chain length (hexyl, octyl and decyl) and unit copolymers (thiophene and ethylenedioxythiophene), the physical, optical and electrical property were observed. The series of copolymers were identified by 1H NMR and FT- IR,
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