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1

Hasegawa, Hiroyuki, Ayako Kimura, and Tetsuya Suzuki. "Microhardness and structural analysis of (Ti,Al)N, (Ti,Cr)N, (Ti,Zr)N and (Ti,V)N films." Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 18, no. 3 (May 2000): 1038–40. http://dx.doi.org/10.1116/1.582296.

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2

Shtansky, D. V., A. N. Sheveiko, M. I. Petrzhik, F. V. Kiryukhantsev-Korneev, E. A. Levashov, A. Leyland, A. L. Yerokhin, and A. Matthews. "Hard tribological Ti–B–N, Ti–Cr–B–N, Ti–Si–B–N and Ti–Al–Si–B–N coatings." Surface and Coatings Technology 200, no. 1-4 (October 2005): 208–12. http://dx.doi.org/10.1016/j.surfcoat.2005.02.126.

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3

Ipaz, L., H. Ruiz-Luna, F. J. Espinoza-Beltrán, and G. Zambrano. "Correlation Between Mechanical Properties and Nanofriction of [Ti–Cr/Ti–Cr–N] n and [Ti–Al/Ti–Al–N] n Multilayers." Tribology Letters 49, no. 2 (December 5, 2012): 403–12. http://dx.doi.org/10.1007/s11249-012-0081-y.

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4

Kuo, Dong-Hau, and Wen-Chieh Liao. "Ti–N, Ti–C–N, Ti–Si–N coatings obtained by APCVD at 650–800 °C." Applied Surface Science 199, no. 1-4 (October 2002): 278–86. http://dx.doi.org/10.1016/s0169-4332(02)00869-3.

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5

Kiryukhantsev-Korneev, Ph V., D. V. Shtansky, M. I. Petrzhik, E. A. Levashov, and B. N. Mavrin. "Thermal stability and oxidation resistance of Ti–B–N, Ti–Cr–B–N, Ti–Si–B–N and Ti–Al–Si–B–N films." Surface and Coatings Technology 201, no. 13 (March 2007): 6143–47. http://dx.doi.org/10.1016/j.surfcoat.2006.08.133.

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6

Sun, Tao, Lang-Ping Wang, Min Wang, Ho-Wang Tong, and William W. Lu. "PIIID-formed (Ti, O)/Ti, (Ti, N)/Ti and (Ti, O, N)/Ti coatings on NiTi shape memory alloy for medical applications." Materials Science and Engineering: C 32, no. 6 (August 2012): 1469–79. http://dx.doi.org/10.1016/j.msec.2012.04.027.

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7

Knotek, O., M. Böhmer, T. Leyendecker, and F. Jungblut. "The structure and composition of TiZrN, TiAlZrN and TiAlVN coatings." Materials Science and Engineering: A 105-106 (December 1988): 481–88. http://dx.doi.org/10.1016/0025-5416(88)90732-x.

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8

Hоvоrun, Т. P., O. V. Pylypenko, M. V. Hovorun, and K. O. Dyadyura. "Methods of Obtaining and Properties of Wear-resistant Coatings Ti and N and Ti, Al and N." Journal of Nano- and Electronic Physics 9, no. 2 (2017): 02026–1. http://dx.doi.org/10.21272/jnep.9(2).02026.

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9

Kim, Seong-Won, Jung-Min Chae, Shin-Hoo Kang, Sung-Soo Ryu, and Hyung-Tae Kim. "Characterization of Ti(C,N) Solid Solutions in Densified Ti(C,N) and TiC-TiN-Ni Cermet." Journal of Korean Powder Metallurgy Institute 15, no. 6 (December 28, 2008): 503–8. http://dx.doi.org/10.4150/kpmi.2008.15.6.503.

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10

Okamoto, H. "N-Ti (Nitrogen-Titanium)." Journal of Phase Equilibria 14, no. 4 (August 1993): 536. http://dx.doi.org/10.1007/bf02671982.

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11

Okamoto, H. "N-Ti (Nitrogen-Titanium)." Journal of Phase Equilibria and Diffusion 34, no. 2 (October 23, 2012): 151–52. http://dx.doi.org/10.1007/s11669-012-0153-6.

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12

Prekel, H., M. J. Klopfstein, M. Giesselbach, S. Patzelt, R. Ghisleni, D. A. Lucca, G. Goch, and H. R. Stock. "Photothermal Investigation of Ti-Cu-N and Ti-Ni-N PVD Films." CIRP Annals 55, no. 1 (2006): 585–88. http://dx.doi.org/10.1016/s0007-8506(07)60488-0.

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13

Tonghe, Zhang, Ji Chengzhou, Shen Jinghua, Chen Jun, Lin Wenlian, Tan Fujin, and Gao Yuzun. "Annealing behaviour of H13 steel implanted with N, Ti and Ti + N." Surface and Coatings Technology 56, no. 2 (January 1993): 143–49. http://dx.doi.org/10.1016/0257-8972(93)90019-k.

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14

Carvalho, S., E. Ribeiro, L. Rebouta, J. Pacaud, Ph Goudeau, P. O. Renault, J. P. Rivière, and C. J. Tavares. "PVD grown (Ti,Si,Al)N nanocomposite coatings and (Ti,Al)N/(Ti,Si)N multilayers: structural and mechanical properties." Surface and Coatings Technology 172, no. 2-3 (July 2003): 109–16. http://dx.doi.org/10.1016/s0257-8972(03)00323-2.

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15

Andreev, A. A., V. M. Beresnev, M. A. Volosova, S. N. Grigor’ev, D. A. Kolesnikov, A. D. Pogrebnyak, I. V. Serdyuk, O. V. Sobol’, and P. V. Turbin. "Tribological characteristics of nanocomposite vacuum-plasma Ti-Hf, Ti-Hf-N, and Ti-Hf-Si-N coatings." Journal of Friction and Wear 34, no. 3 (May 2013): 175–82. http://dx.doi.org/10.3103/s1068366613030033.

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16

Martin, P. J., A. Bendavid, J. M. Cairney, and M. Hoffman. "Nanocomposite Ti–Si–N, Zr–Si–N, Ti–Al–Si–N, Ti–Al–V–Si–N thin film coatings deposited by vacuum arc deposition." Surface and Coatings Technology 200, no. 7 (December 2005): 2228–35. http://dx.doi.org/10.1016/j.surfcoat.2004.06.012.

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17

König, W., and D. Kammermeier. "Performance of TiN-, Ti(C,N)- and (Ti,Al)N-Coated Cutting Tools." Materials Science Forum 102-104 (January 1992): 623–32. http://dx.doi.org/10.4028/www.scientific.net/msf.102-104.623.

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18

Grimberg, I., V. M. Zhitomirsky, R. L. Boxman, S. Goldsmith, and B. Z. Weiss. "Multicomponent Ti–Zr–N and Ti–Nb–N coatings deposited by vacuum arc." Surface and Coatings Technology 108-109 (October 1998): 154–59. http://dx.doi.org/10.1016/s0257-8972(98)00658-6.

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19

Lenguaer, Walter, and Peter Ettmayer. "Investigations of phase equilibria in the TiN and TiMoN systems." Materials Science and Engineering: A 105-106 (November 1988): 257–63. http://dx.doi.org/10.1016/0025-5416(88)90504-6.

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20

Bykov, A. I., I. I. Timofeeva, L. A. Klochkov, A. V. Ragulya, L. P. Isaeva, V. S. Urbanovich, and M. M. Ristic. "Making and structural features of Ti-N-B and Ti-N-C nanocomposites." Powder Metallurgy and Metal Ceramics 47, no. 1-2 (January 2008): 47–53. http://dx.doi.org/10.1007/s11106-008-0008-1.

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21

Shih, K. K., and D. B. Dove. "Ti/Ti‐N Hf/Hf‐N and W/W‐N multilayer films with high mechanical hardness." Applied Physics Letters 61, no. 6 (August 10, 1992): 654–56. http://dx.doi.org/10.1063/1.107812.

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22

Sonoda, T., A. Watazu, J. Zhu, W. Shi, T. Yamada, K. Kato, and T. Asahina. "Surface modification of Ti-6AI-4V alloy with Ti-C/Ti-N/Ti multilayered film by magnetron DC sputtering." Revista de Metalurgia 40, no. 6 (December 30, 2004): 413–15. http://dx.doi.org/10.3989/revmetalm.2004.v40.i6.298.

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23

Lu, Xin-Chun, Bing Shi, Lawrence K. Y. Li, Jianbin Luo, Xiangrong Chang, Zhongzhuo Tian, and Jong-I. Mou. "Nanoindentation and microtribological behavior of Fe–N/Ti–N multilayers with different thickness of Ti–N layers." Wear 251, no. 1-12 (October 2001): 1144–49. http://dx.doi.org/10.1016/s0043-1648(01)00722-0.

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24

Li, Ji, Hai-Sheng Lu, Yong-Wei Wang, and Xin-Ping Qu. "Sputtered Ru–Ti, Ru–N and Ru–Ti–N films as Cu diffusion barrier." Microelectronic Engineering 88, no. 5 (May 2011): 635–40. http://dx.doi.org/10.1016/j.mee.2010.06.031.

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25

Chen, Li, Yong Du, Fei Yin, and Jia Li. "Mechanical properties of (Ti, Al)N monolayer and TiN/(Ti, Al)N multilayer coatings." International Journal of Refractory Metals and Hard Materials 25, no. 1 (January 2007): 72–76. http://dx.doi.org/10.1016/j.ijrmhm.2006.01.005.

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26

Naidoo, Melisha, Oluwagbenga Johnson, Iakovos Sigalas, and Mathias Herrmann. "Preparation of Ti–Ta–(C,N) by mechanical alloying Ti(C,N) and TaC." International Journal of Refractory Metals and Hard Materials 37 (March 2013): 67–72. http://dx.doi.org/10.1016/j.ijrmhm.2012.10.018.

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27

Taşer, A., Z. Orhan, C. Aykaç, O. Ozakin, B. Güzeldir, and M. Sağlam. "Effects of aging on the electrical properties of Au/n-Si/Ti, Cu/n-Si/Ti and AuCu/n-Si/Ti Schottky diodes." Materials Today: Proceedings 46 (2021): 6954–59. http://dx.doi.org/10.1016/j.matpr.2021.03.270.

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28

Vancoille, E., J. P. Celis, and J. R. Roos. "Mechanical properties of heat treated and worn PVD TiN, (Ti, Al)N, (Ti, Nb)N and Ti(C, N) coatings as measured by nanoindentation." Thin Solid Films 224, no. 2 (March 1993): 168–76. http://dx.doi.org/10.1016/0040-6090(93)90428-r.

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29

Daniels, S., R. A. M. Wolters, J. van Zijl, and J. Schildermans. "Ti/TiN/Ti(N) PVD liners for W-plug applications." Microelectronic Engineering 50, no. 1-4 (January 2000): 271–76. http://dx.doi.org/10.1016/s0167-9317(99)00292-0.

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30

Vieira, Maria Teresa, Ana S. Ramos, José M. Castanho, João C. Oliveira, and Albano Cavaleiro. "From Ti–Al- to Ti–Al–N-sputtered 2D materials." Journal of Materials Science 42, no. 22 (November 2007): 9145–53. http://dx.doi.org/10.1007/s10853-007-1933-y.

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31

Wang, Rui Feng, Zhi Ping Sun, Li Yan Zou, and Guo Jun Zhang. "Effect of Ti(C,N) Content on Microstructure and Mechanical Properties of Ti(C,N)/Fe Composites." Advanced Materials Research 583 (October 2012): 215–18. http://dx.doi.org/10.4028/www.scientific.net/amr.583.215.

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Ti(C,N)/Fe composites samples were fabricated in vacuum and Ti(C,N) content was respectively 20vol.%, 30vol.% and 40vol.%. The relationship of microstructure and mechanical properties for Ti(C,N)/Fe composites with various Ti(C,N) content were studied. The results indicated that the flexural strength and wear resistant increased with increasing the content of Ti(C,N)in the range of 0 to 30vol.%, then decreased with further increase of Ti(C,N) content, and the fracture toughness decreases with increasing Ti(C,N) content integrally, while the Vickers hardness increased with the increase of Ti(C,N) content. The microstructure of Ti(C,N)/Fe composites is uniform, fine grains, and grains combine more closely with Ti(C,N) 30vol.%. By comparing the properties of the material was relatively good with Ti(C,N) 30vol.% at 1300°C.
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32

Han, Jeon G., Hyun S. Myung, Hyuk M. Lee, and Leonid R. Shaginyan. "Microstructure and mechanical properties of Ti–Ag–N and Ti–Cr–N superhard nanostructured coatings." Surface and Coatings Technology 174-175 (September 2003): 738–43. http://dx.doi.org/10.1016/s0257-8972(03)00565-6.

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33

Dai, J. Y., Y. G. Wang, D. X. Li, and H. Q. Ye. "Atomic structure at Ti(C,N)-TiB2 interfaces in Ti(C,N)-TiB2-Ni ceramics." Philosophical Magazine A 70, no. 5 (November 1994): 905–16. http://dx.doi.org/10.1080/01418619408242938.

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34

Shi, Zeng Min, Ping Feng, Wen Jun Liu, Yong Zheng, and Jian Li. "Tribological Behavior of Ti(C, N)-Based and Functionally Gradient Ti(C, N)-Based Cermets." Advanced Materials Research 97-101 (March 2010): 1097–103. http://dx.doi.org/10.4028/www.scientific.net/amr.97-101.1097.

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Ti(C, N)-based cermet and functionally gradient Ti(C, N)-based cermet were prepared by vacuum sintering and post surface heat-treatment in nitrogen, respectively. Tribological behaviors of obtained cermets were comparatively studied. Dry sliding wear and cutting test were conducted against quenched medium carbon steel. It was found that a graded structure formed and the surface hardness of functionally gradient Ti(C, N)-based cermet was improved. Friction coefficients of both cermets decreased with the increase of the sliding speed. The friction coefficient of Ti(C, N)-based cermet was lower than that of functionally gradient Ti(C, N)-based cermet at the conditions of higher sliding speed and higher load. The cutting test demonstrated that Ti(C, N)-based cermet exhibited better cutting performance and higher wear resistance than the cemented carbide YT15, cermet TN20 and functionally gradient Ti(C, N)-based cermet, while the functionally gradient Ti(C, N)-based cermet exhibited a similar performance as YT15 and TN20.
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35

Xing, Xiao‐peng, Guan‐jun Wang, Cai‐xia Wang, and Ming‐fei Zhou. "Infrared Photodissociation Spectroscopy of Ti+(CO2)2Ar and Ti+(CO2)n (n=3–7) Complexes." Chinese Journal of Chemical Physics 26, no. 6 (December 2013): 687. http://dx.doi.org/10.1063/1674-0068/26/06/687-693.

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36

Hirvonen, J‐P, M. Nastasi, T. G. Zocco, and T. R. Jervis. "Microstructure and mechanical properties of ion‐beam‐produced Fe‐Ti‐(N), Fe‐Ti‐(C), and Fe‐Ti‐(C,N) surface films." Journal of Applied Physics 67, no. 12 (June 15, 1990): 7292–99. http://dx.doi.org/10.1063/1.344514.

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37

Vaz, F., and L. Rebouta. "Superhard Nanocomposite Ti-Si-N Coatings." Materials Science Forum 383 (December 2001): 143–50. http://dx.doi.org/10.4028/www.scientific.net/msf.383.143.

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38

Banaszek, Katarzyna, and Leszek Klimek. "Ti(C, N) as Barrier Coatings." Coatings 9, no. 7 (July 8, 2019): 432. http://dx.doi.org/10.3390/coatings9070432.

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Metals and their alloys are materials that have long been used in stomatological prosthetics and orthodontics. The side effects of their application include reactions of the body such as allergies. Their source can be corrosion products as well as metal ions released in the corrosion process, which penetrate the surrounding tissue. In order to prevent the harming effect of metal alloys, intensive research has been performed to purify metal prosthetic restorations by way of modifying their surface. The study presents the investigation results of Ti(C, N)-type coatings applied to alloy Ni–Cr by means of the magnetronic method. Five coatings differing in the nitrogen and carbon content were investigated. The studies included the determination of the coatings’ chemical composition, construction, as well as the amount of ions released into the environment: distilled water, 0.9% NaCl and artificial saliva. The performed investigations showed that, in reference to an alloy without a coating, each coating constitutes a barrier reducing the amount of ions transferred into the examined solutions. So, Ti(C, N)-type coatings can be considered for biomedical applications as protective coatings of non-precious metal alloys.
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39

Raghavan, V. "Fe-N-Ti (Iron-Nitrogen-Titanium)." Journal of Phase Equilibria 24, no. 1 (February 1, 2003): 70–72. http://dx.doi.org/10.1361/105497103770331054.

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40

Raghavan, V. "Al-N-Ti (Aluminum-Nitrogen-Titanium)." Journal of Phase Equilibria & Diffusion 27, no. 2 (April 1, 2006): 159–62. http://dx.doi.org/10.1361/154770306x97263.

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41

Raghavan, V. "Fe-N-Ti (iron-nitrogen-titanium)." Journal of Phase Equilibria 24, no. 1 (February 2003): 70–72. http://dx.doi.org/10.1007/s11669-003-0013-5.

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42

Raghavan, V. "Al−N−Ti (Aluminum-Nitrogen-Titanium)." Journal of Phase Equilibria and Diffusion 27, no. 2 (March 2006): 159–62. http://dx.doi.org/10.1007/s11669-006-0046-7.

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43

Knotek, O., R. Breidenbach, F. Jungblut, and F. Löffler. "Superhard Ti-B-C-N coatings." Surface and Coatings Technology 43-44 (December 1990): 107–15. http://dx.doi.org/10.1016/0257-8972(90)90065-k.

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44

Wriedt, H. A., and J. L. Murray. "The N-Ti (Nitrogen-Titanium) system." Bulletin of Alloy Phase Diagrams 8, no. 4 (August 1987): 378–88. http://dx.doi.org/10.1007/bf02869274.

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45

Jonsson, Stefan. "Assessment of the Ti-N System." International Journal of Materials Research 87, no. 9 (September 1, 1996): 691–702. http://dx.doi.org/10.1515/ijmr-1996-870903.

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46

Suzuki, Hisashi, Hideaki Matsubara, Akira Matsuo, and Kunio Shibuki. "Properties of Ti(C,N)-Mo2C-Ni cermets coated with Ti(C,N) by PVD process." Journal of the Japan Society of Powder and Powder Metallurgy 33, no. 2 (1986): 92–97. http://dx.doi.org/10.2497/jjspm.33.92.

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47

Gómez-Esparza, CD, RP Talamantes-Soto, and A. Duarte-Moller. "Evaluation of Mechanical Properties of Ti/Al/Zr-N and Zr/Al/Ti-N Thin Films." Microscopy and Microanalysis 25, S2 (August 2019): 2632–33. http://dx.doi.org/10.1017/s1431927619013898.

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48

Kim, Jung Wook, Sudeep Abraham, Kwang Ho Kim, Jang Hyun Sung, and John J. Moore. "Comparative Study on the Oxidation Resistance between Ti-Al-Si-N and Ti-Al-N Coatings." Solid State Phenomena 118 (December 2006): 317–22. http://dx.doi.org/10.4028/www.scientific.net/ssp.118.317.

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High-temperature oxidation behaviors of Ti-Al-Si-N and Ti-Al-N films were comparatively investigated in this work. Two kinds of Ti0.75Al0.25N and Ti0.69Al0.23Si0.08N films were deposited on WC-Co substrates by a DC magnetron sputtering method using separate Ti3Al(99.9%) and Si(99.99%) targets in a gaseous mixture of Ar and N2. Si addition of 8 at.% into Ti-Al-N film modified its microstructure to a fine composite comprising, Ti-Al-N crystallites and amorphous Si3N4, and to a smoother surface morphology. While the solid solution Ti0.75Al0.25N film had superior oxidation resistance up to around 700, the composite Ti-Al-Si-N film showed further enhanced oxidation resistance. Both Al2O3 and SiO2 layers played roles as a barrier against oxygen diffusion for the quaternary Ti-Al-Si-N film, whereas only the Al2O3 oxide layer formed at surface did a role for the Ti-Al-N film. Oxidation behavior and mechanical stability of the films after oxidation were compared between two films using instrumental analyses such as XRD, GDOES, XPS, and scratch test.
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49

Wally, P., P. Ettmayer, and W. Lengauer. "The TiMoCN system: Stability of the (Ti, Mo)(C, N)1−x phase." Journal of Alloys and Compounds 228, no. 1 (September 1995): 96–101. http://dx.doi.org/10.1016/0925-8388(95)01652-x.

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50

Chen, Li, S. Q. Wang, S. Z. Zhou, Jia Li, and Y. Z. Zhang. "Microstructure and mechanical properties of Ti(C,N) and TiN/Ti(C,N) multilayer PVD coatings." International Journal of Refractory Metals and Hard Materials 26, no. 5 (September 2008): 456–60. http://dx.doi.org/10.1016/j.ijrmhm.2007.10.003.

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