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1

Peddada, S. R., I. M. Robertson, and H. K. Birnbaum. "Hydride precipitation in vapor deposited Ti thin films." Journal of Materials Research 8, no. 2 (1993): 291–96. http://dx.doi.org/10.1557/jmr.1993.0291.

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Titanium hydrides having two different crystal structures were observed in α–Ti thin films grown epitaxially on sapphire substrates by e-beam physical vapor deposition. One of the hydrides (γ-hydride) had a face-centered tetragonal structure (c/a > 1) with an ordered arrangement of hydrogen atoms. The second hydride formed was the fcc δ-hydride. The γ-hydride grew as platelets in the α–Ti lattice with {10$\overline 1$0}Ti habit planes, whereas the γ-hydrides formed directly on the sapphire substrate parallel to the (0001)Ti. These hydrides are one of the principal causes of film decohesion.
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2

Prestipino, R. M., and B. K. Furman. "SIMS/TEM characterization of titanium thin films." Proceedings, annual meeting, Electron Microscopy Society of America 44 (August 1986): 590–91. http://dx.doi.org/10.1017/s0424820100144425.

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Thin metal films are important constituents of semiconductor devices and packages. One metal of primary interest is titanium. It is known that titanium is susceptible to absorption of hydrogen at elevated temperatures and forms hydrides that can cause embrittlement and cracking. In this study secondary ion mass spectroscopy (SIMS) was used to study the absorption of hydrogen into titanium thin films as a function of processing conditions. SIMS/ion imaging provided information on hydrogen segregation and hydride formation. Transmission electron microscopy (TEM) was used to study the microstruct
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3

Rezaei Ardani, Mohammad, Sheikh Abdul Rezan Sheikh Abdul Hamid, Dominic C. Y. Foo, and Abdul Rahman Mohamed. "Synthesis of Ti Powder from the Reduction of TiCl4 with Metal Hydrides in the H2 Atmosphere: Thermodynamic and Techno-Economic Analyses." Processes 9, no. 9 (2021): 1567. http://dx.doi.org/10.3390/pr9091567.

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Titanium hydride (TiH2) is one of the basic materials for titanium (Ti) powder metallurgy. A novel method was proposed to produce TiH2 from the reduction of titanium tetrachloride (TiCl4) with magnesium hydride (MgH2) in the hydrogen (H2) atmosphere. The primary approach of this process is to produce TiH2 at a low-temperature range through an efficient and energy-saving process for further titanium powder production. In this study, the thermodynamic assessment and technoeconomic analysis of the process were investigated. The results show that the formation of TiH2 is feasible at low temperatur
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4

CONFORTO, Egle, and Xavier FEAUGAS. "A Review of Hydride Precipitates in Titanium and Zirconium Alloys: Precipitation, Dissolution and Crystallographic Orientation Relationships." MATEC Web of Conferences 321 (2020): 11042. http://dx.doi.org/10.1051/matecconf/202032111042.

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This work proposes a review of recent results on the formation and dissolution of hydrides in HCP alloys (Ti and Zr alloys) correlated to the nature of crystallographic hydride phases and their ORs. The crystallographic coherence observed between the surface hydride layer and the substrate is very important for many applications as for biomaterials devices. Five particular orientation relationships (OR) were identified between titanium/zirconium hydride precipitates and the oc-Ti and a-Zr substrates. In addition, the nature of hydrides have a large implication on the ductility, the strain hard
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5

Conforto, Egle, Stephane Cohendoz, Cyril Berziou, Patrick Girault, and Xavier Feaugas. "Formation and Dissolution of Hydride Precipitates in Zirconium Alloys: Crystallographic Orientation Relationships and Stability after Temperature Cycling." Materials Science Forum 879 (November 2016): 2330–35. http://dx.doi.org/10.4028/www.scientific.net/msf.879.2330.

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Hydride precipitation due to the spontaneous and fast hydrogen diffusion is often pointed as causing embrittlement and rupture in zirconium alloys used in the nuclear industry. Transmission Electron Microscopy (TEM) and X-Rays Diffraction (XRD) have been used to study the precipitation of hydride phases in zirconium alloys as a function of the hydrogen content. The orientation relationships observed between the hydride phase and the substrate were similar to those previously observed in Titanium hydrides grown on Titanium. Dislocation emission from the hydride precipitates has been directly re
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6

SCHUR, D. "Phase transformations in titanium hydrides." International Journal of Hydrogen Energy 21, no. 11-12 (1996): 1121–24. http://dx.doi.org/10.1016/s0360-3199(96)00058-4.

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7

Setoyama, Daigo, Junji Matsunaga, Masato Ito, et al. "Thermal properties of titanium hydrides." Journal of Nuclear Materials 344, no. 1-3 (2005): 298–300. http://dx.doi.org/10.1016/j.jnucmat.2005.04.059.

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8

Maly-Schreiber, Martha, Robert A. Huggins, and Karl Maly. "Thermodynamic properties of titanium-nickel hydrides." Solid State Ionics 28-30 (September 1988): 873–78. http://dx.doi.org/10.1016/s0167-2738(88)80162-0.

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9

Wanderwalker, D. M. "The formation of hydrides in titanium." Physica Status Solidi (a) 105, no. 2 (1988): K77—K80. http://dx.doi.org/10.1002/pssa.2211050243.

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10

Braga, N. A., N. G. Ferreira, Francisco Piorino Neto, M. R. Baldan, and Carlos Alberto Alves Cairo. "Hydrogen Addition Effect on 3D Porous Titanium Produced by Powder Metallurgy." Materials Science Forum 591-593 (August 2008): 289–93. http://dx.doi.org/10.4028/www.scientific.net/msf.591-593.289.

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Titanium is an attractive material for structural and biomedical applications because of its excellent corrosion resistance, biocompatibility and high strength-to-weight ratio. Power metallurgy was used in this work to prepare 3D porous titanium. The powders became fragile from hydrogenation process and were able to be used to obtain compacts with different porosities by uniaxial pressing and sintering without applied pressure. Since hydrogen dissolves easily in titanium to form titanium hydrides which have a strong influence on the microstructure coarsening and mechanical properties, the stud
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11

LEPEMANGOYE, La Chance, Nicolas CRETON, Virgil OPTASANU, et al. "Impact of rolling conditions on the hydriding of grade 2 titanium welded tubes." MATEC Web of Conferences 321 (2020): 09005. http://dx.doi.org/10.1051/matecconf/202032109005.

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In this article, we study the impact of rolling conditions on the texture of the commercially pure titanium grade 2. In a previous work, NEOTISS in collaboration with ICB laboratory, shown that the texture highly influences the precipitation of hydrides in Titanium. In order to create different textures, Titanium sheets grade 2 are cold rolled asymmetrically and symmetrically with or without lubricant. The inverse pole figures and direct pole figures obtained allow us to deduce that symmetrical cold rolling does not change the grains orientation but generates a rotation of grains along c-axis
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12

de Graaf, Sytze, Jamo Momand, Christoph Mitterbauer, Sorin Lazar, and Bart J. Kooi. "Resolving hydrogen atoms at metal-metal hydride interfaces." Science Advances 6, no. 5 (2020): eaay4312. http://dx.doi.org/10.1126/sciadv.aay4312.

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Hydrogen as a fuel can be stored safely with high volumetric density in metals. It can, however, also be detrimental to metals, causing embrittlement. Understanding fundamental behavior of hydrogen at the atomic scale is key to improve the properties of metal-metal hydride systems. However, currently, there is no robust technique capable of visualizing hydrogen atoms. Here, we demonstrate that hydrogen atoms can be imaged unprecedentedly with integrated differential phase contrast, a recently developed technique performed in a scanning transmission electron microscope. Images of the titanium-t
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13

Koketsu, Hideyuki, Yoshihiro Taniyama, Akio Yonezu, et al. "Mechanical Properties and Fracture of Titanium Hydrides." Zairyo-to-Kankyo 55, no. 5 (2006): 205–11. http://dx.doi.org/10.3323/jcorr.55.205.

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14

Wipf, H., B. Kappesser, and R. Werner. "Hydrogen diffusion in titanium and zirconium hydrides." Journal of Alloys and Compounds 310, no. 1-2 (2000): 190–95. http://dx.doi.org/10.1016/s0925-8388(00)00945-2.

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15

Kazantseva, N. V., A. G. Popov, N. V. Mushnikov, et al. "Thermally unstable hydrides of titanium aluminide Ti3Al." Physics of Metals and Metallography 111, no. 4 (2011): 353–60. http://dx.doi.org/10.1134/s0031918x11030069.

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16

Er, Süleyman, Michiel J. van Setten, Gilles A. de Wijs, and Geert Brocks. "First-principles modelling of magnesium titanium hydrides." Journal of Physics: Condensed Matter 22, no. 7 (2010): 074208. http://dx.doi.org/10.1088/0953-8984/22/7/074208.

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17

TANAKA, K. "INTERNAL FRICTION IN TITANIUM AND ITS HYDRIDES." Le Journal de Physique Colloques 46, no. C10 (1985): C10–119—C10–122. http://dx.doi.org/10.1051/jphyscol:19851027.

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18

Ito, Masato, Daigo Setoyama, Junji Matsunaga, et al. "Electrical and thermal properties of titanium hydrides." Journal of Alloys and Compounds 420, no. 1-2 (2006): 25–28. http://dx.doi.org/10.1016/j.jallcom.2005.10.032.

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19

Olsson, P. A. T., J. Blomqvist, C. Bjerkén, and A. R. Massih. "Ab initio thermodynamics investigation of titanium hydrides." Computational Materials Science 97 (February 2015): 263–75. http://dx.doi.org/10.1016/j.commatsci.2014.10.029.

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20

Conforto, E., I. Guillot, and X. Feaugas. "Solute hydrogen and hydride phase implications on the plasticity of zirconium and titanium alloys: a review and some recent advances." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 375, no. 2098 (2017): 20160417. http://dx.doi.org/10.1098/rsta.2016.0417.

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In this contribution, we propose a review of the possible implications of hydrogen on mechanical behaviour of Zr and Ti alloys with emphasis on the mechanisms of plasticity and strain hardening. Recent advances on the impact of oxygen and hydrogen on the activation volume show that oxygen content hinders creep but hydrogen partially screens this effect. Both aspects are discussed in terms of a locking–unlocking model of the screw dislocation mobility in prismatic slip. Additionally, possible extension of this behaviour is suggested for the pyramidal slip. The low hydrogen solubility in both Zr
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21

Kelton, K. F., and P. C. Gibbons. "Hydrogen Storage in Quasicrystals." MRS Bulletin 22, no. 11 (1997): 69–72. http://dx.doi.org/10.1557/s0883769400034473.

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Quasicrystals may have important applications as new technological materials. In particular, work in our laboratory has shown that some quasicrystals may be useful as hydrogen-storage materials.Some transition metals have a capacity to store hydrogen to a density exceeding that of liquid hydrogen. Such systems allow for basic investigations of solid-state phenomena such as phase transitions, atomic diffusion, and electronic structure. They may also be critical materials for the future energy economy. The depletion of the world's petroleum reserves and the increased environmental impact of conv
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22

Majzoub, E. H., and K. J. Gross. "Titanium–halide catalyst-precursors in sodium aluminum hydrides." Journal of Alloys and Compounds 356-357 (August 2003): 363–67. http://dx.doi.org/10.1016/s0925-8388(03)00113-0.

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23

GAMO, T., Y. MORIWAKI, N. YANAGIHARA, T. YAMASHITA, and T. IWAKI. "Formation and properties of titanium-manganese alloy hydrides." International Journal of Hydrogen Energy 10, no. 1 (1985): 39–47. http://dx.doi.org/10.1016/0360-3199(85)90134-x.

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24

Gao, Ming, J. Bart Boodey, and Robert P. Wei. "Hydrides in thermally charged alpha-2 titanium aluminides." Scripta Metallurgica et Materialia 24, no. 11 (1990): 2135–38. http://dx.doi.org/10.1016/0956-716x(90)90499-7.

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25

Woo, O. T., G. C. Weatherly, C. E. Coleman та R. W. Gilbert. "The precipitation of γ-deuterides (hydrides) in titanium". Acta Metallurgica 33, № 10 (1985): 1897–906. http://dx.doi.org/10.1016/0001-6160(85)90011-2.

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26

Li, J., A. Pflaum, F. Pobell, P. Sekowski, U. Stuhr, and H. Wipf. "Thermal conductivity and heat capacity of titanium hydrides." Journal of Low Temperature Physics 88, no. 3-4 (1992): 309–15. http://dx.doi.org/10.1007/bf00162965.

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27

Volokitina, Tatyana L., Roman S. Laptev, Viktor N. Kudiiarov, Dmitriy V. Gvozdyakov, and Maria N. Babihina. "Investigation of Hydrogen Sorption-Desorption Processes at Gas-Phase Hydrogenation and Defects Formation in Titanium by Means of Electron-Positron Annihilation Techniques." Defect and Diffusion Forum 373 (March 2017): 317–23. http://dx.doi.org/10.4028/www.scientific.net/ddf.373.317.

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The results of hydrogen sorption and desorption processes investigation at commercially pure titanium alloy during hydrogenation at gas atmosphere are shown in this article. Titanium alloy hydrogenation at temperatures 350, 450 и 550 °С leads to δ-hydrides formation in samples’ volume. Hydrogen sorption rates were calculated on the linear parts of sorption curves and equal to 0.15·10-4 wt%/s at 350 °C, 0.86·10-4 wt%/s at 450 °C, 1.55·10-4 wt%/s at 550 °C. Phase transition in titanium-hydrogen system during thermally stimulated hydrogen desorption investigation by the means of short-wave diffra
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28

Kyoi, Daisuke, Toyoto Sato, Ewa Rönnebro, et al. "A new ternary magnesium–titanium hydride Mg7TiHx with hydrogen desorption properties better than both binary magnesium and titanium hydrides." Journal of Alloys and Compounds 372, no. 1-2 (2004): 213–17. http://dx.doi.org/10.1016/j.jallcom.2003.08.098.

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29

POLONI, Alexandre, Abdelali OUDRISS, Juan CREUS, et al. "Hydrogen absorption and hydride formation in pure titanium T40 (grade 2) and TA6V ELI (grade 23) under cathodic polarization in artificial seawater." MATEC Web of Conferences 321 (2020): 09002. http://dx.doi.org/10.1051/matecconf/202032109002.

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Different kinetics of hydrogen absorption in T40 (grade 2) and TA6V ELI (grade 23) under cathodic polarization in artificial seawater have been highlighted. These polarizations were made by applying potentials from -0.8 to -1.8V/SCE in artificial seawater and NaCl solution. Four stages were identified and related in term of hydrogen ingress, hydrides formation and calcareous deposit growth. The formation of γ and δ-hydrides have been observed, localized and characterized using several techniques. On T40, hydrides form as a layer that increases the surface roughness and clusters form in the bul
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30

Li, Zhiming, Ping Ou, Nairong Sun, Zhigang Li, and Aidang Shan. "Face-centered tetragonal titanium hydrides in fine-grained commercial pure (grade 2) titanium." Materials Letters 105 (August 2013): 16–19. http://dx.doi.org/10.1016/j.matlet.2013.04.088.

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31

Salvadori, Enrico, Mario Chiesa, Antonio Buonerba, and Alfonso Grassi. "Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization." Chemical Science 11, no. 46 (2020): 12436–45. http://dx.doi.org/10.1039/d0sc04967k.

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Catalytically competent titanium-hydrides are reactive and difficult to isolate. We use EPR spectroscopy to define the electronic and geometrical structures as well as dynamics of an open-shell Ti-H active in syndiospecific olefin polymerization.
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32

MITROKHIN, S. "Titanium based Laves phase hydrides with high dissociation pressure." International Journal of Hydrogen Energy 21, no. 11-12 (1996): 981–83. http://dx.doi.org/10.1016/s0360-3199(96)00059-6.

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33

MITROKHIN, S. "Titanium-based Laves phase hydrides with high dissociation pressure." International Journal of Hydrogen Energy 22, no. 2-3 (1997): 219–22. http://dx.doi.org/10.1016/s0360-3199(96)00155-3.

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34

Kobayashi, Yoji, Ya Tang, Toki Kageyama, et al. "Titanium-Based Hydrides as Heterogeneous Catalysts for Ammonia Synthesis." Journal of the American Chemical Society 139, no. 50 (2017): 18240–46. http://dx.doi.org/10.1021/jacs.7b08891.

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35

Kazantseva, N. V., N. V. Mushnikov, A. G. Popov, V. A. Sazonova, and P. B. Terent’ev. "Use of mechanoactivation for obtaining hydrides of titanium aluminides." Physics of Metals and Metallography 105, no. 5 (2008): 460–70. http://dx.doi.org/10.1134/s0031918x08050062.

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36

Wen, Jing, Nathalie Allain, and Eric Fleury. "Determination of orientation relationships between FCC-hydride and HCP-titanium and their correlation with hydrides distribution." Journal of Alloys and Compounds 817 (March 2020): 153297. http://dx.doi.org/10.1016/j.jallcom.2019.153297.

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37

Kossler, W. J., H. E. Schone, K. Petzinger, et al. "Sites and diffusion for muons and hydrogen in titanium hydrides." Hyperfine Interactions 31, no. 1-4 (1986): 235–40. http://dx.doi.org/10.1007/bf02401565.

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38

TODA, Kei. "Detection of gaseous hydrides by metal-titanium oxide gas sensors." Bunseki kagaku 39, no. 11 (1990): 611–15. http://dx.doi.org/10.2116/bunsekikagaku.39.11_611.

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39

Olsson, Pär A. T., Matous Mrovec, and Martin Kroon. "First principles characterisation of brittle transgranular fracture of titanium hydrides." Acta Materialia 118 (October 2016): 362–73. http://dx.doi.org/10.1016/j.actamat.2016.07.037.

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40

Zhang, Yiping, Shijian Liao, Yun Xu, and Shoushan Chen. "Active hydrogenation catalysts from titanium complexes and alkali metal hydrides." Journal of Organometallic Chemistry 382, no. 1-2 (1990): 69–76. http://dx.doi.org/10.1016/0022-328x(90)85216-l.

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41

Sanders, J. H., and B. J. Tatarchuk. "Activation and deactivation mechanisms for thin-film iron-titanium hydrides." Journal of the Less Common Metals 147, no. 2 (1989): 277–92. http://dx.doi.org/10.1016/0022-5088(89)90201-4.

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42

Rokhmanenkov, A. "Modeling of nonlinear hydrogen diffusion in titanium hydrides TiH x." International Journal of Hydrogen Energy 42, no. 35 (2017): 22610–14. http://dx.doi.org/10.1016/j.ijhydene.2017.04.085.

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43

Rokhmanenkov, A., and A. Yanilkin. "Simulation of hydrogen thermal desorption and stability titanium hydrides TiH." International Journal of Hydrogen Energy 44, no. 55 (2019): 29132–39. http://dx.doi.org/10.1016/j.ijhydene.2019.03.237.

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44

POLONI, Alexandre, Abdelali OUDRISS, Juan CREUS, et al. "Influence of hydrogen on mechanical properties of pure titanium T40 (grade 2) and TA6V ELI (grade 23): a local approach of fracture." MATEC Web of Conferences 321 (2020): 09004. http://dx.doi.org/10.1051/matecconf/202032109004.

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The effect of hydrogen charging by cathodic polarization on T40 (grade 2) and TA6V ELI (grade 23) in artificial seawater appeared to be dependent on the metallurgical structure of the alloys. Mechanical tensile tests were performed on smooth samples and with different notches without and with hydrogen charging. Evolution of the fracture mode has been studied and the impact of hydrides was questioned. FEM calculation offers the opportunity to associate the local hydrostatic stress σm and equivalent plastic strain εpeq leading to the fracture and to illustrate the evolution of these conditions w
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45

Liesenhoff, Hans, and Wolfgang Sundermeyer. "Chemische Reaktionen in Salzschmelzen, XXI. Titan-vermittelte Synthese von Silanen in Chloroaluminat-Schmelzen / Chemical Reactions in Molten Salts, XXI. Titanium Mediated Synthesis of Silanes in Chloroaluminate Melts." Zeitschrift für Naturforschung B 54, no. 5 (1999): 573–76. http://dx.doi.org/10.1515/znb-1999-0501.

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Silanes of technical interest as starting compounds for semiconducting materials or hydrosilylation reactions, (CH3)xSiH4-x (x = 0, 1,2, 3), are obtained by direct hydrogenation of the corresponding chlorosilanes in the presence of various interstitial hydrides of transition metals (preferably of titanium), which are generated in situ in chloroaluminate melts, and aluminum as a halogen acceptor.
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46

Feng, Xuanyu, Yang Song, Justin S. Chen, et al. "Cobalt-bridged secondary building units in a titanium metal–organic framework catalyze cascade reduction of N-heteroarenes." Chemical Science 10, no. 7 (2019): 2193–98. http://dx.doi.org/10.1039/c8sc04610g.

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47

Ivanova, I. I., Yu N. Podrezov, N. A. Krylova, V. I. Danylenko, O. M. Demidyk, and V. A. Barabash. "Effect of Process and Structural Factors on the Mechanical Properties of Titanium Sintered from Titanium Hydrides." Powder Metallurgy and Metal Ceramics 58, no. 5-6 (2019): 270–77. http://dx.doi.org/10.1007/s11106-019-00078-9.

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48

Gritzay, O. O., P. A. Drutskyy, O. I. Kalchenko, and O. I. Оliynyk. "Determination of hydrogen content in titanium hydrides using neutron filtered beams." Nuclear Physics and Atomic Energy 19, no. 2 (2018): 173–81. http://dx.doi.org/10.15407/jnpae2018.02.173.

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49

Kazantseva, Ludmila A., Irina A. Kurzina, Natalia I. Kosova, et al. "Synthesis of titanium hydrides and obtaining of alloys based on them." Vestnik Тomskogo gosudarstvennogo universiteta. Khimiya, no. 2 (December 1, 2015): 69–75. http://dx.doi.org/10.17223/24135542/2/7.

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50

Ellis, John E., Beatrice Kelsey Stein, and Scott R. Frerichs. "Highly reduced organometallics. 33. Carbonyl hydrides of titanium and corresponding carbonyltitanates." Journal of the American Chemical Society 115, no. 10 (1993): 4066–75. http://dx.doi.org/10.1021/ja00063a027.

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