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Journal articles on the topic 'Titanium (IV) Iodide'

Author: Grafiati

Published: 5 June 2025

Last updated: 2 August 2025

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1

Hayakawa, Ryuuichirou, and Makoto Shimizu. "Titanium(IV) Iodide Promoted Pinacol Coupling." Chemistry Letters 29, no. 7 (2000): 724–25. http://dx.doi.org/10.1246/cl.2000.724.

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2

Manjula, Tirukovela, and Jeyanthi Arasan. "TiI4 Mediated Prins-Type Cyclization of Homoallylic Alcohols and Epoxides: An Efficient Method for the Synthesis of 4-Iodotetrahydropyran Derivatives." Der Pharma Chemica 15, no. 3 (2023): 4. https://doi.org/10.5281/zenodo.13319356.

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3

Jeyanthi, Arasan, and Manjula Tirukovela. "TiI4 Mediated Prins-Type Cyclization of Homoallylic Alcohols and Epoxides: An Efficient Method for the Synthesis of 4-Iodotetrahydropyran Derivatives." DER PHARMA CHEMICA 15, no. 3 (2023): 4. https://doi.org/10.4172/0975-413X.15.3.80-83.

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4

Tirukovela, Manjula, and Jeyanthi Arasan. "TiI4 Mediated Prins-Type Cyclization of Homoallylic Alcohols and Epoxides: An Efficient Method for the Synthesis of 4-Iodotetrahydropyran Derivatives." DER PHARMA CHEMICA 15, no. 3 (2023): 4. https://doi.org/10.5281/zenodo.10951947.

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5

Hayakawa, Ryuuichirou, and Makoto Shimizu. "ChemInform Abstract: Titanium(IV) Iodide Promoted Pinacol Coupling." ChemInform 31, no. 46 (2010): no. http://dx.doi.org/10.1002/chin.200046115.

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6

Liga, Shanti Maria, Sean R. Kavanagh, Aron Walsh, David O. Scanlon, and Gerasimos Konstantatos. "Mixed-Cation Vacancy-Ordered Perovskites (Cs2Ti1-x Sn x X6; X = I or Br): Low-Temperature Miscibility, Additivity, and Tunable Stability." Journal of Physical Chemistry C 127, no. 43 (2023): 1399–21409. https://doi.org/10.1021/acs.jpcc.3c05204.

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Lead toxicity and poor stability under operating conditions are major drawbacks that impede the widespread commercialization of metal-halide perovskite solar cells. Ti(IV) has been considered as an alternative species to replace Pb(II) because it is relatively nontoxic and abundant and its perovskite-like compounds have demonstrated promising performance when applied in solar cells (eta > 3%), photocatalysts, and nonlinear optical applications. Yet, Ti(IV) perovskites show instability in air, hindering their use. On the other hand, Sn(IV) has a similar cationic radius to Ti(IV), adopting th

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7

Oswald, Tim, Nicolai Lauterbach, Marc Schmidtmann та Rüdiger Beckhaus. "Molecular structures of a series of substituted bis(η5-cyclopentadienyl)titanium dihalides Cp R 2TiX 2 [X = F, Cl, Br and I; R = CHPh2, CH(p-Tol)2 and adamantyl]". Acta Crystallographica Section C Structural Chemistry 74, № 4 (2018): 442–51. http://dx.doi.org/10.1107/s205322961800342x.

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Metallocene dihalides and derivatives thereof are of great interest as precursors for catalysts in polymerization reactions, as antitumor agents and, due to their increased stability, as suitable starting materials in salt metathesis reactions and the generation of metallocene fragments. We report the synthesis and structural characterization of a series of eleven substituted bis(η5-cyclopentadienyl)titanium dihalides, namely bis[η5-1-(diphenylmethyl)cyclopentadienyl]difluoridotitanium(IV), [Ti(C18H15)2F2], bis{η5-1-[bis(4-methylphenyl)methyl]cyclopentadienyl}difluoridotitanium(IV), [Ti(C20H19

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8

Mukaiyama, Teruaki, Naritoshi Yoshimura, and Koji Igarashi. "Diastereoselective Pinacol Coupling Reaction of Aliphatic and Aromatic Aldehydes Promoted by Low Valent Titanium Iodide in situ Formed by Titanium(IV) Iodide and Copper." Chemistry Letters 29, no. 7 (2000): 838–39. http://dx.doi.org/10.1246/cl.2000.838.

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9

Balicki, Roman. "Mild and Efficient Deoxygenation of Sulfoxides with Titanium(IV) Chloride/Sodium Iodide Reagent System." Synthesis 1991, no. 02 (1991): 155–56. http://dx.doi.org/10.1055/s-1991-26402.

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10

Cambie, RC, GR Clark, CEF Rickard, PS Rutledge, GR Ryan, and PD Woodgate. "Chemistry of the Podocarpaceae. LXXII. Ring-C Modifications of Totarol." Australian Journal of Chemistry 41, no. 8 (1988): 1171. http://dx.doi.org/10.1071/ch9881171.

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Totarol (1) has been converted into conjugated dienolides which have the B/C-ring systems found in naturally occurring nagilactones A and C and their analogues. Thus, treatment of the epoxide (11) with titanium(IV) tetrachloride affords the desired 7,9(11)- diene (12) and the saturated γ- lactone (23). Treatment of the epoxide (11) with diazabicyclo [3.4.0]non-5-ene gives a high yield of the butenolide (24); the alcohol (25) has been shown to be an intermediate in this reaction. Treatment of (11) with lithium iodide dihydrate in collidine gives the butenolides (24) and (26), and the novel rear

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11

Mukaiyama, Teruaki, Naritoshi Yoshimura, and Koji Igarashi. "ChemInform Abstract: Diastereoselective Pinacol Coupling Reaction of Aliphatic and Aromatic Aldehydes Promoted by Low Valent Titanium Iodide in situ Formed by Titanium(IV) Iodide and Copper." ChemInform 31, no. 46 (2010): no. http://dx.doi.org/10.1002/chin.200046060.

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12

Mishra, Shuddhodan P., and N. Srinivasu. "Radiotracer technique in adsorption study—IX. Adsorption of iodide ions on titanium(IV) oxide powder." International Journal of Radiation Applications and Instrumentation. Part A. Applied Radiation and Isotopes 43, no. 6 (1992): 789–93. http://dx.doi.org/10.1016/0883-2889(92)90243-8.

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13

Murata, Yuki, Yuya Nishi, Mio Matsumura, and Shuji Yasuike. "Palladium-Catalyzed Cross-Coupling Reaction of Bis(cyclopentadienyl)diaryltitaniums with Terminal Alkynes." Reactions 4, no. 4 (2023): 657–66. http://dx.doi.org/10.3390/reactions4040037.

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Organotitanium compounds find application in diverse reactions, including carbon–carbon bond formation and oxidation. While titanium (IV) compounds have been used in various applications, the potential of bis(cyclopentadienyl)diaryltitanium in cross-coupling reactions remains unexplored. This study focuses on Sonogashira-type cross-coupling reactions involving terminal alkynes and organotitanium compounds. Diaryltitanocenes were synthesized using titanocene dichloride with lithium intermediates derived from aryl iodide. Under open-flask conditions, reactions of diphenyltitanocenes with ethynyl

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14

BALICKI, R. "ChemInform Abstract: Mild and Efficient Deoxygenation of Sulfoxides with Titanium(IV) Chloride/Sodium Iodide Reagent System." ChemInform 22, no. 38 (2010): no. http://dx.doi.org/10.1002/chin.199138081.

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15

Marchuk, Margarita, Igor Asanov, Maxim Panafidin, Yuri Vorotnikov, and Michael Shestopalov. "Nano TiO2 and Molybdenum/Tungsten Iodide Octahedral Clusters: Synergism in UV/Visible-Light Driven Degradation of Organic Pollutants." Nanomaterials 12, no. 23 (2022): 4282. http://dx.doi.org/10.3390/nano12234282.

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Emissions of various organic pollutants in the environment becomes a more and more acute problem in the modern world as they can lead to an ecological disaster in foreseeable future. The current situation forces scientists to develop numerous methods for the treatment of polluted water. Among these methods, advanced photocatalytic oxidation is a promising approach for removing organic pollutants from wastewater. In this work, one of the most common photocatalysts—titanium dioxide—was obtained by direct aqueous hydrolysis of titanium (IV) isopropoxide and impregnated with aqueous solutions of o

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16

Satoh, Tetsuya, Kenji Itoh, Masahiro Miura, and Masakatsu Nomura. "Desulfonylative Iodination of Naphthalenesulfonyl Chlorides with Zinc Iodide or Potassium Iodide Catalyzed by Dichlorobis(benzonitrile)palladium(II) in the Presence of Lithium Chloride and Titanium(IV) Isopropoxide." Bulletin of the Chemical Society of Japan 66, no. 7 (1993): 2121–23. http://dx.doi.org/10.1246/bcsj.66.2121.

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17

SATOH, T., K. ITOH, M. MIURA, and M. NOMURA. "ChemInform Abstract: Desulfonylative Iodination of Naphthalenesulfonyl Chlorides with Zinc Iodide or Potassium Iodide Catalyzed by Dichlorobis(benzonitrile) palladium(II) in the Presence of Lithium Chloride and Titanium(IV) Isopropoxide." ChemInform 24, no. 46 (2010): no. http://dx.doi.org/10.1002/chin.199346144.

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18

Levason, William, Melissa L. Matthews, Bhavesh Patel, Gillian Reid, and Michael Webster. "Titanium(IV) iodide complexes with phosphine and arsine donor ligands and the crystal structures of the iron(II)/(III) redox pair [FeI2{o-C6H4(AsMe2)2}2]0/+." Polyhedron 23, no. 4 (2004): 605–9. http://dx.doi.org/10.1016/j.poly.2003.10.010.

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19

Chi, Yongxiang, Yong-Gui Zhou, and Xumu Zhang. "Highly Enantioselective Reductive Amination of Simple Aryl Ketones Catalyzed by Ir−f-Binaphane in the Presence of Titanium(IV) Isopropoxide and Iodine." Journal of Organic Chemistry 68, no. 10 (2003): 4120–22. http://dx.doi.org/10.1021/jo026856z.

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20

Maeda, Kazuhiko. "Highly Efficient Water Oxidation on Rutile Titanium(IV) Oxide Powder in the Presence of Iodate Ions as Reversible Electron Acceptors." Chemistry Letters 43, no. 8 (2014): 1287–88. http://dx.doi.org/10.1246/cl.140375.

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21

Ohtani, Bunsho, Shugo Takeuchi, Mai Takase, and Mai Takashima. "(Invited) Singularity in Chemistry: Digitally Controlled Kinetics of Titania-Photocatalyzed Oxygen Evolution." ECS Meeting Abstracts MA2018-01, no. 31 (2018): 1879. http://dx.doi.org/10.1149/ma2018-01/31/1879.

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Oxygen evolution (EO) from water in heterogeneous photocatalyses is one of the most significant chemical reactions. It has been believed that number of electrons in this multielectron-transfer (MET) process is four with standard electrode potential (SEP) 1.23 V (vs SHE), but there seems to be no effective method to determine the number for any OE reactions, not limited to photocatalysis, except for electrolytic OE in which its electrode potential might suggest n et. Here we present the light intensity-dependent kinetics of titanium(IV) oxide (titania)-photocatalyzed OE and show, for the first

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22

"BILATERAL INGUINAL HERNIA CLINICAL PROFILE AND MANAGEMENT IN RURAL TERTIARY CARE CENTRE- AN PROSPECTIVE INTERVENTIONAL STUDY." International Journal of Medical Science in Clinical Research and Review 05, no. 05 (2022): 844–53. https://doi.org/10.5281/zenodo.7182150.

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Original Research Paper <strong>BILATERAL INGUINAL HERNIA CLINICAL PROFILE AND MANAGEMENT IN RURAL TERTIARY CARE CENTRE- AN PROSPECTIVE INTERVENTIONAL STUDY</strong> <strong><sup>1</sup></strong><strong>Dr Rajiv Sonarkar, <sup>2</sup>Dr Avinash Babruwan Dhumal, <sup>3</sup>Dr Nitin Wasnik</strong> <em><sup>1</sup></em><em>Associate Professor Department of Surgery NKPSIMS & RC & Lata Mangeshkar Hospital Nagpur</em> <em><sup>2</sup></em><em>Senior Resident, Department of General Surgery, NKPSIMS & RC & Lata Mangeshkar Hospital Nagpur</em> <em><sup>3</sup></em><em>Professor and HO

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23

Kavanagh, Seán R., Shanti Liga, Aron Walsh, David O. Scanlon та Gerasimos Konstantatos. "Mixed-cation vacancy-ordered perovskites (Cs₂Ti₁₋ₓSnₓX₆; X = I, Br); low temperature miscibility, additivity and tunable stability". 25 липня 2023. https://doi.org/10.5281/zenodo.8348189.

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Lead toxicity and poor stability under operating conditions are major drawbacks impeding the widespread commercialization of metal halide perovskite solar cells. Ti(IV) has been considered as an alternative species to replace Pb(II) because it is relatively non-toxic, abundant and its perovskite-like compounds have demonstrated promising performance when applied in solar cells (η > 3%), photocatalysts and non-linear optical applications. Yet, Ti(IV) perovskites show instability in air, hindering their use. On the other hand, Sn(IV) has a similar cationic radius to Ti(IV), adopting the s

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24

Kaushal, Raj, Mandeep Kaur, Jatin Kumar, Pratiksha Gupta, Ravikant, and Jyoti Sharma. "Antidiabetic and antioxidant studies of novel synthesized titanium (IV) complex: Design, synthesis, in‐silico docking and in‐vitro studies." Applied Organometallic Chemistry, March 15, 2024. http://dx.doi.org/10.1002/aoc.7443.

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[{TiCl3}2(C3N3S3H)] (where C3N3S3H is Trithiocyanuric acid) was designed and synthesized by the reaction of TiCl4 and trithiocyanuric acid in 2:1 M ratio under stirring and refluxing condition using THF solvent. The synthesized Titanium (IV) complex was characterized by various spectroscopic techniques like FT‐IR, NMR, MASS, XRD, UV–visible spectrophotometer and elemental analysis (CHNSO). Moreover, in‐silico docking studies of the ligand and its Ti (IV) complex were carried out by AutoDockTools‐1.5.6 to study interactions of the complex under study with the receptor protein. Afterwards, both

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25

Shirai, Toshiharu, Hiroyuki Tsuchiya, Ryu Terauchi, et al. "Iodine-supported implants in prevention and treatment of surgical site infections for compromised hosts: a prospective study." Journal of Orthopaedic Surgery and Research 18, no. 1 (2023). http://dx.doi.org/10.1186/s13018-023-03868-5.

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Abstract Background Surgical site infection (SSI) is a common complication following orthopedic implantation. We developed an iodine coating for titanium implants to reduce implant-related infections and conducted a prospective clinical study to evaluate the efficacy and potential drawbacks of iodine-supported implants. Patients and methods Between July 2008 and July 2017, 653 patients (377 male and 27 female patients; mean age, 48.6) with postoperative infection or a compromised status were treated using iodine-loaded titanium implants. The mean follow-up period was 41.7 months. In 477 patien

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26

Chi, Yongxiang, Yong-Gui Zhou, and Xumu Zhang. "Highly Enantioselective Reductive Amination of Simple Aryl Ketones Catalyzed by Ir—f-Binaphane in the Presence of Titanium(IV) Isopropoxide and Iodine." ChemInform 34, no. 38 (2003). http://dx.doi.org/10.1002/chin.200338023.

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