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Journal articles on the topic 'Titanium suboxide'

Author: Grafiati

Published: 14 March 2023

Last updated: 31 July 2025

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1

Eder, Dominik, and Reinhard Kramer. "Stoichiometry of “titanium suboxide”." Physical Chemistry Chemical Physics 5, no. 6 (2003): 1314–19. http://dx.doi.org/10.1039/b210004e.

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2

Schwarzer-Fischer, Eric, Anne Günther, Sven Roszeitis, and Tassilo Moritz. "Combining Zirconia and Titanium Suboxides by Vat Photopolymerization." Materials 14, no. 9 (2021): 2394. http://dx.doi.org/10.3390/ma14092394.

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A recently developed multi-ceramic additive manufacturing process (multi-CAMP) and an appropriate device offer a multi-material approach by vat photopolymerization (VPP) of multi-functionalized ceramic components. However, this process is limited to ceramic powders with a certain translucency for visible light. Electrically conductive ceramic powders are therefore ruled out because of their light-absorbing behavior and dark color. The goal of the collaborative work described in the article was to develop a material combination for this multi-material approach of the additive vat photopolymeriz

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3

Wang, Yaye, Randall “David” Pierce, Huanhuan Shi, Chenguang Li, and Qingguo Huang. "Electrochemical degradation of perfluoroalkyl acids by titanium suboxide anodes." Environmental Science: Water Research & Technology 6, no. 1 (2020): 144–52. http://dx.doi.org/10.1039/c9ew00759h.

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Effective degradation of eight perfluoroalkyl acids by electrooxidation on titanium suboxide anodes is correlated to their respective molecular structures, offering insight into their degradation behaviors.

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4

Wang, Yaye, Randall “David” Pierce, Huanhuan Shi, Chenguang Li, and Qingguo Huang. "Correction: Electrochemical degradation of perfluoroalkyl acids by titanium suboxide anodes." Environmental Science: Water Research & Technology 8, no. 2 (2022): 443. http://dx.doi.org/10.1039/d1ew90044g.

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5

Liang, Jiabin, Shijie You, Yixing Yuan, and Yuan Yuan. "A tubular electrode assembly reactor for enhanced electrochemical wastewater treatment with a Magnéli-phase titanium suboxide (M-TiSO) anode and in situ utilization." RSC Advances 11, no. 40 (2021): 24976–84. http://dx.doi.org/10.1039/d1ra02236a.

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6

Martinez, Miranda, and Anil R. Chourasia. "Characterization of Ti/SnO2 Interface by X-ray Photoelectron Spectroscopy." Nanomaterials 12, no. 2 (2022): 202. http://dx.doi.org/10.3390/nano12020202.

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The Ti/SnO2 interface has been investigated in situ via the technique of x-ray photoelectron spectroscopy. Thin films (in the range from 0.3 to 1.1 nm) of titanium were deposited on SnO2 substrates via the e-beam technique. The deposition was carried out at two different substrate temperatures, namely room temperature and 200 °C. The photoelectron spectra of tin and titanium in the samples were found to exhibit significant differences upon comparison with the corresponding elemental and the oxide spectra. These changes result from chemical interaction between SnO2 and the titanium overlayer at

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7

Zuo, Xiaodan, Qiaoyuan Deng, Tao Yang, et al. "Effect of titanium suboxide on the formation of anatase and rutile phases during annealing of C-Doped Ti–O thin film deposited by DC magnetron sputtering." Functional Materials Letters 13, no. 05 (2020): 2051021. http://dx.doi.org/10.1142/s1793604720510212.

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C-doped Ti–O films with different titanium suboxide contents are prepared by DC magnetron sputtering deposition at different sputtering powers. The films with different phases are formed after annealing at 873[Formula: see text]K in air. The structure of the films is characterized by X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy. The optical properties and surface roughness of the films are investigated by UV–vis spectroscopy and atomic force microscopy, respectively. Photocatalytic activity of the thin films is studied by degrading the methyl orange solution under

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8

Teng, Jie, Guoshuai Liu, Jiabin Liang, and Shijie You. "Electrochemical oxidation of sulfadiazine with titanium suboxide mesh anode." Electrochimica Acta 331 (January 2020): 135441. http://dx.doi.org/10.1016/j.electacta.2019.135441.

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9

Shmychkova, Olesia, Tatiana Luk'yanenko, Valentina Knysh, and Alexander Velichenko. "Titanium Suboxide-Based Composite Electrocatalysts: Physico-Chemical and Semiconductor Properties." ECS Meeting Abstracts MA2022-02, no. 33 (2022): 2448. http://dx.doi.org/10.1149/ma2022-02332448mtgabs.

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Titanium dioxide is one of the main products of chemical industry. Due to its optical properties, it is most widely used in the paint and varnish industry and the production of pigments. Its sensory, adsorption, optical, electrical, and catalytic properties are widely recognized as the objects of close attention of researchers [1]. Due to its high chemical inertness, lack of toxicity and low cost, titanium dioxide is increasingly used as a photocatalyst, while it has a number of significant disadvantages: low quantum efficiency of the process due to weak separation of the electron-hole pair, l

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10

Gong, Yafeng, Yinghua He, An Li, Yi Wang, Jiehua Liu, and Tao Qi. "Palladium-ytterbium bimetallic electrocatalysts supported on carbon black, titanium suboxide, or poly(diallyldimethylammonium chloride)-functionalized titanium suboxide towards methanol oxidation in alkaline media." Ionics 24, no. 10 (2018): 3085–94. http://dx.doi.org/10.1007/s11581-018-2506-6.

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11

Tamaki, Yukimichi, Yu Kataoka, In-Kee Jang, and Takashi Miyazaki. "Bone Regenerative Potential of Mesenchymal Stem Cells on a Micro- Structured Titanium Processed by Wire-Type Electric Discharge Machining." Open Materials Science Journal 4, no. 1 (2010): 113–16. http://dx.doi.org/10.2174/1874088x010040100113.

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A new strategy with bone tissue engineering by mesenchymal stem cell transplantation on titanium implant has been drawn attention. The surface scaffold properties of titanium surface play an important role in bone regenerative potential of cells. The surface topography and chemistry are postulated to be two major factors increasing the scaffold properties of titanium implants. This study aimed to evaluate the osteogenic gene expression of mesenchymal stem cells on titanium processed by wire-type electric discharge machining. Some amount of roughness and distinctive irregular features was obser

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12

Withers, James, John Laughlin, Yasser Elkadi, Jay DeSilva, and Raouf O. Loutfy. "The Electrolytic Production of Ti from a TiO₂ Feed (The DARPA Sponsored Program)." Key Engineering Materials 436 (May 2010): 61–74. http://dx.doi.org/10.4028/www.scientific.net/kem.436.61.

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DARPA instituted an Initiative in Titanium in 2003 to produce titanium, alternatively to the Kroll process, in a billet form for under $4/lb. This DARPA sponsored program has gone into Phase II consisting of utilizing ore/TiO2 as a feed. The TiO2 is carbothermically reduced to a suboxide-carbide (Ti:O:C) which is used anodically to resupply the titanium content in an electrolysis process that deposits titanium in a powder morphology. The deposited powder is uniquely stripped from the cathodes and harvested in a separate stream that permits continuous electrolytic processing to produce titanium

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13

JEE, Hyeok, Ji-won JANG, and Hye-Won SEO*. "Effect of Nitrogen Plasma Treatment on Titanium Suboxide Thin Films." New Physics: Sae Mulli 69, no. 12 (2019): 1303–7. http://dx.doi.org/10.3938/npsm.69.1303.

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14

Haerudin, Hery, Stephan Bertel, and Reinhard Kramer. "Surface stoichiometry of ‘titanium suboxide’ Part IVolumetric and FTIR study." Journal of the Chemical Society, Faraday Transactions 94, no. 10 (1998): 1481–87. http://dx.doi.org/10.1039/a707714i.

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15

Roy, Anshuman, Sung Heum Park, Sarah Cowan, et al. "Titanium suboxide as an optical spacer in polymer solar cells." Applied Physics Letters 95, no. 1 (2009): 013302. http://dx.doi.org/10.1063/1.3159622.

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16

Kuroda, Yoshiyuki, Hikaru Igarashi, Takaaki Nagai, et al. "Templated Synthesis of Carbon-Free Mesoporous Magnéli-Phase Titanium Suboxide." Electrocatalysis 10, no. 5 (2019): 459–65. http://dx.doi.org/10.1007/s12678-019-00544-3.

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17

VELICHENKO, Alexander, Vasyl KORDAN, Olesia SHMYCHKOVA, Valentina KNYSH, and Pavlo DEMCHENKO. "Structure and semiconductor properties of titanium suboxide-based composite electrocatalysts." Chemistry of Metals and Alloys 14, no. 3/4 (2021): 58–63. http://dx.doi.org/10.30970/cma14.0418.

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18

Zhao, Huiru, Yi Wang, Qinghu Tang, et al. "Pt catalyst supported on titanium suboxide for formic acid electrooxidation reaction." International Journal of Hydrogen Energy 39, no. 18 (2014): 9621–27. http://dx.doi.org/10.1016/j.ijhydene.2014.04.088.

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19

Wang, Yi, Huiru Zhao, Qinghu Tang, Hui Zhang, Chang Ming Li, and Tao Qi. "Electrocatalysis of titanium suboxide-supported Pt–Tb towards formic acid electrooxidation." International Journal of Hydrogen Energy 41, no. 3 (2016): 1568–73. http://dx.doi.org/10.1016/j.ijhydene.2015.11.056.

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20

Wang, Yi, Yong Qin, Guicun Li, Zuolin Cui, and Zhikun Zhang. "One-step synthesis and optical properties of blue titanium suboxide nanoparticles." Journal of Crystal Growth 282, no. 3-4 (2005): 402–6. http://dx.doi.org/10.1016/j.jcrysgro.2005.05.030.

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21

Pereira, Rhyz, Anthony Ruffino, Stefan Masiuk, et al. "In-Operando Raman Study on the Use of 2D and Suboxide Titanium Host Materials for Lithium-Sulfur Batteries." ECS Meeting Abstracts MA2023-01, no. 1 (2023): 388. http://dx.doi.org/10.1149/ma2023-011388mtgabs.

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While Lithium-Sulfur (Li-S) batteries have promised high capacities and low-cost material inputs, their potential has yet to be realized due to inherent issues with sulfur cathodes. In particular the polysulfide shuttle effect and sulfur’s intrinsic insulating properties stand in the way of a commercial battery, the demands of which include high sulfur loading and high cycling stability. Engineering the sulfur cathode, via the use of promising new materials has been an avenue of research pursued in the hopes of mitigating the shuttle effect via polysulfide entrapment and introducing more condu

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22

Sabirovas, Tomas, Simonas Ramanavicius, Arnas Naujokaitis, Gediminas Niaura, and Arunas Jagminas. "Design and Characterization of Nanostructured Titanium Monoxide Films Decorated with Polyaniline Species." Coatings 12, no. 11 (2022): 1615. http://dx.doi.org/10.3390/coatings12111615.

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The fabrication of nanostructured composite materials is an active field of materials chemistry. However, the ensembles of nanostructured titanium monoxide and suboxide species decorated with polyaniline (PANI) species have not been deeply investigated up to now. In this study, such composites were formed on both hydrothermally oxidized and anodized Ti substrates via oxidative polymerization of aniline. In this way, highly porous nanotube-shaped titanium dioxide (TiO2) and nano leaflet-shaped titanium monoxide (TiOx) species films loaded with electrically conductive PANI in an emeraldine salt

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23

Kopycinska-Müller, Malgorzata, Luise Schreiber, Eric Schwarzer-Fischer, et al. "Signal-Decay Based Approach for Visualization of Buried Defects in 3-D Printed Ceramic Components Imaged with Help of Optical Coherence Tomography." Materials 16, no. 10 (2023): 3607. http://dx.doi.org/10.3390/ma16103607.

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We propose the use of Optical Coherence Tomography (OCT) as a tool for the quality control of 3-D-printed ceramics. Test samples with premeditated defects, namely single- and two-component samples of zirconia, titania, and titanium suboxides, were printed by stereolithography-based DLP (Digital Light Processing) processes. The OCT tomograms obtained on the green samples showed the capability of the method to visualize variations in the layered structure of the samples as well as the presence of cracks and inclusions at depths up to 130 µm, as validated by SEM images. The structural information

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24

Knysh, V., O. Shmychkova, T. Luk'yanenko, and A. Velichenko. "Electrochemical synthesis and properties of titanium dioxide–titanium suboxides composite for cathodic protection." Voprosy Khimii i Khimicheskoi Tekhnologii, no. 4 (September 2024): 41–50. http://dx.doi.org/10.32434/0321-4095-2024-155-4-41-50.

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This study reports a combined electrochemical method for preparation of a titanium dioxide–suboxide composite with an electrochemically deposited non-continuous platinum layer on the surface, which can be used for cathodic protection of metal structures. Platinum significantly modifies the properties of TiO2, stabilizes the surface, and prevents the formation of a passive non-conductive layer. The coating has significant advantages compared to Ti/Pt, traditionally used for electrochemical protection, as the platinum content in the composite is significantly reduced. Unlike a continuous preciou

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25

Alipour Moghadam Esfahani, Reza, Holly M. Fruehwald, Nadia O. Laschuk, et al. "A highly durable N-enriched titanium nanotube suboxide fuel cell catalyst support." Applied Catalysis B: Environmental 263 (April 2020): 118272. http://dx.doi.org/10.1016/j.apcatb.2019.118272.

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26

Sui, Yufei, Xi Zhu, Lei Li, et al. "Robust titanium suboxide anodes doped by sintering enhance PFOS degradation in water." Chemosphere 379 (June 2025): 144438. https://doi.org/10.1016/j.chemosphere.2025.144438.

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27

Monai, Matteo, Kellie Jenkinson, Angela E. M. Melcherts, et al. "Restructuring of titanium oxide overlayers over nickel nanoparticles during catalysis." Science 380, no. 6645 (2023): 644–51. http://dx.doi.org/10.1126/science.adf6984.

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Reducible supports can affect the performance of metal catalysts by the formation of suboxide overlayers upon reduction, a process referred to as the strong metal–support interaction (SMSI). A combination of operando electron microscopy and vibrational spectroscopy revealed that thin TiO x overlayers formed on nickel/titanium dioxide catalysts during 400°C reduction were completely removed under carbon dioxide hydrogenation conditions. Conversely, after 600°C reduction, exposure to carbon dioxide hydrogenation reaction conditions led to only partial reexposure of nickel, forming interfacial si

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28

Caloudova, Hana, Jana Blahova, Jan Mares, et al. "The effects of dietary exposure to Magnéli phase titanium suboxide and titanium dioxide on rainbow trout (Oncorhynchus mykiss)." Chemosphere 293 (April 2022): 133689. http://dx.doi.org/10.1016/j.chemosphere.2022.133689.

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29

Tsoureas, Nikolaos, Jennifer C. Green, F. Geoffrey N. Cloke, Horst Puschmann, S. Mark Roe, and Graham Tizzard. "Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system." Chemical Science 9, no. 22 (2018): 5008–14. http://dx.doi.org/10.1039/c8sc01127c.

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Bis(pentalene)dititanium Ti<sub>2</sub>(μ:η<sup>5</sup>,η<sup>5</sup>-Pn<sup>†</sup>)<sub>2</sub> trimerises carbon suboxide (OCCCO) to form [{Ti<sub>2</sub>(μ:η<sup>5</sup>,η<sup>5</sup>-Pn<sup>†</sup>)<sub>2</sub>}{μ-C<sub>9</sub>O<sub>6</sub>}], which contains a 4-pyrone core, via the monoadduct [Ti<sub>2</sub>(μ:η<sup>5</sup>,η<sup>5</sup>-Pn<sup>†</sup>)<sub>2</sub> (η<sup>2</sup>-C<sub>3</sub>O<sub>2</sub>)].

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30

Pei, Shuzhao, Han Shi, Jinna Zhang, Shengli Wang, Nanqi Ren, and Shijie You. "Electrochemical removal of tetrabromobisphenol A by fluorine-doped titanium suboxide electrochemically reactive membrane." Journal of Hazardous Materials 419 (October 2021): 126434. http://dx.doi.org/10.1016/j.jhazmat.2021.126434.

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31

Shi, Huanhuan, Yaye Wang, Chenguang Li, Randall Pierce, Shixiang Gao, and Qingguo Huang. "Degradation of Perfluorooctanesulfonate by Reactive Electrochemical Membrane Composed of Magnéli Phase Titanium Suboxide." Environmental Science & Technology 53, no. 24 (2019): 14528–37. http://dx.doi.org/10.1021/acs.est.9b04148.

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32

Lee, Chang Mook, and Jaewu Choi. "Nonlinear thickness and oxidation-dependent transparency and conductance of sputtered titanium suboxide nanofilms." Optical Materials Express 6, no. 6 (2016): 1837. http://dx.doi.org/10.1364/ome.6.001837.

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33

Lee, Jae Hyun, Shinuk Cho, Anshuman Roy, Hee-Tae Jung, and Alan J. Heeger. "Enhanced diode characteristics of organic solar cells using titanium suboxide electron transport layer." Applied Physics Letters 96, no. 16 (2010): 163303. http://dx.doi.org/10.1063/1.3409116.

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34

Yang, Xuan, Guo Jiuji, Zhu Zhaowu, Hui Zhang, and Tao Qi. "Doping effects on the electro-degradation of phenol on doped titanium suboxide anodes." Chinese Journal of Chemical Engineering 26, no. 4 (2018): 830–37. http://dx.doi.org/10.1016/j.cjche.2017.12.007.

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35

Yuan, Y., J. Zhang, and L. Xing. "Effective electrochemical decolorization of azo dye on titanium suboxide cathode in bioelectrochemical system." International Journal of Environmental Science and Technology 16, no. 12 (2019): 8363–74. http://dx.doi.org/10.1007/s13762-019-02417-0.

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36

Alipour Moghadam Esfahani, Reza, and E. Bradley Easton. "Enhancing the Stability and Performance of Mo-Doped Titanium Suboxide Fuel Cell Catalyst Supports." ECS Meeting Abstracts MA2020-01, no. 38 (2020): 1690. http://dx.doi.org/10.1149/ma2020-01381690mtgabs.

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37

Seo, Jung Hwa, Heejoo Kim, and Shinuk Cho. "Build-up of symmetry breaking using a titanium suboxide in bulk-heterojunction solar cells." Physical Chemistry Chemical Physics 14, no. 12 (2012): 4062. http://dx.doi.org/10.1039/c2cp40299h.

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38

Nagao, Masanori, Sayaka Misu, Jun Hirayama, Ryoichi Otomo, and Yuichi Kamiya. "Magneli-Phase Titanium Suboxide Nanocrystals as Highly Active Catalysts for Selective Acetalization of Furfural." ACS Applied Materials & Interfaces 12, no. 2 (2019): 2539–47. http://dx.doi.org/10.1021/acsami.9b19520.

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39

Kumar, Sanjay, Yoshitsugu Kojima, and Gautam Kumar Dey. "Tailoring the hydrogen absorption desorption's dynamics of Mg MgH2 system by titanium suboxide doping." International Journal of Hydrogen Energy 42, no. 34 (2017): 21841–48. http://dx.doi.org/10.1016/j.ijhydene.2017.07.128.

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40

Wang, Yaye, Yifei Wang, Shuping Dong, and Qingguo Huang. "The impact of anions on electrooxidation of perfluoroalkyl acids by porous Magnéli phase titanium suboxide anodes." PLOS ONE 20, no. 1 (2025): e0317696. https://doi.org/10.1371/journal.pone.0317696.

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Previous studies have indicated the great performance of electrooxidation (EO) to mineralize per- and polyfluoroalkyl substances (PFASs) in water, but different anions presented in wastewater may affect the implementation of EO treatment in field applications. This study invetigated EO treatment of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA), two representative perfluoroalkyl acids (PFAAs), using porous Magnéli phase titanium suboxide anodes in electrolyte solutions with different anions present, including NO3-, SO42-, CO32- and PO43-. The experiment results indicate tha

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41

Böhm, Leonard, Johannes Näther, Martin Underberg, et al. "Pulsed electrodeposition of iridium catalyst nanoparticles on titanium suboxide supports for application in PEM electrolysis." Materials Today: Proceedings 45 (2021): 4254–59. http://dx.doi.org/10.1016/j.matpr.2020.12.507.

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42

Lee, Byoung Hoon, Jessica Coughlin, Geunjin Kim, Guillermo C. Bazan, and Kwanghee Lee. "Efficient solution-processed small-molecule solar cells with titanium suboxide as an electric adhesive layer." Applied Physics Letters 104, no. 21 (2014): 213305. http://dx.doi.org/10.1063/1.4880095.

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43

Geng, Xinwei, Yongfeng Xia, Ming Zhu, Jun Zhao, Dongxu Yao, and Yu-Ping Zeng. "The high performance titanium suboxide ceramics prepared by a facile in-situ hot-pressed sintering." Journal of Alloys and Compounds 1010 (January 2025): 178168. https://doi.org/10.1016/j.jallcom.2024.178168.

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44

Teng, Jie, Shijie You, Fang Ma, Xiaodong Chen, and Nanqi Ren. "Enhanced electrochemical decontamination and water permeation of titanium suboxide reactive electrochemical membrane based on sonoelectrochemistry." Ultrasonics Sonochemistry 69 (December 2020): 105248. http://dx.doi.org/10.1016/j.ultsonch.2020.105248.

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45

Zheng, Zhilin, Wangchang Geng, Yi Wang, Yun Huang, and Tao Qi. "NiCo2O4 nanoflakes supported on titanium suboxide as a highly efficient electrocatalyst towards oxygen evolution reaction." International Journal of Hydrogen Energy 42, no. 1 (2017): 119–24. http://dx.doi.org/10.1016/j.ijhydene.2016.11.187.

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46

Aghashahi, Nooshin, Mohammad Reza Mohammadizadeh, and Parviz Kameli. "Variable range hopping conduction mechanisms in reduced rutile TiO₂." Physica Scripta 97, no. 4 (2022): 045408. http://dx.doi.org/10.1088/1402-4896/ac576b.

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Abstract In this study, obtained samples via reducing Rutile TiO2 by Mg are analyzed to determine the titanium suboxide phases and the dominant structural phase in each sample. By increasing the heat treatment temperature or the amount of reducing agent (Mg), the amount of suboxide phases Ti n O2n−1 (1 ≤ n < 10) with the lower n values increases, and TiO is the main phase in the samples with a low electrical resistivity. The hopping conduction mechanism is also investigated in the temperature range of 11.5–300 K, and the characteristic parameters describing the conduction mechanism are dete

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47

Kim, J. S., H. Jee, Y. H. Yu, and H. W. Seo. "Titanium dioxide and suboxide thin films grown with controlled discharge voltage in reactive direct-current sputtering." Thin Solid Films 672 (February 2019): 14–21. http://dx.doi.org/10.1016/j.tsf.2018.12.045.

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48

Rai, Amritesh, Amithraj Valsaraj, Hema C. P. Movva, et al. "Air Stable Doping and Intrinsic Mobility Enhancement in Monolayer Molybdenum Disulfide by Amorphous Titanium Suboxide Encapsulation." Nano Letters 15, no. 7 (2015): 4329–36. http://dx.doi.org/10.1021/acs.nanolett.5b00314.

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49

Liu, Guoshuai, Hao Zhou, Jie Teng, and Shijie You. "Electrochemical degradation of perfluorooctanoic acid by macro-porous titanium suboxide anode in the presence of sulfate." Chemical Engineering Journal 371 (September 2019): 7–14. http://dx.doi.org/10.1016/j.cej.2019.03.249.

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50

Wang, Yaye, Lei Li, Yifei Wang, Huanhuan Shi, Lu Wang, and Qingguo Huang. "Electrooxidation of perfluorooctanesulfonic acid on porous Magnéli phase titanium suboxide Anodes: Impact of porous structure and composition." Chemical Engineering Journal 431 (March 2022): 133929. http://dx.doi.org/10.1016/j.cej.2021.133929.

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