Academic literature on the topic 'Toluene oxidation'

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Journal articles on the topic "Toluene oxidation"

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Schwantes, Rebecca H., Katherine A. Schilling, Renee C. McVay, et al. "Formation of highly oxygenated low-volatility products from cresol oxidation." Atmospheric Chemistry and Physics 17, no. 5 (2017): 3453–74. http://dx.doi.org/10.5194/acp-17-3453-2017.

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Abstract. Hydroxyl radical (OH) oxidation of toluene produces ring-retaining products: cresol and benzaldehyde, and ring-opening products: bicyclic intermediate compounds and epoxides. Here, first- and later-generation OH oxidation products from cresol and benzaldehyde are identified in laboratory chamber experiments. For benzaldehyde, first-generation ring-retaining products are identified, but later-generation products are not detected. For cresol, low-volatility (saturation mass concentration, C* ∼ 3.5 × 104 − 7.7 × 10−3 µg m−3), first- and later-generation ring-retaining products are ident
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Wang, Xi, and Yingwei Li. "Nanoporous carbons derived from MOFs as metal-free catalysts for selective aerobic oxidations." Journal of Materials Chemistry A 4, no. 14 (2016): 5247–57. http://dx.doi.org/10.1039/c6ta00324a.

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A new kind of metal-free catalyst comprised of highly graphitized N-doped nanoporous carbons from direct carbonization of metal–organic frameworks (MOFs) turns out to be an excellent metal-free catalyst for a series of liquid-phase oxidation reactions including aerobic oxidations of cyclohexane and toluene as well as oxidative coupling of amines.
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Melnyk, S. R., V. V. Reutskyi, and Yu R. Melnyk. "Homogeneous catalytic oxidation of toluene under the ultrasonic action." Catalysis and Petrochemistry, no. 32 (2021): 63–74. http://dx.doi.org/10.15407/kataliz2021.32.063.

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The regularities of toluene catalytic oxidation with molecular oxygen catalyzed by cobalt (II) acetate in a liquid phase under the ultrasonic action have been researched. It was found a close relationship between the temperature and pressure of the oxidation process. The relationship determines the reaction rate, the reaction products composition, and the toluene limiting conversion value. It was found that the ratio between a sonochemical reaction rate and a toluene oxidation reaction rate without ultrasonic action increases with increasing the reaction temperature both at the process initial
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Mo, Shengpeng, Qi Zhang, Yuhai Sun, et al. "Gaseous CO and toluene co-oxidation over monolithic core–shell Co3O4-based hetero-structured catalysts." Journal of Materials Chemistry A 7, no. 27 (2019): 16197–210. http://dx.doi.org/10.1039/c9ta03750k.

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Gaseous CO co-existence could improve catalytic toluene oxidation over Co<sub>3</sub>O<sub>4</sub>-based catalysts, and the reaction mechanism on the CO/toluene oxidation may be mutually independent in the presence of both CO and toluene.
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Hou, Tingting, Zhuyan Gao, Jian Zhang, Nengchao Luo, and Feng Wang. "Simultaneously Enhanced Activity and Selectivity for C(sp3)–H Bond Oxidation Under Visible Light by Nitrogen Doping." Transactions of Tianjin University 27, no. 4 (2021): 331–37. http://dx.doi.org/10.1007/s12209-021-00292-w.

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AbstractSelective oxidation of saturated C(sp3)–H bonds in hydrocarbon to target chemicals under mild conditions remains a significant but challenging task because of the chemical inertness and high dissociation energy of C(sp3)–H bonds. Semiconductor photocatalysis can induce the generation of holes and oxidative radicals, offering an alternative way toward selective oxidation of hydrocarbons under ambient conditions. Herein, we constructed N-doped TiO2 nanotubes (N-TNTs) that exhibited remarkable activity and selectivity for toluene oxidation under visible light, delivering the conversion of
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Lv, Tong, and Rui Wang. "Materials Enabling Methane and Toluene Gas Treatment." Materials 17, no. 2 (2024): 301. http://dx.doi.org/10.3390/ma17020301.

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This paper summarizes the latest research results on materials for the treatment of methane, an important greenhouse gas, and toluene, a volatile organic compound gas, as well as the utilization of these resources over the past two years. These materials include adsorption materials, catalytic oxidation materials, hydrogen-reforming catalytic materials and non-oxidative coupling catalytic materials for methane, and adsorption materials, catalytic oxidation materials, chemical cycle reforming catalytic materials, and degradation catalytic materials for toluene. This paper provides a comprehensi
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Wu, Runrun, Shanshan Pan, Yun Li, and Liming Wang. "Atmospheric Oxidation Mechanism of Toluene." Journal of Physical Chemistry A 118, no. 25 (2014): 4533–47. http://dx.doi.org/10.1021/jp500077f.

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Shuying, Li, and Lawrence P. Wackett. "Trichloroethylene oxidation by toluene dioxygenase." Biochemical and Biophysical Research Communications 185, no. 1 (1992): 443–51. http://dx.doi.org/10.1016/s0006-291x(05)81005-8.

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Chen, Hai Feng. "Study of Toluene Removal by Bipolar Corona Discharge Coupled with Photocatalytic." Advanced Materials Research 955-959 (June 2014): 2357–61. http://dx.doi.org/10.4028/www.scientific.net/amr.955-959.2357.

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Experimental study the degradation efficiency of toluene by bipolar corona discharge coupled with TiO2 photocatalysis. Bipolar corona discharge can degrade the toluene efficiently and rapidly, the final products are mainly carbon dioxide and water. Toluene removal efficiency reduces when the initial concentration of toluene increasing, while toluene removal quantity is increased. Removal of toluene decreases with the gas flow rate increasing, the removal quantity first increases and then decreases. Bipolar corona discharge and a photocatalytic coupling can inprove the degradation efficiency fu
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Robinson, Kevin G., Jan G. Pieters, John Sanseverino, et al. "Microbial oxidation and bioluminescence response for toluene and trichloroethylene." Water Science and Technology 38, no. 7 (1998): 1–8. http://dx.doi.org/10.2166/wst.1998.0270.

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Two Pseudomonas strains, P. putida F1 and P. putida TVA8, were used to evaluate biodegradation of toluene and cometabolism of trichloroethylene (TCE) in batch systems. Both organisms effectively utilized toluene although at different rates. The extent of TCE cometabolism was dependent upon the initial mass of toluene present. A relationship between toluene/TCE degradation and bioluminescence production for P. putida TVA8 was explored. A linear relationship between the total amount of toluene degraded and total bioluminescence was found. The slope of this straight line, however, was found to va
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Dissertations / Theses on the topic "Toluene oxidation"

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Boyle, Sarah Ann. "Oxidation of toluene." Thesis, Queen's University Belfast, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.387977.

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Burton, Helen Amanda. "Liquid-phase oxidation and coupling of arenes by Pd(II)/HPA." Thesis, University of Liverpool, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368630.

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Saiman, Mohd Izham Bin. "Heterogeneous gold and palladium based catalysts for solvent-free oxidation of toluene." Thesis, Cardiff University, 2012. http://orca.cf.ac.uk/35776/.

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Catalyzed oxidation of aromatic hydrocarbons with molecular oxygen has been studied for several decades. For example, toluene can be converted into oxidation products such as benzyl alcohol, benzaldehyde, benzoic acid and benzyl benzoate. At present, the principal industrial production of benzoic acid via the oxidation of toluene involves the use of homogeneous cobalt catalysts in an air pressurized aqueous acetic acid mixture in the presence of Mn ions. However, the use of solvent causes difficulties in the separation of catalysts and products, equipment corrosion, and due to the environmenta
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Sihaib, Zakaria. "Oxidation of toluene traces in gas phase in presence of manganese-oxide based catalysts : relationship structure-activity." Thesis, Lyon, 2018. http://www.theses.fr/2018LYSE1029.

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Dans la première partie de mon travail, j'ai préparé quatre catalyseurs différents à base d'oxydes de manganèse: une perovskite (LaMnO3), par voie sol-gel; un oxide simple (Mn2O3), par méthode rapide et un tamis moléculaire octahedrique (OMS-2) par deux méthodes de préparation différentes, via l'état solide (OMS) et la méthode hydrothermale (OMSh). Les propriétés physicochimiques de ces catalyseurs ont été caractérisées par diffraction des rayons X (DRX), adsorption-désorption de N2, analyses thermogravimétriques (ATD/ATG), analyses chimiques (ICP-OES) et réduction en température programmée (H
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Jean-Gilles, Riffard P. "Acetyl-nitrate nitration of toluene by zeolite catalysts and methods of oxidation of graphite nanofibers." Click here for download, 2007. http://proquest.umi.com/pqdweb?did=1375524701&sid=1&Fmt=2&clientId=3260&RQT=309&VName=PQD.

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Isci, Umit. "Novel N-bridged diiron phthalocyanine complexes : synthesis, characterization and application in oxidation." Phd thesis, Université Claude Bernard - Lyon I, 2010. http://tel.archives-ouvertes.fr/tel-00881309.

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The synthetic approach was developed for the preparation of N-bridged diiron phthalocyanines substituted by different electron-withdrawing alkylsulfonyl substituents. Six novel phthalocyanines bearing small (methylsulfonyl, ethylsulfonyl and hexylsulfonyl) and bulky (t-butylsulfonyl, adamantylsulfonyl and cyclohexylsulfonyl) substituents have been prepared and characterized by electrospray ionization mass spectrometry (ESI-MS), UV-Vis, FT-IR and EPR. Two complexes (with hexylsulfonyl and t-butylsulfonyl substituents) were characterized in addition by Mössbauer techniques, X-ray photoelectron s
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Kesavan, Lokesh. "Solvent-free oxidation of primary carbon-hydrogen bonds in toluene using supported gold palladium alloy nanoparticles." Thesis, Cardiff University, 2011. http://orca.cf.ac.uk/55124/.

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Selective oxidation of primary carbon-hydrogen bonds with oxygen is of crucial importance for the sustainable exploitation of available feedstocks. To date, heterogeneous catalysts have either shown low activity and/or selectivity or have required activated oxygen donors. It is reported here that supported gold-palladium (Au-Pd) nanoparticles on carbon or TiO: are active for the oxidation of the primary carbon-hydrogen bonds in toluene and related molecules, giving high selectivities to benzyl benzoate under mild solvent-free conditions. Differences between the catalytic activity of the Au-Pd
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Behar, Siham. "Synthèse d’oxydes métalliques par voie alginate et leur application dans l’oxydation catalytique des COV." Thesis, Montpellier, Ecole nationale supérieure de chimie, 2013. http://www.theses.fr/2013ENCM0003/document.

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Les composés organiques volatils (COV) contribuent fortement à la pollution atmosphérique. Plusieurs techniques sont possibles pour leur élimination parmi lesquelles, l'oxydation catalytique est une alternative intéressante. Ces dernières années de nombreux efforts ont été entrepris pour la conception de catalyseurs à base d'oxyde de métaux de transition afin de remplacer les métaux nobles, généralement plus actifs pour cette réaction, mais chers. Le principal objectif de cette thèse est le développement de nouveaux catalyseurs à base d'oxyde métallique pour l'élimination du toluène, choisi co
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Ibrahim, Maya. "Optimization of catalysts based on copper and manganese oxides supported on hydroxyapatite for the total oxidation of toluene." Thesis, Lille 1, 2020. http://www.theses.fr/2020LIL1R049.

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L'utilisation de procédés catalytiques dans la réduction de la pollution de l’air est répandue et considérée comme l'une des méthodes les plus prometteuses pour l'élimination des polluants atmosphériques. Les catalyseurs hétérogènes sont des outils efficaces pour limiter les émissions toxiques, tels que les composés organiques volatils (COV), parmi lesquels le toluène a été sélectionné comme molécule modèle à utiliser dans cette étude. L'hydroxyapatite (Ca10(PO4)6(OH)2), qui s'est avérée, grâce à des études antérieures, être extrêmement utile dans le domaine de la gestion de l'environnement, e
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Ibrahim, Maya. "Optimization of catalysts based on copper and manganese oxides supported on hydroxyapatite for the total oxidation of toluene." Electronic Thesis or Diss., Université de Lille (2018-2021), 2020. http://www.theses.fr/2020LILUR049.

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L'utilisation de procédés catalytiques dans la réduction de la pollution de l’air est répandue et considérée comme l'une des méthodes les plus prometteuses pour l'élimination des polluants atmosphériques. Les catalyseurs hétérogènes sont des outils efficaces pour limiter les émissions toxiques, tels que les composés organiques volatils (COV), parmi lesquels le toluène a été sélectionné comme molécule modèle à utiliser dans cette étude. L'hydroxyapatite (Ca10(PO4)6(OH)2), qui s'est avérée, grâce à des études antérieures, être extrêmement utile dans le domaine de la gestion de l'environnement, e
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Books on the topic "Toluene oxidation"

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Bittker, David A. Oxidation mechanisms of toluene and benzene. Lewis Research Center, 1995.

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United States. National Aeronautics and Space Administration., ed. Detailed mechanism of toluene oxidation and comparison with benzene. National Aeronautics and Space Administration, 1988.

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Detailed mechanism of toluene oxidation and comparison with benzene. National Aeronautics and Space Administration, 1988.

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Book chapters on the topic "Toluene oxidation"

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Howard, J. A. "In Toluene Oxidation." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch171.

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Jović, Franjo, and Vesna Tomašić. "Photocatalytic Oxidation of Toluene on Modified TiO2 Nanoparticles." In Nanotechnological Basis for Advanced Sensors. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-94-007-0903-4_44.

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Goumri, A., J.-P. Sawerysyn, J.-F. Pauwels, and P. Devolder. "Tropospheric Oxidation of Toluene: Reactions of Some Intermediate Radicals." In Physico-Chemical Behaviour of Atmospheric Pollutants. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-0567-2_48.

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Oliva, G., T. Zarra, V. Senatore, et al. "Abatement of Atmospheric Pollutants: UV–Ozone Oxidation for the Degradation of Gaseous Toluene." In Advances in Science, Technology & Innovation. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-031-00808-5_81.

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Costantini, M., L. Krumenacker, and Rhone Poulenc. "Substituent Effects on the Oxidation of Toluenes by Molecular Oxygen: The Surprising Reactivity of p. Methoxytoluene." In Substituent Effects in Radical Chemistry. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4758-0_28.

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Martin, Andreas, Venkata Narayana Kalevaru, and Jörg Radnik. "Palladium in Heterogeneous Oxidation Catalysis." In Petrochemical Catalyst Materials, Processes, and Emerging Technologies. IGI Global, 2016. http://dx.doi.org/10.4018/978-1-4666-9975-5.ch003.

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Palladium is one of the precious group metals mainly used in automobile catalytic converters. Besides, it has an importance in various catalytic processes. Although it is well known for hydrogenation reactions, various oxidations can also be catalyzed by palladium. This chapter gives an overview on the most common application of palladium catalysts in heterogeneously catalyzed acetoxylation, i.e. the acetoxylation of ethylene to vinyl acetate. Derived from this knowledge, the authors summarize in detail recently accumulated research results in acetoxylation of toluene to benzyl acetate that can be easily converted to benzyl alcohol. The chapter includes a detailed description of catalyst syntheses, gas phase oxidation runs, comprehensive characterizations and a deep understanding in catalyst-feed interaction. This development can turn away the manufacture of important petrochemicals from chlorine chemistry to oxidations using molecular oxygen.
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Ai, M. "Partial Oxidation of Toluene to Benzaldehyde." In Studies in Surface Science and Catalysis. Elsevier, 1991. http://dx.doi.org/10.1016/s0167-2991(08)61149-0.

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Blount, M. Catherine, and John L. Falconer. "Photocatalytic oxidation of toluene on platinum/titania catalysts." In Studies in Surface Science and Catalysis. Elsevier, 2000. http://dx.doi.org/10.1016/s0167-2991(00)80490-5.

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Giamello, E., E. Garrone, S. Coluccia, G. Spoto, and A. Zecchina. "Oxidation of Propene and Toluene on CoO-MgO Solid Solutions: A Spectroscopic Study." In New Developments in Selective Oxidation. Elsevier, 1990. http://dx.doi.org/10.1016/s0167-2991(08)60216-5.

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Michman, M., and M. Weiss. "Selective Electrooxidation of 4-(Di-n-propylsulfamyl)toluene to 4-(Di-n-propylsulfamyl)benzoic acid." In New Developments in Selective Oxidation. Elsevier, 1990. http://dx.doi.org/10.1016/s0167-2991(08)60199-8.

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Conference papers on the topic "Toluene oxidation"

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Ibrahim, Salisu, Ahmed S. AlShoaibi, and Ashwani K. Gupta. "Effect of Toluene Addition on Hydrogen Sulfide Combustion Under Claus Condition." In ASME 2013 Power Conference. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/power2013-98101.

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Experimental results on the effect of different amounts of toluene addition to H2S gas stream are presented. Three toluene concentrations of 0.5%, 1% and 5% in H2S are presented and compared with the baseline case of 100% H2S/air combustion. Temperature data showed that addition of toluene to H2S gas stream increases the flame temperature because of large heating value associated with toluene. Addition of toluene resulted in the production of H2, which increased with increase in the amounts of toluene addition. Furthermore, increased addition of toluene concentration increased the asymptotic v
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Zhang, Yujuan, Lei Zhang, Jiguang Deng, et al. "Synthesis, Characterization, and Catalytic Properties of MnOx/SBA-16 for Toluene Oxidation." In 2014 International Conference on Materials Science and Energy Engineering (CMSEE 2014). WORLD SCIENTIFIC, 2015. http://dx.doi.org/10.1142/9789814678971_0024.

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Kalvachev, Yu, T. Todorova, A. Liutcanova, R. Velinova, and A. Naydenov. "Oxidation Of Benzene, Toluene And Hexane Over Pt Modified Fly Ash Zeolite X." In The 8th World Congress on New Technologies. Avestia Publishing, 2022. http://dx.doi.org/10.11159/icnfa22.142.

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Tayeb, Raihan, and Yuwen Zhang. "Machine-Learning Approach to Modeling Oxidation of Toluene in a Bubble Column Reactor." In ASME 2022 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2022. http://dx.doi.org/10.1115/imece2022-94564.

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Abstract A feed forward machine-learning (ML) model is applied to study bubble induced turbulence and bubble mass transfer in a bubble column reactor. Using direct numerical simulation data for forced turbulence, bubble deformations and flow velocities are predicted. To predict mass transfer, ML sub-grid scale (SGS) modeling technique is introduced for the concentration of reactants and products undergoing parallel competitive reactions in the oxidation of toluene. The ML model replaces the iterative approach associated with the use of analytical profiles for previous SGS models for correcting
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Shankar, Varun, and Felix Leach. "Effects of oxygenate and aromatic content on engine-out aldehyde emissions from pure, binary, and ternary mixtures of ethanol, toluene, and iso-octane." In 2023 JSAE/SAE Powertrains, Energy and Lubricants International Meeting. Society of Automotive Engineers of Japan, 2023. http://dx.doi.org/10.4271/2023-32-0029.

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&lt;div class="section abstract"&gt;&lt;div class="htmlview paragraph"&gt;Sustainable fuel components, such as ethanol, can be blended into gasoline to help reduce fossil fuel consumption. Aldehydes are both observed emissions and major intermediates in the oxidation of gasoline/ethanol fuel mixtures and are solely attributed to the fuel’s alcohol content.&lt;/div&gt;&lt;div class="htmlview paragraph"&gt;This study aims to evaluate the direct impact of toluene, iso-octane, and ethanol on engine-out formaldehyde and acetalde hyde emissions. A single-cylinder direct injection spark ignition engi
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"Thermal Catalytic Oxidation of Toluene by K-OMS 2 Synthesized via Novel Uncalcined Route." In International Conference on Biological, Civil and Environmental Engineering. International Institute of Chemical, Biological & Environmental Engineering, 2014. http://dx.doi.org/10.15242/iicbe.c0314166.

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Vijayaraghavan, Sanjay, and D. Y. Goswami. "Photocatalytic Oxidation of Toluene in Water From an Algae Pond With High Dissolved Oxygen Content." In ASME Solar 2002: International Solar Energy Conference. ASMEDC, 2002. http://dx.doi.org/10.1115/sed2002-1061.

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Water in well-mixed ponds containing photosynthetic algae has been observed to have an extremely high Dissolved Oxygen (DO) content. Up to four times saturation levels of DO have been recorded. Since DO is known to have an important role in the photocatalytic oxidation of organic contaminants in water, it was hypothesized that a faster rate of contaminant destruction would be observed in water drawn from algae ponds supersaturated with DO. In order to verify this hypothesis a bench scale, batch type photoreactor was constructed. Some baseline tests were performed to investigate the influence o
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Ciajolo, A., R. Barbella, A. Tregrossi, et al. "Oxidation and Combustion of Toluene and Paraffin Mixtures: Anti-Knocking Effects and Toxic Pollutant Formation." In 2001 Internal Combustion Engines. SAE International, 2001. http://dx.doi.org/10.4271/2001-24-0023.

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Van Sau, Nguyen, Ngo Thanh An, and Nguyen Quang Long. "Photocatalytic oxidation of toluene in presence of water vapor using sol-gel synthesized N-doped TiO2." In INTERNATIONAL CONFERENCE ON CHEMICAL ENGINEERING, FOOD AND BIOTECHNOLOGY (ICCFB2017): Proceedings of the 3rd International Conference on Chemical Engineering, Food and Biotechnology. Author(s), 2017. http://dx.doi.org/10.1063/1.5000183.

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Guo, Bin, Xurui Hu, Xin Wang, and Shuo Zhang. "Catalytic performances of Cu-Mn-Ce oxide/SiC monolithic catalyst for oxidation of toluene under microwave irradiation." In 2015 2nd International Conference on Machinery, Materials Engineering, Chemical Engineering and Biotechnology. Atlantis Press, 2016. http://dx.doi.org/10.2991/mmeceb-15.2016.117.

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