Academic literature on the topic 'Trans-cyclooctene'

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Journal articles on the topic "Trans-cyclooctene"

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Wang, Ke, Danzhu Wang, Kaili Ji, et al. "Post-synthesis DNA modifications using a trans-cyclooctene click handle." Organic & Biomolecular Chemistry 13, no. 3 (2015): 909–15. http://dx.doi.org/10.1039/c4ob02031f.

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Efficient enzymatic DNA incorporation of trans-cyclooctene thymidine triphosphate (TCO-TTP) is reported. The general handle of trans-cyclooctene can undergo a rapid bioorthogonal cycloaddition with tetrazine, which is suitable for further DNA labeling work.
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de Geus, Mark A. R., G. J. Mirjam Groenewold, Elmer Maurits, Can Araman, and Sander I. van Kasteren. "Synthetic methodology towards allylic trans-cyclooctene-ethers enables modification of carbohydrates: bioorthogonal manipulation of the lac repressor." Chemical Science 11, no. 37 (2020): 10175–79. http://dx.doi.org/10.1039/d0sc03216f.

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Two novel reagents were developed to direct formation of allylic cis-cyclooctene (CCO) ethers, followed by photochemical isomerization to obtain trans-cyclooctene (TCO) ethers. The method was used to cage a bio-active carbohydrate.
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Kiss, Loránd, Enikő Forró, and Ferenc Fülöp. "Novel stereocontrolled syntheses of tashiromine and epitashiromine." Beilstein Journal of Organic Chemistry 11 (April 30, 2015): 596–603. http://dx.doi.org/10.3762/bjoc.11.66.

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A novel stereocontrolled approach has been developed for the syntheses of tashiromine and epitashiromine alkaloids from cyclooctene β-amino acids. The synthetic concept is based on the azetidinone opening of a bicyclic β-lactam, followed by oxidative ring opening through ring C–C double bond and reductive ring-closure reactions of the cis- or trans-cyclooctene β-amino acids.
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Matikonda, Siddharth S., Douglas L. Orsi, Verena Staudacher, et al. "Bioorthogonal prodrug activation driven by a strain-promoted 1,3-dipolar cycloaddition." Chemical Science 6, no. 2 (2015): 1212–18. http://dx.doi.org/10.1039/c4sc02574a.

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Asare-Okai, P. N., E. Agustin, D. Fabris, and M. Royzen. "Site-specific fluorescence labelling of RNA using bio-orthogonal reaction of trans-cyclooctene and tetrazine." Chem. Commun. 50, no. 58 (2014): 7844–47. http://dx.doi.org/10.1039/c4cc02435d.

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Regeta, Khrystyna, Amit Nagarkar, Andreas F. M. Kilbinger, and Michael Allan. "Transient anions of cis- and trans-cyclooctene studied by electron-impact spectroscopy." Physical Chemistry Chemical Physics 17, no. 6 (2015): 4696–700. http://dx.doi.org/10.1039/c4cp04083j.

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Vázquez, Arcadio, Rastislav Dzijak, Martin Dračínský, Robert Rampmaier, Sebastian J. Siegl, and Milan Vrabel. "Mechanism-Based Fluorogenic trans -Cyclooctene-Tetrazine Cycloaddition." Angewandte Chemie International Edition 56, no. 5 (2016): 1334–37. http://dx.doi.org/10.1002/anie.201610491.

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Zhou, Yimin, Roy C. H. Wong, Gaole Dai, and Dennis K. P. Ng. "A bioorthogonally activatable photosensitiser for site-specific photodynamic therapy." Chemical Communications 56, no. 7 (2020): 1078–81. http://dx.doi.org/10.1039/c9cc07938f.

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Inverse-electron-demand Diels–Alder reaction of a 1,2,4,5-tetrazine-substituted boron dipyrromethene with a biotin-conjugated trans-cyclooctene results in site-specific activation of the photoactivity of the former photosensitiser.
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Johann, Kerstin, Dennis Svatunek, Christine Seidl, et al. "Tetrazine- and trans-cyclooctene-functionalised polypept(o)ides for fast bioorthogonal tetrazine ligation." Polymer Chemistry 11, no. 27 (2020): 4396–407. http://dx.doi.org/10.1039/d0py00375a.

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Tetrazine- and trans-cyclooctene-functionalised polypeptides and polypetoids were prepared by ring-opening polymerisation of N-carboxyanhydrides using the respective functional initiators and shown to react in fast bioorthogonal tetrazine ligations.
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Zhang, Yajie, Hong Chen, Tingting Zhang, et al. "Fast-forming BMSC-encapsulating hydrogels through bioorthogonal reaction for osteogenic differentiation." Biomaterials Science 6, no. 10 (2018): 2578–81. http://dx.doi.org/10.1039/c8bm00689j.

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An injectable in situ fast-forming hydrogel was fabricated to encapsulate BMSCs for osteogenic differentiation through the inverse electron demand Diels–Alder click reaction between trans-cyclooctene-modified PEG and tetrazine-modified hyaluronic acid.
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Book chapters on the topic "Trans-cyclooctene"

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Wang, Ping, Liqian Gao, Haipeng Lei, Su Seong Lee, Shao Q. Yao, and Hongyan Sun. "A Versatile Microarray Immobilization Strategy Based on a Biorthogonal Reaction Between Tetrazine and Trans-Cyclooctene." In Methods in Molecular Biology. Springer New York, 2016. http://dx.doi.org/10.1007/978-1-4939-6584-7_6.

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Galiatsatos, Vassilios. "Polyoctenamer." In Polymer Data Handbook. Oxford University PressNew York, NY, 2009. http://dx.doi.org/10.1093/oso/9780195181012.003.0152.

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Abstract Synthesis Ring-opening polymerization of cyclooctene in the presence of Ziegler Natta catalysts. Cyclooctene is polymerized to polyoctenamer (TOR) in a metathesis reaction that produces both linear and cyclic macromolecules. The cis/trans ratio, which determines the degree of crystallinity of TOR, is controlled by the polymerization conditions.
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Taber, Douglass F. "Alkaloid Synthesis: (–)-α-Kainic Acid (Cohen), Hyacinthacine A2 (Fox), (–)-Agelastatin A (Hamada), (+)-Luciduline (Barbe), (+)-Lunarine (Fan), (–)-Runanine (Herzon)." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0058.

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The intramolecular ene cyclization is still little used in organic synthesis. Theodore Cohen of the University of Pittsburgh trapped (J. Org. Chem. 2011, 76, 7912) the cyclization product from 1 with iodine to give 2, setting the stage for an enantiospecific total synthesis of (–)-α-kainic acid 3. Intramolecular alkene hydroamination has been effected with transition metal catalysts. Joseph M. Fox of the University of Delaware isomerized (Chem. Sci. 2011, 2, 2162) 4 to the trans cyclooctene 5 with high diastereocontrol. Deprotection of the amine led to spontaneous cyclization, again with high
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Conference papers on the topic "Trans-cyclooctene"

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Li, Zibo, Shuanglong Liu, Matt Hassink, et al. "Abstract 370: Tetrazine trans-cyclooctene ligation: An efficient18F labeling method for cysteine containing peptides and proteins." In Proceedings: AACR 103rd Annual Meeting 2012‐‐ Mar 31‐Apr 4, 2012; Chicago, IL. American Association for Cancer Research, 2012. http://dx.doi.org/10.1158/1538-7445.am2012-370.

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