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Relevant bibliographies by topics / Transesterification kinetics

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Academic literature on the topic 'Transesterification kinetics'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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Journal articles on the topic "Transesterification kinetics"

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Beljic Durkovic, Biljana B., Jelena D. Jovanovic, and Borivoj K. Adnadjevic. "Comparative kinetics of the alkali-catalyzed sunflower oil methanolysis with co-solvent under conventional and microwave heating with controlled cooling." Green Processing and Synthesis 7, no. 5 (2018): 441–52. http://dx.doi.org/10.1515/gps-2017-0038.

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Abstract The kinetics of the alkali-catalyzed transesterification of sunflower oil with methanol in the presence of co-solvent (TSMPC) were investigated. The kinetics curves of the alkali-catalyzed TSMPC, in the temperature range of 26°C–55°C, were measured for conventional heating (CH) and microwave heating with controlled cooling. The results showed that for both heating modes, the kinetics of the alkali-catalyzed TSMPC reaction can be described with the kinetic model of the pseudo first-order reaction with respect to the concentration of the triglycerides. The values of apparent reaction ra

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Okewale, A. D., Millionaire Freeborn Nestor Abowei, F. O. Agbogun, and C. N. Owabor. "Simplified Rate Expression for Palm Kernel Oil (PKO) and Methanol Alkali Catalyzed Transesterification Reaction." European Journal of Engineering Research and Science 5, no. 5 (2020): 599–606. http://dx.doi.org/10.24018/ejers.2020.5.5.1901.

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The need for the development of simplified kinetics rates expression (-RA) for Vegetable Oils Alkali catalyzed Transesterification processes to enhance biodiesel production motivated this study. The study, therefore aimed at proposing unified simple rate expression that may be a useful prelude to design various reactor types for Alkali Catalyzed Transesterification of palm kernel oil (PKO) and Methanol reactions. The kinetics rate expression is proposed using simple explicit algebraic technique with the consideration that alkali catalyzed transesterification reaction of palm kernel oil and met

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Dąbkowska, Katarzyna, Maciej Pilarek, and Krzysztof W. Szewczyk. "Substrate Inhibition in Lipase-Catalysed Transesterification of Mandelic acid with Vinyl Acetate." Chemical and Process Engineering 33, no. 4 (2012): 539–46. http://dx.doi.org/10.2478/v10176-012-0044-8.

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Kinetic resolution of (R)- and (S)-mandelic acid by its transesterification with vinyl acetate catalysed by Burholderia cepacia lipase has been studied. The influence of the initial substrate concentration on the kinetics of process has been investigated. A modified ping-pong bi-bi model of enzymatic transesterification of (S)-mandelic acid including substrate inhibition has been developed. The values of kinetic parameters of the model have been estimated. We have shown that the inhibition effect revealed over a certain threshold limit value of the initial concentration of substrate.

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Nasreen, Sadia, Hui Liu, Ivana Lukic, Liaqat Qurashi, and Dejan Skala. "Heterogeneous kinetics of vegetable oil transesterification at high temperature." Chemical Industry and Chemical Engineering Quarterly 22, no. 4 (2016): 419–29. http://dx.doi.org/10.2298/ciceq160107011n.

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Currently, the catalytic efficiency and reusability of the solid base catalysts cannot meet the demand of industrial biodiesel production under low temperature. The purpose of this study is to define the kinetics of heterogeneous transesterification process which might be used for the prediction of the biodiesel synthesis at high temperature and pressure. The focus in this study was paid to recently reported data obtained with different catalysts used for biodiesel synthesis in a batch reactor at high temperatures. It was shown that three kinetic models that include: a) irreversible first orde

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Šánek, Lubomír, Pecha Jiří, Jakub Husár, and Karel Kolomazník. "Mathematical modeling of transesterification process kinetics of triglycerides catalyzed by TMAH." MATEC Web of Conferences 292 (2019): 01027. http://dx.doi.org/10.1051/matecconf/201929201027.

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Biodiesel is a renewable fuel mainly produced by methylation of triglycerides of vegetable oils or animal fats. The production processes nowadays are particularly based on the utilization of inorganic alkali catalysts. However, it has been proved that an organic alkali – tetramethylammonium hydroxide (TMAH) – can also be used as a very efficient transesterification catalyst. The work presented herein is focused on mathematical modeling of the kinetics of TMAH-catalyzed transesterification of triglycerides at different reaction conditions, specifically at varying reaction temperature with the a

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Freedman, Bernard, Royden O. Butterfield, and Everett H. Pryde. "Transesterification kinetics of soybean oil 1." Journal of the American Oil Chemists’ Society 63, no. 10 (1986): 1375–80. http://dx.doi.org/10.1007/bf02679606.

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DOSSIN, T., M. REYNIERS, and G. MARIN. "Kinetics of heterogeneously MgO-catalyzed transesterification." Applied Catalysis B: Environmental 62, no. 1-2 (2006): 35–45. http://dx.doi.org/10.1016/j.apcatb.2005.04.005.

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Noureddini, H., and D. Zhu. "Kinetics of transesterification of soybean oil." Journal of the American Oil Chemists' Society 74, no. 11 (1997): 1457–63. http://dx.doi.org/10.1007/s11746-997-0254-2.

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Stamenkovic, Olivera, Miodrag Lazic, Vlada Veljkovic, and Dejan Skala. "Biodiesel production by enzyme-catalyzed transesterification." Chemical Industry 59, no. 3-4 (2005): 49–59. http://dx.doi.org/10.2298/hemind0504049s.

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The principles and kinetics of biodiesel production from vegetable oils using lipase-catalyzed transesterification are reviewed. The most important operating factors affecting the reaction and the yield of alkyl esters, such as: the type and form of lipase, the type of alcohol, the presence of organic solvents, the content of water in the oil, temperature and the presence of glycerol are discussed. In order to estimate the prospects of lipase-catalyzed transesterification for industrial application, the factors which influence the kinetics of chemically-catalysed transesterification are also c

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Okullo, Aldo A., and Abraham K. Temu. "Modelling the Kinetics of Jatropha Oil Transesterification." Energy and Power Engineering 07, no. 04 (2015): 135–43. http://dx.doi.org/10.4236/epe.2015.74013.

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Dissertations / Theses on the topic "Transesterification kinetics"

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Zhang, Wei. "Sustainable Polycarbonate Nanocomposites: Impact of Production Method and Composition." University of Toledo / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1417954859.

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Nelson, Daniel R. "Transesterification and Recovery of Intracellular Lipids Using a Single Step Reactive Extraction." DigitalCommons@USU, 2010. https://digitalcommons.usu.edu/etd/642.

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A single-step, extractive reaction for extraction of lipids such as biodiesel components, omega-3 fatty acids, or other triglycerides from microbial cells was examined. Conventional methods for lipid extraction use toxic solvents, and require multiple steps and long processing times. When the goal is to produce fatty acid methyl esters or FAMEs, the extracted lipids are subjected to a separate transesterification reaction with simple alcohols in the presence of an acid or base catalyst. A simplified, single-step reactive extraction method can be applied that combines the sequential extraction

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Visser, Hendrik Petrus. "Biodiesel production from a butter factory effluent / H.P. Visser." Thesis, North-West University, 2012. http://hdl.handle.net/10394/9250.

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The production of biodiesel from a butter factory effluent was the main focus of the study. The alkali transesterification reaction was used to produce the biodiesel. The effect of the temperature, alcohol to oil molar ratio, catalyst concentration and the reaction time was investigated to determine the optimal reaction conditions. The reaction temperature varied from 45 °C to 65 °C with a 5 °C increment. The alcohol to oil molar ratio varied from 3:1 to 8:1 with an increment of 1:1. The experiments with varying catalyst load were carried out at 0.8 wt%, 1.0 wt% and 1.2wt%. The reaction time w

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PEITER, Amanda Santana. "Estudo experimental, simulação e modelagem do efeito de agitação e mistura no processo da produção de biodiesel de soja (Glycine max) metílico e etílico." Universidade Federal de Campina Grande, 2017. http://dspace.sti.ufcg.edu.br:8080/jspui/handle/riufcg/1469.

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Submitted by Maria Medeiros (maria.dilva1@ufcg.edu.br) on 2018-08-16T12:27:26Z No. of bitstreams: 1 AMANDA SANTANA PEITER - TESE (PPGEQ) 2017.pdf: 4504888 bytes, checksum: 524c2d78079fab537fef86ee47f99f28 (MD5)<br>Made available in DSpace on 2018-08-16T12:27:26Z (GMT). No. of bitstreams: 1 AMANDA SANTANA PEITER - TESE (PPGEQ) 2017.pdf: 4504888 bytes, checksum: 524c2d78079fab537fef86ee47f99f28 (MD5) Previous issue date: 2017-09-15<br>O consumo de combustíveis derivados do petróleo aumenta a cada ano, o que resulta no aumento da poluição atmosférica. Devido a isso a economia mundial necessit

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Pereira, Maria de Fatima. "Óxido de zinco dopado para produção de biodiesel." Universidade Federal da Paraíba, 2016. http://tede.biblioteca.ufpb.br:8080/handle/tede/9190.

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Submitted by ANA KARLA PEREIRA RODRIGUES (anakarla_@hotmail.com) on 2017-08-01T11:30:58Z No. of bitstreams: 1 arquivototal.pdf: 3636328 bytes, checksum: ddc2927ae330b27ef4de24fdb3975d47 (MD5)<br>Made available in DSpace on 2017-08-01T11:30:58Z (GMT). No. of bitstreams: 1 arquivototal.pdf: 3636328 bytes, checksum: ddc2927ae330b27ef4de24fdb3975d47 (MD5) Previous issue date: 2016-08-22<br>Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES<br>Powders of pure zinc oxide (ZnO) and zinc oxide doped with 5% Al3+ (ZNAL) were obtained by the Pechini method using Zn(NO3)2.6H2O and

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Bennadji, Hayat. "Biodiesel : combustion des esthers éthyliques d'huiles végétales comme additifs au pétrodiesel." Thesis, Vandoeuvre-les-Nancy, INPL, 2010. http://www.theses.fr/2010INPL044N/document.

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Le biodiesel est un biocarburant, composé d'un mélange de mono-esters d'acide gras saturés et insaturés avec une longue chaîne carbonée. Ce travail de thèse présente les données de la littérature sur l'origine du biodiesel et son procédé de fabrication ; sont présentées aussi les performances et les émissions des moteurs diesel fonctionnant au biodiesel et la cinétique d'oxydation du biodiesel. Des efforts ont été faits pour mettre en évidence les principales différences entre les esters méthyliques et éthyliques tout en montrant que d'autres recherches sont encore à développer. Pour ces raiso

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LOREK, SERGE. "Etude de la modification de copolymeres d'olefines par des reactions d'echange et de condensation en milieu fondu." Université Louis Pasteur (Strasbourg) (1971-2008), 1989. http://www.theses.fr/1989STR13053.

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Stabilisation de melanges de polymeres incompatibles (eva et polyamide 11 par des reactions de condensation interpolymeres. Modification chimique de copolymeres d'olefines a fonctions ester laterales par transesterification et aminolyse, en solution et a l'etat fondu, dans un malaxeur discontinu

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Kadi, Mohamed El Amine. "Contribution à l'étude de l'influence des biocarburants et de leurs propriétés sur le fonctionnement des moteurs à combustion interne." Thesis, Ecole nationale supérieure Mines-Télécom Atlantique Bretagne Pays de la Loire, 2020. http://www.theses.fr/2020IMTA0207.

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Le réchauffement climatique, dû essentiellement aux gaz à effet de serre, et l’augmentation de la demande mondiale en énergies fossiles ainsi que leur épuisement rapide, représentent des défis environnementaux et économiques mondiaux,qui ont incité la communauté mondiale à se tourner vers les énergies alternatives et renouvelables. Cette thèse s’inscrit dans cette optique de développement des énergies renouvelables. Le travail de recherche peut se résumer en deux grands axes, où le premier englobe le développement du procédé de production de biodiesel en continu avec différentes matières premi

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Paiva, Eduardo José Mendes de. "Estudo da produção de biodiesel a partir de óleo de babaçu e etanol utilizando a transesterificação alcalina tradicional com agitação mecânica e assistida por ultrassons." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/97/97137/tde-26092012-171745/.

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Neste trabalho foram sintetizados ésteres etílicos do óleo de babaçu através da catálise alcalina em meio homogêneo. O planejamento de experimentos foi utilizado como ferramenta de otimização e também na identificação dos principais fatores que influenciam nas conversões em ésteres etílicos. As reações de transesterificação foram realizadas através de duas metodologias de processo - a tradicional com agitação mecânica e a promovida por ondas ultrassônicas. A espectrometria de ressonância magnética nuclear foi utilizada na quantificação das conversões de todos os experimentos e a análise termog

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Dantas, Hermesson Jales. "Estudo Termoanalítico, Cinético e Reológico de Biodiesel Derivado do Óleo de Algodão." Universidade Federal da Paraíba, 2006. http://tede.biblioteca.ufpb.br:8080/handle/tede/4578.

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Made available in DSpace on 2015-05-07T14:49:36Z (GMT). No. of bitstreams: 0 Previous issue date: 2006-02-23<br>Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES<br>Most of the world energy consumption derives from oil, coal and natural gas. The shortage of the energy sources, especially the energy from fossil fuels, and moreover the impossibility of its renewal has motivated the development of technologies that allow for the usage of renewable energy sources. Biodiesel is biodegradable, renewable and it obeys the cycle of carbon. It is defined as a blend of mono-alky

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Books on the topic "Transesterification kinetics"

1

Zhou, Weiyang. Kinetics and phase behaviour of transesterification of triglycerides. 2006.

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Book chapters on the topic "Transesterification kinetics"

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Canoira, Laureano, Ramón Alcántara, Nikolaos Tsiouvaras, et al. "Biodiesel from Waste Olive Oil: Transesterification Kinetics, Exhaust Emissions and Fuel Consumption." In Highway and Urban Environment. Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-90-481-3043-6_7.

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Lugt, J. P., H. Elfrink, J. Evenaar, and H. J. Doddema. "Kinetics and Validation of Mathematical Models of Enantioselective Transesterification in Organic Solvents." In Microbial Reagents in Organic Synthesis. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2444-7_21.

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Hailegiorgis, Sintayehu Mekuria, Shuhaimi Mahadzir, and Duvvuri Subbarao. "Reaction Kinetics Study for Microwave Energy Pretreated Jatropha Curcas L In-Situ Transesterification." In ICGSCE 2014. Springer Singapore, 2015. http://dx.doi.org/10.1007/978-981-287-505-1_16.

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Marangoni, Alejandro G. "Biodiesel Synthesis via Transesterification of Soybean Oil with Methanol." In Kinetic Analysis of Food Systems. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-51292-1_6.

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Baêsso, Raphaela M., Pâmella A. Oliveira, Gabriel C. Moraes, André V. Alvarenga, and Rodrigo P. B. Costa-Félix. "Ultrasound as a Metrological Tool for Monitoring Transesterification Kinetics." In Advanced Chemical Kinetics. InTech, 2018. http://dx.doi.org/10.5772/intechopen.70501.

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Trejo-Zárraga, Fernando, Felipe de Jesús Hernández-Loyo, Juan Carlos Chavarría-Hernández, and Rogelio Sotelo-Boyás. "Kinetics of Transesterification Processes for Biodiesel Production." In Biofuels - State of Development. InTech, 2018. http://dx.doi.org/10.5772/intechopen.75927.

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Granjo, José F. O., Belmiro P. M. Duarte, and Nuno M. C. Oliveira. "Identifiability of the glyceride transesterification kinetics via alkaline catalysis." In Computer Aided Chemical Engineering. Elsevier, 2017. http://dx.doi.org/10.1016/b978-0-444-63965-3.50050-7.

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Indlekofer, M., M. Hoeschele, M. Rizzi, and M. Reuss. "Kinetics and Engineering Studies of Lipase-Catalyzed Transesterification in Organic Solvent." In Progress in Biotechnology. Elsevier, 1992. http://dx.doi.org/10.1016/b978-0-444-89046-7.50093-x.

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Esonye, Chizoo, Okechukwu Donminic Onukwuli, Akuzuo Uwaoma Ofoefule, Cyril Sunday Ume, and Nkiruka Jacintha Ogbodo. "Sea Almond as a Promising Feedstock for Green Diesel: Statistical Optimization and Power Rate Law Based Chemical Kinetics of Its Consecutive Irreversible Methanolysis." In Prunus. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.93880.

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For successful industrial scale-up and effective cost analysis of transesterification process, presentation of complimentary research data from process optimization using statistical design techniques, chemical kinetics and thermodynamics are essential. Full factorial central composite design (FFCCD) was applied for the statistical optimization of base methanolysis of sea almond (Terminalia catappa) seed oil using response surface methodology (RSM) coupled with desirability function analysis on quadratic model. Reaction time had the most significant impact on the biodiesel yield. Optimum conditions for biodiesel yield of 93.09 wt% validated at 92.58 wt% were 50.03°C, 2.04 wt% catalyst concentration, 58.5 min and 4.66 methanol/oil molar ratio with overall desirability of 1.00. Ascertained fuel properties of the FAME were in compliance with international limits. GC–MS, FTIR and NMR characterizations confirmed unsaturation and good cold-flow qualities of the biodiesel. Based on power rate law, second-order kinetic model out-performed first-order kinetic model. Rate constants of the triglyceride (TG), diglycerides (DG) and monoglycerides (MG) hydrolysis were in the range of 0.00838–0.0409 wt%/min while activation energies were 12.76, 15.83 and 22.43 kcal/mol respectively. TG hydrolysis to DG was the rate determining step. The optimal conditions have minimal error and would serve as a springboard for industrial scale-up of biodiesel production from T. catappa seed oil.

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Janajreh, Isam, and Manar Almazrouei. "Chemical Kinetic and High Fidelity Modeling of Transesterification." In Biofuels - Challenges and opportunities. IntechOpen, 2019. http://dx.doi.org/10.5772/intechopen.80008.

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Conference papers on the topic "Transesterification kinetics"

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Giraldo, Jorge, Jaime Garci´a, Antonio Bula, Marco Sanjuan, and Adria´n A´vila. "Extended Arrhenius Kinetic Model for the Transesterification Reaction of Biodiesel From Palm Oil and Ethanol." In ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-43512.

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Modeling and understanding reaction kinetics is essential for processes and equipment design. This paper presents a kinetic analysis of the transesterification reaction of palm oil extracted in the Colombian north coast with ethanol to produce biodiesel. The analysis is based in actual lab scale production and it considers a set of three reactions in a batch reactor with dynamic behavior. It was found that the kinetics does not adjust to the common Arrhenius equation model, therefore an extended Arrhenius equation model was proposed. This extended model captures temperature effects better than

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Alok K Singh and SANDUN D FERNANDO. "Yield and the Reaction Kinetics of Transesterification of Soybean Oil Using Solid Catalysts." In 2007 Minneapolis, Minnesota, June 17-20, 2007. American Society of Agricultural and Biological Engineers, 2007. http://dx.doi.org/10.13031/2013.23073.

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Yan, Yun-Jun, Yan-Li Fan, Wen-Juan Yang, et al. "Kinetics of transesterification catalyzed by immobilized lipase from Pseudomonas cepacia G63 in microaqueous system." In 2016 International Conference on Advanced Materials and Energy Sustainability (AMES2016). WORLD SCIENTIFIC, 2017. http://dx.doi.org/10.1142/9789813220393_0059.

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Yunus, Robiah, and Azhari Muhammad Syam. "Kinetics of transesterification of jatropha curcas-based triglycerides with an alcohol in the presence of alkaline catalyst." In Renewable Energy Conference (INREC). IEEE, 2010. http://dx.doi.org/10.1109/inrec.2010.5462576.

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Okeke, Eric O. "Modelling the Transient Behaviours of the Kinetics in the Transesterification of Palm Oils Reveals Prospects for Customisation of Esters for Drilling Fluids Formulation." In International Petroleum Technology Conference. International Petroleum Technology Conference, 2013. http://dx.doi.org/10.2523/iptc-16573-ms.

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Han, Wei, Rachaneewan Charoenwat, and Brian H. Dennis. "Numerical Investigation of Biodiesel Production in Capillary Microreactor." In ASME 2011 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. ASMEDC, 2011. http://dx.doi.org/10.1115/detc2011-48765.

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Synthesis of biodiesel through transesterification of vegetable oil with methanol has been experimentally studied in different types of microreactors though detailed numerical simulation has not yet been presented. The capillary microreactor has the potential to greatly intensify mass transfer between immiscible fluids that would result in higher chemical reaction rates. A segmented flow pattern of oil and methanol forms within the reactor. It has been shown experimentally that the two phase flow has dramatic benefits on the intensification of mass transfer and heat transfer. Such reactors hav

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Shahla, Sanaz, Gek Cheng Ngoh, and Rozita Yusoff. "Kinetic Study of the Transesterification of Palm Oil with Ethanol." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_161.

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Yang, Bo. "Kinetic Studies on Transesterification of Biodiesel Prepared in Ionic Liquids." In AASRI International Conference on Industrial Electronics and Applications (IEA 2015). Atlantis Press, 2015. http://dx.doi.org/10.2991/iea-15.2015.177.

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Prasad D.M, R., V. V. Kong, D. Sathiyamoorthy, A. Z. Sulaiman, R. Senthilkumar, and N. W. Yahya. "Sonication assisted transesterification of Jatropha oil for the production of biodiesel: a kinetic study." In 7th Brunei International Conference on Engineering and Technology 2018 (BICET 2018). Institution of Engineering and Technology, 2018. http://dx.doi.org/10.1049/cp.2018.1581.

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