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Relevant bibliographies by topics / Transition metal carbonyls

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Academic literature on the topic 'Transition metal carbonyls'

Author: Grafiati

Published: 4 June 2021

Last updated: 12 February 2022

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Journal articles on the topic "Transition metal carbonyls"

1

Kiremire, Enos Masheija Rwantale. "Unusual underground Capping Carbonyl Clusters of Palladium." International Journal of Chemistry 8, no. 1 (January 21, 2016): 145. http://dx.doi.org/10.5539/ijc.v8n1p145.

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<p>Transition metal carbonyls form unlike boranes a wide range of clusters. High nuclearity carbonyl clusters have a tendency to form capped clusters. Using the method of series explained in this paper, many capped carbonyl clusters have been identified for group 7, 8, 9 and 10 transition metals such as rhenium, osmium, rhodium and palladium. The series have discovered that palladium form exclusively capped carbonyl clusters. Furthermore, it has been discovered that some of the capped clusters have negative nuclear closo function. Such carbonyls have been regarded as capping underground. This paper presents the unique characteristic of high nuclearity capping carbonyl clusters of palladium.</p>

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Schaefer, Henry F., and R. Bruce King. "Unsaturated binuclear homoleptic metal carbonyls M2(CO)x (M = Fe, Co, Ni; x = 5, 6, 7, 8). Are multiple bonds between transition metals possible for these molecules?" Pure and Applied Chemistry 73, no. 7 (July 1, 2001): 1059–73. http://dx.doi.org/10.1351/pac200173071059.

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Modern density functional methods, which yield geometrical parameters and energies close to experimental values for known metal carbonyls such as Fe(CO)5 and Fe2(CO)9, have been extended to unsaturated binary binuclear metal carbonyls. Novel optimized structures have been discovered containing metalmetal multiple bonds, four-electron bridging carbonyl groups, and metal electronic configurations less than 18 electrons.

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Gutmann, Michael, Jörg M. Janello, and Markus S. Dickebohm. "Ultrafast dynamics of transition metal carbonyls." Chemical Physics 239, no. 1-3 (December 1998): 317–29. http://dx.doi.org/10.1016/s0301-0104(98)00348-6.

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Xie, Y., and H. F. Schaefer. "The Characterization of Metal–Metal Bonds in Unsaturated Binuclear Homoleptic Transition Metal Carbonyls. The Compliance Matrix." Zeitschrift für Physikalische Chemie 217, no. 3 (March 1, 2003): 189–204. http://dx.doi.org/10.1524/zpch.217.3.189.20468.

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AbstractThe compliance matrix (inverse force constant matrix) has been used to estimate metal–metal bond character for the homoleptic transition metal carbonyls Fe2(CO)n and Co2(CO)n. The results are often in agreement with other methods, but the compliance matrix provides a unique measure while other methods may be ambiguous. The more unsaturated compounds with fewer carbonyls have stronger metal–metal linkages, indicating a general, if not infallible, correlation between the diagonal compliance matrix element and the formal bond order, given by the 18-electron rule. It is found that the apparent metal–metal bond strength, as judged by the compliance matrix, is significantly enhanced by the bridging (as opposed to terminal) carbonyls. Thus one must only make precise comparisons between systems with the same numbers of bridging carbonyls.

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Ervin, Kent M. "Metal-ligand interactions: Gas-phase transition metal cluster carbonyls." International Reviews in Physical Chemistry 20, no. 2 (April 2001): 127–64. http://dx.doi.org/10.1080/01442350010028532.

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Reiter, Dominik, Richard Holzner, Amelie Porzelt, Philipp Frisch, and Shigeyoshi Inoue. "Silylated silicon–carbonyl complexes as mimics of ubiquitous transition-metal carbonyls." Nature Chemistry 12, no. 12 (October 19, 2020): 1131–35. http://dx.doi.org/10.1038/s41557-020-00555-4.

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WATANABE, Yoshihisa, Take-aki MITSUDO, Teruyuki KONDO, Kenji WADA, and Motohiro AKAZOME. "Novel Reactions Catalyzed by Transition Metal Carbonyls." Journal of The Japan Petroleum Institute 37, no. 5 (1994): 471–79. http://dx.doi.org/10.1627/jpi1958.37.471.

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Assefa, M. K., J. L. Devera, A. D. Brathwaite, J. D. Mosley, and M. A. Duncan. "Vibrational scaling factors for transition metal carbonyls." Chemical Physics Letters 640 (November 2015): 175–79. http://dx.doi.org/10.1016/j.cplett.2015.10.031.

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Koridze, A. A. "Acetylide derivatives of transition metal cluster carbonyls." Russian Chemical Bulletin 49, no. 7 (July 2000): 1135–63. http://dx.doi.org/10.1007/bf02495755.

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Kiremire, Enos Masheija Rwantale. "The Main Group Elements, Fragments, Compounds and Clusters Obey the 4n Rule and Form 4n Series: They are Close relatives to Transition Metal Counterparts via the 14n Linkage." International Journal of Chemistry 8, no. 2 (April 27, 2016): 94. http://dx.doi.org/10.5539/ijc.v8n2p94.

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<p>The paper presents numbers which were derived from 4n-based series in a matrix table. The numbers agree precisely with the total number of valence electrons surrounding the respective skeletal elements. The series approach focuses mainly on the number of skeletal elements and their respective number of valence electron content regardless of the origin of the electrons and the type of skeletal elements. For instance, any 6 skeletal elements of transition metal carbonyls surrounded by 86 valence electrons coded as (6,86), series S = 14n+2 normally adopt an octahedral geometry whereas (6,26) series S = 4n+2 for main group elements also tend to adopt an octahedral shape. The transition metal carbonyl cluster series were extensively covered in our previous articles. This paper demonstrates that the main group fragments, clusters and molecules which we normally explain by terms such as valency, valence electrons and octet rule also obey the 4n-based series. The fragments, molecules and clusters of the main group elements correspond well to those of respective transition metal clusters especially the carbonyls if the masking electrons are removed from them. Hence, the series approach is a qualitative method that acts as a unifier of some transition metal clusters with some main group elements clusters.</p>

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Dissertations / Theses on the topic "Transition metal carbonyls"

1

Orrin, Rachel H. "Photo-oxidation of transition metal carbonyls." Thesis, University of Reading, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317044.

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Young, George Hansen. "Reactions of transition-metal propargyl complexes with polynuclear metal carbonyls /." The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487672631602474.

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Johnson, Frank P. A. "Intermediates and excited states of transition metal carbonyls." Thesis, University of Newcastle Upon Tyne, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335483.

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Gang, Jun. "Infrared spectroscopy of jet-cooled transition metal carbonyls." Thesis, University of Leicester, 1995. http://hdl.handle.net/2381/33684.

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Rotationally resolved infrared absorption spectra of jet-cooled transition metal carbonyls in the region of CO stretching vibrations near 2000 cm-1 are reported in this thesis. The molecules span spherical, symmetric and asymmetric tops. Theories and their deductions related to the explanation of the various aspects of spectra are simply elucidated. The measurement of the band centres of spectra of M(CO)6 (M=Cr, Mo, W) has an improvement of 103 in precision. The rotational constants determined are very close to those derived from electron diffraction results. Analysis of the spectra of MeMn(CO)5 (Me=CH3, CD3) of two strongly allowed bands yielded values for the band centres and rotational constants for parallel bands of both isotopic species, and for the perpendicular band of CH3Mn(CO)5; the latter also provided an estimate of the Coriolis constant for this vibration. The spectra were consistent with essentially free rotation of the methyl group. The rotational constants were in close agreement with those derived from electron diffraction data; however, the B rotation constants provide a revised estimate for the axial Mn-CO bond length. The parallel band of C5H5Mn(CO)3 is analysed and the band centre and B rotational constant of excited state are estimated. Three bands of C4H6Fe(C0)3, one of which exhibits essentially a-type transitions, the second b-type transitions, and the third a- and c-type transitions, are analysed. The results confirm the effective Cs symmetry of the Fe(C0)3 unit and yield values for the band centres and rotational constants of the upper levels of two of the three bands. The relative intensities of the a and c components of the hybrid band provide an estimate of 1:4 for the ratio of the square of the transition moments of this vibration. Spectra of C5H5Co(CO)2 are also reported, and band centres of the two bands of CO stretching vibrations are estimated.

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Westwell, Jeremy R. "Fast infrared spectroscopy of excited states." Thesis, University of Nottingham, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262165.

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Larcombe, Helen Eileen. "An investigation into the bulk nature of some transition metal carbonyls." Thesis, University of Southampton, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241180.

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Boyd, Edwin Pressley. "Hydroboration Studies on Transition Metal Carbonyl Anions and Chemical Vapor Deposition of Metallic Thin Films Using Homonuclear and Heteronuclear Metal Carbonyls /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487929745332985.

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何毅雯 and Ngai-man Emmie Ho. "The chemistry of ruthenium carbonyl clusters containing nitrene and nitrido ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B3124029X.

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Ho, Ngai-man Emmie. "The chemistry of ruthenium carbonyl clusters containing nitrene and nitrido ligands /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21982351.

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Abbott, Laurence Colin. "Time-resolved and steady-state laser spectroscopic studies of binuclear transition metal carbonyls in solution." Thesis, University of York, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265559.

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Books on the topic "Transition metal carbonyls"

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Scott, McIndoe J., ed. Transition metal carbonyl cluster chemistry. Amsterdam, The Netherlands: Gordon and Breach Science Publishers, 2000.

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Sellow, Khaled Ahmed F. Studies of the reactions of metal carbonyl complexes with phosphorus and nitrogen-containing ligands. Dublin: University College Dublin, 1998.

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Raithby, Paul R. Transition Metal Cluster Carbonyls. Ellis Horwood, 1993.

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McIndoe, J. Scott, and Paul J. Dyson. Transition Metal Carbonyl Cluster Chemistry (Advanced Chemistry Texts, Volume 2). CRC, 2000.

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Dyson, Paul J., and J. Scott McIndoe. Transition Metal Carbonyl Cluster Chemistry. CRC Press, 2018. http://dx.doi.org/10.1201/9781315273815.

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Weiss, Keith D. The activation of carbon monoxide and carbon dioxide by transition metal carbonyl complexes. 1986.

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Book chapters on the topic "Transition metal carbonyls"

1

Pruchnik, Florian P., and Stan A. Duraj. "Metal Carbonyls." In Organometallic Chemistry of the Transition Elements, 23–127. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2076-8_2.

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Ley, Steven V., and Caroline M. R. Low. "Transition Metal Carbonyls and Ultrasound." In Reactivity and Structure Concepts in Organic Chemistry, 105–19. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74672-7_14.

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Taylor, M. J. "Reactions of Metal Carbonyls and Other Transition metal compounds." In Inorganic Reactions and Methods, 152–53. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch138.

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Ridge, Douglas P. "Reactions of Transition Metal Ions with Cycloalkanes and Metal Carbonyls." In Structure/Reactivity and Thermochemistry of Ions, 165–75. Dordrecht: Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3787-1_7.

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Werner, Helmut. "Transition Metal Carbonyls: From Small Molecules to Giant Clusters." In Profiles in Inorganic Chemistry, 1–43. New York, NY: Springer New York, 2008. http://dx.doi.org/10.1007/978-0-387-09848-7_4.

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Simpson, Charles Q., and Michael B. Hall. "Theoretical Calculations on the Interaction of Bridging Carbonyls with Transition Metal Dimers." In Metal-Metal Bonds and Clusters in Chemistry and Catalysis, 327. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2492-6_36.

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Rösch, N., H. Jörg, and B. I. Dunlap. "Applications of the LCGTO-Xα Method to Transition Metal Carbonyls." In Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry, 179–87. Dordrecht: Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4656-9_13.

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8

Grevels, F. W. "Photochemistry of Organo-metal Carbonyls: Stereochemical and Catalytic Aspects." In Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory, 141–71. Dordrecht: Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2698-4_7.

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Stufkens, D. J., T. Graaf, G. J. Stor, and A. Oskam. "Photochemistry of Metal-Metal Bonded Carbonyls and its Relationship to Electron Transfer Chain Catalysis." In Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory, 217–32. Dordrecht: Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2698-4_9.

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Eberhardt, W., C. T. Chen, W. K. Ford, E. W. Plummer, and H. R. Moser. "Fragmentation of CO and Transition Metal Carbonyls Following Soft X-Ray Excitation." In Springer Series in Surface Sciences, 50–67. Berlin, Heidelberg: Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-642-82547-7_7.

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Conference papers on the topic "Transition metal carbonyls"

1

Feng, Bo, Cheng-Yang Wang, and Bin Zhu. "Novel AC-M-SCC Anode Materials for Solid Oxide Fuel Cells Using Methanol at Intermediate or Low Temperature." In ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2005. http://dx.doi.org/10.1115/fuelcell2005-74140.

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In this paper, novel anode materials for solid oxide fuel cells which can directly operate liquid fuels at intermediate or low temperature were investigated. These materials were based on the activated carbons supported transition metal catalysts (AC-M) and the solid carbonate-ceria composite (SCC) materials, which were prepared via the sol-gel route. The SCCs possess both oxide-ion and proton conductivity, being used as multi-ion conductors. Activated carbons supported transition metals were used to improve the characters of anode materials and especially to enhance the anode catalyst function to liquid fuels, e.g., methanol. The internal reforming of liquid fuels was proved. There is no external reforming system needed. We used also the chemical methods to improve the commercial activated carbons. The microstructure, conductivity and electrochemical properties of anode materials were investigated as functions of the activated carbon pre-treating condition. Using these novel materials, the power intensity of 0.2 W/cm2 was achieved for fuel cells directly operating the methanol at 600 °C.

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Mulenko, Sergay A. "Laser-induced heterogeneous processes at deposition of elements from vapors of transition-metal carbonyles." In Laser Processing of Advanced Materials and Laser Microtechnologies, edited by Friedrich H. Dausinger, Vitali I. Konov, Vladimir Y. Baranov, and Vladislav Y. Panchenko. SPIE, 2003. http://dx.doi.org/10.1117/12.515614.

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Sablier, M., L. Capron, H. Mestagh, C. Rolando, N. Billy, G. Gouédard, and J. Vigué. "Gas phase reaction of atomic hydrogen, atomic nitrogen radical with transition metal carbonyl cations." In The 50th international meeting of physical chemistry: Molecules and grains in space. AIP, 1994. http://dx.doi.org/10.1063/1.46576.

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Dong, Fang, Enguang Zhang, Qiaowei Tang, Qinping Guo, and Jinli Qiao. "Doped Mesoporous Carbons Derived from Transition Metal Iron and Chitosan as Efficient Non-Precious Cathode Catalysts for Oxygen Reduction Reaction in Alkaline Electrolyte." In 2017 6th International Conference on Energy, Environment and Sustainable Development (ICEESD 2017). Paris, France: Atlantis Press, 2017. http://dx.doi.org/10.2991/iceesd-17.2017.169.

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