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Relevant bibliographies by topics / Transition metal chelates

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Academic literature on the topic 'Transition metal chelates'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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Journal articles on the topic "Transition metal chelates"

1

Jaeger, David A., Robin Jose, Alvaro Mendoza, and Robert P. Apkarian. "Surfactant transition metal chelates." Colloids and Surfaces A: Physicochemical and Engineering Aspects 302, no. 1-3 (2007): 186–96. http://dx.doi.org/10.1016/j.colsurfa.2007.02.021.

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Sasikala T, Greeshma KP, Gnana Priya K, Muthulingam S, and Nandhakumar C. "Synthesis, characterization and chelating properties of tannin-8-hydroxy quinoline - formaldehyde polymer." GSC Advanced Research and Reviews 5, no. 2 (2020): 019–23. http://dx.doi.org/10.30574/gscarr.2020.5.2.0083.

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Tannin obtained from Eucalyptus plant, condensed with formaldehyde and then 8-hydroxy quinoline. The so called obtained polymer designated as TFQ was used for metal chelate formation. Thus Transition metal chelates of TFQ with Zn+2, Co+2, Cu+2, Ni+2 and Mn+2 metal ions were prepared. The ligand TFQ and its all five metal chelates were characterized by nitrogen content, IR, UV-Visible spectral studies, magnetic moments and thermogravimetry. The antimicrobial activity of all the samples has also been monitored against common microbes.

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Sasikala, T., KP Greeshma, Priya K. Gnana, S. Muthulingam, and C. Nandhakumar. "Synthesis, characterization and chelating properties of tannin-8-hydroxy quinoline - formaldehyde polymer." GSC Advanced Research and Reviews 5, no. 2 (2020): 019–23. https://doi.org/10.5281/zenodo.4319550.

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Tannin obtained from Eucalyptus plant, condensed with formaldehyde and then 8-hydroxy quinoline. The so called obtained polymer designated as TFQ was used for metal chelate formation. Thus Transition metal chelates of TFQ with Zn<sup>+2</sup>, Co<sup>+2</sup>, Cu<sup>+2</sup>, Ni<sup>+2</sup> and Mn<sup>+2</sup> metal ions were prepared. The ligand TFQ and its all five metal chelates were characterized by nitrogen content, IR, UV-Visible spectral studies, magnetic moments and thermogravimetry.   The antimicrobial activity of all the samples has also been monitored against c

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Varshney, Anshita, and A. P. Mishra. "Novel Ni(II) and Zn(II) Schiff base metal chelates as promising DNA binder, Antioxidant and Antifungal agents." Mediterranean Journal of Chemistry 14, no. 2 (2024): 94. http://dx.doi.org/10.13171/mjc02405211777varshney.

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<p>Schiff base ligands and their 3d-metal chelates have gained significant attention due to various applications in various scientific platforms. Due to their chelating propensity, they possess a wide range of biological, biochemical, catalytic, clinical, dying, and pharmacological properties.<strong> </strong>Here, in present studies,<strong> </strong>two novel Ni(II) and Zn(II) transition metal chelates have been synthesized by condensing their metal salts with Schiff base ligand 4-chloro-2-(2,5-dimethoxybenzylideneamino)-5-nitrophenol<strong> </strong&

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5

T., M. Bhagat, and P. Rathod S. "Synthesis Of Transition Metal Complexes With Newly Synthsised Chelates And Its Effect On Seed Germination." International Journal of Advance and Applied Research S6, no. 18 (2025): 83–86. https://doi.org/10.5281/zenodo.15254800.

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<em>Newly synthesized heterocyclic compound act as a chelating agent. It is also proved, the metal chelates have drug activity and some metal chelates acts as plant growth regulator. Hence we have synthesizes </em><em>2-(2’-hydroxy-3’-methoxy phenyl)-4- nitro-6-chloro benzothiazolyl hydrazones </em><em>and check the chelating tendency of newly synthesized heterocyclic compound. </em><em>2-(2’-hydroxy-3’-methoxy phenyl)-4- nitro-6-chloro benzothiazolyl hydrazones </em><em>were treated with metal ions like Ni++, Cu++, Zn++ at different PH and different laboratory conditio

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Smentek, Lidia, and B. Andes Hess. "Conformational Analysis of Eu(III)-(Ethylenedinitrilo)tetrakis(methylphosphonates) (EDTMP)." Collection of Czechoslovak Chemical Communications 73, no. 11 (2008): 1437–56. http://dx.doi.org/10.1135/cccc20081437.

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The optimal geometries obtained from DFT calculations are presented for Eu(III)-EDTMP (the parent system) and cages associated with the water molecules and carbonate and hydroxide ions. The numerical results demonstrate the existence of two conformers of each cage, which might explain the observation of two spectroscopic lines previously assigned to the electric dipole transition 7F0 ↔ 5D0 of Eu3+. It is also found that the water molecules are associated with the chelate via hydrogen bonds with the oxygens of the phoshonate arms, while the carbonate and hydroxide ions are chelated with the lan

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7

B., K. DWIVEDI, and N. SRIVASTAVA I. "Transition Metal Schiff Base Chelates as Ligands towards Tin(ll) Halides and -lsothiocyanate." Journal of Indian Chemical Society Vol. 62, Mar 1985 (1985): 246–49. https://doi.org/10.5281/zenodo.6302589.

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Department of Chemistry, B. S, N.<em> </em>V. Degree College, Lucknow Department of Chemistry, Lucknow University, Lucknow-228007 <em>Manuscript received 21 March 1984, reputed 16 October 1984, </em><em>accepted 15 'ebruary 1985</em> Transition Metal Schiff Base Chelates as Ligands towards Tin(ll) Halides and -lsothiocyanate.

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Patel, S. N., and Y. S. Patel. "Preparation, Characterization and Antifungal Activity of Metal Chelates of 5-[2-{2-(4-fluorophenyl)-5-nitro-1H-imidazol-1-yl}ethoxy]methyl-8-hydroxyquinoline." Research Journal of Chemistry and Environment 27, no. 4 (2023): 26–32. http://dx.doi.org/10.25303/2704rjce026032.

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5-chloromethyl-8-hydroxyquinoline (CMQ) hydro-chloride is reacted with flunidazole to yield a novel ligand namely 5-(flunidazoylmethyl)-8-hydro-xyquinoline (FHQ). The transition metal chelates of FHQ ligand were prepared using Cu2+, Co2+, Ni2+, Mn2+, Zn2+ and Cd2+ metal salts. The ligand FHQ and its all metal chelates were duly characterized for elemental content, spectral features, M: L (metal: ligand) ratio and magnetic moment. Antifungal activity of all the samples was tested against plant pathogens.

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B., ANANDAM, and LINGAIAH P. "A Study on Metal Chelates of Substituted Hydroxyphenylpyrazoles with some Bivalent Transition Metal Ions." Journal of Indian Chemical Society Vol. 70, Jan 1993 (1993): 8–10. https://doi.org/10.5281/zenodo.5902578.

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Department of Chemistry, C. K. M. Arts and Science College, Warangal-506 009 Department of Chemistry, Kakaliya University, Warangal-506 009 <em>Manuscript received 2 September 1991, revised 1 September 1992, accepted 17 September 1992</em> The stability constants of metal chelate & of substituted hydroxyphenylpyrazoles, viz. 3(5)-(2· hydroxyphenyl)· -(3)-phenylpyrazole (OHPPPz), 3(5)<em>·</em>(2·hydroxyphenl)-5(3)-(4·chlororphenl) pyrazole (OHPCPPz) and 3·(2-bydroxyphenyl)-1 ,5-diphenylpyrazole (OHPDPPz) with Co<sup>II</sup> Ni<sup>II</sup>. C

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Hamil, Abdusalam, Marei El-ajaily, Lila Basher, Asma Ramli, Miloud Miloud, and S. A. Saad. "Mixed ligand chelates using Schiff base and 2-aminobenzoic acid as ligands." Libyan Journal of Medical Research 18, no. 1 (2024): 1–17. http://dx.doi.org/10.54361/10.26719/llmr18-1.01.

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The ligands under investigation were used to form five mixed ligand chelates with some transition metal ions. The ligands and their chelates were offered to several analytical and spectroscopic tools. Based on the obtained results; an octahedral structure was proposed for all the chelates. Also, the antibacterial activity was tested on two types of bacteria; Staphylococcus aureus and E.coli species.

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Dissertations / Theses on the topic "Transition metal chelates"

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Eapen, M. J. "Solvent extraction of some transition metal chelates." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 1986. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/3279.

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Monzittu, Francesco Matteo. "Main group and transition metal-based chelates for PET applications." Thesis, University of Southampton, 2018. https://eprints.soton.ac.uk/422231/.

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[AlCl3(BnMe2-tacn)] was radiolabelled by Cl/18F halide exchange reactions in the presence of 2.99 mol. equiv. of KF at pH 4 CH3CO2Na buffer solution with addition of 18F-target water, to give [Al18F19F2(BnMe2-tacn)] with RCY up to 24 %. The radio-product was purified through a simple SPE purification protocol in 99 % RCP and it shows excellent stability in 50 % EtOH/PBS solution for >3h. [GaF3(BnMe2-tacn)] can be successfully 18F-radiolabelled using a precursor concentration as low as 27 nM through 18F/19F isotopic exchange reactions, using 18F-target water in a 75 % MeCN/H2O solution, in good

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Duncan, Nathan C. Garner Charles M. "Tridentate nitrogen ligands derived from 2,6-bis-hydrazinopyridine (BHP) preparation and study of the 2,6-bis-hydrasonopyridines, 2, 6-bis-pyrazolylpytidines, and 2,6-bis-indazolylpyridines /." Waco, Tex. : Baylor University, 2009. http://hdl.handle.net/2104/5320.

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James, Daniel Stuart. "Novel nitrogen-sulfur chelate ligands for asymmetric catalysis." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287727.

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Bowley, P. A. "Some chelate ring opening and related reactions of transition metal complexes." Thesis, University of Leeds, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234695.

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Woodman, Paul Richard. "Chiral complexes of the early transition metals with biaryl chelate ligands." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310016.

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Werner, Irina [Verfasser]. "Late-transition-metal cyclopentadienyl chelate complexes with silylphosphane or secondary phosphane tethers / Irina Werner." Hannover : Technische Informationsbibliothek und Universitätsbibliothek Hannover (TIB), 2015. http://d-nb.info/1077019580/34.

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Lledos, Marina. "New bifunctional chelators for main group and transition metals : from molecules to materials and their biomedical applications." Thesis, University of Bath, 2018. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.767579.

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This work describes investigations into the synthesis of new potential multimodal agents for medical imaging of cancer cells. For this purpose, two approaches were used: (i) based on novel fluorescent nanohybrids based on iron oxide nanoparticles, and (ii) based on a symmetric tripodal core that can be functionalised, giving rise to bifunctional chelating molecular and nanocomposite agents. Each Chapter of this thesis describes the synthesis andcharacterisation of the different components of the desired probes. The cellular viability of the as-prepared imaging agents was evaluated using differ

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9

Jäger, Norbert. "Molekülmechanische und quantenchemische Berechnung der räumlichen und elektronischen Struktur von Vanadium(IV)- und Oxo-Rhenium(V)-Chelaten dreizähnig diacider Liganden." Phd thesis, Universität Potsdam, 1998. http://opus.kobv.de/ubp/volltexte/2005/154/.

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In dieser Arbeit wurden die Molekülstrukturen und die elektronischen Eigenschaften von Vanadium(IV)- und Oxo-Rhenium(V)-Chelaten mit einem kombinierten molekülmechanisch-quantenchemischen Ansatz untersucht, um sterische und elektronische Effekte der Komplexierung mit einem theoretischen Modell zu quantifizieren. Es konnte gezeigt werden, daß auf diese Weise detaillierte Aussagen zu den Bindungsverhältnissen der Metallchelate getroffen werden können. Die Berechnung der Molekülstrukturen gelingt mit exzellenter Übereinstimmung mit den Kristallstrukturen der Komplexe. Die molekülmechanischen Bere

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Bagnol, Thibault. "Etude Fondamentale et Application en Catalyse de Métaux de Transition Précoces Complexés à de Nouveaux Ligands Hémilabiles contenant des Hétéroéléments." Thesis, Bordeaux, 2020. http://www.theses.fr/2020BORD0014.

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De récents travaux ont mis en évidence l’augmentation de l’activité catalytique des catalyseurs contenant un centre métallique électrophile induit grâce aux ligands. L’insertion d’un atome de bore dans ces complexes métalliques représente une approche pertinente pour augmenter la nature électrophile de ces complexes grâce aux propriétés intrinsèques de l’atome de bore. Cependant, peu d’exemples de tels complexes métalliques sont décrits dans la littérature. Au cours de cette thèse, nous nous sommes intéressés à de nouveaux ligands hémilabiles pour la catalyse en hydrofonctionnalisation via l’e

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Books on the topic "Transition metal chelates"

1

Rigby, Keith. Single-crystal EPR studies of some low symmetry transition metal chelate complexes. Univeristy of Manchester, 1993.

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2

Highland, Ronald G. Spectroscopic properties of mixed-ligand chelates of closed-shell transition metal complexes. 1985.

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Book chapters on the topic "Transition metal chelates"

1

Glasbeek, Max. "Excited State Spectroscopy and Excited State Dynamics of Rh(III) and Pd(II) Chelates as Studied by Optically Detected Magnetic Resonance Techniques." In Transition Metal and Rare Earth Compounds. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/3-540-44447-5_2.

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Coogan, T. P., D. G. Stump, D. A. Barsotti, and I. Y. Rosenblum. "Superoxide Dismutase Modification and Genotoxicity of Transition-Metal Ion Chelators." In Biological Reactive Intermediates III. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4684-5134-4_25.

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3

Zhou, J. Y., T. Luo, W. L. She, et al. "Metal-to-Ligand Charge Transfer Spectra for Transition Metal Complexes of Chelated Aromatic Ligands: Theory and Experiment." In Laser in Forschung und Technik / Laser in Research and Engineering. Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-80263-8_38.

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Fages, F. "Fluorescent, Siderophore-Based Hydroxamate Chelators for the Detection of Transition-Metal Ions." In Chemosensors of Ion and Molecule Recognition. Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-3973-1_16.

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Patton, Wayne F. "Background-Free Protein Detection in Polyacrylamide Gels and on Electroblots Using Transition Metal Chelate Stains." In Springer Protocols Handbooks. Humana Press, 2009. http://dx.doi.org/10.1007/978-1-59745-198-7_49.

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6

Tkáč, A., and E. Hanušovská-Tkáčová. "Alternating Reactivity of Radicals Coordinated to Chelated Transition Metals or Metalloenzymes and Chemical Carcinogenesis." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_105.

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Hirayama, T. "The Activity-based Sensing of Biological Transition Metals." In Fluorescent Chemosensors. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/9781839167324-00326.

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Metal ions are involved in various biological processes, and their essential roles and pathological involvement have facilitated the development of new synthetic chemical tools for the detection and monitoring of metal ions in cells and living organisms. For example, fluorescent and other optical probes have been used to study metal homeostasis and alterations with spatial and temporal resolution. They are categorized into chelation-based and activity-based probes based on their detection mechanism. Chelation-based probes have been used since the 1980s and operate through the complexation of a

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McCleverty, Jon. "Metals in solution." In Chemistry of the First-row Transition Metals. Oxford University Press, 1999. http://dx.doi.org/10.1093/hesc/9780198501510.003.0003.

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This chapter examines the occurrence of the dissociation of ligands, which may have a reaction between the ligands or the metal and the solvent and aggregation in order to give di- or oligo-nuclear species. It describes the thermodynamic stability of a complex that can be revealed by an equilibrium constant and relates its concentration to the concentration of all other related species when the system has reached equilibrium. It also analyses the kinetic stability of a species that refers to the speed at which transformation leads to the attainment of equilibrium. The chapter reviews the metal

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Wilkins, Patricia C., and Ralph G. Wilkins. "The d-block – nonredox chemistry." In Inorganic Chemistry in Biology. Oxford University Press, 1997. http://dx.doi.org/10.1093/hesc/9780198559337.003.0007.

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This chapter discusses transition elements with a propensity for facile one or two electron changes that feature heavily in the oxidoreductases. It analyses the H<sub>2</sub>O liability that is essential for the metal ions to operate in metalloenzymes wherein the substitution of H<sub>2</sub>O by substrate is often a necessary step and is rarely rate limiting in the overall mechanism. It also explains how a substrate is added to the existing coordinated ligands, which is possible because the metal ions have variable coordination numbers. The chapter talks about the loss of liability when the m

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Toyokuni, Shiny A. "Iron-overload model." In Experimental protocols for reactive oxygen and nitrogen species. Oxford University PressOxford, 2000. http://dx.doi.org/10.1093/oso/9780198506683.003.0091.

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Abstract Redox cycling is a characteristic of transition metals such as iron. Iron is an essential metal in mammals for oxygen transport by haemoglobin and for the function of many enzymes including catalase and cytochromes. However, the ‘free’ or ‘catalytic’ form of iron mediates in the production of reactive oxygen species via the Fenton reaction and induces oxidative stress. ‘Free’ iron is quite cytotoxic, as well as mutagenic and carcinogenic. There is an increasing number of reports of an association between increased body iron stores and increased risk of cancer. Intraperitoneal injectio

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Conference papers on the topic "Transition metal chelates"

1

Chen, Tzu-Yu, Sang-Hea Shim, and M. Linda Lin. "Polarization Studies of Mild Steel in the Presence of Chelants at High Temperature." In CORROSION 1990. NACE International, 1990. https://doi.org/10.5006/c1990-90143.

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Abstract Corrosion of mild steel in the presence of chelants, such as EDTA and NTA, was studied at 180°F (82°C) using the potentiodynamic polarization and linear polarization techniques. In a rotating cylinder system, the effects of chelant concentration, pH, rotating speed, and calcium addition in deaerated solutions were investigated. At pH 9, the corrosion was at least partially controlled by diffusion in the presence of 20 or 200 ppm of EDTA or NTA. The rate of corrosion increased with increasing rotating speed (rpm) and chelant concentration. At pH 11 and 200 ppm EDTA or NTA, the anodic d

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Saunders, B. R., K. S. Murray, R. J. Fleming, and D. G. McCulloch. "A physical and spectroscopic study of polypyrrole films containing tetrasulfonated metallophthalocyanine and transition metal EDTA chelates." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834702.

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Mouas, Toma, amel djedouani, ghada boukerzaza, chawki Benssuici, and manel bouabellou. "EFFICIENT SYNTHESIS OF DHA TRANSITION METAL CHELATES AS POTENT ANTIOXIDANTS, ENZYME INHIBITOR AND ANTIMICROBIAL AGENTS." In 1st International Electronic Conference on Biomedicine. MDPI, 2021. http://dx.doi.org/10.3390/ecb2021-10262.

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Durand, Erwann, Nastassia Kaugarenia, Nathalie Barouh, Pierre Villeneuve, and Romain Kapel. "Antioxidant chelating peptides production from Rapeseed meal proteins proteolysis." In 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/whcd7145.

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The oxidative chemical degradation produced by reactive species (free radicals, oxygen, etc.) is responsible for the deterioration of most of the formulated products. One of the main properties of an antioxidant lies in its capacity to limit the chemical propagation of oxidation by reducing free radicals. Another strategy to prevent oxidation is binding transition metals, since they are ubiquitous and deeply involved in the initiation and propagation of lipids oxidation. Naturally occurring phospholipids, polyphenols, proteins, or peptides that can bind metal ions could be more valued than syn

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Li, Tingbin, Yali Hu, Chunlin Ma, Guofang He, Dong Xu, and Quan Ren. "The relationship between the hybrid form of center metal-atom and the third order nonlinear optical property of 1,3-dithiole-2-thione-4,5-dithiolato-S, S' (dmit) bis-chelate transition metal complexes study by z-scan." In Photonics Asia 2007, edited by Yiping Cui, Qihuang Gong, and Yuen-Ron Shen. SPIE, 2007. http://dx.doi.org/10.1117/12.755351.

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Denton, Mark S., and William D. Bostick. "Downselect Ion Specific Media (ISM) Utilization in Upset and Outage Conditions." In The 11th International Conference on Environmental Remediation and Radioactive Waste Management. ASMEDC, 2007. http://dx.doi.org/10.1115/icem2007-7187.

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This paper presents a process that has been used to help nuclear power plant (NPP) clients resolve some of their more challenging waste water processing issues. These treatment issues may become even more evident during outage conditions, due (in part) to associated decontamination activities that may cause off-normal chemical conditions, which may subsequently change both the peak levels of activities for radionuclides introduced into the collected waste water and also the chemical forms in which they may exist (e.g., formation of colloids or soluble chelates). In one NPP waste processing exa

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