Academic literature on the topic 'Transition metal complexes. Ligands (Biochemistry)'

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Dissertations / Theses on the topic "Transition metal complexes. Ligands (Biochemistry)"

1

Cheung, Wai Man. "Transition metal complexes with dichalcogenoimidodiphosphinate ligands /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202007%20CHEUNG.

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2

Smith, Charles J. "Transition metal complexes on novel, polydentate, water-soluble, phosphine ligands /." free to MU campus, to others for purchase, 1997. http://wwwlib.umi.com/cr/mo/fullcit?p9841335.

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3

Lutterman, Daniel Aaron. "Investigation of transition metal complexes with potential photochemical applications." Columbus, Ohio : Ohio State University, 2007. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1184601514.

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4

Don, Ming-jaw. "Ligand Substitution Studies in the Tetracobalt Cluster Co₄(CO)₁₀([mu]₄-PPh₂) and Synthesis and Reactivity Studies in the Fe₂Pt and FeCo₂ Mixed-metal Clusters." Thesis, University of North Texas, 1991. https://digital.library.unt.edu/ark:/67531/metadc279335/.

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The kinetics of ligand substitution for CO in Co4(CO)10(mu4-PPh2) , 1, have been investigated for the ligands P(OMe)3, P(OEt)3, PPh2H, P(0-i-Pr)3, P(n-Bu)3, PPh3, P(i-Pr)3, and PCy3 over a wide temperature range.
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5

Hunt, Sean W. Richmond Michael G. "Synthesis and characterization of platinum(II)(2-(9-anthracenylylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione)(dichloride), platinum(II)(2-(9-anthracenylylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(maleonitriledithiolate), and platinum(II)(4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione)(4-methyl-1,2-benzene dithiol)." [Denton, Tex.] : University of North Texas, 2009. http://digital.library.unt.edu/ark:/67531/metadc12135.

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6

Hunt, Sean W. "Synthesis and Characterization of Platinum(II)(2-(9-anthracenylylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione)(dichloride), Platinum(II)(2-(9-anthracenylylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione(maleonitriledithiolate), and Platinum(II)(4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione)(4-Methyl-1,2-benzene dithiol)." Thesis, University of North Texas, 2009. https://digital.library.unt.edu/ark:/67531/metadc12135/.

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Substitution of the 1,5-cyclooctadiene (cod) ligand in PtCl2(cod) (1) by the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) yields PtCl2(bpcd) (2). Knoevenagel condensation of 2 with 9-anthracenecarboxaldehyde leads to the functionalization of the bpcd ligand and formation of the corresponding 2-(9-anthracenylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (abpcd) substituted compound PtCl2(abpcd) (3), which is also obtained from the direct reaction of 1 with the abpcd ligand in near quantitative yield. The reaction of 3 with disodium maleonitriledithi
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7

Liu, Jie. "Substitution chemistry of the cobalt complexes RCCo3(CO)9 (R = H, CHO) with the diphosphine ligand: 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses, X-ray structures and reactivity." Thesis, University of North Texas, 2001. https://digital.library.unt.edu/ark:/67531/metadc3043/.

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The reaction between the tetrahedrane cluster RCCo3(CO)9{R = CHO (1), H (3)} and the redox-active diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3- dione (bpcd) leads to the replacement of two CO groups and formation of RCCo3(CO)7(bpcd) {R = CHO (2), H (4)}. Clusters 2 and 4 are thermally unstable and readily transform into the new P-C bond cleavage cluster 5. All three clusters 2, 4, and 5 have been isolated and fully characterized in solution by IR and 31P NMR spectroscopy. VT 31P NMR data indicate that the bpcd ligand in RCCo3(CO)7(bpcd) is fluxional at 187 K in THF. Clusters
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8

Skinner, Michael E. G. "Transition metal complexes of diamide-diamine ligands." Thesis, University of Oxford, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.365390.

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9

Seidel, Scott William 1971. "Transition metal complexes containing chelating amido ligands." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/47411.

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10

Olson, Michael David. "Pyrazolyl based ligands in transition metal complexes." Thesis, University of British Columbia, 1989. http://hdl.handle.net/2429/27610.

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Several uninegative/ multidentate pyrazolyl based ligands were synthesized [eg. HBPZ₃₋, HBpz”₃₋, MeGapz₃₋/ MeGapz” ₃₋, H2BpZ₂₋/ Me2Bpz₂₋/ Me2GapZ₂₋/ Me2Gapz"₂₋/ Me₂Gapz(OCH₂CH₂NH₂)⁻Me₂Gapz(OCH₂CH₂CH=CH₂)⁻ ; pz pyrazolyl/ pz" = 3, 5 dimethylpyrazolyl]. These ligands were reacted with the sterically hindered metal complex, HBpz*₃MCl (M = Co, Ni; pz* = 3-iPr-4-Br-pyrazolyl) and the mixed-ligand transition metal complexes of general formulae, HBpz*₃ML, were isolated. The X-ray crystal structure of one such complex, HBpz*₃Nipz"₃BH was determined showing a near octahedral arrangement of ligands abo
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