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1

Chia, Y. Y., and M. G. Tay. "An insight into fluorescent transition metal complexes." Dalton Trans. 43, no. 35 (2014): 13159–68. http://dx.doi.org/10.1039/c4dt01098a.

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Three types of fluorescent emissions were found in the transition metal complexes namely pure fluorescence, thermal activated delayed fluorescence and fluorescence-phosphorescence dual emissions. The characteristics of these fluorescent emissions are reviewed in this perspective.
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2

Sathish, Veerasamy, Arumugam Ramdass, Pounraj Thanasekaran, Kuang-Lieh Lu, and Seenivasan Rajagopal. "Aggregation-induced phosphorescence enhancement (AIPE) based on transition metal complexes—An overview." Journal of Photochemistry and Photobiology C: Photochemistry Reviews 23 (June 2015): 25–44. http://dx.doi.org/10.1016/j.jphotochemrev.2015.04.001.

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3

Wang, Junsi, Yue Lu, Niamh McGoldrick, Caishun Zhang, Wenbo Yang, Jianzhang Zhao, and Sylvia M. Draper. "Dual phosphorescent dinuclear transition metal complexes, and their application as triplet photosensitizers for TTA upconversion and photodynamic therapy." Journal of Materials Chemistry C 4, no. 25 (2016): 6131–39. http://dx.doi.org/10.1039/c6tc01926a.

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4

Wang, Bei-Bei, Huiping Zuo, John Mack, Poulomi Majumdar, Tebello Nyokong, Kin Shing Chan, and Zhen Shen. "Optical properties and electronic structures of axially-ligated group 9 porphyrins." Journal of Porphyrins and Phthalocyanines 19, no. 08 (August 2015): 973–82. http://dx.doi.org/10.1142/s108842461550073x.

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A series of group 9 metal tetra-(p-tolyl)-porphyrin ( M(ttp) , M = Co(II) , Rh(III) , Ir(III)) complexes with axial phenyl substituents have been synthesized and characterized. An aryl bromide cleavage reaction of transition metal complexes was used to prepare the complexes from Co(ttp) , Rh(ttp) Cl and Ir(ttp)COCl , respectively. Magnetic circular dichroism (MCD) spectroscopy and TD-DFT calculations have been used to study trends in the optical spectra and electronic structures. The effect of introducing different para-substituents on the phenyl substituents was examined. During fluorescence emission studies, phosphorescence was observed for the Ir(III) complexes in the near infrared (NIR) region.
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5

Li, Zhi-Feng, Xiao-Ping Yang, Hui-Xue Li, and Guo-Fang Zuo. "Phosphorescent Modulation of Metallophilic Clusters and Recognition of Solvents through a Flexible Host-Guest Assembly: A Theoretical Investigation." Nanomaterials 8, no. 9 (September 2, 2018): 685. http://dx.doi.org/10.3390/nano8090685.

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MP2 (Second order approximation of Møller–Plesset perturbation theory) and DFT/TD-DFT (Density functional theory/Time-dependent_density_functional_theory) investigations have been performed on metallophilic nanomaterials of host clusters [Au(NHC)2]+⋅⋅⋅[M(CN)2]−⋅⋅⋅[Au(NHC)2]+ (NHC = N-heterocyclic carbene, M = Au, Ag) with high phosphorescence. The phosphorescence quantum yield order of clusters in the experiments was evidenced by their order of μS1/ΔES1−T1 values ( μ S 1 : S0 → S1 transition dipole, ∆ E S 1 − T 1 : splitting energy between the lowest-lying singlet S1 and the triplet excited state T1 states). The systematic variation of the guest solvents (S1: CH3OH, S2: CH3CH2OH, S3: H2O) are employed not only to illuminate their effect on the metallophilic interaction and phosphorescence but also as the probes to investigate the recognized capacity of the hosts. The simulations revealed that the metallophilic interactions are mainly electrostatic and the guests can subtly modulate the geometries, especially metallophilic Au⋅⋅⋅M distances of the hosts through mutual hydrogen bond interactions. The phosphorescence spectra of hosts are predicted to be blue-shifted under polar solvent and the excitation from HOMO (highest occupied molecular orbital) to LUMO (lowest unoccupied molecular orbital) was found to be responsible for the 3MLCT (triplet metal-to-ligand charge transfer) characters in the hosts and host-guest complexes. The results of investigation can be introduced as the clues for the design of promising blue-emitting phosphorescent and functional materials.
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6

Liang, Ai-Hua, Fu-Quan Bai, Jian Wang, Jian-Bo Ma, and Hong-Xing Zhang. "Theoretical Studies on Phosphorescent Materials: The Conjugation-Extended PtII Complexes." Australian Journal of Chemistry 67, no. 10 (2014): 1522. http://dx.doi.org/10.1071/ch14032.

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A theoretical study on the PtII complex A based on a dimesitylboron (BMes2)-functionalized [Pt(C^N)(acac)] (C^N = 2-phenyl-pyridyl, acac = acetylaceton) complex, as well as three conjugation-extended analogues of the methylimidazole (C*) ligand BMes2-[Pt(C^C*)(acac)] complexes B–D is performed. Their theoretical geometries, electronic structures, emission properties, and the radiative decay rate constants (kr) were also investigated. The energy differences between the two highest occupied orbitals with dominant Pt d-orbital components (Δddocc) of D both at the ground and excited states are the smallest of all. Compared with B, the charge transfer in D possesses a marked trend towards the extended conjugated group, while C changed inconspicuously. The lowest-lying absorptions and the phosphorescence of them can be described as a mixed metal-to-ligand charge transfer (MLCT)/intra-ligand π→π* charge transfer (ILCT) and 3MLCT/3ILCT, respectively. The variation of charge transfer properties induced by extended conjugation and the radiative decay rate constants (kr) calculated revealed that D is a more efficient blue phosphorescence material with a 497 nm emission transition.
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7

Li, Kai, Yong Chen, Jian Wang, and Chuluo Yang. "Diverse emission properties of transition metal complexes beyond exclusive single phosphorescence and their wide applications." Coordination Chemistry Reviews 433 (April 2021): 213755. http://dx.doi.org/10.1016/j.ccr.2020.213755.

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8

Chen, Hsing-Yi, Cheng-Han Yang, Yun Chi, Yi-Ming Cheng, Yu-Shan Yeh, Pi-Tai Chou, Hsi-Ying Hsieh, Chao-Shiuan Liu, Shie-Ming Peng, and Gene-Hsiang Lee. "Room-temperature NIR phosphorescence of new iridium (III) complexes with ligands derived from benzoquinoxaline." Canadian Journal of Chemistry 84, no. 2 (February 1, 2006): 309–18. http://dx.doi.org/10.1139/v05-253.

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A new series of new iridium (III) complexes (1–5) bearing ligands derived from benzoquinoxaline were designed and synthesized. X-ray structural analyses of 1 reveal a distorted octahedral geometry around the Ir atom in which the pyrazolate chelate is located opposite to the cis-oriented carbon donor atoms of benzoquinoxaline, while the benzoquinoxaline ligands adopt an eclipse configuration and their coordinated nitrogen atoms and carbon adopt trans- and cis-orientation, respectively. Complexes 1–5 exhibit moderate NIR phosphorescence with peak maxima located at around 910–930 nm. As supported by the TDDFT approach, the transition mainly involves benzoquinoxaline 3π–π* intraligand charge transfer (ILCT) and metal (Ir) to benzoquinoxaline charge transfer (MLCT) of which the spectroscopy and dynamics of relaxation have been thoroughly investigated. The relatively weak NIR emission can be tentatively rationalized by the low energy gap of which the radiationless deactivation may be governed by nearly temperature-independent, weak-bonding motions in combination with a minor channel incorporating small torsional motions associated with phenyl ring in the benzoquinoxaline sites.Key words: phosphorescence, NIR, iridium, benzoquinoxaline, isoquinoline, bipyridine, pyrazolate, acetylacetonate.
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9

Wang, Xue-Mei, Jia-Yan Qiang, Ai-Quan Jia, Bihai Tong, and Qian-Feng Zhang. "Syntheses, crystal structures and phosphorescence properties of cyclometalated iridium(III) bis(pyridylbenzaldehyde) complexes with dithiolate ligands." Zeitschrift für Naturforschung B 72, no. 12 (December 20, 2017): 941–46. http://dx.doi.org/10.1515/znb-2017-0105.

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AbstractThe synthesis of three neutral bis-cyclometalated iridium(III) complexes [Ir(pba)2(S^S)] (pbaH=4-(2-pyridyl)benzaldehyde; S^S=Et2NCS2− (1), iPrOCS2− (2), (nPrO)2PS2− (3)) from [{Ir(μ-Cl)(pba)2}2] and the corresponding sodium or potassium dithiolates in methanol-dichloromethane is described. The composition of complexes 1–3 is discussed on the basis of 1H NMR, 13C NMR, IR, and mass spectroscopy, and the crystal structures of 1 and 3 were determined by X-ray crystallography. The absorption and emission spectra show that the [Ir(pba)2(S^S)] complexes may be effective candidates as green-emitting phosphorescent materials. The stability of the three cyclometalated iridium(III) complexes towards different transition metal ions was also investigated in acetonitrile-water solvent.
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10

Connell, Timothy U., and Paul S. Donnelly. "Labelling proteins and peptides with phosphorescent d6 transition metal complexes." Coordination Chemistry Reviews 375 (November 2018): 267–84. http://dx.doi.org/10.1016/j.ccr.2017.12.001.

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11

Braunschweig, Holger, Theresa Dellermann, Rian D. Dewhurst, Benjamin Hupp, Thomas Kramer, James D. Mattock, Jan Mies, Ashwini K. Phukan, Andreas Steffen, and Alfredo Vargas. "Strongly Phosphorescent Transition Metal π-Complexes of Boron–Boron Triple Bonds." Journal of the American Chemical Society 139, no. 13 (March 27, 2017): 4887–93. http://dx.doi.org/10.1021/jacs.7b00766.

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12

Baranova, Kristina F., Aleksei A. Titov, Oleg A. Filippov, Alexander F. Smol’yakov, Alexey A. Averin, and Elena S. Shubina. "Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence." Crystals 10, no. 10 (September 29, 2020): 881. http://dx.doi.org/10.3390/cryst10100881.

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Two silver nitrate complexes with bisphosphines were obtained and characterized: [Ag(dcypm)]2(NO3)2 (1; dcypm = bis(dicyclohexylphosphino)methane) and [Ag(dppm)]2(Me2PzH)n(NO3)2 (n = 1, 2a; n = 2, 2b; dppm = bis(diphenylphosphino)methane, Me2PzH = 3,5-dimethylpyrazole). The steric repulsions of bulky cyclohexyl substituents prevent additional ligand coordination to the silver atoms in 1. Compounds obtained feature the bimetallic eight-member cyclic core [AgPCP]2. The intramolecular argenthophilic interaction (d(Ag···Ag) = 2.981 Å) was observed in complex 1. In contrast, the coordination of pyrazole led to the elongation of Ag···Ag distance to 3.218(1) Å in 2a and 3.520 Å in 2b. Complexes 1 and 2a possess phosphorescence both in the solution and solid state. Time-dependent density-functional theory (TD-DFT) calculations demonstrate the origin of their different emission profile. In the case of 1, upon excitation, the electron leaves the Ag–P bonding orbital and locates on the intramolecular Ag···Ag bond (metal-centered character). Complex 2a at room temperature exhibits a phosphorescence originating from the 3(M + LP+N)LPhCT state. At 77 K, the photoluminescence spectrum of complex 2a shows two bands of two different characters: 3(M + LP+N)LPhCT and 3LCPh transitions. The contribution of Ag atoms to the excited state in both complexes 2a and 2b decreased relative to 1 in agreement with the structural changes caused by pyrazole coordination.
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13

Hosseini, Ahmad R., Cheong Yang Koh, Jason D. Slinker, Samuel Flores-Torres, Héctor D. Abruña, and George G. Malliaras. "Addition of a Phosphorescent Dopant in Electroluminescent Devices from Ionic Transition Metal Complexes." Chemistry of Materials 17, no. 24 (November 2005): 6114–16. http://dx.doi.org/10.1021/cm050986h.

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14

Ikeda, Shigeru, Seiichi Yamamoto, Tohru Azumi, and G. A. Crosby. "Phosphorescence and zero-field optically detected magnetic resonance studies of (nd)10 transition-metal complexes. 1. ZnX2(phen) (X = Cl, Br, I)." Journal of Physical Chemistry 96, no. 16 (August 1992): 6593–97. http://dx.doi.org/10.1021/j100195a017.

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15

Powell, B. J. "Theories of phosphorescence in organo-transition metal complexes – From relativistic effects to simple models and design principles for organic light-emitting diodes." Coordination Chemistry Reviews 295 (July 2015): 46–79. http://dx.doi.org/10.1016/j.ccr.2015.02.008.

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16

Zadlo, Andrzej, Krystian Mokrzyński, Shosuke Ito, Kazumasa Wakamatsu, and Tadeusz Sarna. "The influence of iron on selected properties of synthetic pheomelanin." Cell Biochemistry and Biophysics 78, no. 2 (May 24, 2020): 181–89. http://dx.doi.org/10.1007/s12013-020-00918-1.

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Abstract It is believed that while eumelanin plays photoprotective and antioxidant role in pigmented tissues, pheomelanin being more photoreactive could behave as a phototoxic agent. Although the metal ion-sequestering ability of melanin might be protective, transition metal ions present in natural melanins could affect their physicochemical properties. The aim of this research was to study iron binding by pheomelanin and analyze how such a binding affects selected properties of the melanin. Synthetic pheomelanin (CDM), prepared by enzymatic oxidation of DOPA in the presence of cysteine was analyzed by electron paramagnetic resonance (EPR) spectroscopy, spectrophotometry, chemical analysis, and time-resolved measurements of singlet oxygen phosphorescence. Iron broadened EPR signal of melanin and increased its optical absorption. Iron bound to melanin exhibited EPR signal at g = 4.3, typical for high-spin iron (III). Iron bound to melanin significantly altered the kinetics of melanin photodegradation, which in turn modified the accessibility and stability of the melanin–iron complexes as indicated by the release of iron from melanin induced by diethylenetriaminepentaacetic acid and KCN. Although bound to melanin iron little affects initial stages of photodegradation of CDM, the effect of iron becomes more pronounced at later stages of melanin photolysis.
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17

Jing, De-Kun, Han-Ru Xu, Xiao-Han Yang, Rui-Lian Yang, Zhuo Liu, Shao-Bin Dou, Zheng-Rong Mo, Gao-Nan Li, and Zhi-Gang Niu. "New yellow/orange-emitting heteroleptic iridium(III) complexes with 5,7-difluoro-2-phenylbenzothiazole ligand." Journal of Chemical Research 44, no. 1-2 (November 21, 2019): 67–71. http://dx.doi.org/10.1177/1747519819889014.

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Two new phosphorescent iridium(III) complexes, (dfbt)2Ir(pic) and (dfbt)2Ir(acac) (dfbt = 5,7-difluoro-2-phenylbenzothiazole, pic = picolinate, acac = acetylacetonate), have been synthesized and characterized. Upon photoexcitation, both complexes exhibit strong yellow–orange emission in CH2Cl2 solution at room temperature with absolute quantum yields up to 99.0% and emission lifetimes up to 1.23 μs. The spectroscopic property has been calculated by density functional theory and time-dependent density functional theory, thus suggesting that the lowest absorption and the emission originate from the metal-to-ligand charge transfer/ligand-centered transition.
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18

Li, Elise Y., Yi-Ming Cheng, Cheng-Chih Hsu, Pi-Tai Chou, Gene-Hsiang Lee, I.-Hui Lin, Yun Chi, and Chao-Shiuan Liu. "Neutral RuII-Based Emitting Materials: A Prototypical Study on Factors Governing Radiationless Transition in Phosphorescent Metal Complexes†." Inorganic Chemistry 45, no. 20 (October 2006): 8041–51. http://dx.doi.org/10.1021/ic060066g.

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19

Kimachi, Seiya, Shigeru Ikeda, and Tohru Azumi. "Phosphorescence and zero-field optically detected magnetic resonance studies of (nd)10 transition-metal complexes. 2. CdX2(phen) (X = Cl, Br, and I; phen = 1,10-phenanthroline)." Journal of Physical Chemistry 99, no. 19 (May 1995): 7242–45. http://dx.doi.org/10.1021/j100019a005.

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20

Niehaus, Thomas A., Thomas Hofbeck, and Hartmut Yersin. "Charge-transfer excited states in phosphorescent organo-transition metal compounds: a difficult case for time dependent density functional theory?" RSC Advances 5, no. 78 (2015): 63318–29. http://dx.doi.org/10.1039/c5ra12962a.

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A series of 17 platinum(ii) and iridium(iii) complexes have been investigated theoretically and experimentally to elucidate the charge-transfer character in emission from the lowest triplet state. TDDFT is found to be surprisingly accurate.
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21

Cebrián, Cristina, and Matteo Mauro. "Recent advances in phosphorescent platinum complexes for organic light-emitting diodes." Beilstein Journal of Organic Chemistry 14 (June 18, 2018): 1459–81. http://dx.doi.org/10.3762/bjoc.14.124.

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Phosphorescent organometallic compounds based on heavy transition metal complexes (TMCs) are an appealing research topic of enormous current interest. Amongst all different fields in which they found valuable application, development of emitting materials based on TMCs have become crucial for electroluminescent devices such as phosphorescent organic light-emitting diodes (PhOLEDs) and light-emitting electrochemical cells (LEECs). This interest is driven by the fact that luminescent TMCs with long-lived excited state lifetimes are able to efficiently harvest both singlet and triplet electro-generated excitons, thus opening the possibility to achieve theoretically 100% internal quantum efficiency in such devices. In the recent past, various classes of compounds have been reported, possessing a beautiful structural variety that allowed to nicely obtain efficient photo- and electroluminescence with high colour purity in the red, green and blue (RGB) portions of the visible spectrum. In addition, achievement of efficient emission beyond such range towards ultraviolet (UV) and near infrared (NIR) regions was also challenged. By employing TMCs as triplet emitters in OLEDs, remarkably high device performances were demonstrated, with square planar platinum(II) complexes bearing π-conjugated chromophoric ligands playing a key role in such respect. In this contribution, the most recent and promising trends in the field of phosphorescent platinum complexes will be reviewed and discussed. In particular, the importance of proper molecular design that underpins the successful achievement of improved photophysical features and enhanced device performances will be highlighted. Special emphasis will be devoted to those recent systems that have been employed as triplet emitters in efficient PhOLEDs.
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22

Lo, Kenneth Kam-Wing, and Steve Po-Yam Li. "Utilization of the photophysical and photochemical properties of phosphorescent transition metal complexes in the development of photofunctional cellular sensors, imaging reagents, and cytotoxic agents." RSC Advances 4, no. 21 (2014): 10560. http://dx.doi.org/10.1039/c3ra47611a.

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23

Lo, Kenneth Kam-Wing, and Steve Po-Yam Li. "ChemInform Abstract: Utilization of the Photophysical and Photochemical Properties of Phosphorescent Transition Metal Complexes in the Development of Photofunctional Cellular Sensors, Imaging Reagents, and Cytotoxic Agents." ChemInform 45, no. 28 (June 26, 2014): no. http://dx.doi.org/10.1002/chin.201428237.

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24

Denninger, U., J. J. Schneider, G. Wilke, R. Goddard, R. Krömer, and C. Krüger. "Transition metal complexes." Journal of Organometallic Chemistry 459, no. 1-2 (October 1993): 349–57. http://dx.doi.org/10.1016/0022-328x(93)86088-y.

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25

Bojan, Vilma R., José M. López-de-Luzuriaga, Elena Manso, Miguel Monge, and M. Elena Olmos. "Metal-Induced Phosphorescence in (Pentafluorophenyl)gold(III) Complexes." Organometallics 30, no. 17 (September 12, 2011): 4486–89. http://dx.doi.org/10.1021/om200537w.

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26

Brothers, Penelope J., and Warren R. Roper. "Transition-metal dihalocarbene complexes." Chemical Reviews 88, no. 7 (November 1988): 1293–326. http://dx.doi.org/10.1021/cr00089a014.

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27

Barron, Andrew R., and Geoffrey Wilkinson. "Transition-metal aluminohydride complexes." Polyhedron 5, no. 12 (January 1986): 1897–915. http://dx.doi.org/10.1016/s0277-5387(00)87113-2.

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28

Brisdon, Brian J., and Richard A. Walton. "Transition metal butadienyl complexes." Polyhedron 14, no. 10 (May 1995): 1259–76. http://dx.doi.org/10.1016/0277-5387(95)00060-6.

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29

Hlatky, Gregory G., and Robert H. Crabtree. "Transition-metal polyhydride complexes." Coordination Chemistry Reviews 65 (July 1985): 1–48. http://dx.doi.org/10.1016/0010-8545(85)85020-7.

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30

Ziessel, Raymond, Muriel Hissler, Abdelkrim El-ghayoury, and Anthony Harriman. "Multifunctional transition metal complexes." Coordination Chemistry Reviews 178-180 (December 1998): 1251–98. http://dx.doi.org/10.1016/s0010-8545(98)00060-5.

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31

Kalt, Dominique, and Ulrich Schubert. "Transition metal silyl complexes." Inorganica Chimica Acta 306, no. 2 (August 2000): 211–14. http://dx.doi.org/10.1016/s0020-1693(00)00175-4.

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32

Braunschweig, Holger, Rian D. Dewhurst, and Viktoria H. Gessner. "Transition metal borylene complexes." Chemical Society Reviews 42, no. 8 (2013): 3197. http://dx.doi.org/10.1039/c3cs35510a.

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33

Starodub, Vladimir A., and T. N. Starodub. "Isotrithionedithiolate transition metal complexes." Russian Chemical Reviews 80, no. 9 (September 30, 2011): 829–53. http://dx.doi.org/10.1070/rc2011v080n09abeh004199.

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34

Hall, Chris, and Robin N. Perutz. "Transition Metal Alkane Complexes†." Chemical Reviews 96, no. 8 (January 1996): 3125–46. http://dx.doi.org/10.1021/cr9502615.

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35

Cundari, Thomas R. "Transition metal imido complexes." Journal of the American Chemical Society 114, no. 20 (September 1992): 7879–88. http://dx.doi.org/10.1021/ja00046a037.

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36

Hitchcock, Peter B., Michael F. Lappert, and Michael J. McGeary. "Dimetallostannylene-transition-metal complexes." Organometallics 9, no. 3 (March 1990): 884–86. http://dx.doi.org/10.1021/om00117a064.

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37

de Azevedo, Cristina G., and K. Peter C. Vollhardt. "Oligocyclopentadienyl Transition Metal Complexes." Synlett 2002, no. 07 (2002): 1019–42. http://dx.doi.org/10.1055/s-2002-32572.

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38

Werner, H., J. Wolf, F. J. G. Alonso, M. L. Ziegler, and O. Serhadli. "Vinylidene transition-metal complexes." Journal of Organometallic Chemistry 336, no. 3 (December 1987): 397–411. http://dx.doi.org/10.1016/0022-328x(87)85200-2.

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39

Knorr, Michael, and Ulrich Schubert. "Transition-metal silyl complexes." Journal of Organometallic Chemistry 365, no. 1-2 (April 1989): 151–61. http://dx.doi.org/10.1016/0022-328x(89)87175-x.

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40

Stevens, Raymond C., John S. Ricci, Thomas F. Koetzle, and Wolfgang A. Herrmann. "Transition metal methylene complexes." Journal of Organometallic Chemistry 412, no. 3 (July 1991): 425–34. http://dx.doi.org/10.1016/0022-328x(91)86087-7.

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41

Schubert, U. "Transition-metal silyl complexes." Transition Metal Chemistry 16, no. 1 (February 1991): 136–44. http://dx.doi.org/10.1007/bf01127889.

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42

Werner, H., D. Schneider, and M. Schulz. "Vinylidene transition-metal complexes." Journal of Organometallic Chemistry 451, no. 1-2 (June 1993): 175–82. http://dx.doi.org/10.1016/0022-328x(93)83024-p.

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43

Lappert, M. F. "Transition Metal Carbyne Complexes." Journal of Organometallic Chemistry 461, no. 1-2 (November 1993): C7—C8. http://dx.doi.org/10.1016/0022-328x(93)83302-c.

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44

B�tiu, C., I. Panea, L. Ghizdavu, L. David, and S. Ghizdavu Pellascio. "Divalent transition metal complexes." Journal of Thermal Analysis and Calorimetry 79, no. 1 (January 2005): 129–34. http://dx.doi.org/10.1007/s10973-004-0573-6.

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45

Zhou, Wei, Wen-Jie Pan, Jie Chen, Min Zhang, Jin-Hong Lin, Weiguo Cao, and Ji-Chang Xiao. "Transition-metal difluorocarbene complexes." Chemical Communications 57, no. 74 (2021): 9316–29. http://dx.doi.org/10.1039/d1cc04029d.

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46

Ravotto, Luca, and Paola Ceroni. "Aggregation induced phosphorescence of metal complexes: From principles to applications." Coordination Chemistry Reviews 346 (September 2017): 62–76. http://dx.doi.org/10.1016/j.ccr.2017.01.006.

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47

Zhang, Jian Po, Li Jin, Xing Jin, Xiu Yun Sun, and Fu Quan Bai. "Effect of Ligands on the Photoluminescence Performance of Ir(III) Complexes: A Theoretical Exploration." Advanced Materials Research 798-799 (September 2013): 219–22. http://dx.doi.org/10.4028/www.scientific.net/amr.798-799.219.

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A series of iridium (III) complexes (C^N)2Ir (Pic) (C^N = Phi (1), Ppi (2), Mpfpi (3), and Cpfpi (4) have been investigated theoretically to explore their electronic structures and spectroscopic properties. The calculate bond lengths of Ir-N and Ir-O in the ground state agree well with the corresponding experimental results. At the TD-DFT and PCM levels, 1-4 give rise to absorptions at 359, 360, 348, and 335 nm and phosphorescent emissions at 454 , 469, 441, and 425 nm, respectively. The transitions of 1-4 are all attributed to {[d (Ir)+π (C^N)][π*(C^N) or π*(Pic)]} charge transfer. It is shown that the emissions are significantly dominated by the metal participating in the frontier molecular orbitals and affected by the C^N ligands.
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48

Frohnapfel, David S., and Joseph L. Templeton. "Transition metal η2-vinyl complexes." Coordination Chemistry Reviews 206-207 (September 2000): 199–235. http://dx.doi.org/10.1016/s0010-8545(00)00269-1.

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49

Brunner, H., A. Köllnberger, T. Burgemeister, and M. Zabel. "Optically active transition metal complexes." Polyhedron 19, no. 12 (June 2000): 1519–26. http://dx.doi.org/10.1016/s0277-5387(00)00416-2.

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50

Meier, K. "Photopolymerization with transition metal complexes." Coordination Chemistry Reviews 111 (December 1991): 97–110. http://dx.doi.org/10.1016/0010-8545(91)84014-v.

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