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Journal articles on the topic 'Transition Metal Oxides (TMOs) - Novel Crystal Structure'

Author: Grafiati
Published: 7 September 2023
Last updated: 31 July 2025

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1

Kang, Yihong, Hanhan Xie, Danni Liu, et al. "Facile mass production of self-supported two-dimensional transition metal oxides for catalytic applications." Chemical Communications 55, no. 76 (2019): 11406–9. http://dx.doi.org/10.1039/c9cc06261k.

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2

Yi, Di, Jian Liu, Shang-Lin Hsu, et al. "Atomic-scale control of magnetic anisotropy via novel spin–orbit coupling effect in La2/3Sr1/3MnO3/SrIrO3 superlattices." Proceedings of the National Academy of Sciences 113, no. 23 (2016): 6397–402. http://dx.doi.org/10.1073/pnas.1524689113.

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Magnetic anisotropy (MA) is one of the most important material properties for modern spintronic devices. Conventional manipulation of the intrinsic MA, i.e., magnetocrystalline anisotropy (MCA), typically depends upon crystal symmetry. Extrinsic control over the MA is usually achieved by introducing shape anisotropy or exchange bias from another magnetically ordered material. Here we demonstrate a pathway to manipulate MA of 3d transition-metal oxides (TMOs) by digitally inserting nonmagnetic 5d TMOs with pronounced spin–orbit coupling (SOC). High-quality superlattices comprising ferromagnetic
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3

Bajdich, Michal, Benjamin Comer, Neha Bothra, Ruchika Mahajan, Frank Ablid-Pedersen, and Kirsten Winther. "Development of Activity-Stability Descriptors for Transition Metal Oxide Electrocatalysis." ECS Meeting Abstracts MA2024-01, no. 44 (2024): 2443. http://dx.doi.org/10.1149/ma2024-01442443mtgabs.

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The discovery of high-performing catalysts for the oxygen reduction and oxygen evolution reactions (ORR/OER) and related oxidative reactions is critical for the development of energy-efficient hydrogen fuel cells and electrolyzers. To achieve this goal, affordable and abundant alternatives to precious metal catalysts with sufficient stability and catalytic activity must be discovered. Ab-initio catalytic simulations combined with machine learning (ML) methods can play an important role in screening a larger search space of potential electrocatalysts materials of higher structural and compositi
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4

Chen, Yang, Man Li, Chengyu Xue, and Fuxiang Wei. "Construction of CuCo2O4@NiFe-LDH Core–Shell Heterostructure for High-Performance Hybrid Supercapacitors." Metals 15, no. 6 (2025): 659. https://doi.org/10.3390/met15060659.

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Transition metal oxides (TMOs) are considered to be highly promising materials for supercapacitor electrodes due to their low cost, multiple convertible valence states, and excellent electrochemical properties. However, inherent limitations, including restricted specific surface area and low electrical conductivity, have largely restricted their application in supercapacitors. In this paper, core–shell heterostructures of nickel–iron layered double hydroxide (NiFe-LDH) nanosheets uniformly grown on CuCo2O4 nanoneedles were synthesized by hydrothermal and calcination methods. It is found that t
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Bothra, Neha, Michal Bajdich, Benjamin Comer, Kirsten Winther, and Frank Abild Pedersen. "Computational Search for a Descriptor of Electrocatalysis in Transition Metal-Oxides." ECS Meeting Abstracts MA2023-01, no. 45 (2023): 2482. http://dx.doi.org/10.1149/ma2023-01452482mtgabs.

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Currently, the most effective electrocatalysts for oxygen reduction (ORR) and oxygen evolution reactions (OER) are comprised of noble metal oxides, which bring issues of high cost and scarcity. Discovering earth-abundant alternatives is challenging due to the costly and time-consuming experiments. High-throughput atomistic simulation of catalysts can be an efficient route for enabling the better design and discovery of new electrocatalysts. The efficient use of this approach relies on an activity descriptor that can capture the qualitative and quantitative catalytic trends. In the past, multip
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Nam, Ki-Hun, Shan Yan, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, and Marca M. Doeff. "High-Entropy Spinel Oxide as Conversion Anodes for Li-Ion Batteries." ECS Meeting Abstracts MA2024-02, no. 2 (2024): 231. https://doi.org/10.1149/ma2024-022231mtgabs.

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The burgeoning sector of electric vehicles has significantly spurred the exploration of high-energy density and long-term cycling life electrode materials for advanced lithium-ion batteries (LIBs). Presently, the constrained capacity of commercialized graphite (LiC6: 372 mAh g–1) and Li4Ti5O12 (Li7Ti5O12: 175 mAh g–1) anodes falls short of meeting the heightened requirements for energy density in such applications. Transition metal oxides (TMOs, MxOy) with conversion reaction have been widely scrutinized as next-generation LIB anode materials owing to their resonable reversible capacity in com
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7

Chchiyai, Zakaria, Oumayema El Ghali, Abdelilah Lahmar, Jones Alami, and Bouchaib Manoun. "Design and Performance of a New Zn0.5Mg0.5FeMnO4 Porous Spinel as Anode Material for Li-Ion Batteries." Molecules 28, no. 20 (2023): 7010. http://dx.doi.org/10.3390/molecules28207010.

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Due to the low capacity, low working potential, and lithium coating at fast charging rates of graphite material as an anode for Li-ion batteries (LIBs), it is necessary to develop novel anode materials for LIBs with higher capacity, excellent electrochemical stability, and good safety. Among different transition-metal oxides, AB2O4 spinel oxides are promising anode materials for LIBs due to their high theoretical capacities, environmental friendliness, high abundance, and low cost. In this work, a novel, porous Zn0.5Mg0.5FeMnO4 spinel oxide was successfully prepared via the sol–gel method and
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8

Song, Tengfei, Lin Chen, Dominika Gastol, et al. "Realization High-Voltage Stabilization of O3-Type Layered Oxide Cathodes for Sodium-Ion Batteries by Sn Simultaneously Dual Modification." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 718. http://dx.doi.org/10.1149/ma2023-024718mtgabs.

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The total global production of lithium-ion batteries (LIBs) used in electric vehicles and stationary energy storage devices has increased sharply to reach the targeted Net Zero by 2050. This leads to concerns about the future and long-term availability and cost of critical raw materials (cobalt, nickel, lithium and copper) employed in LIBs. Therefore, alternative new-generation batteries with comparable performance but using less critical raw materials are needed. Sodium-ion Batteries (NIBs) offer a wealth of possibilities for inexpensive and sustainable energy storage devices. To maximize the
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9

Bunge, Jonas, Doris Grumelli, Jan Ole Fehrs, et al. "Stability of the Fe3O4 (√2 x √2)R 45° Surface in 0.1 M NaOH Investigated by High-Energy Surface X-Ray Diffraction." ECS Meeting Abstracts MA2023-02, no. 58 (2023): 2830. http://dx.doi.org/10.1149/ma2023-02582830mtgabs.

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Transition metal oxides, especially Fe, Co, and Ni oxides, are of great interest as electrocatalysts for the oxygen evolution reaction (OER) in alkaline solution. However, detailed data on the atomic-scale oxide-electrolyte interface structure of these systems are rare. We present studies of a model oxide electrocatalyst, -reconstructed Fe3O4(001). This oxide surface has been extensively investigated under ultrahigh vacuum (UHV) conditions, leading to a detailed understanding of its atomic structure [2]. In previous in situ surface X-ray diffraction studies, we demonstrated that the reconstruc
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10

Sengupta, Abhinanda, Ajit Kumar, Aakash Ahuja, et al. "Nano-Crystallites of P2-Type Layered Transition Metal Oxide High Voltage Cathode for Sodium-Ion Battery." ECS Meeting Abstracts MA2022-02, no. 64 (2022): 2332. http://dx.doi.org/10.1149/ma2022-02642332mtgabs.

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In this era of transitioning from conventional sources of energy to non-conventional, sodium-ion battery research has been burgeoning as an indigenous solution to energy storage applications, considering the sustainability, cost effectiveness, high availability and a familiar redox chemistry 1. P2-type Na2/3Ni1/3Mn2/3O2 is one of the preeminent cathode for sodium-ion batteries because of their environmental friendliness, open framework, superior specific capacity, higher operating voltage and air-moisture stability. However, rapid capacity decay on charging it to a higher voltage because of P2
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11

Wang, Rongguang, Tian Xiao, Youki Nagayasu, and Yunhan Ling. "Electrodeposition of Cr Mn Fe Co Ni Oxy-Carbide in Organic Solvent-Based Solutions." ECS Meeting Abstracts MA2025-01, no. 23 (2025): 1413. https://doi.org/10.1149/ma2025-01231413mtgabs.

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The combustion of fossil fuels is causing severe global warming due to carbon dioxide (CO2) emissions. Under such a background, the utilization of green hydrogen gas, which is generated by water splitting with renewable solar or wind energy, is attracting much attention. In water splitting, the oxygen evolution reaction (OER) is kinetically inert in transferring four electrons compared to the hydrogen evolution reaction (HER). Generally, the overpotential for water electrolysis strongly depends on the catalytic activity of the anodic electrode. Various active and stable Ru/Ir-based electrocata
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12

Liao, Kuowei, Weijie Cao, Neha Thakur, et al. "Electronic Structure Investigation of BSCF Catalysts during Electrochemical Water Electrolysis by Using Time Zero Analysis and Advanced Operando X-Ray Absorption Spectroscopy." ECS Meeting Abstracts MA2024-01, no. 34 (2024): 1737. http://dx.doi.org/10.1149/ma2024-01341737mtgabs.

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The rapid increase in global energy demands and environmental awareness regarding the excessive use of fossil fuel has spurred significant academic interest in the development of alternative energy conversion and storage technologies that prioritize both efficiency and environmental sustainability. Among all kinds of renewable energy, hydrogen energy holds the potential to create a carbon free clean society, and a possible solution to the environmental issues.1 Electrochemical water splitting is considered as a greener approach for pure H2, which involved cathodic hydrogen evolution reaction (
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13

Ramachandran, Hari, Edward Weian Mu, Eder Lomeli, et al. "Hole Localization Induces Anionic Redox in Li-Ion Cathodes." ECS Meeting Abstracts MA2024-02, no. 2 (2024): 224. https://doi.org/10.1149/ma2024-022224mtgabs.

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Anionic redox is defined as the depopulation of electronic states consisting of unhybridized or minimally hybridized O 2p orbitals. In recent years, anionic redox has been investigated in great detail due its potential to increase the high-voltage capacity of Na-ion and Li-ion intercalation positive electrodes (cathodes) for batteries. However, anionic redox almost always manifests alongside a gamut of undesirable effects, from > 1 V of hysteresis, to voltage and capacity fade over hundreds of cycles. These effects have hindered the widespread utilization and commercialization of anionic re
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14

Norouzi, Nazgol, Darrell Omo-Lamai, Timofey Averianov, Farbod Alimohammadi, and Ekaterina Pomerantseva. "Molybdenum Oxide/Dopamine-Derived Carbon Electrodes with Enhanced Electrochemical Activity in Energy Storage Systems." ECS Meeting Abstracts MA2022-02, no. 2 (2022): 137. http://dx.doi.org/10.1149/ma2022-022137mtgabs.

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Herein, a versatile sol-gel reaction produces new electrode materials consisting of tightly integrated molybdenum oxide and carbon derived from chemically incorporated dopamine molecules, and the materials show enhanced electrochemical activity in nonaqueous Li-ion and aqueous Zn-ion energy storage systems. The novel synthesis entails the oxidation of molybdenum in aqueous solutions of excess and limited dopamine (Dopa) hydrochloride via a hydrogen peroxide-initiated process. The transformation of molybdenum under the condition of Dopa excess (Mo:Dopa molar ratio of 1:1) resulted in the format
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15

-, Bhoora Ram. "Synthesis and Advanced Applications of Transition Metal Oxides." International Journal For Multidisciplinary Research 6, no. 5 (2024). http://dx.doi.org/10.36948/ijfmr.2024.v06i05.29889.

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Transition metal oxide semiconductor materials have gained significant attention in recent years because of their unique electrical, magnetic, and optical features. Transition metal oxides (TMOs) with partially filled d-shells have a wide range of characteristics and play important roles in a variety of technological applications. They are influenced by stoichiometry changes, which alter their physical, chemical, and electrical properties. Controlled synthesis, doping, and post-synthesis treatments can all have an impact on the size, shape, crystal structure, and overall attributes of TMOs. Th
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16

He, Nan, Kin Wa Kwan, and Alfonso Hing Wan Ngan. "Enhancing the Light‐Induced Actuation of Nickel Oxyhydroxide by Aluminum Doping." Advanced Materials Technologies, November 23, 2024. http://dx.doi.org/10.1002/admt.202401263.

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AbstractMaterial‐based actuators for developing miniature robotic systems is an emerging field of interest. Transition metal oxides/hydroxides (TMOs) are introduced for light‐induced actuation based on their effective photothermal mechanism of water deintercalation from their turbostratic crystal structures. Previous studies have demonstrated doping different metal ions into TMOs can make the crystals more turbostratic (more disordered), which can be utilized to enhance the light‐induced actuation is hypothesized. This work studies the effectiveness of aluminum (Al) doping in increasing the tu
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17

Lao Bin, Zheng Xuan, Li Sheng, and Wang Zhi-Ming. "Research progress of novel quantum states and charge-spin interconversion in transition metal oxides." Acta Physica Sinica, 2023, 0. http://dx.doi.org/10.7498/aps.72.20222219.

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For satisfying the efficient storage and processing of massive data in the information technology era, spintronic device attracts tremendous attention due to its low power consumption and non-volatile feature. Spin source material, which can efficiently generates spin current, is an important constituent of novel spin-orbit torque device. The efficiency of spin current generation in spin source materials directly determines the performance of various spintronic devices. In the nearly two decades, great progress has been achieved in exploring high-efficient spin source material systems, as well
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18

Ma, Jie, Siyang Xing, Yabo Wang, Jinhu Yang, and Fei Yu. "Kinetic-Thermodynamic Promotion Engineering toward High-Density Hierarchical and Zn-Doping Activity-Enhancing ZnNiO@CF for High-Capacity Desalination." Nano-Micro Letters 16, no. 1 (2024). http://dx.doi.org/10.1007/s40820-024-01371-y.

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AbstractDespite the promising potential of transition metal oxides (TMOs) as capacitive deionization (CDI) electrodes, the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity, posing a major obstacle. Herein, we prepared the kinetically favorable ZnxNi1 − xO electrode in situ growth on carbon felt (ZnxNi1 − xO@CF) through constraining the rate of OH− generation in the hydrothermal method. ZnxNi1 − xO@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores, benefitting the ion transport/electron transf
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19

Alsharabi, Rim M., Jay Singh, Preeti S. Saxena, and Anchal Srivastava. "Ultra‐sensitive electrochemical immunosensor based on 2D vanadium diselenide (VSe2) for efficient detection of pathogens: Salmonella Typhimurium." Luminescence 39, no. 9 (2024). http://dx.doi.org/10.1002/bio.4896.

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AbstractLayered transition metal dichalcogenides (TMDs), with an extensive surface area, intriguing tunable electrical and optical features, and a distinctive Van der Waals layered structure, yield outstanding sensing properties. Essentially, most TMDs originally existed in the crystallographic phase of a 2H trigonal prismatic structure, which is semiconducting in nature with poor electrocatalytic activity. In contrast, vanadium diselenide (VSe2) with its metastable metallic 1 T octahedral crystal structure has been proven to be an outstanding electrode material, embracing exceptional electroc
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20

Sardar, Suman, Megha Vagadia, Tejas M. Tank, Jayaprakash Sahoo, and D. S. Rana. "Exploring anisotropic phases and spin transport in perovskite heterostructures: Insights into 3d/5d interfaces for antiferromagnetic spintronics." Journal of Applied Physics 135, no. 8 (2024). http://dx.doi.org/10.1063/5.0181284.

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Transition metal oxides (TMOs) demonstrate a broad spectrum of properties encompassing electronic correlations, anisotropic transport, magnetism, and optical behavior. The anisotropy arises from both intrinsic crystal symmetry and extrinsic factors like epitaxial strain and structural asymmetry at TMO interfaces. Weiss and Neel's work has elucidated anisotropic magnetic behavior in antiferromagnetic (AFM) materials. AFM TMOs exhibit unique magnetotransport behavior, including weak antilocalization (WAL) and anisotropic magnetoresistance (AMR). Understanding the magnetic structure and band topo
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21

Janauer, Gerald G., Rongji Chen, Arthur D. Dobley, Peter Y. Zavalij, and M. Stanley Whittingham. "Low Temperature Synthesis of Lamellar Transition Metal Oxides Containing Surfactant Ions." MRS Proceedings 457 (1996). http://dx.doi.org/10.1557/proc-457-533.

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ABSTRACTRecently there has been much interest in reacting vanadium oxides hydrothermally with cationic surfactants to form novel layered compounds. A series of new transition metal oxides, however, has also been formed at or near room temperature in open containers. Synthesis, characterization, and proposed mechanisms of formation are the focus of this work. Low temperature reactions of vanadium pentoxide and ammonium (DTA) transition metal oxides with long chain amine surfactants, such as dodecyltrimethylammonium bromide yielded interesting new products many of which are layered phases. DTA4H
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22

Bian, Zhiping, Mitsuki Yoshimura, Ahrong Jeong, et al. "Solid‐State Electrochemical Thermal Switches with Large Thermal Conductivity Switching Widths." Advanced Science, June 25, 2024. http://dx.doi.org/10.1002/advs.202401331.

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AbstractThermal switches that switch the thermal conductivity (κ) of the active layers are attracting increasing attention as thermal management devices. For electrochemical thermal switches, several transition metal oxides (TMOs) are proposed as active layers. After electrochemical redox treatment, the crystal structure of the TMO is modulated, which results in the κ switching. However, the κ switching width is still small (<4 W m−1 K−1). In this study, it demonstrates that LaNiOx‐based solid‐state electrochemical thermal switches have a κ switching width of 4.3 W m−1 K−1. Fully oxidized L
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23

Dugu, Sita, Rebecca W. Smaha, Shaham Quadir, et al. "Thin film synthesis, structural analysis, and magnetic properties of novel ternary transition metal nitride MnCoN2." Physical Review Materials 8, no. 10 (2024). http://dx.doi.org/10.1103/physrevmaterials.8.104411.

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Recent high-throughput computational searches have predicted many novel ternary nitride compounds providing new opportunities for materials discovery in underexplored phase spaces. Nevertheless, there are hardly any predictions and/or syntheses that incorporate only transition metals into new ternary nitrides. Here, we report on the synthesis, structure, and properties of MnCoN2, a new ternary nitride material comprising only transition metals and N. We find that crystalline MnCoN2 can be stabilized over its competing binaries, and over a tendency of this system to become amorphous, by control
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24

Lu, Qiyang, Changhee Sohn, Guoxiang Hu, et al. "Metal–insulator transition tuned by oxygen vacancy migration across TiO2/VO2 interface." Scientific Reports 10, no. 1 (2020). http://dx.doi.org/10.1038/s41598-020-75695-1.

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Abstract Oxygen defects are essential building blocks for designing functional oxides with remarkable properties, ranging from electrical and ionic conductivity to magnetism and ferroelectricity. Oxygen defects, despite being spatially localized, can profoundly alter global properties such as the crystal symmetry and electronic structure, thereby enabling emergent phenomena. In this work, we achieved tunable metal–insulator transitions (MIT) in oxide heterostructures by inducing interfacial oxygen vacancy migration. We chose the non-stoichiometric VO2-δ as a model system due to its near room t
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25

Zheng, Jingxuan, Dapeng Meng, Junxin Guo, Anyu Zhang, and Zhao Wang. "Construction of “Metal Defect/Oxygen Defect Junction” in ZnFe2O4–NiCo2O4 Heterostructures for Enhancing Electrocatalytic Oxygen Evolution." Small, September 18, 2024. http://dx.doi.org/10.1002/smll.202407177.

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AbstractDefect engineering is a promising approach to improve the conductivity and increase the active sites of transition metal oxides used as catalysts for the oxygen evolution reaction (OER). However, when metal defects and oxygen defects coexist closely within the same crystal, their compensating charges can diminish the benefits of both defect structures on the catalyst's local electronic structure. To address this limitation, a novel strategy that employs the heterostructure interface of ZnFe2O4–NiCo2O4 to spatially separate the metal defects from the oxygen defects is proposed. This con
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26

Jin, Feng, Shiyu Fan, Mingqiang Gu, et al. "Topotactic Reduction‐Driven Crystal Field Excitations in Brownmillerite Manganite Thin Films." Advanced Functional Materials, February 19, 2025. https://doi.org/10.1002/adfm.202501893.

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AbstractTopotactic reduction of perovskite oxides offers a powerful approach for discovering novel phenomena, such as superconducting infinite‐layer nickelates and polar metallicity, and is commonly accompanied by the emergence of multiple valence states and/or complex crystal fields of transition metals. However, understanding the complex interplay between crystal chemistry, electronic structure, and physical properties at the spin‐ and orbital‐resolved levels in these reduced systems remains elusive. Here, x‐ray absorption spectroscopy, resonant inelastic x‐ray scattering (RIXS), and density
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27

Raabe, Jan-Christian, Lea Hombach, Maximilian J. Poller, et al. "Synthesis and characterization of Co(II) substituted Keggin‐type polyoxometalates as novel catalysts for the hydroformylation of 1‐hexene in a thermomorphic solvent system." ChemCatChem, March 21, 2024. http://dx.doi.org/10.1002/cctc.202400395.

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Polyoxometalates (POMs) are a unique class of metal oxides, being of huge interest for the catalysis society. Co(II)‐substituted phosphomolybdate POMs (namely H7[PCoMo11O40], H11[PCo2Mo10O40] and H15[PCo3Mo9O40]) have been successfully synthesized for the first time. The structure of the new Co(II) substituted POMs was solved by single‐crystal X‐ray diffraction as well as vibrational (FTIR and Raman) and magnetic (NMR and EPR) spectroscopy and found to be of the Keggin‐type. The Co‐POMs were then applied as molecular catalysts for the hydroformylation of 1‐hexene in a thermomorphic solvent mix
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28

Lieber, Charles M., Eric W. Wong, Hongjie Dai, Benjamin W. Maynor, and Luke D. Burns. "Growth and Structure of Carbide Nanorods." MRS Proceedings 410 (1995). http://dx.doi.org/10.1557/proc-410-103.

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ABSTRACTRecent research on the growth and structure of carbide nanorods is reviewed. Carbide nanorods have been prepared by reacting carbon nanotubes with volatile transition metal and main group oxides and halides. Using this approach it has been possible to obtain solid carbide nanorods of TiC, SiC, NbC, Fe3C, and BCx having diameters between 2 and 30 nm and lengths up to 20 µm. Structural studies of single crystal TiC nanorods obtained through reactions of TiO with carbon nanotubes show that the nanorods grow along both [110] and [111] directions, and that the rods can exhibit either smooth
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29

Blanchet, Miles D., Bethany E. Matthews, Steven R. Spurgeon, Steve M. Heald, Tamara Isaacs-Smith, and Ryan B. Comes. "Jahn–Teller-driven phase segregation in MnxCo3−xO4 spinel thin films." Journal of Vacuum Science & Technology A 41, no. 5 (2023). http://dx.doi.org/10.1116/6.0002329.

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Transition metal spinel oxides comprised of earth-abundant Mn and Co have long been explored for their use in catalytic reactions and energy storage. However, understanding functional properties can be challenging due to differences in sample preparation and the ultimate structural properties of the materials. Epitaxial thin film synthesis provides a novel means of producing precisely controlled materials to explore the variations reported in the literature. In this work, MnxCo3−xO4 samples from x = 0 to x = 1.28 were synthesized through molecular beam epitaxy and characterized to develop a ma
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Zhao Kenan, Li Sheng, Lu Zengxing, et al. "Crystal Orientation Regulation of Spin-Orbit Torque Efficiency and Magnetization Switching in SrRuO<sub>3</sub> Thin Films." Acta Physica Sinica, 2024, 0. http://dx.doi.org/10.7498/aps.73.20240367.

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Spintronic devices utilize the spin property of electrons for the storage, transmission, and processing of information, inherently possessing advantages such as low power consumption and non-volatility, thus attracting widespread attention from both academia and industry. Spin-orbit torque(SOT) is an efficient method of manipulating magnetic moments using electric current for writing, harnessing the spin-orbit coupling (SOC) effect within materials to achieve the mutual conversion between charge current and spin current. Enhancing the efficiency of charge-spin conversion is a critical issue in
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31

Abdel-Hameed, S. A. M., Fatma H. Margha, Ola N. Almasarawi, and M. A. Marzouk. "Synthesis, Characterization, and Photoluminescence Properties of High and Low-Temperature Dimorphs of Pb2WO5 Glass-Ceramic for Photocatalytic Application." Journal of Inorganic and Organometallic Polymers and Materials, January 31, 2025. https://doi.org/10.1007/s10904-025-03612-y.

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Abstract In this study, pure Pb2WO5 with its two dimorphs, high temperature (HT) and low temperature (LT) forms, were successfully crystallized via melt-quenching technique in the system PbO. WO3. Al2O3. The influence of adding definite amounts of different transition metal oxides (TMO) such as ZnO, TiO2, CuO, MnO2, and V2O5 on the crystalline structure, optical, and photocatalytic activity were investigated. X-ray diffraction revealed a high degree of crystallization of pure Pb2WO5 in undoped and ZnO, TiO2, CuO, and MnO2 -doped samples. Only the V2O5-doped sample revealed crystallization of P
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