Academic literature on the topic 'Transition metals and their compounds'

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Journal articles on the topic "Transition metals and their compounds"

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Krauss, H. L., and G. Langstein. "Surface compounds of transition metals." Journal of Molecular Catalysis 65, no. 1-2 (March 1991): 101–12. http://dx.doi.org/10.1016/0304-5102(91)85087-i.

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Xing, Qiwu, Hans L. Krauss, and Wolfgang Milius. "Surface compounds of transition metals." Journal of Molecular Catalysis 90, no. 1-2 (May 1994): 75–80. http://dx.doi.org/10.1016/0304-5102(93)e0362-k.

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Wisian-neilson, P., K.-T. Nguyen, T. Wang, S. Rippstein, C. Claypool, and F. J. Garcia-alonso. "Phosphorus-Nitrogen Compounds Incorporating Transition Metals." Phosphorus, Sulfur, and Silicon and the Related Elements 87, no. 1-4 (February 1994): 277–85. http://dx.doi.org/10.1080/10426509408037460.

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Koksharova, T. V., T. V. Mandzii, T. S. Skakun, and Yu A. Anisimov. "TRANSITION METALS COORDINATION COMPOUNDS WITH BENZOHYDRAZID." Odesa National University Herald. Chemistry 22, no. 1(61) (March 3, 2017): 79–94. http://dx.doi.org/10.18524/2304-0947.2017.1(61).94714.

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Holloway, Clive, and Milan Melnik. "Crystallographic and structural characterisation of heterometallic platinum compounds: Part I. Heterobinuclear Pt compounds." Open Chemistry 9, no. 4 (August 1, 2011): 501–48. http://dx.doi.org/10.2478/s11532-011-0054-2.

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AbstractThis review covers almost 290 heterobinuclear Pt derivatives. When the heterometals (M) are non transition and the binuclear are found both with and without a metal to metal bond. Where M is a transition metal or actinide, only those with a metal-metal bond have been included here. There are thirteen non-transition metals (Sn, Hg, Ge, Sb, Tl, Zn, Pb, Cd, Na, K, Ga, Ca and In). The shortest Pt-M bond distance is 235.2(1) (Pt-Ge). There are eighteen transition metals (Fe, W, Rh, Re, Pd, Ag, Ir, Mo, Mn, Re, Co, Cu, Cr, Au, Ni, Ti, Ta and V). The shortest Pt-M bond distance is 249.5(2) pm (Pt-Cr). There is one example of an actinide, Pt-Th at 298.4(1) pm. The Pt atom has oxidation numbers 0, +2 and +4. The Pt coordination geometries include square planar (most common), trigonal bipyramidal, pseudo octahedral (Pt(IV)) and a few prevalently capped trigonal prismatic seven coordinate species. There are at least two types of isomerism distortion and polymerisation. Factors affecting bond lengths and angles are discussed and some ambiguities in coordination polyhedra are outlined.
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Ghedini, M., S. Armentano, R. Bartolino, F. Rustichelli, G. Torquati, N. Kirov, and M. Petrov. "New Liquid Crystalline Compounds Containing Transition Metals." Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 151, no. 1 (October 1987): 75–91. http://dx.doi.org/10.1080/00268948708075321.

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Davis, L. C. "Photoemission from transition metals and their compounds." Journal of Applied Physics 59, no. 6 (March 15, 1986): R25—R64. http://dx.doi.org/10.1063/1.336323.

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Koksharova, T. V. "ANIONS FUNCTIONS IN TRANSITION METALS COORDINATION COMPOUNDS." Odesa National University Herald. Chemistry 21, no. 1(57) (April 26, 2016): 6. http://dx.doi.org/10.18524/2304-0947.2016.1(57).67508.

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Melník, Milan, Peter Mikuš, and Clive Holloway. "Crystalographic and structural characterization of heterometallic platinum compounds. Part III: heterotrinuclear compounds." Open Chemistry 11, no. 6 (June 1, 2013): 827–900. http://dx.doi.org/10.2478/s11532-013-0226-3.

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AbstractThis review article includes over three hundred and sixty heterotrinuclear platinum complexes of the composition Pt2M (205 examples), PtM2 (132 examples) and PtMM (24 examples). The heterometals include the non-transition and transition metals. Three metal atoms form a wide variability of frameworks: M3 triangular, dicapped M3 triangular, V shaped M3, M3 linear, five-, six- and seven- metallocycles and unique structures of which triangular and linear are the most common. This has led to a rich chemistry of platinum not only from variability of metals, but also from their framework and stereochemistry. The shortest Pt-M (non-transition) and Pt-M (transition) bonds are 2.315(1) Å for Pt-Ga and 2.4896(9) Å for Pt-Co. The shortest Pt-Pt bond distance is 2.581(1) Å. Two complexes exist in two isomeric forms and several others contain crystallographically independent molecules. All are typical examples of distortion isomerism. Correlations between structural parameters, heterometal and ligand donor atoms are developed and discussed.
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Alsayeed, Raghda, Dalia Mahmood Jamil, Huda Ghalib Salman, and Mohammed H. Al-Mashhadani. "Synthesis of Novel Trimethoprim Complexes and Their Analysis by Ultraviolet Derivative Spectroscopy." Materials Science Forum 1021 (February 2021): 200–209. http://dx.doi.org/10.4028/www.scientific.net/msf.1021.200.

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In this research, the actions of antibiotic trimethoprim alone and with metals combained. Then assayed through formation of base transition metal compounds as ligands have the chance to achieve an unusual arrangement and stability complexes of coordination. We show advancement in using transtional metal compounds medications for treamentt manyl human illnesses such as carcinomas, lymphomas, control of infections, anti-inflammatory disorders, diabetes, with neurological conditions. This combination with transition metal observed the interaction can be separated by derivative spectroscopic method and measure the characterization of compound by IR and UV spectroscopy.
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Dissertations / Theses on the topic "Transition metals and their compounds"

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Sze-To, Lap, and 司徒立. "The structural chemistry of coordination compounds containing d-block or f-block metals." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45204470.

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McGilligan, Brian Stephen. "Organometallic and related compounds of transition metals." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46441.

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Berry, Adam. "Anionic polyhydride compounds of the transition metals." Thesis, University of Oxford, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.670367.

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Carson, Cantwell G. "Noble and transition metal aromatic frameworks synthesis, properties, and stability /." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29657.

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Thesis (Ph. D.)--Materials Science and Engineering, Georgia Institute of Technology, 2009.
Committee Chair: Rina Tannenbaum; Committee Co-Chair: Rosario A. Gerhardt; Committee Member: E. Kent Barefield; Committee Member: Karl I. Jacob; Committee Member: Preet Singh; Committee Member: R. Bruce King. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Collinson, J. S. "The reactions of lithium compounds with transition metals and hydrogen." Thesis, University of Nottingham, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355432.

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Ng, Yuk-wai, and 吳育煒. "Electronic transitions of transition metal monoborides." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/195989.

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Dube, Paul A. "Properties of magnetic transition metal-bromide graphite intercalation compounds /." *McMaster only, 2002.

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Haddad, Timothy Samir. "Phosphine complexes of zirconium, hafnium and the lanthanoid metals." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/31012.

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The synthesis of a variety of new lanthanoid phosphine complexes has been achieved by complexing either one or two amido-diphosphine ligands to yttrium, lutetium or lanthanum. At room temperature, the seven-coordinate bis(amido- diphosphine) complexes, MCl[N(SiMe₂CH₂PR₂)₂]₂- are fluxional and display NMR spectra indicative of complexes where the phosphorus donors are rapidly exchanging, probably via a dissociation-reassociation pathway. It is possible to generate thermally unstable hydrocarbyl complexes of the type, M(R)[N(SiMe₂CH₂PMe₂)₂]₂, which undergo a clean first order elimination of R-H to generate cyclometallated complexes of the type, M[N(SiMe₂CHPMe₂)(SiMe₂CH₂PMe₂)][N(SiMe₂CH₂PMe₂)₂]; the yttrium derivative was crystallographically characterized. These thermally robust compounds will undergo a-bond metathesis with H₂ and D₂ at high temperature, but appear to be too sterically congested to react with larger molecules. The synthesis of a series of mono(amido-diphosphine) lanthanoid complexes, MCl₂ [N(SiMe₂CH₂PR₂)₂], (R = Me, Ph, Pr', Bu[symbol omitted]) has also been achieved. Complexes of the type, MCl₂[N(SiMe₂CH₂PMe₂)₂], are insoluble in hydrocarbon solvents, presumably because they are oligomeric in nature. They will however, dissolve in THF probably forming seven-coordinate bis(THF) monomers. Attempts to alkylate these compounds generally led to decomposition; the cyclometallated bis(ligand) complex, M[N(SiMe₂CHPMe₂)(SiMe₂CH₂PMe₂)] [N(SiMe2CH2PMe2)2], was identified as the major product. A route to a dimeric mono(amido-diphosphine) allyl complex, {YCl(allyl)[N(SiMe₂CH₂PMe₂)₂]}₂ (characterized by crystallography) was found via the reaction of allyl-MgCl or Mg(allyl)₂(dioxane) with YCl[N(SiMe₂CH₂PMe₂)₂]₂. The mono(ligand) complexes containing bulky phosphine donors (R = Ph, Bu[symbol omitted], Pr[symbol omitted]) are soluble in hydrocarbon solvents; YCl₂[N(SiMe₂CH₂PPr[symbol omitted]₂)₂] can be isolated as either a THF adduct or as the base-free dimer. A new reaction, mediated by a zirconium or hafnium amido-diphosphine complex, where allyl and butadiene moieties are coupled together to generate a coordinated [ɳ⁴:ɳ¹-CH₂=CHCH=CHCH₂CH₂CH₂]¹- fragment has been investigated. The process is very sensitive to the nature of the ancillary ligands at the metal. For MCl(ɳ⁴-C₄H₆)[N(SiMe₂CH₂PR₂)₂] complexes, after the addition of allylMgCl, the transformation takes about one hour when M = Hf & R = Pr[symbol omitted], two hours when M = Zr & R = Pr[symbol omitted], a week when M = Hf & R = Me, and results only in decomposition when M = Zr & R = Me. Similarly, for the zirconium mediated coupling of 1-methylallyl with butadiene, when R = Me, decomposition occurs and when R = Pr[symbol omitted], after two hours the coupling is complete. Two of the four possible coupled products are formed in unequal amounts, and the coupling occurs exclusively at the substituted end of the 1-methylallyl unit as determined by X-ray crystallography. Which diastereomer is formed in excess was not determined. The reduction of ZrCl₃[N(SiMe₂CH₂PR₂)₂] (R = Pr[symbol omitted] or Bu[symbol omitted]) with Na/Hg amalgam under nitrogen results in the formation of a binuclear zirconium dinitrogen complex, {ZrCl[N(SiMe₂CH₂PR₂)₂]}₂ (μ-ɳ²:ɳ²-N₂). X-ray crystallography (for R = Pr[symbol omitted]) reveals that the N₂ ligand is symmetrically bound in a side-on fashion to both metals. In addition, the N—N bond length of 1.548 (7) Å, the longest bond length ever reported for a dinitrogen complex, indicates that the dinitrogen has been reduced to a N₂⁴⁻ hydrazido ligand. Protonation of the complex with HCl results in a quantitative formation of hydrazine.
Science, Faculty of
Chemistry, Department of
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Thu, Hung-yat. "Catalytic C-H bond functionalization reactions catalyzed by rhodium(III) porphyrin, palladium(II) and platinum(II) acetate complexes." View the Table of Contents & Abstract, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38027872.

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Lock, Philippa Edlyne. "The structures and dynamics of organometallic-arene complexes and bimetallic clusters /." *McMaster only, 2001.

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Books on the topic "Transition metals and their compounds"

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d-block chemistry. Oxford: Oxford University Press, 1994.

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Jones, Chris J. D- and f-block chemistry. New York: J. Wiley, 2002.

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Chemistry of the transition metals. 5th ed. Hoboken, N.J: Wiley, 2009.

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Crabtree, Robert H. The organometallic chemistry of the transition metals. 2nd ed. New York: Wiley, 1994.

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The organometallic chemistry of the transition metals. 4th ed. Hoboken, N.J: John Wiley, 2005.

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Crabtree, Robert H. The organometallic chemistry of the transition metals. 3rd ed. New York: John Wiley, 2001.

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The organometallic chemistry of the transition metals. New York: Wiley, 1988.

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Crabtree, Robert H. Organometallic chemistry of the transition metals. Chichester: Wiley, 1992.

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Transition metals in the synthesis of complex organic molecules. Mill Valley, Calif: University Science Books, 1994.

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G, Söderberg Björn C., ed. Transition metals in the synthesis of complex organic molecules. 3rd ed. Sausalito, Calif: University Science Books, 2009.

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Book chapters on the topic "Transition metals and their compounds"

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Economou, Eleftherios N. "Transition Metals and Compounds." In The Physics of Solids, 409–36. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02069-8_15.

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Lerf, A. "Unsolvated Metal Intercalation Compounds: Transition Metals." In Inorganic Reactions and Methods, 276. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145203.ch169.

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Johnson, B. F. G., and J. A. Mccleverty. "Nitric Oxide Compounds of Transition Metals." In Progress in Inorganic Chemistry, 277–359. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166086.ch5.

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Ferguson, G. "Transition-metal Compounds." In Structure Reports, 904–1686. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-017-3154-6_3.

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Sarma, D. D., and S. R. Barman. "Electronic Structure of Transition Metal Compounds." In Spectroscopy of Mott Insulators and Correlated Metals, 126–38. Berlin, Heidelberg: Springer Berlin Heidelberg, 1995. http://dx.doi.org/10.1007/978-3-642-57834-2_11.

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Peacock, R. D. "Some Fluorine Compounds of the Transition Metals." In Progress in Inorganic Chemistry, 193–249. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166031.ch4.

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Maire, Jean-Claude, Ulrich Krüerke, Marlis Mirbach, Wolfgang Petz, and Christa Siebert. "Organogallium-Transition Metal Compounds." In Ga Organogallium Compounds, 308–12. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-662-07374-2_12.

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Weidlein, Johann. "Organoindium-Transition Metal Compounds." In In Organoindium Compounds, 329–36. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_10.

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Romańczyk, Piotr P., and Stefan S. Kurek. "Molecular Electrochemistry of Coordination Compounds—A Correlation Between Quantum Chemical Calculations and Experiment." In Transition Metals in Coordination Environments, 409–38. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-11714-6_13.

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King, R. B. "Transition Metal Cluster Compounds." In Progress in Inorganic Chemistry, 287–473. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166161.ch4.

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Conference papers on the topic "Transition metals and their compounds"

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Bahador, S. K. "Transition metal chalcogenides and Lamellar compounds: their science & technology 36 - electrocatalysis by mocl compounds in energy conversion & storage systems." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835907.

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Stoyanova, A., C. de Graaf, R. Broer, Theodore E. Simos, and George Maroulis. "Many-Electron Bands in Transition Metal Compounds." In COMPUTATIONAL METHODS IN SCIENCE AND ENGINEERING: Theory and Computation: Old Problems and New Challenges. Lectures Presented at the International Conference on Computational Methods in Science and Engineering 2007 (ICCMSE 2007): VOLUME 1. AIP, 2007. http://dx.doi.org/10.1063/1.2836029.

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Soni, Shubhangi, Netram Kaurav, A. Jain, S. Shah, and K. K. Choudhary. "Pressure induced structural phase transition in IB transition metal nitrides compounds." In NANOFORUM 2014. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4917593.

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REDDY, B. V. "MAGNETISM OF TRANSITION METAL CLUSTERS AND THEIR COMPOUNDS." In Proceedings of the International Symposium. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812793805_0017.

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Lekishvili, N., Kh Barbakadze, W. Brostow, T. Datashvili, A. Fainleib, and O. Grigorieva. "Inorganic-organic hybrid antibiocorrosive covers based on polyurethanes and coordination compounds of some transition metals." In 6TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS (TOP) AND COMPOSITES. AIP, 2012. http://dx.doi.org/10.1063/1.4738469.

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de Groot, Frank. "X-ray absorption and dichroism of transition metal compounds." In X-RAY AND INNER-SHELL PROCESSES. ASCE, 1997. http://dx.doi.org/10.1063/1.52258.

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Burzo, E. "Induced transition metal moments in rare-earth (yttrium) compounds." In SIXTH INTERNATIONAL CONFERENCE OF THE BALKAN PHYSICAL UNION. AIP, 2007. http://dx.doi.org/10.1063/1.2733125.

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Burzo, Emil. "Exchange enhanced paramagnetism of rare-earth (yttrium)-transition metal compounds." In TIM14 PHYSICS CONFERENCE - PHYSICS WITHOUT FRONTIERS. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4937245.

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Ivashchenko, V. I., and N. R. Mediukh. "Ab-initio Study of the Heterostructures Based on Transition Metal Compounds." In 2018 IEEE 8th International Conference Nanomaterials: Application & Properties (NAP). IEEE, 2018. http://dx.doi.org/10.1109/nap.2018.8915052.

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Burzo, Emil, Madalin Bunoiu, and Iosif Malaescu. "Exchange Interactions and Magnetocaloric Effects in Rare-Earth-Transition Metal Compounds." In PROCEEDINGS OF THE PHYSICS CONFERENCE: TIM—08. AIP, 2009. http://dx.doi.org/10.1063/1.3153458.

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Reports on the topic "Transition metals and their compounds"

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Jimenez, J., D. L. Ederer, and T. Shu. Raman scattering in transition metal compounds: Titanium and compounds of titanium. Office of Scientific and Technical Information (OSTI), April 1997. http://dx.doi.org/10.2172/603585.

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Rothwell, I. P. Catalytic arene hydrogenation using early transition metal hydride compounds. Office of Scientific and Technical Information (OSTI), March 1993. http://dx.doi.org/10.2172/6443562.

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Vasbinder, Michael John. Oxidations of Organic and Inorganic Substrates by Superoxo-, hydroperoxo-, and oxo-compounds of the transition metals. Office of Scientific and Technical Information (OSTI), January 2006. http://dx.doi.org/10.2172/897378.

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Doerrer, Linda H. Development of Earth-Abundant Transition Metal Compounds for Water Oxidation. Office of Scientific and Technical Information (OSTI), January 2019. http://dx.doi.org/10.2172/1489778.

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Adams, R. The transformation of organic amines by transition metal cluster compounds. Office of Scientific and Technical Information (OSTI), February 1990. http://dx.doi.org/10.2172/7108222.

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Rothwell, I. P. Catalytic arene hydrogenation using early transition metal hydride compounds. Progress report. Office of Scientific and Technical Information (OSTI), March 1993. http://dx.doi.org/10.2172/10159596.

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Dunkerton, L., C. Hinckley, J. Tyrrell, and P. Robinson. Interactions of sulfur-containing compounds with transition metal clusters and metal surfaces III. Office of Scientific and Technical Information (OSTI), January 1989. http://dx.doi.org/10.2172/7019171.

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Adams, R. D. The transformation of organic amines by transition metal cluster compounds: Progress report. Office of Scientific and Technical Information (OSTI), November 1994. http://dx.doi.org/10.2172/10105409.

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Yang, Ning. Synchrotron Diffraction Studies of Spontaneous Magnetostriction in Rare Earth Transition Metal Compounds. Office of Scientific and Technical Information (OSTI), December 2004. http://dx.doi.org/10.2172/835381.

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Steimle, T. C. Generation, detection and characterization of gas-phase transition metal aggregates and compounds. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/7276622.

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