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Journal articles on the topic 'Trimethylphenol'

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1

Nazarova, M., and I. Mammadzadeh. "SYNTHESIS OF TRIMETHYLPHENOLS IN THE CATALYTIC ALKYLATION OF XYLENOL AND METHANOL AND APPLICATION IN THE PRODUCTION OF VITAMIN E (TOCOPHEROL)." Slovak international scientific journal, no. 92 (February 14, 2025): 4–6. https://doi.org/10.5281/zenodo.14869675.

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In this article, the alkylation reactions of 2,6-, 2,5- and 2,3-dimethylphenols in the presence of methanol and CrCaY zeolite were investigated. The experiments were carried out at a temperature of 360°C and a volume flow rate of 0.82 st·¹. The results show that, regardless of the catalyst composition, the main conversion product of 2,6-dimethylphenol is 2,4,6-trimethylphenol. In the presence of CrCaY zeolite, 2,3,6-trimethylphenol is also formed with some selectivity. The potential application of trimethylphenols obtained in the alkylation process in the synthesis of tocophero
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2

Ziemer, Burkhard, and Oxana Surygina. "2,4,6-Trimethylphenol." Acta Crystallographica Section C Crystal Structure Communications 56, no. 11 (2000): e528-e528. http://dx.doi.org/10.1107/s0108270100013524.

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3

Gordon, JLM, MP Hartshorn, RJ Martyn, AJ Morgan, WT Robinson, and GJ Wright. "The Chlorination of Some Substituted 2,4-Dimethylphenols." Australian Journal of Chemistry 47, no. 2 (1994): 289. http://dx.doi.org/10.1071/ch9940289.

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Chlorination reactions of 2-chloro-3,4,6-trimethylphenol (4), 2-chloro-4,6-dimethylphenol (5) and 3-chloro-2,4,6-trimethylphenol (6) are described. In acetic acid or acetic anhydride solution, chlorinations yield predominantly the corresponding 4-chlorocyclohexa-2,5-dienones (8), (17a) and (29), but in carbon tetrachloride containing pyridine products are formed which result from the modification of the 4-methyl group in each substrate. X-Ray crystal structure analyses are reported for compounds (7), (14), (28) and (31).
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4

Hartshorn, MP, KA Hayman, RJ Martyn, et al. "The Chlorination of 4-Chloro-2,3,6-trimethylphenol. Some Addition-Reactions of 4,6-Dichlorocyclohexa-2,4-dienones." Australian Journal of Chemistry 43, no. 10 (1990): 1729. http://dx.doi.org/10.1071/ch9901729.

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Reaction of a mixture of 6-chlorocyclohexa-2,4-dienones (4) and (5) with chlorine in acetic acid gives the tetrachloro ketones (2) and (3), the major products of chlorination of 2,3,6-trimethylphenol (1a) or 4-chloro-2,3,6-trimethylphenol (1b). Reactions of this mixture of 6- chlorocyclohexa-2,4-dienones (4) and (5) in acetic acid with chlorine acetate, chlorine, chlorine in the presence of sodium acetate, and in benzene with nitrogen dioxide are described. -Ray crystal structure determinations are reported for compounds (3), (6)-(8) and (11)-(13).
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5

Гребенникова, Ольга Валентиновна, Александрина Михайловна Сульман, Степан Петрович Михайлов, Елена Игоревна Шиманская, and Валентина Геннадьевна Матвеева. "OXIDATION OF ORGANIC COMPOUNDS BY MAGNETIC BIOCATALYST." Вестник Тверского государственного университета. Серия: Химия, no. 1(39) (March 19, 2020): 31–39. http://dx.doi.org/10.26456/vtchem2020.1.4.

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В статье описывается синтез магнитного биокатализатора на основе иммобилизованной пероксидазы. Данный биокатализатор тестировался в реакции окисления 2,3,6-триметилфенола с помощью пероксида водорода до 2,3,5-триметилгидрохинона (полупродукта витамина Е). В работе выбран метод синтеза магнитных наночастиц. Подобраны оптимальные условия проведения процесса окисления 2,3,6-триметилфенола в присутствии магнитного биокатализатора (начальная концентрация субстрата, температура, рН). The article describes the synthesis of a magnetic biocatalyst based on immobilized peroxidase. This biocatalyst was t
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6

Гребенникова, Ольга Валентиновна, Александрина Михайловна Сульман, Владимир Петрович Молчанов, Елена Михайловна Михайлова, Ирина Павловна Шкилева, and Валентина Геннадьевна Матвеева. "STUDY OF THE KINETICS OF ENZYMATIC OXIDATION OF 2,3,6-TRIMETHYLPHENOL IN THE PRESENCE OF IMMOBILIZED PEROXIDASE." Вестник Тверского государственного университета. Серия: Химия, no. 4(42) (December 21, 2020): 7–15. http://dx.doi.org/10.26456/vtchem2020.4.1.

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В работе изучался процесс окисления 2,3,6-триметилфенола в присутствии иммобилизованной пероксидазы корня хрена. В результате такого окисления был получен полупродукт витамина Е (2,3,5-триметилгидрохинон). Иммобилизация фермента проводилась на магнитные наночастицы, на SiO и AlO. Все исследованные биокатализаторы показали стабильную работу в процессе окисления 2,3,6-триметилфенола с помощью пероксида водорода. Таким образом, синтезированные биокаталитические ферментные системы могут успешно применяться в качестве альтернативных катализаторов окисления замещенных фенолов с целью получения биоло
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7

Saux, Clara, Luis R. Pizzio, and Liliana B. Pierella. "2,3,5-Trimethylphenol oxidation over Co-based solid catalysts." Applied Catalysis A: General 452 (February 2013): 17–23. http://dx.doi.org/10.1016/j.apcata.2012.11.037.

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8

Li, Kuo-Tseng, and Pang-Yih Liu. "Oxidation of 2,4,6-trimethylphenol using iron-based catalysts." Applied Catalysis A: General 272, no. 1-2 (2004): 167–74. http://dx.doi.org/10.1016/j.apcata.2004.05.038.

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9

Shen, Yu, Fumin Wang, Chaoqun Yang, and Xubin Zhang. "Synthesis and Characterisation of Hierarchically Porous HZSM-5 as Catalysts for the Synthesis of 2,3,5-Trimethyl-1,4-benzoquinone." Australian Journal of Chemistry 70, no. 6 (2017): 691. http://dx.doi.org/10.1071/ch16392.

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Hierarchical HZSM-5 were synthesised by controlled desilication in alkaline medium and characterised by field-emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy, inductively coupled plasma–atomic emission spectrometry, N2 adsorption–desorption, and Fourier transform infrared spectroscopy. The catalytic performance of HZSM-5 towards the selective oxidation of 2,3,6-trimethylphenol by H2O2 was evaluated. Recyclability tests were also carried out. The results showed that 2,3,5-trimethyl-1,4-benzoquinone was produced in high yields (i.e. 90 %), corresponding
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10

Chambers, MV, MP Hartshorn, WT Robinson, and J. Vaughan. "The Nitration of 2,3,4-Tribromo-5,6-dimethylphenol and 3,4-Dibromo-2,5,6-trimethylphenol." Australian Journal of Chemistry 38, no. 1 (1985): 133. http://dx.doi.org/10.1071/ch9850133.

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The nitrations of 2,3,4-tribromo-5,6-dimethylphenol (9) and 3,4- dibromo-2,5,6-trimethylphenol (10) with fuming nitric acid in acetic acid give 2,5,6-trinitrocyclohex-3-enones in addition to 6-hydroxy-2,5-dinitrocyclohex-3-enones. X-ray crystal structure determinations are reported for the trinitro ketones (21) and (22), and the hydroxy dinitro ketones (23) and (24).
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11

Oyaizu, Kenichi, Kei Saito, and Eishun Tsuchida. "Copper-Catalyzed Oxidative Coupling of 2,4,6-Trimethylphenol with Oxygen." Chemistry Letters 29, no. 11 (2000): 1318–19. http://dx.doi.org/10.1246/cl.2000.1318.

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12

Demidova, Ekaterina I., Serafima A. Znoyko, Evgeny E. Molchanov, Vladimir E. Maizlish, and Oleg A. Petrov. "SYNTHESIS AND SPECTRAL PROPERTIES OF PHTHALOCYANINES WITH 2,3,5-TRIMETHYLPHENOXY AND NITRO GROUPS." ChemChemTech 68, no. 2 (2024): 52–61. https://doi.org/10.6060/ivkkt.20256802.7160.

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Phthalonitrile containing a 2,3,5-trimethylphenol fragment and a nitro group at the periphery was synthesized on the basis of 4-bromo-5-nitrophthalonitrile. Tetrakis-2,9,16,24-(2,3,5-trimethylphenoxy)tetrakis-3,10,17,25-nitrophthalocyanine and its metallocomplexes with zinc and magnesium were synthesized on its basis by the "nitrile" method. The latter was used to obtain the corresponding phthalocyanine - ligand. All synthesized compounds were characterized by differential scanning calorimetry, elemental analysis, 1H NMR, infrared spectroscopy and MALDI-TOF spectrometry. Spectral-luminescent p
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13

İşci, Ümit, Ayşe Gül Gürek, Vefa Ahsen, and Alexander B. Sorokin. "Preparation of iron phthalocyanine complex bearing four tetraazamacrocycles as a precursor for oxidation catalyst with two catalytic sites." Journal of Porphyrins and Phthalocyanines 13, no. 06 (2009): 747–52. http://dx.doi.org/10.1142/s1088424609000851.

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The synthesis of the iron phthalocyanine bearing four fused tetraazamacrocycles starting from N,N',N″,N‴-tetrakis(p-tolylsulfonyl)triethylenetetraamine and 1,2-dibromo-4,5-bis(bromomethyl)benzene is reported. The exchange of protecting tosyl groups by acetyl groups was necessary to obtain iron phthalocyanine. The efficiency of iron phthalocyanine as oxidation catalyst was tested for the practically important oxidation of 2,3,6-trimethylphenol (TMP) at different reaction conditions.
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14

Latos, Piotr, Agnieszka Siewniak, Natalia Barteczko, Sebastian Jurczyk, Sławomir Boncel, and Anna Chrobok. "Highly Active Trifloaluminate Ionic Liquids as Recyclable Catalysts for Green Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-Benzoquinone." Catalysts 10, no. 12 (2020): 1469. http://dx.doi.org/10.3390/catal10121469.

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An effective method for the synthesis of 2,3,6-trimethyl-1,4-benzoquinone via the oxidation of 2,3,6-trimethylphenol as the key step in the in the preparation of vitamin E was presented. An aqueous solution of H2O2 was used as the oxidant and Lewis acidic trifloaluminate ionic liquids [emim][OTf]-Al(OTf)3, χAl(OTf)3 = 0.25 or 0.15 as catalysts. Trifloaluminate ionic liquids were synthesised by the simple reaction between 1-ethyl-3-methylimidazolium trifluoromethanesulfonate (triflate) [emim][OTf] and aluminium triflate used in sub-stoichiometric quantities. The influence of the reaction parame
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15

Roslan, Nurliana, Salasiah Endud, Zainab Ramli, and Hendrik Oktendy Lintang. "Copper(II) Porphyrin as Biomimetic Catalyst for Oxidation of Trimethylphenol." Materials Science Forum 846 (March 2016): 706–11. http://dx.doi.org/10.4028/www.scientific.net/msf.846.706.

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Synthetic metalloporphyrins have long been recognized either as functional models or mimics of the cytochrome P-450 enzymes and they are versatile compounds with potential use in drug delivery, catalysis and electronics. In the present study, the metalloporphyrin, (meso-tetra-(p-sulfonatophenyl)-porphyrinato)copper, CuTSPP was synthesized in the reaction between free-base porphyrin, meso-tetra (p-sulfonatophenyl)porphyrin, H2TSPP and copper(II) acetate monohydrate. The materials were characterized using Fourier Transform Infrared Spectroscopy (FTIR), Ultraviolet-Visible (UV-Vis) Spectroscopy,
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16

Li, Meng, Mingwei Wu, Biwei Pan, et al. "Aerobic Oxidation of 2,3,6-Trimethylphenol with Reusable Homogenized Copper Catalysts." Chemical Research in Chinese Universities 37, no. 3 (2021): 751–56. http://dx.doi.org/10.1007/s40242-021-0025-x.

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17

Aguer, Jean-Pierre, Daté Tétégan, and Claire Richard. "Humic substances mediated phototransformation of 2,4,6-trimethylphenol: a catalytic reaction." Photochemical & Photobiological Sciences 4, no. 6 (2005): 451. http://dx.doi.org/10.1039/b416925e.

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18

Arvin, Erik, Bjørn K. Jensen, and Anders Torp Gundersen. "Biodegradation Kinetics of Phenols in an Aerobic Biofilm at Low Concentrations." Water Science and Technology 23, no. 7-9 (1991): 1375–84. http://dx.doi.org/10.2166/wst.1991.0590.

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Aerobic biodegradation of the phenols: phenol, 2-methylphenol, 4-methylphenol, 2,4-dimethylphenol, 3,5-dimethylphenol and 2,4,6-trimethylphenol was studied in a biofilm reactor to establish kinetic constants under conditions where the phenols were the sole carbon sources. Phenol concentrations were very low, in the µg/l concentration range. 2,4,6-trimethylphenol was not degraded. The degradation of the other phenols was 1'st order at concentrations in the bulk phase below 20-50 µg/l. Zero order reaction seemed to govern the reaction above 200 µg/l. The l'st order rate constants are 3-30 times
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19

Гребенникова, Ольга Валентиновна. "KINETIC PARAMETERS OF THE ENZYMATIC REACTION OF OXIDATION OF 2,3,6-TRIMETHYLPHENOL." Вестник Тверского государственного университета. Серия: Химия, no. 3(41) (November 10, 2020): 23–28. http://dx.doi.org/10.26456/vtchem2020.3.3.

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В работе приводится расчет кинетических параметров V и K для реакции окисления 2,3,6-триметилфенола пероксидом водорода в присутствии нативной и иммобилизованной пероксидазы корня хрена. Иммобилизация пероксидазы осуществлялась на магнитные наночастицы FeO и неорганические носители SiO, AlO. Образцы SiO и AlO были предварительно модифицированы и активированы, с помощью хитозана и глутарового альдегида, соответственно. Магнитные наночастицы предварительно обрабатывались 3-аминопропилтриэтоксисиланом для обеспечения поверхности носителя необходимыми для ковалентной иммобилизации функциональными
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20

Hartshorn, MP, JA Kennedy, RW Simpson, J. Vaughan, and GJ Wright. "Some Rearrangements of 2,4,6-Tri-t-butyl-4-nitrocyclohexa-2,5-dienone." Australian Journal of Chemistry 38, no. 5 (1985): 735. http://dx.doi.org/10.1071/ch9850735.

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Rearrangement of 2,4,6-tri-t-butyl-4-nitrocyclohexa-2,5-den (20) in benzene gives the 4-hydroxy dienone (21) and the mono-de-t- butylated 1,2-benzoquinone (22). The rearrangement is not affected by the addition of mesitylene , but the phenol-coupling product (26) is formed in the presence of p-cresol, and the nitromethyl phenol (31) is formed when the nitro dienone (20) rearranges in the presence of 2,4,6- trimethylphenol (29). The rearrangements of the nitro dienone (20) in methanol are described.
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21

张, 合. "Co(Salphen) Linear Polymer for Catalyzing the Oxidation Of 2,3,6-Trimethylphenol." Studies in Synthetic Chemistry 07, no. 02 (2019): 11–17. http://dx.doi.org/10.12677/ssc.2019.72003.

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22

Aguer, Jean-Pierre, Gilles Mailhot, and Michèle Bolte. "Unexpected 2,4,6-trimethylphenol oxidation in the presence of Fe(iii) aquacomplexes." New J. Chem. 30, no. 2 (2006): 191–96. http://dx.doi.org/10.1039/b514691g.

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23

Li, Kuo-Tseng, and Pang-Yih Liu. "2,4,6-Trimethylphenol oxidation with ferrous chloride catalyst: Effect of acetoxime addition." Journal of Molecular Catalysis A: Chemical 241, no. 1-2 (2005): 72–78. http://dx.doi.org/10.1016/j.molcata.2005.06.062.

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24

Bushmelev, V. A., T. A. Kondrat'eva, M. A. Lipkin, and A. V. Kondrat'ev. "Methods for the preparation of 2,3,5-trimethylhydroquinone from 2,4,6-trimethylphenol (review)." Pharmaceutical Chemistry Journal 25, no. 5 (1991): 340–49. http://dx.doi.org/10.1007/bf00772128.

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25

Kawaguchi, Hideki. "Rates of sensitized photo-oxidation of 2,4,6-trimethylphenol by humic acid." Chemosphere 27, no. 11 (1993): 2177–82. http://dx.doi.org/10.1016/0045-6535(93)90130-w.

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26

Kholdeeva, O. A., A. V. Golovin, and I. V. Kozhevnikov. "Oxidation of 2,3,6-trimethylphenol in the presence of phosphomolybdovanadium heteropoly acids." Reaction Kinetics & Catalysis Letters 46, no. 1 (1992): 107–13. http://dx.doi.org/10.1007/bf02096685.

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27

Kholdeeva, O. A., A. V. Golovin, R. I. Maksimovskaya, and I. V. Kozhevnikov. "Oxidation of 2,3,6-trimethylphenol in the presence of molybdovanadophosphoric heteropoly acids." Journal of Molecular Catalysis 75, no. 3 (1992): 235–44. http://dx.doi.org/10.1016/0304-5102(92)80128-4.

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28

MCKECHNIE, M., D. C. NONHEBEL, and I. SCULLION. "ChemInform Abstract: Oxidative Coupling of 2,4,6-Trimethylphenol with Fenton′s Reagent." ChemInform 24, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.199349149.

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29

Oyaizu, Kenichi, Kei Saito, and Eishun Tsuchida. "ChemInform Abstract: Copper-Catalyzed Oxidative Coupling of 2,4,6-Trimethylphenol with Oxygen." ChemInform 32, no. 13 (2001): no. http://dx.doi.org/10.1002/chin.200113065.

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30

Jansen, R. J. J., H. M. van Veldhuizen, and H. van Bekkum. "Heteropoly anion on carbon: characterization and use in 2,3,6-trimethylphenol oxidation." Journal of Molecular Catalysis A: Chemical 107, no. 1-3 (1996): 241–46. http://dx.doi.org/10.1016/1381-1169(95)00173-5.

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31

Hartshorn, MP, MC Judd, RW Vannoort, and GJ Wright. "The Nitration of 4-Methylphenol, 3,4-Dimethylphenol and 3,4,5-Trimethylphenol With Nitrogen Dioxide." Australian Journal of Chemistry 42, no. 5 (1989): 689. http://dx.doi.org/10.1071/ch9890689.

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Reaction of 4-methylphenol (la) with excess nitrogen dioxide in either benzene or dichloromethane gives the 4-nitro dienone (2a) and the 2,6-dinitrophenol (5). Similar reactions of 3,4-dimethylphenol (Ib) yields the 4-nitro dienone (2b), the 2,6-dinitrophenol (8) and the 4-hydroxy 2,6-dinitro dienone (9), while reaction of 3,4,5-trimethylphenol (1c) gives the 4-nitro dienone (2c), the 2,4-dinitro dienone (11) and the 2,4,6-trinitro dienone (12a). The reaction pathways by which these products are formed are described and the results of reactions of postulated intermediates with nitrogen dioxide
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32

Гребенникова, Ольга Валентиновна, Александрина Михайловна Сульман, Елена Игоревна Шиманская, and Анастасия Евгеньевна Филатова. "SYNTHESIS OF BIOCATALYTIC SYSTEMS USING HORSERADISE ROOT PEROXIDASE." Вестник Тверского государственного университета. Серия: Химия, no. 2(48) (July 7, 2022): 7–15. http://dx.doi.org/10.26456/vtchem2022.2.1.

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В статье описываются несколько способов синтеза биокатализаторов на основе пероксидазы корня хрена (К.Ф. 1.11.1.7), иммобилизованной на различные носители (магнитные наночастицы FeO, SiO, AlO, сверхсшитый полистирол марки MN-100 и Sepabeads EC-HA). Полученные биокаталитические системы могут применяться для экологически безопасного синтеза полупродукта витамина Е - 2,3,5триметилгидрохинона с помощью окисления 2,3,6-триметилфенола пероксидом водорода. В работе использовался ковалентный метод иммобилизации ферментов. В качестве модифицирующего агента использовался хитозан, для активации ферментно
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33

MANGEMATIN, S., and A. B. SOROKIN. "Synthesis and catalytic properties of a novel phthalocyanine covalently grafted onto silica." Journal of Porphyrins and Phthalocyanines 05, no. 09 (2001): 674–80. http://dx.doi.org/10.1002/jpp.379.

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The iron complex of 2(3),9(10),16(17),23(24)-tetra[1,5-di(3-triethoxysilyl-propyl)biuryl]phthalocyanine (1) was prepared by reacting iron tetraaminophthalocyanine with 3-(triethoxysilyl)propyl isocyanate. This complex was directly grafted onto silica to give a supported catalyst without preliminary modification of silica support. This supported catalyst was successfully applied in clean catalytic oxidations by using molecular oxygen in combination with isobutyraldehyde. Cyclooctene, cyclohexene and styrene were oxidized to corresponding epoxides with 90, 78 and 74% yields, respectively. 2,3,6-
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34

Matveeva, O. V., N. V. Lakina, V. Yu Doluda, I. P. Shkileva, V. G. Matveeva, and E. M. Sulman. "Effect of peroxidase immobilization on the activity of biocatalysts in trimethylphenol oxidation." Catalysis in Industry 7, no. 2 (2015): 161–69. http://dx.doi.org/10.1134/s2070050415020063.

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35

Larson, S. B., S. H. Simonsen, G. E. Martin, S. Puig-Torres, and K. Smith. "Structure of 2-(2-chloro-3-pyridylthio)-3,5,6-trimethylphenol at 163 K." Acta Crystallographica Section C Crystal Structure Communications 42, no. 6 (1986): 766–68. http://dx.doi.org/10.1107/s0108270186094611.

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36

Kouras-Hadef, Sofia, Amina Amine-Khodja, Sabrina Halladja, and Claire Richard. "Influence of humic substances on the riboflavin photosensitized transformation of 2,4,6-trimethylphenol." Journal of Photochemistry and Photobiology A: Chemistry 229, no. 1 (2012): 33–38. http://dx.doi.org/10.1016/j.jphotochem.2011.12.011.

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37

Matveeva, O., N. Lakina, V. Matveeva, et al. "Biocatalitic Oxidation of 2,3,6-Trimethylphenol Over Immobilized Horseradish Peroxidase in Nonaqueous Media." Topics in Catalysis 54, no. 16-18 (2011): 1309–17. http://dx.doi.org/10.1007/s11244-011-9753-3.

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38

Pei, Dan-Yu, Meng-Jun Su, Yue-Yan Wang, Guang-Wen Chu, Yong Luo, and Jian-Feng Chen. "Process intensification of 2,3,6-trimethylphenol oxidation in a rotating packed bed reactor." Chemical Engineering and Processing - Process Intensification 149 (March 2020): 107842. http://dx.doi.org/10.1016/j.cep.2020.107842.

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39

BUSHMELEV, V. A., T. A. KONDRAT'EVA, M. A. LIPKIN, and A. V. KONDRAT'EV. "ChemInform Abstract: Methods for the Synthesis of 2,3,5-Trimethylhydroquinone from 2,4,6- Trimethylphenol." ChemInform 23, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199239324.

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40

Calvert, JL, MP Hartshorn, WT Robinson, and GJ Wright. "Nitration of 4-Chloro-2,3,6-trimethylphenol, 3-Chloro-2,4,6-trimethylphenol and 2,3,4,6-Tetramethylphenol; 15N-Labeling Studies in the Reaction of 2,3,4,6-Tetramethyl-4-nitrocyclohexa-2,5-dienone With Nitrogen Dioxide." Australian Journal of Chemistry 46, no. 11 (1993): 1629. http://dx.doi.org/10.1071/ch9931629.

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The effects of C3 and C4 substituents (Cl, Me) on the reactions of 2,6-dimethylphenols (10)-(12) with nitrogen dioxide in benzene have been examined. In the course of this work X-ray crystal analyses are reported for 14 compounds (13)-(16), (19), (21), (32), (34), (36) and (38)-(42). A 15N-labelling study of the reaction of 2,3,4,6-tetramethyl-4-nitrocyclohexa-2,5-dienone (37) with nitrogen dioxide in benzene is reported.
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41

Rodikova, Yu A., and E. G. Zhizhina. "Homogeneous Catalysts Based on Heteropoly Acid Solutions for Redox Processes. III. Development of an Effective Method for Synthesis of 2,3,5-trimethyl-1,4-benzoquinone." Kataliz v promyshlennosti 19, no. 1 (2019): 19–32. http://dx.doi.org/10.18412/1816-0387-2019-1-19-32.

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Various methods for preparation of 2,3,5-trimethyl-1,4-benzoquinone (TMQ) – the key semiproduct for synthesis of vitamin E – through catalytic oxidation of 2,3,6-trimethylphenol (TMP) are considered. Potentials of aqueous solutions of Mo-V-P heteropoly acids (HPA) as catalysts for oxidation of TMP with oxygen are shown. Various technological modes of application of HPA for the said reaction are analyzed, among which are a one-stage homogeneous acetic acid oxidation of TMP and a two-phase two-stage method. The efficiency of the two-stage method is demonstrated; it provides a high (up to 99.5 %)
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42

Yang, Yin, Marie-José Battesti, Jean Costa, and Julien Paolini. "Melissopalynological and Volatile Analysis of Honeys from Corsican Arbutus unedo Habitat." Natural Product Communications 9, no. 10 (2014): 1934578X1400901. http://dx.doi.org/10.1177/1934578x1400901030.

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Thirty Corsican “autumn maquis” honeys were characterized by the typical combination of autumnal taxa: Arbutus unedo, Hedera helix, Smilax aspera, Rosmarinus officinalis, and two Asteraceae pollen forms. Corsican origin was characterized by the diversity of the taxa's biogeographical origins and significant presence of Castanea sativa and Quercus sp. Volatile fractions of “autumn maquis” honeys were dominated by isophorone and 3,4,5-trimethylphenol. The latter is reported in A. unedo honey for the first time. Otherwise, both A. unedo flower and “autumn maquis” honeys exhibited high contents of
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43

Li, Ying, Wei Liu, Mingzhu Wu, Zhongzhou Yi, and Jucheng Zhang. "Selective photoinduced oxidation of 2,3,5-trimethylphenol to 2,3,5-trimethylbenzoquinone catalyzed by hypocrellins/CuCo2O4." Mendeleev Communications 20, no. 4 (2010): 218–19. http://dx.doi.org/10.1016/j.mencom.2010.06.012.

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44

Grebennikova, Olga, Aleksandrina Sulman, Valentina Matveeva, and Ester Sulman. "Physical–chemical analysis and kinetics of the magnetic biocatalyst for 2,3,6,-trimethylphenol oxidation." Reaction Kinetics, Mechanisms and Catalysis 130, no. 1 (2020): 317–29. http://dx.doi.org/10.1007/s11144-020-01762-3.

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45

Bodnar, Z., T. Mallat, and A. Baiker. "Oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone with catalytic amount of CuCl2." Journal of Molecular Catalysis A: Chemical 110, no. 1 (1996): 55–63. http://dx.doi.org/10.1016/1381-1169(96)00042-8.

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46

Sadikova, Larisa M., Yulia M. Sadykova, Alena V. Zalaltdinova, et al. "The reactions of 2-ethoxyvinyldichlorophosphonate with 4-chloro- or 4-bromoresorcinols and 2,3,5-trimethylphenol." Phosphorus, Sulfur, and Silicon and the Related Elements 191, no. 11-12 (2016): 1562–63. http://dx.doi.org/10.1080/10426507.2016.1213260.

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47

Meng, Xiangju, Zhenhua Sun, Sen Lin, et al. "Catalytic hydroxylation of 2,3,6-trimethylphenol with hydrogen peroxide over copper hydroxyphosphate (Cu2(OH)PO4)." Applied Catalysis A: General 236, no. 1-2 (2002): 17–22. http://dx.doi.org/10.1016/s0926-860x(02)00282-x.

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48

Paluch, M. "Surface mixed adsorption films of 2,4,6- trimethylphenol-2,4,6-trichlorophenol at aqueous solution/air interface." Colloid & Polymer Science 276, no. 7 (1998): 648–52. http://dx.doi.org/10.1007/s003960050293.

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49

Sadykova, Yulia M., Larisa M. Sadikova, Alina R. Badrtdinova, Alexey B. Dobrynin, Alexander R. Burilov, and Michael A. Pudovik. "Condensation of 2-Ethoxyvinylphosphonic Acid Dichloroanhydride with 2,3,5-Trimethylphenol. Novel Method for Preparation of Phosphacoumarins." Phosphorus, Sulfur, and Silicon and the Related Elements 190, no. 12 (2015): 2267–72. http://dx.doi.org/10.1080/10426507.2015.1073283.

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50

Ma, He, Xiu-Qin Hu, Yong-Chun Luo, and Peng-Fei Xu. "3,4,5-Trimethylphenol and Lewis Acid Dual-Catalyzed Cascade Ring-Opening/Cyclization: Direct Synthesis of Naphthalenes." Organic Letters 19, no. 24 (2017): 6666–69. http://dx.doi.org/10.1021/acs.orglett.7b03392.

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